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Mechanical Retention and Waterproof Properties of Bacterial Cellulose-Reinforced Thermoplastic Starch Biocomposites Modified with Sodium Hexametaphosphate

Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials Ministry of Education, Key Laboratory for the Green Preparation and Application of Functional Materials, Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China
School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China
Department of Materials Engineering, Kun Shan University, Tainan 710710, Taiwan
Graduate School of Material Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan
Author to whom correspondence should be addressed.
Academic Editor: Maryam Tabrizian
Materials 2015, 8(6), 3168-3194;
Received: 7 April 2015 / Revised: 23 May 2015 / Accepted: 27 May 2015 / Published: 2 June 2015
The waterproof and strength retention properties of bacterial cellulose (BC)-reinforced thermoplastic starch (TPS) resins were successfully improved by reacting with sodium hexametaphosphate (SHMP). After modification with SHMP, the tensile strength (σf) and impact strength (Is) values of initial and conditioned BC-reinforced TPS, modified with varying amounts of SHMP(TPS100BC0.02SHMPx), and their blends with poly(lactic acid)((TPS100BC0.02SHMPx)75PLA25) specimens improved significantly and reached a maximal value as SHMP content approached 10 parts per hundred parts of TPS resin (phr), while their moisture content and elongation at break (ɛf) was reduced to a minimal value as SHMP contents approached 10 phr. The σf, Is and ɛf retention values of a (TPS100BC0.02SHMP10)75PLA25 specimen conditioned for 56 days are 52%, 50% and 3 times its initial σf, Is and ɛf values, respectively, which are 32.5 times, 8.9 times and 40% of those of a corresponding conditioned TPS100BC0.02 specimen, respectively. As evidenced by FTIR analyses of TPS100BC0.02SHMPx specimens, hydroxyl groups of TPS100BC0.02 resins were successfully reacted with the phosphate groups of SHMP molecules. New melting endotherms and diffraction peaks of VH-type crystals were found on DSC thermograms and WAXD patterns of TPS or TPS100BC0.02 specimens conditioned for 7 days, while no new melting endotherm or diffraction peak was found for TPS100BC0.02SHMPx and/or (TPS100BC0.02SHMPx)75PLA25 specimens conditioned for less than 14 and 28 days, respectively. View Full-Text
Keywords: waterproof; strength retention; thermoplastic starch waterproof; strength retention; thermoplastic starch
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MDPI and ACS Style

Wang, D.-W.; Xu, Y.-J.; Li, X.; Huang, C.-M.; Huang, K.-S.; Wang, C.-K.; Yeh, J.-T. Mechanical Retention and Waterproof Properties of Bacterial Cellulose-Reinforced Thermoplastic Starch Biocomposites Modified with Sodium Hexametaphosphate. Materials 2015, 8, 3168-3194.

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