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Open AccessArticle

Reducing the Magnesium Content from Seawater to Improve Tailing Flocculation: Description by Population Balance Models

1
Water Research Center for Agriculture and Mining (CRHIAM), Concepción 4030000, Chile
2
Faculty of Engineering and Architecture, Universidad Arturo Prat, Almirante Juan José Latorre 2901, Antofagasta 1244260, Chile
3
Departamento de Ingeniería Química y Procesos de Minerales, Facultad de Ingeniería, Universidad de Antofagasta, Av. Angamos 601, Antofagasta 1240000, Chile
4
Departamento de Ingeniería Metalúrgica y Minas, Universidad Católica del Norte, Antofagasta 1270709, Chile
5
Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, Valparaíso 2340000, Chile
*
Author to whom correspondence should be addressed.
Metals 2020, 10(3), 329; https://doi.org/10.3390/met10030329
Received: 18 January 2020 / Revised: 19 February 2020 / Accepted: 24 February 2020 / Published: 2 March 2020
(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)
Experimental assays and mathematical models, through population balance models (PBM), were used to characterize the particle aggregation of mining tailings flocculated in seawater. Three systems were considered for preparation of the slurries: i) Seawater at natural pH (pH 7.4), ii) seawater at pH 11, and iii) treated seawater at pH 11. The treated seawater had a reduced magnesium content in order to avoid the formation of solid complexes, which damage the concentration operations. For this, the pH of seawater was raised with lime before being used in the process—generating solid precipitates of magnesium that were removed by vacuum filtration. The mean size of the aggregates were represented by the mean chord length obtained with the Focused beam reflectance measurement (FBRM) technique, and their descriptions, obtained by the PBM, showed an aggregation and a breakage kernel had evolved. The fractal dimension and permeability were included in the model in order to improve the representation of the irregular structure of the aggregates. Then, five parameters were optimized: Three for the aggregation kernel and two for the breakage kernel. The results show that raising the pH from 8 to 11 was severely detrimental to the flocculation performance. Nevertheless, for pH 11, the aggregates slightly exceeded 100 µm, causing undesirable behaviour during the thickening operations. Interestingly, magnesium removal provided a suitable environment to perform the tailings flocculation at alkaline pH, making aggregates with sizes that exceeded 300 µm. Only the fractal dimension changed between pH 8 and treated seawater at pH 11—as reflected in the permeability outcomes. The PBM fitted well with the experimental data, and the parameters showed that the aggregation kernel was dominant at all-polymer dosages. The descriptive capacity of the model might have been utilized as a support in practical decisions regarding the best-operating requirements in the flocculation of copper tailings and water clarification. View Full-Text
Keywords: copper tailings; enhanced flocculation; water recovering; magnesium removal; population balance model; seawater flocculation copper tailings; enhanced flocculation; water recovering; magnesium removal; population balance model; seawater flocculation
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MDPI and ACS Style

Quezada, G.R.; Jeldres, M.; Toro, N.; Robles, P.; Jeldres, R.I. Reducing the Magnesium Content from Seawater to Improve Tailing Flocculation: Description by Population Balance Models. Metals 2020, 10, 329.

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