U-Pb Dating and Geochemical Characteristics of Zircon and Apatite from Ore-Bearing Porphyry of Huxu Au-Dominated Polymetallic Deposit in Dongxiang Volcanic Basin, South China

The Huxu Au-dominated deposit is a representative intermediate sulfidation epithermal deposit in the middle section of the Gan-Hang belt. The formation of such deposits is commonly closely related to deep magmatism. However, the specific relationship between the formation of the Huxu deposit and the magmatic rocks, and the tectonic setting of the related magmatism and mineralization in this deposit still remains unclear. In this study, we present the results of U-Pb dating, major and trace element analysis, and Nd isotope analysis of the magmatic zircon and apatite from the ore-bearing quartz diorite porphyry in the Huxu deposit. The results show that the U-Pb ages of zircon and apatite from the quartz diorite porphyry are 137.9 ± 1.3 Ma and 130 ± 16 Ma, respectively; the total content of rare earth elements (ΣREEs) in the zircons ranges from 446.66 to 2752.92 ppm, exhibiting enrichment in heavy REE and depletion in light REE, with a slightly negative Eu anomaly and a slightly positive Ce anomaly; the ΣREEs in the apatite is relatively high, ranging from 3252.02 to 13,155.92 ppm, averaged 5604.16 ppm, and exhibits a right-leaning mode with light REE enrichment and heavy REE depletion, with a moderate degree of negative Eu anomaly; the distribution of ¹⁴³Nd/¹⁴⁴Nd ratios of the apatite is rather concentrated (0.512145–0.512271), and the εNd(t) value calculated based on the U-Pb age of apatite ranges from −8.31 to 5.79. By combining the geological characteristics and the geochemical data of the deposit and the ore-bearing magmatic rocks, we propose that the ore-bearing quartz diorite porphyry of the Huxu Au-dominated polymetallic deposit belongs to I-type granite; the parental magma is the mixture of juvenile and ancient crustal melts; the tectonic setting of the intrusion and mineralization is the continental margin arc related to the subduction of the ancient Pacific Ocean Plate in the Early Cretaceous Epoch; and the ore-forming fluids and metals are provided by deep magma.