The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Instruments
2.2. Synthesis and Initial Characterization
2.3. Determination of Crystal Structure
3. Results and Discussion
3.1. Structure and Characterization
3.2. Thermogravimetric Analysis
3.3. Roles of Organic Amines
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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1 | 2 | 3 | 4 | |
---|---|---|---|---|
Empirical formula | C8N4H34Al2P4O18 | C3N2H17GaP2O8 | H5In2P3O10 | H11In2P3O13 |
Formula weight | 651.96 | 340.83 | 487.59 | 541.62 |
Temperature | 293(2) K | 293(2) K | 293(2) K | 296(2) K |
Wavelength | 0.71073 Å | 0.71073 Å | 0.71073 Å | 0.71073 Å |
Crystal system, space group | Orthorhombic, Pccn | Monoclinic, P21/c | Monoclinic, P21 | Monoclinic, P21 |
Unit cell dimensions | a = 8.2701(12)Å b =16.791(2) Å c = 8.6711(13) Å α = 90.00° β = 99.110(4)° γ = 90.00° | a = 11.084(3) Å b = 7.093(2) Å c = 17.352(4) Å α = 90.00° β = 119.127(14)° γ = 90.00° | a = 6.6057(5) Å b = 10.1900(8) Å c = 7.5004(6) Å α = 90.00° β = 109.4560(10)° γ = 90.00° | a = 8.0064(5) Å b = 10.3793(6) Å c = 8.4640(5) Å α = 90.00° β = 113.3540(10)° γ = 90.00° |
Volume | 1204.1(3) Å3 | 1191.7(5) Å3 | 476.04(6) Å3 | 645.74(7) Å3 |
Z, Calculated density | 2, 1.704 Mg/m3 | 4, 1.889 Mg/m3 | 2, 3.402 Mg/m3 | 2, 2.775 Mg/m3 |
Absorption coefficient | 0.474 mm−1 | 2.606 mm−1 | 5.385 mm−1 | 4.001 mm−1 |
F(000) | 612 | 688 | 456 | 512 |
Crystal size | 0.21 × 0.20 × 0.18 mm3 | 0.22 × 0.20 × 0.19 mm3 | 0.21 × 0.20 × 0.18 mm3 | 0.21 x 0.20 x 0.18 mm3 |
Theta range for data collection | 2.43 to 28.38° | 2.10 to 28.42° | 2.88 to 28.31° | 2.62 to 28.33° |
Limiting indices | −11 ≤ h ≤ 10, −22 ≤ k ≤ 22, −11 ≤ l ≤ 9 | −14 ≤ h ≤ 14, −7 ≤ k ≤ 9, −14 ≤ l ≤ 23 | −7 ≤ h ≤ 8, −12 ≤ k ≤ 13, −10 ≤ l ≤ 7 | −10 ≤ h ≤ 10, −10 ≤ k ≤ 13, −10 ≤ l ≤ 11 |
Reflections collected/unique | 8066/1502 [R(int) = 0.0390] | 8121/2957 [R(int) = 0.0423] | 3502/2023 [R(int) = 0.0182] | 4778/2575 [R(int) = 0.0235] |
Completeness to theta = 28.31 | 99.8% | 98.6% | 99.9% | 100.0% |
Refinement method | Full-matrix least-squares on F2 | Full-matrix least-squares on F2 | Full-matrix least-squares on F2 | Full-matrix least-squares on F2 |
Final R indices [I > 2σ(I)] | R1 = 0.0591, wR2 = 0.1929 | R1 = 0.0882, wR2 = 0.2064 | R1 = 0.0162, wR2 = 0.0408 | R1 = 0.0209, wR2 = 0.0470 |
R indices (all data) | R1 = 0.0698, wR2 = 0.2029 | R1 = 0.0945, wR2 = 0.2075 | R1 = 0.0163, wR2 = 0.0409 | R1 = 0.0219, wR2 = 0.0474 |
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Wang, X.; Dong, Z.; Meng, C.; Wang, W.; Yang, H.; Zhuo, X.; Yang, S. The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates. Materials 2020, 13, 1752. https://doi.org/10.3390/ma13071752
Wang X, Dong Z, Meng C, Wang W, Yang H, Zhuo X, Yang S. The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates. Materials. 2020; 13(7):1752. https://doi.org/10.3390/ma13071752
Chicago/Turabian StyleWang, Xuelei, Zhaojun Dong, Chao Meng, Wei Wang, Hairui Yang, Xizhun Zhuo, and Shaobin Yang. 2020. "The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates" Materials 13, no. 7: 1752. https://doi.org/10.3390/ma13071752