Interfacial Imide Polymerization of Functionalized Filled Microcapsule Templates by the Pickering Emulsion Method for the Rapid Removal of 3,4,5-Trichlorophenol from Wastewater
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Preparation of GO Nanosheets
2.3. Preparation of the C-O/W Microcapsule Adsorbent
2.4. Characterization
2.5. Adsorption Isotherm and Kinetics Experiments
2.6. Cyclic and Actual Sample Adsorption Experiments
3. Results and Discussion
3.1. Design and Preparation of the C-O/W Microcapsules
3.2. Characterization Analysis of the C-O/W Microcapsules
3.3. Effect of the Solution pH on the Adsorption of 3,4,5-TCP
3.4. Adsorption Kinetics Analysis
3.5. Adsorption Isotherms and Thermodynamics Analysis
3.6. Adsorption Selectivity and Regeneration Performance Analysis
3.7. Actual Sample Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Kinetic Model | ||||
---|---|---|---|---|
Pseudo-first-order | Qe,e (mg/g) | Qe,c (mg/g) | k1 (min−1) | R2 |
125.81 | 123.67 | 1.034 | 0.5889 | |
Pseudo-second-order | Qe,c (mg/g) | k2 × 103(g(mg·min)) | t1/2 | R2 |
126.58 | 0.58 | 13.88 | 0.9469 | |
Particle diffusion equation | kid1 | kid2 | Rid12 | Rid22 |
7.742 | 0.156 | 0.992 | 0.921 |
Sorbents | T (K) | Langmuir Isotherm Equations | Freundlich Isotherm Equations | ||||
---|---|---|---|---|---|---|---|
Qm (mg/g) | KL × 103 (L/mg) | R2 | KF (mg1−n·Ln/g) | 1/n | R2 | ||
C-O/W | 278 | 671 | 3.35 | 0.9294 | 4.700 | 0.7649 | 0.9267 |
288 | 783 | 3.74 | 0.9587 | 6.075 | 0.7628 | 0.9606 | |
298 | 866 | 8.34 | 0.9700 | 12.70 | 0.7508 | 0.9561 |
Adsorbed Target | T (K) | ΔG (kJ/mol) | ΔH (kJ/mol) | ΔS (J/(mol·K)) |
---|---|---|---|---|
278 | −0.193 | |||
3,4,5-TCP | 288 | −1.619 | 39.45 | 142.6 |
298 | −3.045 |
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Wei, Z.; Ma, X.; Wang, P.; Pan, J. Interfacial Imide Polymerization of Functionalized Filled Microcapsule Templates by the Pickering Emulsion Method for the Rapid Removal of 3,4,5-Trichlorophenol from Wastewater. Nanomaterials 2022, 12, 3439. https://doi.org/10.3390/nano12193439
Wei Z, Ma X, Wang P, Pan J. Interfacial Imide Polymerization of Functionalized Filled Microcapsule Templates by the Pickering Emulsion Method for the Rapid Removal of 3,4,5-Trichlorophenol from Wastewater. Nanomaterials. 2022; 12(19):3439. https://doi.org/10.3390/nano12193439
Chicago/Turabian StyleWei, Zhuangxin, Xinmin Ma, Pan Wang, and Jianming Pan. 2022. "Interfacial Imide Polymerization of Functionalized Filled Microcapsule Templates by the Pickering Emulsion Method for the Rapid Removal of 3,4,5-Trichlorophenol from Wastewater" Nanomaterials 12, no. 19: 3439. https://doi.org/10.3390/nano12193439