Recent Advances in Joining Technologies for Aluminum/Magnesium Dissimilar Metals: A Review
Abstract
1. Introduction
2. Challenges in Aluminum/Magnesium Dissimilar Metals
2.1. Intermetallic Compounds
2.2. Defect Formation
2.2.1. Oxide Inclusions
2.2.2. Cracks
2.2.3. Porosity
2.3. Corrosion
3. Joining Technologies for Al/Mg Dissimilar Metals
3.1. Solid-State Welding
3.1.1. Friction Stir Welding
3.1.2. Ultrasonic Welding
3.1.3. Diffusion Bonding
3.1.4. Explosive Welding
3.1.5. Magnetic Pulse Welding
3.2. Fusion Welding
3.2.1. Laser Welding
3.2.2. Arc Welding
3.2.3. Resistance Spot Welding
3.3. Brazing
3.4. Mechanical Joining: Riveting
4. Comparison of Different Al/Mg Joining Technologies
5. Long-Term Service Performance
5.1. Corrosion Behavior
5.2. Fatigue Behavior
5.3. Thermal Exposure
6. Numerical Simulation and Data-Driven Prediction
6.1. Multiphase-Field Modeling
6.2. CFD Modeling
6.3. Finite Element Modeling
6.4. Molecular Dynamics Simulation
6.5. Data-Driven Prediction and Parameter Optimization
7. Conclusions and Outlook
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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| Material | Tm (°C) | Tb (°C) | k (W/(m·K)) | Cp (J/(kg·K)) | CTE (10−6/K) | Crystal Structure | Atomic Radius (10−10 m) | Main Oxide | Oxide Tm (°C) |
|---|---|---|---|---|---|---|---|---|---|
| Al | 660 | 2470 | 207–237 | 935 | 23.8 | FCC | 1.43 | Al2O3 | >2000 |
| Mg | 648.8 | 1090 | 145–156 | 1087 | 25.8 | HCP | 1.36 | MgO | >2000 |
| Parameter | Material | Optimal Parameters | Strength/Load | Ref. |
|---|---|---|---|---|
| Material position, tool offset, rotation and welding speed | 6061-T6 Al/AZ31B Mg (t = 3/3 mm) | Mg located on AS; tool offset toward Mg side: 0.3 mm; 700 rpm; 50 mm/min | 175 MPa | [33] |
| Tool rotation speed | AA1050 Al/AZ91 Mg (t = 3/3 mm) | 600 rpm; 23.5 mm/min | 1977.9 N | [35] |
| Pin length and rotation speed | AA6061-T6 Al/AZ31B-H24 Mg (t = 3/3 mm) | 4.25 mm pin; 600 rpm; 100 mm/min; 2.5° tilt angle | 212 ± 6 N/mm | [36] |
| Pin length and material configuration | Al/Mg (t = 3/3 mm) | Mg/Al; 3.8 mm pin; 800 rpm; 30 mm/min | 246 N/mm | [37] |
| Pin profile | 5A06 Al/AZ80 Mg (t = 5/5 mm) | T-pin; 1180 rpm; 75 mm/min | 3.425 kN | [38] |
| Rotation speed and welding speed | AZ91D Mg/AA7075 Al (t = 6.35/6.35 mm) | 800 r/min; 20 mm/min | 116.64 MPa | [39] |
| Variable-pitch thread pin and material configuration | 6061-T6 Al/AZ31 Mg (t = 3/3 mm) | Mg-Al configuration; variable-pitch thread pin; 700 rpm; 100 mm/min; 2.5° tilt angle | 217 N/mm | [20] |
| Single-pass/double-pass welding; rotation speed and welding speed | Al 5754-H111/AZ31-O Mg (t = 4/4 mm) | Single-pass welding; 500 rpm; 45 mm/min | 3.2 kN | [40] |
| Interlayer | Material System | Bonding Conditions (°C/MPa/min) | Interfacial IMCs | Max. Shear Strength (MPa) | Ref. |
|---|---|---|---|---|---|
| Ni | Al1060/Mg | 440/1/90 | Al3Ni2, Al3Ni, Mg2Ni | 20.5 | [77] |
| Cu | Pure Al/Pure Mg | 480/15/90 | CuAl2, CuAl, Cu4Al3, Mg–Cu compounds | 31.2 | [78] |
| Ni/Cu | 2A12/AZ31 | 460–520/10/60 | Al3Ni2, Al3Ni, Mg2Ni, Mg3AlNi2 | 53.78 | [79] |
| Zn | Al5083/ZK60 | 365, 335/4/120 | α-Al + MgZn2, Al–Zn eutectoid products, MgZn2 | 38.6 | [80] |
| Zn/Sn | 5083Al/AZ31 | 200, 339/4/60 + 120 | Mg(Zn), α-Mg + Mg7Zn3 + τ, Mg–Al–Zn solid solution | 76.8 | [81] |
| AgCuZn | 3003/AZ31 | 420/8/120 | Al solid solution diffusion zone, Ag3Mg + CuMg2 | 66 | [82] |
| Ti | AA6060/AZ31B | 415/8.5/60 | Al3Mg2, Al12Mg17 | 48.3 | [83] |
| Ag | Al5083/AZ31C | 470/1/60 | MgAg, Mg3Ag, Ag2Al | 31.6 | [84] |
| Zn–2Bi | 5083Al/AZ31 | 335/4/360 | Al(Zn) solid solution, Al–Zn eutectoid products, MgZn2 | 20 | [85] |
| Ni/Al | Pure Al/Pure Mg | 430/1/60 | Al3Ni, Al3Ni2, Mg–Al–Ni compounds | 24.8 | [77] |
| Interlayer | Process | Reaction Products | Reported Joint Performance | Engineering Advantage | Main Limitation | Ref. |
|---|---|---|---|---|---|---|
| Ti–Ni composite foil | LBW | TiAl, Ti3Al, Al3NiTi2 | 145.76 MPa | Improved barrier continuity by Ti–Ni combined reactions | More complex preparation; barrier failure may form Mg–Al IMCs | [102] |
| Ti foil | CW-LW + filler | Ti3Al, TiAl3 | 1684 N/cm | Blocks direct Al–Mg reaction; supports Mg/Ti and Ti/Al bonding | Ti layer may fail under excessive heat input | [100] |
| Ti foil | LAHW + LBO | Al–Mg–Ti reaction layer | — | Improves Ti-layer heating uniformity and interface continuity | Ti-layer continuity remains heat-input sensitive | [109] |
| Ni interlayer | LW/B | MgNi2, Mg2Ni, AlNi | 410 ± 25 N | Promotes Mg–Ni and Al–Ni reactions; reduces direct Al–Mg reaction | Hard Ni-containing phases may weaken local regions | [101] |
| Ni interlayer | DMP-LW | Al–Ni reaction products | — | Separates Mg-side and Al-side molten pools | Fracture may occur near hard Al–Ni products | [112] |
| CoCrFeNi medium-entropy alloy powder | LBW | Al-rich AlxCoCrFeNi phase | 100.12 MPa | Flexible composition design; possible solid-solution strengthening | Powder uniformity and repeatability remain difficult | [104] |
| Ti/V/Cr mixed powder | LBW | In situ AlCrTiV solid solution | 1122.56 N | Strong multi-element interface regulation | Powder handling and cost are relatively high | [105] |
| V foil | IR–blue HLBW | V–Al reaction products | 1.85 kN | Improves keyhole stability and Mg evaporation behavior | Higher material cost and process complexity | [111] |
| Materials | Process | Main Process Parameters | Strength/Load | Ref. |
|---|---|---|---|---|
| 0.2 mm AZ31B Mg/0.2 mm 6061 Al | NS-PLW | P = 25 W; v = 30 mm/s; f = 20 kHz; pulse width = 10 ns; line spacing = 0.2 mm; defocus = 0 | 76.5 N | [21] |
| 0.2 mm AZ31B Mg/0.2 mm 6061 Al | NS-PLW | P = 25 W; v = 30 mm/s; f = 20 kHz; line spacing = 0.04 mm; energy density ≈ 459.4 J/mm2 | 121.5 N | [97] |
| 0.2 mm AZ31B Mg/0.2 mm 6061 Al | PLW | P = 25 W; v = 50 mm/s; f = 20 kHz; pulse width = 10 ns; line spacing = 0.2 mm; defocus = 0 | 101.5 N | [98] |
| 2 mm 6061-T6 Al/2 mm AZ31B Mg; 0.1 mm Ti foil | 8-shaped LBO | P = 3.1 kW; v = 1.8 m/min; defocus = +4 mm; r = 0.2 mm; L = 2 mm; Ar = 20 L/min | 4.4 kN | [11] |
| 2 mm AZ31B Mg/2 mm 6061 Al | Infinite-shaped LBO | P = 2100 W; v = 30 mm/s; A = 2.0 mm; f = 100 Hz | 163.6 MPa | [99] |
| 1.5 mm AZ31 Mg/1.5 mm 6061 Al; 0.5 mm Ti interlayer; 1.2 mm AZ61 filler wire | CW-LW | P = 1600 W; v = 200 mm/min; wire feed speed = 1200 mm/min; defocus = +5 mm; Ar = 20 L/min; Ti IL = 0.5 mm | 1684 N/cm | [100] |
| 1.5 mm AA5182 Al/1.5 mm ZEK100 Mg; 0.2 mm Ni interlayer; 1.6 mm ZnAl22 filler wire | LBW + Ni IL | P = 2.2 kW; v = 0.2 m/min; He = 15 L/min; Ni IL = 0.2 mm; ZnAl22 filler = 1.6 mm | 410 ± 25 N | [101] |
| 2 mm AZ31 Mg/2 mm 5A06 Al; Ti–Ni interlayer, 0.08 mm Ti + 0.02 mm Ni | LBW | P = 1617 W; v = 30 mm/s; spot diameter = 0.2 mm; defocus = 0; Ar = 15 L/min; Ti–Ni IL intact | 145.76 MPa | [102] |
| 1.5 mm AZ31 Mg/1.5 mm 6061 Al; 0.1 mm Cu foil | 8-shaped LBO | P = 1190 W; v = 30 mm/s; A = 1.5 mm; f = 60 Hz; defocus = 0; Ar = 20 L/min; Cu IL = 0.1 mm | 784.1 N | [103] |
| 2 mm AZ31B Mg/2 mm 5A06 Al; 200 μm CoCrFeNi MEA powder layer | LBW | P = 1300 W; v = 70 mm/s; spot diameter = 83 μm; wavelength = 1080 nm; Ar = 15 L/min; MEA layer = 200 μm | 100.12 MPa | [104] |
| 2 mm AZ31B Mg/2 mm 5A06 Al; 0.1 mm Ti/V/Cr mixed-powder interlayer | LBW | P = 1155 W; v = 35 mm/s; spot diameter = 0.2 mm; defocus = 0; Ar = 15 L/min; Ti/V/Cr powder layer = 0.1 mm | 1122.56 N | [105] |
| 2 mm AZ31 Mg/1.5 mm 6061 Al; 2 mm Zn filler wire | LO-TIG | P = 400 W; v = 800 mm/min; pulse duration = 3 ms; f = 30 Hz; TIG current = 80 A; DLAP = 2 mm | 1190 N/cm | [107] |
| 1.5 mm AZ31 Mg/1.5 mm 6061 Al; 0.1 mm Ti foil | MF-assisted LBW | P = 1400 W; v = 30 mm/s; defocus = +1 mm; laser head angle = 20°; MF = 30 mT; Ti IL = 0.1 mm | 887.79 N | [110] |
| 1.5 mm AZ31 Mg/1.5 mm 6061 Al; 0.1 mm V foil | IR–blue hybrid LBW | P = 1200 W; IR = 1140 W; blue laser = 60 W; v = 30 mm/s; Ar = 20 L/min; V IL = 0.1 mm | 1.85 kN | [111] |
| Process | Joining Time | Applicability | Industrial Scalability | Equipment Cost | Environmental/Safety Concern | Ref. |
|---|---|---|---|---|---|---|
| FSW | Medium, usually seconds to minutes | Suitable for sheets and plates; effective for butt and lap joints | High for linear welds and plate structures; limited for complex three-dimensional paths | Medium; tool wear and rigid fixturing should be considered | Low fume emission; rotating tool, clamping force, and tool wear require process control | [33,41,56] |
| USW | Very short, usually seconds | Suitable for foils, thin sheets, battery tabs, and localized lap joints | High for small components and tab-type joints; restricted by sonotrode size and joint geometry | Low to medium; sonotrode and power system are required | Noise and mechanical vibration; excessive energy may cause indentation or local damage | [63,67,71] |
| DB | Long, usually minutes to hours | Suitable for precision joining, laminated structures, and small-batch components | Low to medium; limited by long holding time, surface preparation, pressure, and vacuum/inert atmosphere | High; vacuum furnace, pressure system, and thermal control are required | High energy consumption; vacuum or inert gas protection is usually needed | [73,79] |
| EXW | Instantaneous, usually microseconds to milliseconds | Suitable for large-area clad plates and layered structures | Medium; useful for large plates but difficult for small, complex, or precision components | Medium to high; explosive setup, tooling, and safety facilities are required | Explosion shock, noise, dust, and strict safety qualification requirements | [87,88,91] |
| MPW | Instantaneous, usually microseconds | Suitable for sheets and tubes with controlled gap and good electrical conductivity | Medium; promising for high-speed joining, but sensitive to assembly accuracy and coil design | High; capacitor bank, coil, and high-voltage system are required | High-voltage electromagnetic system; coil damage and impact safety should be considered | [13,94,95] |
| LBW | Short, usually seconds | Suitable for precise, automated, and localized joining; adaptable to beam oscillation, interlayers, and hybrid beams | High for automated production, but the process window is narrow for Al/Mg joining | High; laser source, optics, shielding, and beam-control systems are required | Laser safety, Mg evaporation, spatter, porosity, shielding gas use, and fume extraction | [21,100,111] |
| AW | Medium, usually seconds to minutes | Suitable for lap and butt joints; CMT is more favorable than conventional TIG/MIG because of lower heat input | Medium to high; equipment is mature, but Al/Mg reaction control remains difficult | Medium; arc power source, wire feeding, shielding, and fixtures are needed | Arc radiation, fume, shielding gas consumption, and filler-related environmental concerns | [117,120,124] |
| RSW | Very short, usually milliseconds to seconds | Suitable for local lap joints and automotive spot-joining lines | High for spot joining; limited for wide-area continuous bonding | Medium; electrode, power supply, and pressure system are required | High current, electrode wear, spatter, Mg-side melting, and local porosity | [125,131] |
| Brazing | Medium, usually seconds to minutes depending on heating and ultrasonic assistance | Suitable for low-temperature joining and reduced base-metal melting; useful for thin sheets and temperature-sensitive structures | Medium; filler selection and wetting stability are key constraints | Low to medium; filler metals, heating system, and sometimes ultrasonic equipment are required | Possible flux/filler residues; brittle Mg2Sn/MgZn2 phases and filler-related issues should be controlled | [137,140] |
| SPR | Very short, usually seconds | Suitable for multi-material sheet assembly, especially automotive structures; F-SPR improves Mg sheet formability | High for mechanical assembly; local joint quality depends on rivet, die, and stack sequence | Low to medium; rivets, dies, and riveting equipment are required | Rivet-induced damage, galvanic corrosion, lap-gap corrosion, adhesive aging, and cyclic-load degradation | [148,150,151] |
| Descriptor | Recommended Focus | Reliability Implication | Ref. |
|---|---|---|---|
| IMC phase type | Identify Al3Mg2, Al12Mg17 and interlayer-derived phases such as Mg2Ni, AlNi, Mg2Cu, MgZn2, Mg2Sn, or multi-element phases | Different phases show different brittleness, corrosion sensitivity, and fracture tendency | [29,101,105,141] |
| Thickness distribution | Report average thickness and local maximum thickness, rather than only a single mean value | Local thickening may control crack initiation more directly than average thickness | [22,73] |
| Continuity and morphology | Distinguish continuous, semi-continuous, discontinuous, lamellar, island-like, or interlocking products | Continuous brittle layers provide preferential crack-propagation paths | [56,61,93] |
| Defect coupling | Observe whether IMCs are connected with pores, oxide inclusions, cracks, voids, or unbonded regions | Coupled defects reduce effective bonded area and accelerate interfacial failure | [21,31,131] |
| Fracture-path relation | Compare fracture surface and post-fracture cross-section | Fracture inside IMCs or along IMC/matrix interfaces indicates poor interfacial reliability | [42,67,124] |
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Qiu, T.; Osman Zahid, M.N.B. Recent Advances in Joining Technologies for Aluminum/Magnesium Dissimilar Metals: A Review. Metals 2026, 16, 804. https://doi.org/10.3390/met16070804
Qiu T, Osman Zahid MNB. Recent Advances in Joining Technologies for Aluminum/Magnesium Dissimilar Metals: A Review. Metals. 2026; 16(7):804. https://doi.org/10.3390/met16070804
Chicago/Turabian StyleQiu, Tianwei, and Muhammed Nafis Bin Osman Zahid. 2026. "Recent Advances in Joining Technologies for Aluminum/Magnesium Dissimilar Metals: A Review" Metals 16, no. 7: 804. https://doi.org/10.3390/met16070804
APA StyleQiu, T., & Osman Zahid, M. N. B. (2026). Recent Advances in Joining Technologies for Aluminum/Magnesium Dissimilar Metals: A Review. Metals, 16(7), 804. https://doi.org/10.3390/met16070804

