Leaching of Pure Chalcocite in a Chloride Media Using Sea Water and Waste Water

Abstract

Chalcocite is the most important and abundant secondary copper ore in the world with a rapid dissolution of copper in an acid-chloride environment. In this investigation, the methodology of surface optimization will be applied to evaluate the effect of three independent variables (time, concentration of sulfuric acid and chloride concentration) in the leaching of pure chalcocite to extract the copper with the objective of obtaining a quadratic model that allows us to predict the extraction of copper. The kinetics of copper dissolution in regard to the function of temperature is also analyzed. An ANOVA indicates that the linear variables with the greatest influence are time and the chloride concentration. Also, the concentration of chloride-time exerts a significant synergic effect in the quadratic model. The ANOVA indicates that the quadratic model is representative and the R² value of 0.92 is valid. The highest copper extraction (67.75%) was obtained at 48 h leaching under conditions of 2 mol/L H₂SO₄ and 100 g/L chloride. The XRD analysis shows the formation of a stable and non-polluting residue; such as elemental sulfur (S⁰). This residue was obtained in a leaching time of 4 h at room temperature under conditions of 0.5 mol/L H₂SO₄ and 50 g/L Cl⁻.

1. Introduction

Most of the copper minerals on the planet correspond to sulfur minerals and a smaller amount of oxidized minerals. A report by COCHILCO [1] mentions that the world copper production is currently 19.7 million tons. Seventy-five percent of this total comes from the pyrometallurgical processing of copper sulfide minerals processed in smelting plants [2], and 25% by the hydrometallurgical route [3].

There is a need to generate a new momentum that overcomes a certain stagnation in the growth capacity of the mining industry. Even in its role as a surplus generator, large-scale mining faces great challenges. These include an increase in costs due to various factors; such as the deterioration of laws and other elements associated with the aging of deposits and input costs to be compatible with sustainable development demands [4].

Sulfur minerals have been treated for decades with flotation and pyrometallurgical processes [5], which result in major environmental problems; such as tailings dams and the generation of acid drainage (sulfuric acid and oxides of iron) by the oxidation of sulfur minerals with a high presence of pyrite. This sulfide is one of the most common and abundant minerals in the world and is associated with hydrothermal mineralization [6]. On the other hand, foundries produce large emissions of sulfur dioxide (SO₂), which together, with NO_x and CO₂, can cause large problems; such as acid rain and increasing local pollution, therefore, the abatement of waste gases is an important task for the protection of the environment [7,8,9]. As a result, new hydrometallurgical alternatives are being developed in the mining industry, because they are more ecological and economic processes to recover copper [10,11].

Chalcocite is the most abundant copper sulfide mineral after chalcopyrite [5,12], and it is the copper sulfide the most easily treated by hydrometallurgical routes [13]. Several investigations have been carried out for the leaching of this mineral with the use of multiple additives and in different media such as; bioleaching [14,15,16,17,18], ferric sulfate solution [19], chloride media [20,21,22,23], pressure leaching for chalcocite [24] and synthetic chalcocite (white metal) [25].

When operating in sulphated or chloride media, the oxidative dissolution of the chalcocite occurs in two stages [13,19,20,23,25].

Cu₂S + 2Fe³⁺ = Cu²⁺ + 2Fe²⁺ + CuS

(1)

CuS + 2Fe³⁺ = Cu²⁺ + 2Fe²⁺ + S⁰

(2)

The first stage of leaching of the chalcocite is much faster than the second stage. This is controlled by diffusion of the oxidant on the surface of the ore at low values of activation energy (4–25 kJ mol⁻¹) [19]. The second stage is slower and can be accelerated depending on the temperature [13,26].

The investigations shown in

Table 1. Comparison of previous investigations of chalcocite with the use of Cl⁻.

Investigation	Leaching Agent	Parameters Evaluated	Reference	Cu Ext (%)
The kinetics of leaching chalcocite (synthetic) in acidic oxygenated sulphate-chloride solutions	NaCl, H2SO4, HCl, HNO3 and Fe3+	Oxygen flow, stirring speed, temperature, sulfuric acid concentration, ferric ions concentration, chloride concentration and particle size.	[20]	97
The kinetics of dissolution of synthetic covellite, chalcocite and digenite in dilute chloride solutions at ambient temperatures	HCl, Cu2+ and Fe3+	Potential effect, chloride concentration, acid concentration, temperature, dissolved oxygen and pyrite effect.	[13]	98
Leaching kinetics of digenite concentrate in oxygenated chloride media at ambient pressure	CuCl2, HCl and NaCl	Effect of stirring speed, oxygen flow, cupric ion concentration, chloride concentration, acid concentration and temperature effect.	[27]	95
Leaching of sulfide copper ore in a NaCl–H2SO4–O2 media with acid pre-treatment	NaCl and H2SO4	Chloride concentration, effect of agitation with compressed air, percentage of solids and particle size.	[22]	78

were obtained as a result of high extractions (90%), but these results were obtained with the application of high temperatures and/or with the addition of ferric or cupric ions as an oxidizing agent. In addition, the previous investigations were made with mixtures of copper sulfides, with the presence of gangue or with the use of synthetic chalcocite. It is emphasized that the present investigation will include a leaching of pure chalcocite in a chlorinated medium, without the addition of oxidizing agents (Fe^{3 +}, Cu^{2 +}, etc.) and at room temperature.

A chalcocite leaching is performed with the injection of O₂ at ambient pressure in a H₂SO₄-NaCl solution, where the leaching agents are Cu²⁺, CuCl⁺, CuCl₂ and Cu${\mathrm{Cl}}_3^{-}$, which are generated during leaching in a Cu²⁺/Cl⁻ system. The general reaction of chalcocite leaching is as follows:

$${\mathrm{Cu}}_2\mathrm{S}+0.5{\mathrm{O}}_2+2{\mathrm{H}}^{+}+4{\mathrm{Cl}}^{-}=2\mathrm{Cu}{\mathrm{Cl}}_2^{-}+{\mathrm{H}}_2\mathrm{O}+{\mathrm{S}}^0,$$

(3)

While the chalcocite leaching reactions occur in two stages, guiding us to Equation (3), the following occurs:

$${\mathrm{Cu}}_2\mathrm{S}+2{\mathrm{Cl}}^{-}+{\mathrm{H}}^{+}+0.25{\mathrm{O}}_2=\mathrm{Cu}{\mathrm{Cl}}_2^{-}+\mathrm{CuS}+0.5{\mathrm{H}}_2\mathrm{O},$$

(4)

$$\mathrm{CuS}+2{\mathrm{Cl}}^{-}+{\mathrm{H}}^{+}+0.25{\mathrm{O}}_2=0.5{\mathrm{H}}_2\mathrm{O}+\mathrm{Cu}{\mathrm{Cl}}_2^{-}+{\mathrm{S}}^0,$$

(5)

The resulting products expected from this chalcocite leaching should be soluble copper; such as Cu${\mathrm{Cl}}_2^{-}$ and a solid residue of elemental sulfur (S⁰) with covellite residues or copper polysulfides (CuS₂) that still contain valuable metals.

The Cu${\mathrm{Cl}}_2^{-}$ is the predominant soluble specie due to the complexation of Cu (I) with the presence of Cl⁻ at room temperature, in a system of high concentrations of chloride (greater than 1 M). This Cu${\mathrm{Cl}}_2^{-}$ is stable in a range of potentials between 0–500 mV and pH < 6–7 (depending on the chloride concentration in the system) [20,28].

The shortage of fresh water in arid areas is an economic, environmental and social problem [29]. The use of sea water has become increasingly important for mining in Chile, not only because of its positive effects on leaching processes due to its chloride content, but also as a strategic and indispensable resource. For example, some metallic and non-metallic mining companies in the north of Chile have deposits rich in copper, gold, silver, iron and minerals from salt lakes, which are found in hyper-arid zones and at high altitudes, which emphasizes the necessity of this resource [30]. In addition, it is important to mention that the Chilean authorities have indicated that large-scale mining projects involving the use of water from aquifers will not be authorized [31]. An attractive alternative is the use of waste water from desalination plants. These companies produce drinking water for the population, however, their disposal product pollutes the oceans, for this reason, it is necessary to think of possible alternatives to recycle this resource and at the same time optimize extraction processes in local mining.

In the present investigation, a statistical analysis will be carried out using the methodology of surface optimization (design of the central composite face) to sensitize independent parameters (time, sulfuric acid concentration and chloride concentration) in the leaching of a pure mineral of chalcocite in chlorinated media. In addition, the effect on chloride concentration in the system will be evaluated when operating with potable water, seawater and reusing waste water.

2. Materials and Methods

2.1. Chalcocite

The pure chalcocite mineral used for the present investigation was collected manually directly from the veins by expert geologists from Mina Atómica, located in the region of Antofagasta, Chile.

The pure chalcocite samples were checked by X-ray diffraction (XRD) analysis, using an automatic and computerized X-ray diffractometer Bruker model Advance D8 (Bruker, Billerica, MA, USA). Figure 1 shows the results of the XRD analysis, indicating the presence of 99.9% chalcocite. The chemical analysis was performed by atomic emission spectrometry via induction-coupled plasma (ICP-AES), the sample of chalcocite was digested using aqua regia and HF.

Table 2. Chemical analysis of the chalcocite ore.

Component	Cu	S0
Mass (%)	79.83	20.17

shows the chemical composition of the samples. The samples for XRD and ICP-OES were ground in a porcelain mortar to reach a size range between −147 + 104 μm. The procedures described were performed in the applied geochemistry laboratory of the department of geological sciences of the Universidad Católica del Norte.

2.2. Leaching and Leaching Tests

The sulfuric acid used for the leaching tests was grade P.A., Merck brand, purity 95–97%, density 1.84 kg/L and molecular weight of 98.08 g/mol, though the tests also work with the use of sea water and waste water from the “Aguas Antofagasta” Desalination Plant.

Table 3. Chemical analysis of waste water.

Compound	Concentration (g/L)
Fluorine (F−)	0.01
Calcium (Ca2+)	0.80
Magnesium (Mg2+)	2.65
Bicarbonate (HCO3−)	1.10
Chloride (Cl−)	39.16
Calcium carbonate (CaCO3)	13.00

shows the chemical composition of waste water.

Leaching tests were carried out in a 50 mL glass reactor with a 0.01 S/L ratio. A total of 200 mg of chalcocite ore in a size range between −147 + 104 μm and the addition of NaCl at different concentrations were maintained in agitation and suspension with the use of a 5-position magnetic stirrer (IKA ROS, CEP 13087-534, Campinas, Brazil) at a speed of 600 rpm and the temperature was controlled using an oil-heated circulator (Julabo, St. Louis, MO, USA). The temperature range tested in the experiments was 25 °C. Also, the tests were performed in duplicate and measurements (or analyzes) were carried out on 5 mL aliquot and diluted to a range of dilutions using atomic absorption spectrometry with a coefficient of variation ≤5% and a relative error between 5 to 10%. Measurements of pH and oxidation-reduction potential (ORP) of leach solutions were made using a pH-ORP meter (HANNA HI-4222, St. Louis, MO, USA). The ORP solution was measured in a combination ORP electrode cell of a platinum working electrode and a saturated Ag/AgCl reference electrode.

2.3. Experimental Design

The effects of independent variables on Cu extraction rates from leaching of chalcocite were studied using the response surface optimization method [32,33,34,35]. The central composite face (CCF) design and a quadratic model were applied to the experimental design for Cu₂S leaching.

Twenty-seven experimental tests were carried out to study the effects of time, chloride and H₂SO₄ concentration as independent variables. Minitab 18 software (version 18, Pennsylvania State University, State College, PA, USA) was used for modeling and experimental design, which allowed the study of the linear and quadratic effects of the independent variables. The experimental data were fitted by multiple linear regression analysis to a quadratic model, considering only those factors that helped to explain the variability of the model. The empirical model contains coefficients of linear, quadratic, and two-factor interaction effects.

The general form of the experimental model is represented by:

$$Y=\left(overall constant\right)+\left(linear effects\right)+\left(interaction effects\right)+\left(curvature effects\right),$$

(6)

$$Y=b_0+b_1{x}_1+b_2{x}_2+b_3{x}_3+b_{12}{x}_1{x}_2+b_{13}{x}_1{x}_3+b_{23}{x}_2{x}_3+b_{11}{x}_1^2+b_{22}{x}_2^2+b_{33}{x}_3^2,$$

(7)

Where, $x_1$ is time, $x_2$ is Chloride, $x_3$ is H₂SO₄ concentration, and $b$ is the variable coefficients.

Table 4. Experimental parameters for the central design of the composite face.

Experimental Parameters	Low	Medium	High
Time (h)	4	8	12
Concentration	20	50	100
Cl− (g/L)
Concentration	0.5	1	2
H2SO4 (mol/L)
Codifications	−1	0	1

presents the ranges of parameter values used in the experimental model. The variable values are codified in the model. The following Equation (8) is used for transforming a real value (Z_i) into a code value (X_i) according to the experimental design:

$$X_i=\frac{Z_i-\frac{Z_{high}+Z_{low}}{2}}{\frac{Z_{high}-Z_{low}}{2}},$$

(8)

$Z_{high}$ and $Z_{low}$ are the highest and lowest levels of a variable, respectively [36].

A factorial design was applied involving three factors, each one having three levels thus 27 experimental tests were carried out in

Table 5. Experimental configuration and Cu extraction.

Exp. No.	Time (h)	Cl− (g/L)	H2SO4 (mol/L)	Cu Ext. (%)
1	4	20	0.5	31.63
2	4	20	1	33.25
3	4	20	2	37.00
4	4	50	0.5	32.25
5	4	50	1	33.38
6	4	50	2	38.00
7	4	100	0.5	44.75
8	4	100	1	44.88
9	4	100	2	46.19
10	8	20	0.5	35.75
11	8	20	1	38.75
12	8	20	2	43.00
13	8	50	0.5	48.13
14	8	50	1	49.50
15	8	50	2	50.63
16	8	100	0.5	51.50
17	8	100	1	53.00
18	8	100	2	54.88
19	12	20	0.5	52.25
20	12	20	1	52.75
21	12	20	2	52.63
22	12	50	0.5	53.13
23	12	50	1	53.13
24	12	50	2	53.00
25	12	100	0.5	53.25
26	12	100	1	53.88
27	12	100	2	55.63

, evaluating the effect of time and H₂SO₄ and chloride concentration.

The statistical R², R²_adj, p-values and Mallows’s Cp indicate whether the model obtained is adequate to describe Cu extraction under a given domain. The R² coefficient is a measure of the goodness of fit, which measures the proportion of total variability of the dependent variable with respect to its mean, which is explained by the regression model. The p-values represent statistical significance, which indicates whether there is a statistically significant association between the response variable and the terms. The predicted R² was used to determine how well the model predicts the response for new observations. Finally, Mallows’s Cp is a precise measure in the model, estimating the true parameter regression [36].

3. Results

3.1. ANOVA

An ANOVA analysis (

Table 6. ANOVA (analysis of variance) Cu extraction.

Source	F-Value	p-Value
Regression	22.73	0
Time	123.15	0
Cl−	45.25	0
H2SO4	5.44	0.03
Time × Time	2.06	0.17
Cl− × Cl−	0.13	0.72
H2SO4 × H2SO4	0.00	0.97
Time × Cl−	10.27	0.01
Time × H2SO4	1.18	0.29
Cl− × H2SO4	0.31	0.59

) showed F-value and p-value for the model.

In the contour plot in Figure 2, it is observed that Cu extraction increases at long times, high chloride concentration, and high H₂SO₄ concentration.

Table 6 shows ANOVA analysis. There is no significant effect (p > 0.05) of the interactions concentration of chloride concentration of H₂SO₄ and time-concentration of H₂SO₄ in copper extraction, complying with the theory that the increase in sulfuric acid concentration does not have a great influence on the leaching of chalcocite above 0.02 mol/L [19,22]. Rather, it is only the time-concentration interaction of chloride that must be considered in the model. Additionally, the effects of curvature of the variable chloride concentration and H₂SO₄ concentration do not contribute significantly to explaining the variability of the model. On the other hand, the linear effects of chloride time and concentration contribute to explaining the experimental model, as shown in the contour plot of Figure 2.

Figure 3 and Figure 4 show that time, chloride and H₂SO₄ concentration, as well as the interaction of time-H₂SO₄ and Cl-H₂SO₄ affected Cu extraction.

In Figure 3, the linear effects demonstrate what has been said by several authors [13,20,37], with respect to the effect of the concentration of chloride present in the leaching media and the effect of sulfuric acid concentration. The concentration of chloride has a great impact on the dissolution of copper from a sulfide; such as chalcocite. According to Velásquez-Yévenes et al. [38], the chloride ions present in the media increase the rate of oxidation of cuprous ions, while Cheng and Lawson [20,39] proposed that the effect of chloride ions promotes the formation of long sulfide crystals that allow the reactants to penetrate the sulfide layer, since in their tests they noticed that, in the absence of chloride ions, the kinetics of dissolution decreased considerably and that covellite did not dissolve. This with time was supported in the research of Nicol and Basson [37], without the presence of chloride ions or with a very low concentration of ions, the potential needed to dissolve covellite is very high.

Figure 4 shows the mean Cu extraction at different combinations of factor levels. In the interaction time-chloride, the lines are not parallel, and the plot indicates that there is an interaction between the factors. On the other hand, the interaction between time-H₂SO₄ and chloride-H₂SO₄ is low.

Equation (9) presents the Cu extraction model over the range of experimental conditions after eliminating the non-significant coefficients.

$$\%\mathrm{Extraction}=0.47782+0.07472x_1+0.04462x_2+0.01568x_3-0.0163x_1^2-0.02546x_1{x}_2,$$

(9)

Where $x_1, x_2$ and $x_3$ are codified variables that respectively represent time, chloride and H₂SO₄ concentration.

An ANOVA test indicated that the quadratic model adequately represented Cu extraction from Cu₂S under the established parameter ranges. The model did not require adjustment and it was validated by the R² value (0.92) and R²_adj value (0.90). The ANOVA analysis showed that the factors indicated influence Cu extraction from Cu₂S (F_Regression (22.73) > F_{T,95% confidence level} = F_5,21 (2.68)). On the other hand, the p-value of the model (Equation (9)) is lower than 0.05, indicating that the model is statistically significant.

The Mallows’s Cp = 3.62 (constant + 5 predictors) indicated that the model was accurate and did not present bias in estimating the true regression coefficients. This value of Cp of Mallows allows comparison with other models and establishes that the model found is the one that is most adjustable, due to the Cp closest to the number of constants and predictors.

In addition, all variance inflation factors (VIF) values are close to one, which ensures that there is no multicollinearity.

It also allows for prediction with an acceptable future forecast margin of error of R²_pred = 0.8684.

Finally, from the adjustment of the ANOVA analysis, it was found that the factors considered, after analysis of the main components, explained the variation in the response. The difference between the R² and R²_pred of the model was minimal, thus reducing the risk that the model was over adjusted. That means, the probability that the model fits only in the sample data is lower. The ANOVA analysis indicated that time, chloride concentration, H₂SO₄ concentration and the interaction of time-chloride are the factors that explain to a greater extent the behavior of the system for the sampled data set.

Table 5 shows that the increase in sulfuric acid concentration does not affect copper dissolution, obtaining similar results under similar conditions of leaching, only a minimum amount of sulfuric acid is needed in the leaching system. This result is consistent with other investigations, since according to Cheng and Lawson [20], a concentration of sulfuric acid of 0.02 mol/L, is sufficient to perform a leaching of chalcocite and its subsequent phases as it is the djurleite, digenite ore [22]. After this value its effect is null.

On the other hand, it is shown that at a leaching time of 12 h, the values of copper extraction do not vary regardless of the concentration of chloride and sulfuric acid. This could be explained with Equations (4) and (5); Equation (4) is the rapid reaction of the transformation of chalcocite to covellite, in which a low activation energy is required to achieve its transformation [13]. When covellite is formed (Equation (5)), it needs more energy (about 72 kJ approximately) to achieve its dissolution and later become a copper polysulfide (CuS₂), what it requires is even more demanding conditions to achieve its complete dissolution [37].

3.2. Effect on the Chloride Concentration

It has been known since the 1970s that it is beneficial to work with chloride ions in the leaching of sulfide minerals [23,40]. In Figure 5a, when operating at higher chloride concentrations, higher copper recoveries are obtained. When operating with the highest chloride concentrations (100 g/L), the highest recovery (68.82%) is obtained at 48 h. However, a large difference in copper recoveries cannot be seen when operating at chloride concentrations between 20 and 50 g/L. At 48 h and 20 g/L, a recovery of 63.58% of Cu was obtained and for chloride concentrations of 50 g/L, 65.45% was obtained. On the other hand, in Figure 5b it is observed that with the use of waste water (39.16 g/L of Cl⁻), results similar to those presented in Figure 5a were obtained in a Cl⁻ concentration of 50 g/L, so it is noted that the presence of calcium ions, fluorine, magnesium and calcium carbonate did not affect the dissolution of copper from the chalcocite. In the tests carried out with seawater, which has approximately a concentration of 20 g/L Cl⁻, obtained copper extractions of up to 63.4% at 48 h with a concentration of 0.5 mol/L of sulfuric acid. In previous investigations [13,20], it has been determined that leaching is independent of a chloride concentration between 0.5 and 2 mol/L, but a greater kinetic of dissolution is observed in the first minutes and then the difference decreases as a function of time and behavior similar to that of Figure 5.

Figure 6 shows a residue analysis performed under the conditions of 50 g/L Cl⁻ and 0.5 mol/L H₂SO₄, in a leaching time of 4 h. The result of this XRD is useful to understand the behavior of the chalcocite in a short time and in low reagent conditions, and to observe which mineralogical species are forming. The results show a high formation of synthetic covellite (77.34 wt %), early formation of elemental sulfur (20.20 wt %) and a remaining chalcocite (4.46 wt %), which still does not dissolve. From this, it follows that the transformation of chalcocite to covellite is faster than the transformation of covellite to elemental sulfur, which is similar to that observed in Equations (4) and (5), also, according to Figure 5, the slope of the curve is decreasing slowly, which means less kinetics of copper dissolution as a function of time. In the investigation of Senanayake [28], it is reported that the dissolution of chalcocite in a chloride-iron-water system at 25 °C occurs at potentials greater than 500 mV with a pH < 4, while in the research of Miki et al. [13] it is reported that the chalcocite dissolution occurs rapidly at a potential of 500 mV but stops when it reaches 50% copper extraction. When the potential increases to 550 mV, this extraction increases again because once it reaches 50% copper extraction, the mineral present is mainly covellite, which has a dissolution kinetics lower than the chalcocite and that needs potentials greater than 600 mV to dissolve.

4. Conclusions

The present investigation shows the experimental results necessary to dissolve Cu from a chalcocite mineral in chloride media. The findings of this study were:

• The linear variables with the greatest influence in the model are: time, chloride concentration and sulfuric acid concentration, respectively.
• Under normal pressure and temperature conditions, only the chloride-time concentration exerts a significant synergistic effect on the extraction of copper from a chalcocite mineral.
• The ANOVA analysis indicates that the presented quadratic model is adequate to represent the copper extractions and the value of R² (0.92) validates it.
• The highest copper extraction is achieved under conditions of low concentration of sulfuric acid (0.5 mol/L), high concentrations of chloride (100 g/L) and a prolonged leaching time (48 h) to obtain an extraction of 67.75% copper.
• The XRD analysis shows the formation of a stable and non-polluting residue; such as elemental sulfur (S⁰). This residue was obtained in a leaching time of 4 h at room temperature under conditions of 0.5 mol/L H₂SO₄ and 50 g/L Cl⁻.