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Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments

Department of Organic Chemistry and Institute of Organic Synthesis (ISO), Faculty of Sciences, University of Alicante, PO Box 99, 03080 Alicante, Spain
Authors to whom correspondence should be addressed.
Catalysts 2018, 8(5), 202;
Received: 19 April 2018 / Revised: 8 May 2018 / Accepted: 9 May 2018 / Published: 11 May 2018
(This article belongs to the Special Issue Solid-Supported Reagents in Palladium-Catalyzed Transformations)


The Sonogashira cross-coupling reaction is the most frequently employed synthetic procedure for the preparation of arylated alkynes, which are important conjugated compounds with multiple applications. Despite of their rather high price, this reaction is usually catalyzed by palladium species, making the recovery and reuse of the catalyst an interesting topic, mainly for industrial purposes. Easy recycle can be achieved anchoring the palladium catalyst to a separable support. This review shows recent developments in the use of palladium species anchored to different solid supports as recoverable catalysts for Sonogashira cross-coupling reactions. View Full-Text
Keywords: palladium; catalysis; Sonogashira reaction; supported reagents; cross-coupling reactions palladium; catalysis; Sonogashira reaction; supported reagents; cross-coupling reactions

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Alonso, D.A.; Baeza, A.; Chinchilla, R.; Gómez, C.; Guillena, G.; Pastor, I.M.; Ramón, D.J. Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments. Catalysts 2018, 8, 202.

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