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Article

Radiolabeling of Micro-/Nanoplastics via In-Diffusion

1
Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Research Site Leipzig, Permoserstr. 15, 04318 Leipzig, Germany
2
Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Bautzner Landstraße 400, 03148 Dresden, Germany
*
Author to whom correspondence should be addressed.
Nanomaterials 2023, 13(19), 2687; https://doi.org/10.3390/nano13192687
Submission received: 11 September 2023 / Revised: 25 September 2023 / Accepted: 26 September 2023 / Published: 30 September 2023
(This article belongs to the Section Environmental Nanoscience and Nanotechnology)

Abstract

Micro- and nanoplastics are emerging pollutants with a concerning persistence in the environment. Research into their environmental impact requires addressing challenges related to sensitively and selectively detecting them in complex ecological media. One solution with great potential for alleviating these issues is using radiolabeling strategies. Here, we report the successful introduction of a 64Cu radiotracer into common microplastics, namely polyethylene, polyethylene terephthalate, polystyrene, polyamide, and polyvinylidene dichloride, which allows the sensitive detection of mere nanograms of substance. Utilizing a Hansen Solubility Parameter screening, we developed a swelling and in-diffusion process for tetraphenylporphyrin-complexed 64Cu, which permits one-pot labeling of polymer particles.
Keywords: microplastics; radiolabeling; in-diffusion; Hansen Solubility Parameters microplastics; radiolabeling; in-diffusion; Hansen Solubility Parameters
Graphical Abstract

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MDPI and ACS Style

Stricker, A.; Hilpmann, S.; Mansel, A.; Franke, K.; Schymura, S. Radiolabeling of Micro-/Nanoplastics via In-Diffusion. Nanomaterials 2023, 13, 2687. https://doi.org/10.3390/nano13192687

AMA Style

Stricker A, Hilpmann S, Mansel A, Franke K, Schymura S. Radiolabeling of Micro-/Nanoplastics via In-Diffusion. Nanomaterials. 2023; 13(19):2687. https://doi.org/10.3390/nano13192687

Chicago/Turabian Style

Stricker, Alexandra, Stephan Hilpmann, Alexander Mansel, Karsten Franke, and Stefan Schymura. 2023. "Radiolabeling of Micro-/Nanoplastics via In-Diffusion" Nanomaterials 13, no. 19: 2687. https://doi.org/10.3390/nano13192687

APA Style

Stricker, A., Hilpmann, S., Mansel, A., Franke, K., & Schymura, S. (2023). Radiolabeling of Micro-/Nanoplastics via In-Diffusion. Nanomaterials, 13(19), 2687. https://doi.org/10.3390/nano13192687

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