Geochemical Characteristics and Chemostratigraphic Analysis of Wufeng and Lower Longmaxi Shales, Southwest China

The demand for shale gas has propelled researchers to focus on precise and high-resolution stratigraphic divisions for homogeneous shales, of which the late-Ordovician Wufeng (O₃w) and the early-Silurian Longmaxi (S₁l) formations in southwest China are two of the best candidates for shale gas exploration in China. However, systematic chemostratigraphic work for these strata is still sparse, and the existing chemostratigraphic work either lack representativeness in terms of the proxies used or are subjective during their division procedures. Thus, automatic division process based on multi proxies and an objective statistical technique was applied to establish a quantitative, high-resolution, and robust chemostratigraphic scheme for the Wufeng and lower Longmaxi shales. The geochemical analysis unveils that the Wufeng and Lower Longmaxi shales show prominent heterogeneities in terrigenous inputs, redox conditions, and paleoproductivity, enabling the potential application of chemostratigraphy to these strata. Based on these heterogeneities, the chemostratigraphic scheme for the Wufeng and Lower Longmaxi shales has been established, and the whole strata could be divided into 13 chemozones using constrained clustering analysis. The chemostratigraphic scheme could not only be comparable to the regional sequence stratigraphic scheme but also more objective and higher-resolution. The high TOC content and brittle minerals within chemozone C1 makes it the most preferable layer for shale gas exploration and development. This research gives a systematic chemostratigraphic analysis on Wufeng and Lower Longmaxi shales, which testifies the feasibility and potential of usage of chemostratigraphy for Chinese shale gas exploration and development.