1. Introduction
Air pollution has remained a major concern in recent decades and unfavorably affects the health of residents living in both developed and underdeveloped countries [
1,
2,
3]. Millions of people worldwide are exposed to high levels of air pollution, which has raised human health concerns. Some of the contemporary environmental threats resulting from the consequences of human activities include greenhouse effects, ozone holes, acid rain, deforestation and photochemical smog as a main responsible threat. The combined effect of ambient (outdoor) and household (indoor) air pollution poses a major threats to health and environment. In 2014, approximately 92% of the global population resided in areas where World Health Organization (WHO) air pollution standards were not satisfied [
4,
5]. Rapid population growth and industrial development have led to an increase in pollution rates. According to the WHO, particle pollution, ground-level ozone (
), sulfur dioxide (
), nitrogen dioxide (
), and carbon monoxide (
) have been monitored. In addition, other pollutants occur in air comprising suspended material, such as dust, gaseous pollutants, smoke, hydrocarbons, fumes, volatile organic compounds (
), polycyclic aromatic hydrocarbons (
), and halogen derivatives, which may cause vulnerability to many diseases at high concentrations [
6]. Moreover, Alsaber et al. [
7] detected an increased risk of rheumatoid arthritis (RA) in subjects exposed to
through evaluation of the disease activity score with 28 examined joints (DAS-28), and based on the Kuwait Registry for Rheumatic Diseases, they described the detrimental effects of short-term exposure to
and
on RA progression, while no correlation was found in regard to particulate matter with an aerodynamic diameter smaller than 10 microns (
),
and CO. Over the last few decades, Kuwait has experienced rapid socioeconomic and infrastructure development. The steady increase in its population, human activities, transportation fleet and power demand has contributed to environmental air pollution in Kuwait [
8,
9]. The major sources of air pollution in Kuwait include petrochemical plants, power plants, refineries and gasoline and diesel vehicles. The large number of motorized vehicles and construction expansion in industrial areas have greatly contributed to an increase in the air pollution level. In a study by [
10], Kuwait was found to be the most polluted country in Southwest Asia. In July 2018, Kuwait recorded the highest air quality index (AQI) value, i.e., 301, which is hazardous and associated with serious health effects. The daily and annual concentrations of particulate matter with an aerodynamic diameter of at least 2.5 (
) and
in Kuwait exceeded the threshold values (daily mean
: 10
; 24-h mean
: 25
; daily mean
: 20
; 24-h mean
: 25
) defined by the WHO [
11]. The chemical composition of these particulates in dust fallout and reported high concentrations of calcite and quartz [
12]. They concluded that long-term exposure to these particulates could cause serious respiratory effects. Several studies on air pollution in Kuwait indicated a notable increase in various air pollutants, such as methane (
),
,
,
, nitrogen oxides (
) and total sulfur (
), over a certain period [
13,
14,
15,
16]. Another study demonstrated that traffic was the major source of air pollution in the district adjacent to the Kuwait City center, while oil refineries contributed the most to the ambient air pollution level in a rural district [
17]. Albassam et al. [
18] studied three pollutants, namely,
,
and nonmethane hydrocarbons (
), in the vicinity of a congested area in Kuwait. They found that the
concentration was much higher than the corresponding standard limit defined by the Environmental Public Authority of Kuwait (K-EPA) (an hourly maximum of 3.65 ppm and a daily average value of 1.6 ppm), which corresponded to the traffic conditions in the area. The authors focused on the impact of urban growth resulting in vehicle fleet increase in two case studies involving residential areas. They recorded excess
and
concentrations in both case studies. To date, no major analysis has been performed of air pollution in both industrial and residential areas, thereby identifying the sources of pollutants in Kuwait. Consequently, the aim of the present study is to measure the concentration of certain major air pollutants in industrial and residential areas. The pollutants addressed are
, nitrogen monoxide (
),
,
,
, benzene (
),
and
, while weather variables, such as the temperature, humidity and wind speed, were also considered.
This paper presents air pollution measurements from 2012 to 2017 based on ten monitoring stations at various locations across Kuwait. The monitoring stations were categorized into two distinct categories: the first category was defined as residential areas (including seven stations), and the second category was defined as industrial areas (including three stations). The main objective of this study is to analyze the associations with meteorological variables (wind speed, wind direction, temperature and relative humidity) on the concentrations of pollutants , and , , , , and in Kuwait via exploratory data analysis techniques. Additionally, the pollutant concentrations in residential and industrial areas were compared.
3. Results
Table 1 summarizes the results of the descriptive statistics of the individual pollutants (
,
,
,
,
,
,
,
and
) over the six-year study period (2012–2017), including the average, S.D., percentiles, and maximum and minimum values. The results indicated that the average concentrations of air pollutants
,
,
and
during the 2012–2017 study period were
,
,
and
, respectively, with corresponding maximum values of 0.03, 0.42, 1.03 and 1.21, respectively. Furthermore, in the Kuwait environment, the average concentrations of air pollutants
,
and
were
,
and
, respectively, with corresponding maximum values of 68.98, 75.22 and 59.42, respectively. The average concentrations recorded for air pollutants
and
were
and
, respectively, with corresponding maximum values of 0.37 and 0.05, respectively.
Table 2 summarizes the comparison results between the industrial and residential stations corresponding to the studied pollutants. Independent sample
t-test was conducted to compare the mean differences between industrial and residential stations in term of pollutants concentration. The daily mean difference among all air pollutants was significant, i.e., in terms of
,
,
,
,
,
, and
, which also applied to weather parameter humidity. The analysis indicated high concentrations of
,
,
,
and
in the residential areas, whereas the daily
and
concentrations were high in the industrial areas. The difference in daily concentration between air pollutants
and
was statistically insignificant. The recorded daily average
,
,
,
and
concentrations in the residential areas were
,
,
,
and
, respectively, whereas the
and
concentrations in the industrial areas reached
and
, respectively.
The study results demonstrated that the overall daily average and concentrations were lower than the corresponding K-EPA standard values in both the industrial and residential areas. Furthermore, the daily concentration exceeded the K-EPA threshold value in the residential areas, while the daily concentration exceeded the K-EPA threshold value in both the industrial and residential areas.
Table 3 presents the descriptive statistics of the meteorological parameters (the wind speed, temperature and relative humidity). The results revealed that the average value of the wind speed, temperature and relative humidity during the 2012–2017 period was
,
and
, respectively.
Appendix A provides the daily average concentration of the studied pollutants in the industrial areas. The comparison results were significant and indicated a significant difference among the air pollutants in the considered industrial areas. The daily concentrations of
,
and
were lower than the K-EPA standard values defined for industrial areas except for the SUK site, where the daily
concentration matched the K-EPA standard value of
. The daily concentration of
at all the sites exceeded the corresponding threshold value defined by the K-EPA. Additionally, the results demonstrated that the daily average humidity and wind speed were high at the SUB site, whereas the daily temperature was high at the SUK site.
Appendix B lists the daily average concentration of the studied pollutants at the residential stations. The comparison results were significant and indicated a significant difference among the air pollutants in the considered residential areas. The daily concentrations of
,
and
at all the sites exceeded the corresponding threshold values defined by the K-EPA for residential areas except for the JAH site, where the daily concentration of
was lower than the standard value. Moreover, corresponding to the air pollutant
, the average daily concentration was lower than the standard value in all the residential areas, while the standard value was nearly matched at only the FAH site. The results also demonstrated that the daily average humidity was high at the RUM site, whereas the daily temperature and wind speed were high at the SAA and FAH stations, respectively.
Values of the Pearson correlation coefficient are listed in
Table 4, indicating the variation in each pollutant to that in the other air pollutants. If a given pollutant attains a strong correlation with other pollutants, it may thus be deduced that these pollutants most likely originate from the same emission source, while a low correlation coefficient value suggests different emission sources. The analysis results revealed a significantly high correlation between
and
(
), followed by that between
and
(
), suggesting a notable dependence. Moreover, the determined high correlation coefficient value indicated a high possibility of the same emission sources for
,
and
.
The correlation among the remaining air pollutants was not strong, indicating a high possibility of different emission sources. However, the analysis results revealed a relatively high correlation between
and
, since the presence of
in the air is a result of the No oxidation reaction in the surrounding air (
), followed by that between ozone (
) and temperature (
). Ozone production accelerates at high temperatures in summer. Short-term exposure to zone has been linked to adverse health effects [
25].
The obtained values of the correlation coefficients were also significant for all the air pollutants except for the association between
,
and
and
and that between
and
, which were statistically insignificant at
. We can see from
Table 4 that most of the pollutants resulted negative correlation with atmospheric temperature and relative humidity; however, they showed variable response to seasonal variation of meteorological parameters and this results agreed with [
26].
The analysis results indicated that the average daily concentration of pollutant was below the K-EPA daily standard value of for industrial areas (0.065 ppm), but it exceeded the allowable range defined for residential areas (0.030 ppm). The analysis also indicated that the daily concentration of air pollutant matched the K-EPA standard level of (0.030 ppm), whereas in regard to , it exceeded the threshold value (0.09 ). Additionally, the results demonstrated that the average daily concentration of this pollutant was below the K-EPA daily standard value (0.08 ). and were characterized by the highest measurements, while the and measurements were the lowest.
Figure 3 shows the trend of the air pollutant components during the period from 2012–2017. The observed trend demonstrated that the concentrations of pollutants
,
,
,
and
were the lowest from 2016–2017, except pollutant
, which exhibited an increasing trend before the beginning of 2017. Furthermore, it was observed that air pollutants
and
exhibited a decreasing trend for the period from 2013–2016 and then an increasing trend in 2017. It was also found that the
concentration reached its highest level at a certain point during the period from 2014–2015. The analysis trend did not reveal a consistent pattern for all the pollutants.
Figure 3 shows that the
,
and
concentrations were lower than
ppm,
ppm and
ppm, respectively.
and
did not reveal any trend during the period from 2014–2016 because of missing data values. It should be noted that due to the missing
data and the importance of
, it is preferable to replace
with
.
The daily, hourly, weekly and monthly mean variations in the pollutant concentration are shown in
Figure 4,
Figure 5 and
Figure 6. In regard to
,
and
, the two highest mean values were recorded in the months of January and December, and the lowest
and
concentrations were recorded in June, whereas the
concentration was the lowest during the period from June to July. The
concentration exhibited the reverse pattern to that of
,
and
. The
concentration peaked in July, and it gradually decreased thereafter until the end of the year, when the lowest
concentration was recorded in January and December.
Figure 5 shows that the concentration of pollutant
was the highest, followed by
and
. The figure shows that the
and
concentrations were high in the winter season and low in the summer season, whereas
exhibited the opposite trend, where the concentration was high during the summer period and low during the winter period.
Generally, regarding , a high mean concentration occurred in early summer (June and August), with low mean values observed in winter (November–February). In the present study, low nitrogen oxide emission levels (, and ) were observed in the winter. This may occur because of the very mild temperatures in Kuwait during the winter, which led to a very low energy demand for heating purposes and resulted in lower nitrogen oxide emission rates. However, during the summer season, a higher energy consumption was observed because of the intense and continuous use of air conditioners. A large amount of energy is required to operate this equipment, provided by the combustion of large amounts of fuel, resulting in an increase in the nitrogen oxide emission rates (, and ).
Figure 5 shows that the concentration of pollutant
was the highest, followed by
and
. The figure reveals that the
and
concentrations were high in the winter season and low in the summer season, whereas
exhibited the reverse trend. In regard to
, the concentration was high during the summer period and low during the winter period.
Figure 6 shows that the
pollution level was the highest in the summer months (April and June–July), while it was the lowest in the months of February and November. The average concentration of pollutant
was low throughout the entire study period (2012–2017).
Description of Exposure Data
Box plots of the monthly pollutant concentration after suitable transformation from 2012 to 2017 are shown in
Figure 7. Box plots constitute a method to graphically depict data based on a five-number summary (minimum, first quartile (Q1), median, third quartile (Q3), and maximum).
Figure 8 shows the air pollutant concentration in the form of polar coordinates throughout the study period from 2012–2017. A polar plot shows a graphical analysis of a given database rather than a quantitative analysis. It is constructed based on the average pollutant concentration as a function of the wind speed.
Figure 8 shows that the concentrations of pollutants
and
exhibited almost the same pattern. The concentration of these pollutants was higher at a wind speed of 5 m/s from west to east and the lowest at the northwest site. The polar plots for
,
and
with slight variations revealed low pollutant concentrations at wind speeds ranging from 5–10 m/s. However, high
concentrations were also observed at certain points along the southeast direction. The polar plot for
demonstrated a uniform contribution along all wind directions, except for a slightly low concentration along the east-north direction and a high concentration at a few points in time along the southeast direction at wind speeds ranging from 20–25 m/s. The high concentrations of these pollutants at low wind speeds suggested that these air pollutants may be dispersed at high wind speeds.
The State of Kuwait faces a growing risk of health-related problems due to the poor air quality originating from its various industrial and domestic activities. Dust stemming from adjacent deserts passing through areas containing industrial emission sources may carry both living (biogenic) and nonliving (chemical) constituents. Regular monitoring and careful statistical examination of all measured air pollutants could help in maintaining a clean healthy environment and resolving pollution-related problems in a timely manner. In the present study, time series statistical testing revealed low nitrogen oxide emission levels (, and ) in the winter. This may occur because of the very mild temperatures in Kuwait during the winter, which led to a very low energy demand for heating purposes and resulted in lower nitrogen oxide emission rates. However, in the summer season, a higher energy consumption was observed because of the intense and continuous use of air conditioners. A large amount of energy is required to operate air conditioners, provided by the combustion of large amounts of fuel, resulting in an increase in the nitrogen oxide emission rates (, and ). In addition, This could be due to their locations near highways and oil industries centers. Petrochemical industries and oil refineries in southern Kuwait are major sources of air pollution in the country.