Co(II/III) Complexes with Benzoxazole and Benzothiazole Ligands as Efficient Heterogenous Photocatalysts for Organic Dyes Degradation
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Characterization
2.2. Description of the Structures
2.3. Cyclic Voltammetry
2.4. Photostability and Photodegradation Studies
2.5. Optical Properties of Compounds
3. Materials and Methods
3.1. Materials and Physical Measurements
3.2. Synthesis of Ligands
3.3. Synthesis of Complexes (1–3)
3.3.1. Complex 1 [CoIII(L1)2]
3.3.2. Complex 2 [CoIIL2](O2-NO)2
3.3.3. Complex 3 [CoIIL3(O-NO2)2(CH3OH)]
3.4. X-ray Crystallography
3.5. Cyclic Voltammetry
3.5.1. Reagents and Solutions
3.5.2. Electrodes
3.6. Photocatalytic Studies
3.6.1. Photocatalytic and Degradation Experiments
3.6.2. Photostability Experiments
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
Abbreviations
AR18 | Acid Red 18 |
CV | cyclic voltammetry |
DMF | dimethylformamide |
DR | diffuse-reflectance |
RB21 | Reactive Blue 21 |
SCE | saturated calomel electrode |
TBAP | tetrabutylammonium perchlorate |
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Entry | Dye | Source of Irradiation | Type of Photolysis | Kinetic Constant k [min−1] |
---|---|---|---|---|
1 | Reactive Blue 21 | Sunlight | self-decomposition | 7 × 10−4 |
2 | 254 nm | 8 × 10−4 | ||
3 | Sunlight | TiO2-catalyzed | 4.9 × 10−3 | |
4 | 254 nm | 4.1 × 10−3 | ||
5 | Sunlight | 1-catalyzed | 7 × 10−4 | |
6 | 254 nm | 2.5 × 10−3 | ||
7 | Sunlight | 2-catalyzed | 2.6 × 10−3 | |
8 | 254 nm | 1.2 × 10−3 | ||
9 | Sunlight | 3-catalyzed | 5 × 10−4 | |
10 | 254 nm | na * | ||
11 | Acid Red 18 | Sunlight | self-decomposition | 1.5 × 10−3 |
12 | 254 nm | 0.4 × 10−3 | ||
13 | Sunlight | TiO2-catalyzed | 1.6 × 10−3 | |
14 | 254 nm | 0.3 × 10−3 | ||
15 | Sunlight | 1-catalyzed | 6 × 10−4 | |
16 | 254 nm | na * | ||
17 | Sunlight | 2-catalyzed | 2.3 × 10−3 | |
18 | 254 nm | 2.5 × 10−3 | ||
19 | Sunlight | 3-catalyzed | 0–45 min induction period 45–120 min K = 8 × 10−4 | |
20 | 254 nm | na * |
HL1 | L2 | L3 | 1 | 2 | 3 | |
---|---|---|---|---|---|---|
Energy gap [eV] | 1.550 | 2.205 | 1.625 | 1.774 | 1.774 | 1.621 |
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Szymańska, M.; Czepa, W.; Hołubowicz, C.; Świsłocka, R.; Łuczak, T.; Kubicki, M.; Karpińska, J.; Fik-Jaskółka, M.A.; Patroniak, V. Co(II/III) Complexes with Benzoxazole and Benzothiazole Ligands as Efficient Heterogenous Photocatalysts for Organic Dyes Degradation. Catalysts 2019, 9, 913. https://doi.org/10.3390/catal9110913
Szymańska M, Czepa W, Hołubowicz C, Świsłocka R, Łuczak T, Kubicki M, Karpińska J, Fik-Jaskółka MA, Patroniak V. Co(II/III) Complexes with Benzoxazole and Benzothiazole Ligands as Efficient Heterogenous Photocatalysts for Organic Dyes Degradation. Catalysts. 2019; 9(11):913. https://doi.org/10.3390/catal9110913
Chicago/Turabian StyleSzymańska, Martyna, Włodzimierz Czepa, Cezary Hołubowicz, Renata Świsłocka, Teresa Łuczak, Maciej Kubicki, Joanna Karpińska, Marta A. Fik-Jaskółka, and Violetta Patroniak. 2019. "Co(II/III) Complexes with Benzoxazole and Benzothiazole Ligands as Efficient Heterogenous Photocatalysts for Organic Dyes Degradation" Catalysts 9, no. 11: 913. https://doi.org/10.3390/catal9110913