Application-Oriented Valorization Routes and Arrangements for Agro-Industrial Residues and By-Products: A Scoping Review Across Sectors and Application Scales
Abstract
1. Introduction
2. Materials and Methods
2.1. Review Design and Reporting
2.2. Research Questions and PCC Framework
- (i)
- Which valorization routes and arrangements for agro-industrial residues and by-products are reported in studies with an application interface, and how are they distributed across sectors and application scales?
- (ii)
- Which limitations, barriers, facilitators, gaps, and recommendations are reported in relation to their implementation and transferability?
2.3. Eligibility Criteria
2.4. Information Source and Search Strategy
2.5. Selection of Sources of Evidence
2.6. Data Charting Process and Data Items
2.7. Classification and Synthesis of Results
2.8. Critical Appraisal of Sources of Evidence
3. Results and Discussion
3.1. Study Selection
3.2. Study Profile and Overall Distribution
3.3. Valorization Routes and Arrangements by Sector and Application Scale
3.4. Implementation Conditions, Gaps, and Recommendations
3.5. Limitations of the Review
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| PCC Element | Definition in This Review |
|---|---|
| Population | Agro-industrial residues, by-products, and co-products generated during food, biomass, and agricultural raw-material processing. |
| Concept | Valorization, resource recovery, productive use, environmental management, and circularity routes or arrangements with an explicit application interface. |
| Context | Agro-industrial systems, processing plants, supply chains, sectors, and regional, territorial, or national settings, with no restrictions on country or facility size. |
| Criterion | Inclusion Criteria | Exclusion Criteria |
|---|---|---|
| Document type | Peer-reviewed research articles. | Reviews, editorials, letters, commentaries, conference papers, book chapters, reports, and other gray literature. |
| Agro-industrial context | Studies involving identifiable agro-industrial systems, processing facilities, supply chains, sectors, or territories. | Household, retail, or municipal food waste without a connection to agro-industrial processing. |
| Material investigated | Residues, by-products, or co-products associated with agro-industrial production processes. | Materials not linked to an identifiable agro-industrial process. |
| Valorization concept | Valorization, resource recovery, productive use, environmental management, or circularity routes and arrangements. | Studies limited to analytical characterization without a valorization or management interface. |
| Application interface | Explicit connection with a process, product, facility, supply chain, sector, or territory. | Laboratory proof-of-concept studies without discussion of application, implementation, or transferability. |
| Study information | Extractable information on sector, scale, strategy, implementation conditions, barriers, facilitators, gaps, or recommendations. | Studies without sufficient information for classification or synthesis. |
| Publication period and language | No restrictions. | None. |
| Study | Year | Country | Sector | Residue/ By-Product | Route or Arrangement | Scale/Context | Main Contribution |
|---|---|---|---|---|---|---|---|
| [17] | 2025 | Colombia | Multisectoral agro-industrial residues | Biomass ash | Use as a supplementary cementitious material | Supply chain/sector | Develops a network and pricing model that integrates costs, location, transportation, and emissions. |
| [18] | 2022 | Mexico | Sugarcane and sugar-energy agro-industry | Sugarcane bagasse | Heat and power cogeneration | Plant-level case study and modeling | Assesses the environmental, economic, and social sustainability of energy systems at a Mexican sugar mill. |
| [19] | 2024 | Spain | Multisectoral agro-industrial residues | Ash and various residues | Alkali-activated materials | Laboratory | Demonstrates the use of residues as activators and silica sources while controlling leaching. |
| [20] | 2025 | Mexico | General food processing | Nejayote | Precipitation of Ca–P minerals | Laboratory | Characterizes the effluent and tests calcium and phosphorus recovery through a physicochemical route. |
| [21] | 2011 | Brazil | Sugarcane and sugar-energy agro-industry | Sugarcane trash | Energy recovery | Supply chain/sector | Examines availability, environmental implications, and the integration of biomass into energy and biofuel systems. |
| [22] | 2025 | Colombia | Vegetable oils and oilseeds | Residual palm biomass | Combustion for steam and electricity generation | Regional/ national | Compares bioenergy scenarios with fossil fuels across a regional network of plants. |
| [23] | 2016 | Greece | Multisectoral agro-industrial residues | Agro-industrial biomass | Energy-use planning | Regional/ national | Quantifies regional flows and estimates their potential for energy production. |
| [24] | 2016 | Greece | Vegetable oils and oilseeds | Olive by-products | Solar drying for use as solid fuel | Pilot | Tests solar drying as a pretreatment for energy valorization. |
| [25] | 2020 | Malaysia | Vegetable oils and oilseeds | Lignocellulosic residues | Accelerated composting | Laboratory | Evaluates physicochemical and microbial changes during co-composting. |
| [26] | 2022 | Sweden | Agri-food supply chains, policy, and governance | Multiple local material flows | Industrial symbiosis | Regional/ national | Proposes territorial connections to redirect underutilized resources toward local food production. |
| [27] | 2019 | Brazil | Meat and slaughter | Various solid residues | Diagnosis and management | Plant-level diagnostic assessment | Identifies the generation, segregation, and destination of residues in a poultry-processing facility. |
| [28] | 2021 | Spain | Beverages and industrial fermentation | Brewery spent grain | Low-temperature industrial drying | Plant-level simulation | Models a hybrid solar–biomass system and assesses its thermoenergetic and economic performance. |
| [29] | 1996 | Thailand | Vegetable oils and oilseeds | Palm residues | Energy-based, agricultural and industrial routes | Regional/ national | Maps combined alternatives for solid and liquid streams from palm oil production. |
| [30] | 2024 | Australia | Dairy | Cheese whey | Filtration, ion exchange, and electrodialysis | Pilot | Recovers salts and generates reusable products from whey. |
| [31] | 2025 | United States | Dairy | Acid whey | Chitosan pretreatment | Laboratory | Reduces solids and facilitates subsequent resource-recovery stages. |
| [32] | 2020 | Canada | Dairy | Cheese whey | Membrane separation | Plant-level simulation | Compares industrial ultrafiltration and microfiltration scenarios in terms of eco-efficiency. |
| [33] | 2013 | Greece | Vegetable oils and oilseeds | Olive mill effluent | Drying and solid recovery | Pilot | Evaluates drying to obtain a solid product with recovery potential. |
| [34] | 2025 | Spain | Vegetable oils and oilseeds | Olive mill residue | Co-composting | Plant-level empirical case study | Validates combinations of carbon and nitrogen sources in industrial windrows. |
| [35] | 2016 | Italy | Vegetable oils and oilseeds | Olive oil by-products | Combustion and energy recovery | Plant-level empirical case study | Compares the costs, energy use, and emissions associated with the local use of biomass and methane. |
| [36] | 2010 | Malaysia | Vegetable oils and oilseeds | EFB, POME, and decanter cake | Windrow composting | Plant-level empirical study | Tests turning, moisture control, and mixture formulation in a commercial plant. |
| [37] | 2010 | Cuba | Sugarcane and sugar-energy agro-industry | Filter cake and bagasse | Co-combustion in boilers | Plant-level experimental study | Demonstrates the technical and operational feasibility of the combined energy recovery of both residues. |
| [38] | 2025 | Australia | Dairy | Whey | Collection and processing network | Supply chain/sector | Optimizes location, budget, and outsourcing under uncertainty in residue generation. |
| [39] | 2020 | Ukraine | Vegetable oils and oilseeds | Sunflower husks | Heat, electricity, and cogeneration | Plant-level data and scenarios | Compares energy alternatives, costs, and emission reductions in industrial facilities. |
| [40] | 2010 | Spain | Multisectoral agro-industrial residues | Olive-processing residues, winery waste, and sludge | Composting and co-composting | Pilot | Demonstrates the effects of mixture structure, aeration, and the C/N ratio in a closed reactor. |
| [41] | 2018 | Norway | General food processing | Various food co-products | Cascading valorization and upcycling | Supply chain/sector | Links technology, logistics, regulation, and markets across different food value chains. |
| [42] | 2019 | Indonesia | Vegetable oils and oilseeds | Palm-derived streams | Bioenergy, nutrient recovery, and integrated arrangements | Regional/ national | Models regional expansion, infrastructure, and route combinations under logistical constraints. |
| [43] | 2025 | Saudi Arabia | Vegetable oils and oilseeds | Olive residues | Composting and bioenergy | Multiscale | Integrates agricultural and energy-based routes and discusses collection, markets, and institutional support. |
| [44] | 2025 | Brazil | Fisheries and aquaculture | Saline fish-processing sludge | Composting with halotolerant bacteria | Laboratory | Demonstrates residue stabilization under salinity control and inoculation conditions. |
| [45] | 2023 | India | Agri-food supply chains, policy, and governance | Agri-food residues | Resource efficiency and governance | Regional/ national | Analyzes policies, infrastructure, data, and circularity targets in the Indian sector. |
| [46] | 2026 | China | Vegetable oils and oilseeds | Acidified soybean soapstock | Composting with a mineral conditioner | Laboratory | Identifies the proportion of lignite that improves process performance, emissions, and agronomic quality. |
| Dimension | Category | n | % |
|---|---|---|---|
| Agro-industrial sector | Vegetable oils and oilseeds | 12 | 40.0% |
| Dairy | 4 | 13.3% | |
| Meat and slaughter | 1 | 3.3% | |
| Fisheries and aquaculture | 1 | 3.3% | |
| Beverages and industrial fermentation | 1 | 3.3% | |
| General food processing | 2 | 6.7% | |
| Agri-food supply chains, policy, and governance | 2 | 6.7% | |
| Multisectoral agro-industrial residues | 4 | 13.3% | |
| Sugarcane and sugar-energy agro-industry | 3 | 10.0% | |
| Application scale | Laboratory | 6 | 20.0% |
| Pilot or semi-industrial | 4 | 13.3% | |
| Industrial or plant-level context | 9 | 30.0% | |
| Supply-chain or sectoral | 4 | 13.3% | |
| Regional, territorial, or national | 6 | 20.0% | |
| Multiscale | 1 | 3.3% | |
| Valorization strategy | Biological | 6 | 20.0% |
| Energy-based | 8 | 26.7% | |
| Material | 2 | 6.7% | |
| Chemical or physicochemical | 6 | 20.0% | |
| Organizational and systemic | 4 | 13.3% | |
| Integrated or multiple routes | 4 | 13.3% |
| Strategy | Main Routes or Arrangements | Recurring Residues or Sectors | Observed Scales | Representative Studies |
|---|---|---|---|---|
| Biological | Composting, co-composting, and aerobic conversion using inoculants or conditioners | Palm and olive residues, fish-processing sludge, multisectoral residues, and acidified soapstock | Laboratory, pilot, and industrial contexts | [25,34,36,40,44,46] |
| Energy-based | Combustion, co-combustion, cogeneration, heat and power recovery, and drying for use as solid fuel | Sugarcane bagasse and trash, palm biomass, sunflower husks, and olive oil by-products | Pilot, plant-level, supply-chain, and regional contexts | [18,21,22,35,39] |
| Material | Incorporation of ash and residues into cementitious and alkali-activated materials | Biomass ash and agro-industrial residues from different value chains | Laboratory and supply-chain contexts | [17,19] |
| Chemical or physicochemical | Precipitation, drying, filtration, membrane separation, ion exchange, electrodialysis, and pretreatments | Cheese whey, acid whey, nejayote, brewery spent grain, and olive-processing effluent | Laboratory, pilot, and industrial contexts | [20,28,30,31,32,33] |
| Organizational and systemic | Diagnosis, waste management, industrial symbiosis, network design, governance, and resource efficiency | Food-processing plant residues, whey, and territorial or agri-food flows | Plant-level, supply-chain, and regional contexts | [26,27,38,45] |
| Integrated or multiple routes | Combination of energy-based, agricultural, material, or organizational routes and cascading valorization | Palm and olive streams and various food co-products | Supply-chain, regional, and multiscale contexts | [29,41,42,43] |
| Domain | Barriers or Limitations | Facilitators or Recommendations | Representative Studies |
|---|---|---|---|
| Technical and operational | Variability in composition, moisture, acidity, or salinity; need for process control, pretreatment, and equipment adaptation | Operational monitoring, use of bulking agents or inoculants, plant compatibility, and validation at larger scales | [37,40,44,46] |
| Economic and financial | Initial investment, incomplete cost data, sensitivity to energy prices, and transportation or outsourcing expenses | Sensitivity analysis, avoided disposal and fuel costs, revenue from energy or co-products, and phased implementation | [35,38,39,42] |
| Logistics | Geographically dispersed generation, high moisture content or perishability, and difficulties related to collection, storage, transportation, and access to infrastructure | Local use, dedicated networks, cluster arrangements, and territorial planning of material flows | [36,41,42,43] |
| Organizational and governance | Insufficient coordination among stakeholders, fragmented responsibilities, limited databases, and uneven policy implementation | Industrial symbiosis, cooperative models, data sharing, partnerships, and clear allocation of responsibilities | [26,27,41,45] |
| Regulatory and institutional | Sanitary and environmental constraints, legal classification of by-products, unstable incentives, and a lack of specific circularity targets | Clear standards, renewable energy incentives, compliance monitoring, and innovation policies | [39,40,41,44,45] |
| Scale-up and evaluation | Findings concentrated in case studies or small-scale applications, heterogeneous indicators, and limited longitudinal or comparable information | Demonstration studies, long-term monitoring, a core set of indicators, and replication in other contexts | [17,19,44,46] |
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de Sousa, J.E.; Vieira, M.E.; Bandeira, D.J.A.; Silva, J.C.K.; Bandeira, R.T.; Bandeira, Á.N.T.; Neto, A.S.S.; Gomes, M.F.; Santos, P.C.d.; Silva, D.D.E.d.; et al. Application-Oriented Valorization Routes and Arrangements for Agro-Industrial Residues and By-Products: A Scoping Review Across Sectors and Application Scales. Agriculture 2026, 16, 1951. https://doi.org/10.3390/agriculture16181951
de Sousa JE, Vieira ME, Bandeira DJA, Silva JCK, Bandeira RT, Bandeira ÁNT, Neto ASS, Gomes MF, Santos PCd, Silva DDEd, et al. Application-Oriented Valorization Routes and Arrangements for Agro-Industrial Residues and By-Products: A Scoping Review Across Sectors and Application Scales. Agriculture. 2026; 16(18):1951. https://doi.org/10.3390/agriculture16181951
Chicago/Turabian Stylede Sousa, Jackson Epaminondas, Marlene Evangelista Vieira, Diego José Araújo Bandeira, Julyana Carvalho Kluck Silva, Romeu Tavares Bandeira, Ágda Nara Tavares Bandeira, Agenor Sousa Santos Neto, Mila Façanha Gomes, Paulo Cesar dos Santos, Dalva Damiana Estevam da Silva, and et al. 2026. "Application-Oriented Valorization Routes and Arrangements for Agro-Industrial Residues and By-Products: A Scoping Review Across Sectors and Application Scales" Agriculture 16, no. 18: 1951. https://doi.org/10.3390/agriculture16181951
APA Stylede Sousa, J. E., Vieira, M. E., Bandeira, D. J. A., Silva, J. C. K., Bandeira, R. T., Bandeira, Á. N. T., Neto, A. S. S., Gomes, M. F., Santos, P. C. d., Silva, D. D. E. d., Xavier, K. B., & Carvalho, A. J. C. d. (2026). Application-Oriented Valorization Routes and Arrangements for Agro-Industrial Residues and By-Products: A Scoping Review Across Sectors and Application Scales. Agriculture, 16(18), 1951. https://doi.org/10.3390/agriculture16181951

