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Two Interpenetrated Zn(II) Coordination Polymers: Synthesis, Topological Structures, and Property
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Coordination Assemblies of Zn(II) Coordination Polymers: Positional Isomeric Effect and Optical Properties

School of Chemistry and Chemical Engineering, Fuyang Normal University, Fuyang 236041, China
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Crystals 2019, 9(12), 664; https://doi.org/10.3390/cryst9120664
Received: 6 November 2019 / Revised: 4 December 2019 / Accepted: 6 December 2019 / Published: 10 December 2019
(This article belongs to the Special Issue Crystal Structure and Thermal Studies of Coordination Compounds)
Two Zn(II) coordination polymers (CPs) [Zn(L)(pphda)] (1) and [Zn(L)(ophda)]·H2O (2) were prepared by reactions of ZnSO4·7H2O based on the N-donor 1,4-di(1H-imidazol-4-yl)benzene (L) ligand and two flexible carboxylic acids isomers of 1,4-phenylenediacetic acid (H2pphda) and 1,2-phenylenediacetic acid (H2ophda) as mixed ligands, respectively. Structures of CPs 1 and 2 were characterized by elemental analysis, Infrared spectroscopy (IR), thermogravimetric analysis and single-crystal X-ray diffraction. The CP 1 is a fourfold interpenetrating 66-diamond (dia) architecture, while 2 is a 2D (4, 4) square lattice (sql) layer based on the Zn2(cis-1,2-ophda2−)2 binuclear Zn(II) subunits. The luminescent property, including luminescence lifetime and quantum yield (QY), have been investigated for CPs 1 and 2. View Full-Text
Keywords: assembly; coordination polymers; optical properties assembly; coordination polymers; optical properties
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MDPI and ACS Style

Liu, C.-J.; Zhang, T.-T.; Li, W.-D.; Wang, Y.-Y.; Chen, S.-S. Coordination Assemblies of Zn(II) Coordination Polymers: Positional Isomeric Effect and Optical Properties. Crystals 2019, 9, 664.

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