Nascent Rice Husk as an Adsorbent for Removing Cationic Dyes from Textile Wastewater
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Adsorbate Solution
2.2. Thermal Treatment and Characterization of Rice Husk
2.3. Batch Adsorption Experiments
3. Results and Discussion
3.1. Impact of Thermal Treatment on the Adsorption Capacity of Rice Husk
3.2. Kinetic Studies
3.3. Adsorption Isotherm
3.4. Thermodynamics
3.5. Influence of solution pH
3.6. Effect of Adsorbent Dosage
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Adsorbate | Pseudo-First-Order Kinetics | Pseudo-Second-Order Kinetics | ||||
---|---|---|---|---|---|---|
qe (mg/g) | k1 (1/h) | R2 | qe (mg/g) | k2 (g/mg/h) | R2 | |
MB | 17.1038 | 1.6835 | 0.9848 | 18.1906 | 0.1537 | 0.9641 |
CV | 18.9546 | 2.8671 | 0.9185 | 20.2015 | 0.2275 | 0.9649 |
Adsorbate | Langmuir Isotherm | Freundlich Isotherm | ||||
---|---|---|---|---|---|---|
Qm (mg/g) | KL (L/mg) | R2 | KF | 1/n | R2 | |
MB | 25.4645 | 0.3068 | 0.9868 | 7.3348 | 0.3155 | 0.9062 |
CV | 24.4781 | 0.2493 | 0.9785 | 7.4143 | 0.2773 | 0.9107 |
Adsorbent | Adsorption Capacity (mg/g) | Particle Size | pH | Temperature (°C) | Reference |
---|---|---|---|---|---|
Papaya seeds | 555.56 | 125−250 µm | 4.00 | 30 | [74] |
Periwinkle shells | 500 | 150 μm | 7.00 | 25 | [75] |
Date stones | 398.19 | 250 μm | 7.00 | 30 | [76] |
Bamboo activated carbon | 286 | 1–2 mm | 3.70 | 25 | [77] |
Chitosan beads | 262 | 4.42 mm | NA | 30 | [78] |
Pea shells | 246.91 | 212 µm | NA | 25 | [79] |
Alfa grass | 200 | 500–650 µm | 12.0 | 20 | [80] |
Broad bean peels | 192.7 | 350−400 μm | 5.00 | 30 | [81] |
Garlic peels | 142.86 | NA | 6.00 | 50 | [82] |
Natural poplar leaf | 135.35 | 0.425−0.850 mm | 7.00 | 20 | [83] |
Pine-tree leaf biomass | 126.58 | <350 μm | 9.20 | 30 | [84] |
Modified clay-ball | 100 | 1−2 mm | NA | 50 | [85] |
Palm kernel fiber | 95.4 | 50–80 μm | 7.20 | 25 | [49] |
Peanut husk | 72.13 | 0.425−0.85 mm | 7.00 | 20 | [27] |
Wheat bran | 54.79 | 150−250 µm | 6.00 | 20 | [86] |
Rice husk | 25.46 | 0.075−1.16 mm | 7.00 | 25 | This study |
Rice bran | 20.29 | 150−250 µm | 6.00 | 20 | [86] |
Adsorbate | Temperature (K) | ∆H° (kJ/mol) | ∆S° (J/mol K) | ∆G° (kJ/mol) |
---|---|---|---|---|
MB | 288 | 28.50 | 0.103 | −1.1115 |
298 | −1.9774 | |||
308 | −3.1703 | |||
CV | 288 | 151.53 | 0.535 | −2.7018 |
298 | −7.6901 | |||
308 | −13.4146 |
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Quansah, J.O.; Hlaing, T.; Lyonga, F.N.; Kyi, P.P.; Hong, S.-H.; Lee, C.-G.; Park, S.-J. Nascent Rice Husk as an Adsorbent for Removing Cationic Dyes from Textile Wastewater. Appl. Sci. 2020, 10, 3437. https://doi.org/10.3390/app10103437
Quansah JO, Hlaing T, Lyonga FN, Kyi PP, Hong S-H, Lee C-G, Park S-J. Nascent Rice Husk as an Adsorbent for Removing Cationic Dyes from Textile Wastewater. Applied Sciences. 2020; 10(10):3437. https://doi.org/10.3390/app10103437
Chicago/Turabian StyleQuansah, Jude Ofei, Thandar Hlaing, Fritz Ndumbe Lyonga, Phyo Phyo Kyi, Seung-Hee Hong, Chang-Gu Lee, and Seong-Jik Park. 2020. "Nascent Rice Husk as an Adsorbent for Removing Cationic Dyes from Textile Wastewater" Applied Sciences 10, no. 10: 3437. https://doi.org/10.3390/app10103437