Analysis of Han Dynasty Red Pottery Eave-End Tile from the Minyue Kingdom Ruins
Abstract
1. Introduction
2. Materials and Methods
2.1. Han Dynasty Red Pottery Eave-End Tiles (Wadang) from the Minyue Kingdom
2.2. Analysis Methods
- (1).
- Petrographic analysis. Petrographic analysis is used to observe the microstructure and phase composition characteristics of eave-end tiles (Wadang). Several representative samples were selected, cut, mounted, and polished to thin slices of approximately 30 μm in thickness. Polarized light microscopy (Leica DM4500P, Wetzlar, Hesse, Germany) was used for the analysis under parallel and crossed light, with a magnification of 50×–200×. Extended Depth of Field (EDF) technology was employed to synthesize multiple focal planes into a single clear image for detailed morphological analysis. The morphology, particle size distribution, and porosity of the quartz, feldspar, calcite, and glass phase components in the tiles were analyzed through thin-section images, thereby allowing us to infer their firing temperature and process level. Scanning electron microscopy (SEM, ZEISS EVO18) was used for additional observation of some samples to confirm the sintering relationship between mineral particles.
- (2).
- Quantitative image analysis. To supplement qualitative lithofacies observations and achieve accurate characterization of the distribution of mixed components, we conducted a quantitative analysis of thin-section micrographs based on digital image segmentation. Using a custom Python (Version 3.14.3) script based on the OpenCV library, the original images were converted from RGB to HSV (hue, saturation, lightness) color space to enhance the contrast between mineral inclusions and the clay matrix. An adaptive thresholding algorithm was applied to segment quartz grains based on their high brightness and low saturation characteristics, followed by morphological opening to remove noise. Statistical analysis was then performed on the segmented binary masks to calculate the quartz area fraction (Quartz Area Fraction, %) to indicate the abundance of mixed materials. Furthermore, the geometric parameters of individual grains were extracted, including equivalent diameter (for assessing grain size distribution), roundness (4π × area/perimeter2, for assessing grain roundness), and aspect ratio, providing quantitative data support for interpreting raw material origin and processing standardization.
- (3).
- X-ray diffraction analysis (XRD). XRD was used to identify the main mineral phases in the eave-end tile (Wadang) samples. The experiment used a Bruker D8 Advance X-ray diffractometer, Cu Kα radiation (λ = 1.5406 Å), tube voltage of 40 kV, and tube current of 40 mA. The scanning range was 5–80° (2θ), step size 0.02°, and scanning rate 2°/min. The samples were crushed to a particle size of <75 μm and then loaded into the sample holder for compaction. The obtained diffraction patterns were matched with the Powder Diffraction File (PDF)-4 of the International Centre for Diffraction Data (ICDD) database (https://www.icdd.com/pdf-4-minerals/, accessed on 8 October 2025) and qualitatively identified in combination with JCPDS cards. The main mineral identified was quartz, while other trace phases were not detected due to the masking effect of the strong quartz peaks and their low content. For some samples, the crystal phase ratio was estimated using a semi-quantitative method to assist in determining the firing temperature and raw material ratio.
- (4).
- Raman spectroscopy analysis. Raman spectroscopy is used to identify the mineral structure and glass phase characteristics of the samples. A Horiba LabRAM HR Evolution Raman spectrometer was used, with a laser wavelength of 532 nm and a laser power controlled at <1 mW to avoid thermal damage. The microscope magnification was 50×. The spectral acquisition range was 100–2000 cm−1, and each sample was tested three times and averaged. Raman data were processed and baseline corrected using LabSpec 6 software. The main mineral vibration peaks (such as Si–O stretching vibration and Al–O angular vibration) were determined via comparison with the literature database and verified with the XRD results to identify possible amorphous phases and mineral transformation characteristics.
3. Results
3.1. Petrographic Analysis Results
3.2. Microstructural Heterogeneity Analysis
3.3. XRD Analysis
3.4. Raman Spectroscopy Analysis
4. Discussion
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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| Sample | 1 | 2 | 3 | 4 |
|---|---|---|---|---|
| Quartz Area (%) | 9.37 | 12.38 | 17.67 | 21.30 |
| Total Count | 2229 | 4047 | 6415 | 3182 |
| Mean Size (µm) | 4.08 | 4.19 | 3.77 | 5.97 |
| Median Size (µm) | 2.56 | 2.73 | 2.40 | 3.74 |
| Max Size (µm) | 192.24 | 50.84 | 63.27 | 95.57 |
| Circularity | 0.62 | 0.63 | 0.59 | 0.54 |
| Aspect Ratio | 1.46 | 1.37 | 1.37 | 1.44 |
| Process Steps | Process Name | Process Type |
|---|---|---|
| 1 | Selecting the inner mold | (1). Inner mold structure: Several wooden sticks are placed vertically to form a cylinder. (2). Isolation membrane type: Type A with pockmarks, Type B with convex dots (tiles unearthed from the ruins of the Minyue Kingdom are mainly of this type), Type C with cloth patterns |
| 2 | Throwing | Type A clay strips are coiled around the inner mold; Type B clay sheets are rolled around the inner mold. |
| 3 | Beating to shape | Type A uses a rope-patterned roller; Type B uses a rope-patterned pottery paddle. |
| 4 | Trimming the convex surface of barrel tiles | Type A: all-over rope pattern; Type B: plain and interlaced rope pattern sections; Type C: plain at the beginning with rope pattern at the end (this is the main type of eave-end tiles excavated from the Imperial City of the Minyue Kingdom Ruins); Type D: plain (no patterns or designs). |
| 5 | Trimming the concave surface of barrel tiles | After removing the inner mold, rotate the wheel to finish the surface. After partially finishing the surface, tap the convex points. |
| 6 | Making dangmian (front face) | (1). Theme: rope pattern, animal pattern, plant pattern, cloud pattern, text. (2). Structure: winding structure, symmetrical structure, etc. There is a relationship of inheritance and development between different themes and structures |
| 7 | Making the side wheel | Type A is coiled with mud strips; Type B is molded; Type C is without side wheel. |
| 8 | Connecting the dangmian (front face) to the barrel tiles | Type A: the dangmian and the barrel tile are manufactured integrally and then cut; Type B: the dangmian and the barrel tile are manufactured separately and then joined, leaving no cut marks; Type C: the dangmian and the barrel tile are manufactured separately, joined with clay strips, and then cut (this type of dangmian tile was primarily found at the Imperial City of the Minyue Kingdom). |
| 9 | Making the tile lip | Type A: wheel-made, the tile lip and barrel tile are manufactured separately and then joined; Type B: one end of the barrel tile is pressed inward to form the lip. |
| 10 | Cutting the barrel tile and dangmian | Type A: knife cutting; Type B: knife cutting and rope cutting (this type was used at the Ruins of Han Dynasty Ruins in Chengcun Village); Type C: rope cutting. |
| 11 | Finishing the dangbei (back face) | Some craftsmen trim the dangbei (back face), demonstrating their meticulous craftsmanship. |
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Share and Cite
Zhou, S.; Zhu, Y.; Zhang, L.; Deng, Q.; Liang, J.; Guo, Z.; Liu, W.; Zheng, L.; Chen, Y. Analysis of Han Dynasty Red Pottery Eave-End Tile from the Minyue Kingdom Ruins. Buildings 2026, 16, 2222. https://doi.org/10.3390/buildings16112222
Zhou S, Zhu Y, Zhang L, Deng Q, Liang J, Guo Z, Liu W, Zheng L, Chen Y. Analysis of Han Dynasty Red Pottery Eave-End Tile from the Minyue Kingdom Ruins. Buildings. 2026; 16(11):2222. https://doi.org/10.3390/buildings16112222
Chicago/Turabian StyleZhou, Shihui, Yufei Zhu, Lei Zhang, Qingnian Deng, Jingwei Liang, Zekai Guo, Wei Liu, Liang Zheng, and Yile Chen. 2026. "Analysis of Han Dynasty Red Pottery Eave-End Tile from the Minyue Kingdom Ruins" Buildings 16, no. 11: 2222. https://doi.org/10.3390/buildings16112222
APA StyleZhou, S., Zhu, Y., Zhang, L., Deng, Q., Liang, J., Guo, Z., Liu, W., Zheng, L., & Chen, Y. (2026). Analysis of Han Dynasty Red Pottery Eave-End Tile from the Minyue Kingdom Ruins. Buildings, 16(11), 2222. https://doi.org/10.3390/buildings16112222
