3.1. Defossilisation of Cement Production by Resistance and Microwave Heating
As an example of how electrification can lead to different production models, two case studies will be discussed concerning the electrification of the calcination process in cement production.
Cement is an indispensable material in today’s global society. It has been calculated that the annual global consumption of cement is equivalent to half a ton for each person on the planet [
22]. It is anticipated that global cement demand will increase as a consequence of population growth and the trend of further urbanisation. Cement production is a significant contributor to CO
2 emissions, accounting for approximately 8% of the global total [
23]. This is due to the fact that the majority of a plant’s emissions are associated with the production process. Process CO
2 emissions cannot be eliminated simply by replacing fossil fuels, because the process emission of carbon dioxide (CO
2) cannot be avoided by replacing the use of hydrocarbon-derived fuels. This follows directly from the calcination reaction:
It is important to note that the process emission, which is unavoidable and results in the release of more than 400 g of process CO
2 per kg of cement [
24], is in addition to the CO
2 released from the combustion of fuels used to power the process (250 g of combustion CO
2 per kg of cement [
24]). It can be concluded that there are two principal methods by which to reduce the CO
2 emissions linked to the production of cement. Firstly, there is the capture of the CO
2 released in the chemical calcination process. Secondly, there is the supply of thermal energy by an energy source with a low CO
2 impact. Two European projects, LEILAC and DESTINY, are investigating these possibilities.
LEILAC demonstrates the feasibility of employing resistance heating as a substitute for an existing gas-supplied process.
As demonstrated by the utilisation of microwave heating in the DESTINY project, there is potential to further decarbonise cement production by reducing the scale of the production model towards small on-site cement production.
3.1.1. LEILAC: Electrification as Substitution
The LEILAC (Low Emissions Intensity Lime And Cement) initiative is structured across two sequential development phases. The first of these, LEILAC1, achieved the direct isolation of process-related CO
2 emissions. The LEILAC separation unit (
Figure 6) is designed to enable the efficient capture of the unavoidable greenhouse gas emissions inherent to lime and cement manufacturing.
The technology fundamentally redesigns the conventional calciner process by transferring heat to limestone indirectly through a purpose-engineered steel vessel. This distinctive configuration maintains complete segregation between furnace flue gases and the decomposition products, allowing highly pure CO2 to be extracted as it evolves from the calcium carbonate matrix. Integration into existing cement facilities requires only minimal process modifications, as the unit essentially substitutes the conventional calciner without introducing additional reagents or auxiliary operations. As a result, the liberated CO2 stream can be recovered under conditions of elevated chemical purity.
The construction of a pilot installation at the Heidelberg Cement facility in Lixhe, Belgium, was completed within the LEILAC1 framework.
The results from LEILAC1 showed that both raw limestone and cement meal can be successfully processed; that effective CO2 separation is achievable; and that—when assessed independently of the broader system—the energy overhead associated with indirect calcination is comparable to that of conventional direct calcination. Additional noteworthy outcomes include the absence of material accumulation on the inner vessel walls; no measurable structural or operational degradation of the tube following repeated calcination cycles; negligible interference with host plant operations or clinker output; and a strong safety record throughout operation.
A subsequent initiative—LEILAC2—co-funded by the EU Horizon 2020 programme with supplementary industrial investment, was launched in April 2020. Incorporating insights gained during LEILAC1, LEILAC2 was planned to commission a demonstration facility at Heidelberg Cement’s Ennigerloh site in Germany, targeting the separation of approximately 100,000 tonnes of CO2 annually within a scalable modular architecture.
The LEILAC2 project is designed to validate technology scale-up under operational conditions, while pursuing tighter thermal and process integration to maximise overall system efficiency in a retrofit scenario with minimal disruption to clinker yield and quality.
The demonstration facility will additionally explore the feasibility of low-carbon heat sources for supplying the calcination energy requirement, including electrical heating and alternative fuels with elevated biomass content. In this context, a multi-energy management framework has been investigated, yielding encouraging preliminary results.
Within the LEILAC2 scope, the existing LEILAC1 pilot plant will undergo electrification through the replacement of gas-fired burners with resistive heating elements. This selection is technically motivated by the requirement to preserve the existing production configuration to the greatest extent possible, as resistive heating represents a comparatively straightforward drop-in replacement for conventional gas combustion systems.
At a commercial scale, process performance and economics are expected to improve beyond current LEILAC2 projections through a series of subsequent optimisation measures, including the utilisation of kiln off-gases, recovery of thermal energy from the CO2 stream, enhanced preheating strategies, reduced separation distances between process units and the preheater tower, and increased thermal insulation levels.
3.1.2. DESTINY: Microwave Heating Enabling New Production Paradigms
The DESTINY project develops 915 MHz microwave technology for the continuous processing of granular materials in energy-intensive industries, including cement production. Proprietary microwave system details are protected under non-disclosure agreements.
The project introduces a novel firing concept that substitutes conventional combustion with direct microwave–material interaction, complementing traditional production systems.
Figure 7 contrasts a conventional rotary kiln with the DESTINY microwave (µw) kiln configuration.
Unlike conventional large-scale kilns, which exhibit diminished performance under reduced production conditions, the DESTINY kiln sustains high operational efficiency even in downscaled process configurations.
The project indicates progress toward the following performance targets:
Capacity to accommodate ± 30% fluctuations in energy input within the timeframes typical of renewable-energy variability, with a negligible degradation in specific energy efficiency;
A 40% gain in energy efficiency, depending on the industrial sector and product type;
Resource (fuel) efficiency improvements exceeding 40%;
A 45% reduction in CO2 emissions under steady-state conditions, excluding electricity generation contributions;
A 15% decrease in both OPEX and CAPEX.
In large conventional rotary kilns, material residence times typically exceed two hours. The miniaturised rotary fluidised bed employed in the DESTINY concept enables superior microwave coupling, reducing the residence time to under two minutes.
A key advantage of the container-scale DESTINY microwave unit lies in its capacity for on-demand, point-of-use production.
Experimental investigations have confirmed the feasibility of activating natural kaolinitic clays through microwave irradiation at activation temperatures in the range of 520–540 °C. Adequate reactivity was obtained at a low throughput of 12 kg/h. At an elevated production rate of 25 kg/h, the pozzolanic activity index at 28 days reached only 88%. Achieving higher mass flow rates with sufficient activation levels remains an open technical challenge.
3.1.3. Comparison LEILAC and DESTINY: Two Different Production Models
The European research initiatives LEILAC and DESTINY represent two complementary pathways toward the electrification of the energy-intensive cement sector. LEILAC exemplifies electrification as a substitution strategy, whereas DESTINY embodies electrification as a fundamental transformation of the production model.
The LEILAC electrification approach involves replacing conventional gas-fired combustion systems with electric resistance heating elements, while preserving the large-scale production architecture of standard cement manufacturing processes.
The container-scale process equipment underpinning DESTINY, based on microwave heating technology, enables downscaled production with competitive efficiency and supports a lean, on-site, demand-driven manufacturing model. The DESTINY paradigm further benefits from inherent scalability, allowing the production capacity to be adjusted upward or downward while maintaining satisfactory efficiency across varying output rates.
Both the electrification of conventional process configurations (LEILAC) and the adoption of new production models enabled by advanced electrotechnologies (DESTINY) represent complementary strategies for reducing the climate footprint associated with growing cement demand.
When determining the economically optimal solution for any given context in the pursuit of the complete defossilisation of cement production, both large-scale centralised manufacturing and container-scale, on-site, demand-driven production should be evaluated. The effectiveness of microwave interaction at elevated temperatures is particularly promising, as it allows process temperatures to remain closer to the thermochemical threshold of the calcination reaction by virtue of the direct and instantaneous coupling of electromagnetic energy with the material. Resistive heating, by contrast, relies on convective and radiative heat transfer mechanisms, necessitating element temperatures of up to 2000 °C to ensure adequate thermal flux to the material.
The LEILAC case demonstrates that electricity can serve as a straightforward substitution for fossil-based energy in contexts where continuity with existing production infrastructure is a priority. The microwave-based DESTINY concept, however, illustrates that electricity is not simply an energy carrier interchangeable with conventional fossil fuels. The volumetric and instantaneous nature of microwave–material interaction highlights a specific physical interaction mechanism that creates opportunities for new process configurations and for production models—such as container-scale manufacturing—that may be more appropriate than centralised large-scale production in some operational and economic contexts.
3.2. Electrification of a Strip Heating Line
To estimate the substitution potential of a given thermoprocessing installation, a simple and robust strategy is needed. This is achieved through a hierarchical evaluation (
Figure 8) of process and economic requirements, which was formulated as part of the IGF Project EnabEL [
25]. The practical example discussed in this section applies this method to a typical industrial scenario involving a gas-fired heating and holding process for steel strips within an annealing and pickling line (
Figure 9). The installation consists of two independent heating zones/furnaces, each with a chamber length of 15 m and a chamber width/height of 3 m. The steel strip is initially heated from room temperature to 1200 °C and is then held at this temperature for 30 s.
The installation handles a throughput of 37 tonnes per hour. The strip dimensions are a width of 1500 mm and a thickness of 1 mm. In the heating zone, burners with a combined total power output of 12 MW have been installed.
3.2.1. Available Technologies
Industrial gas burners can achieve substantial power densities of >300 kW/m2, and, naturally, the furnaces were built around the power source. Therefore, the most challenging part in the design of electric substitution concepts is to fulfil the process requirements. For achieving furnace temperatures of >1000 °C using electrically conductive workpieces, only three technologies are already established on the market: indirect resistive heating, direct resistance heating and inductive heating.
In the case of indirect resistive heating, the technical principle is simple: heating elements (HEs) made of metallic alloys or high temperature ceramics are mounted on the furnace walls [
26]. These elements are then heated to a high temperature, transferring thermal energy to the workpiece via radiation. This way, nearly all electric energy is transferred into thermal energy. Electric efficiencies of 95–98% are common. In the considered temperature range, three types of heating elements with their respective, maximum element temperature are available on the market: metallic FeCrAl alloys up to 1450 °C and ceramic HEs made from SiC up to 1600 °C or from MoSi
2 up to 1800 °C [
26]. Unfortunately, SiC-HE possess a non-optimal operational behaviour, especially in the case of high-power applications. SiC-HEs experience a change in resistance over their lifetime (ageing) [
27]. Additionally, SiC HE resistance deviates strongly during the manufacturing process [
28]. Due to this operational behaviour, it is suggested that SiC-HEs should only be used if no other option is available, and they are therefore excluded from further evaluation. FeCrAl-HEs can achieve wall loadings up to 100 kW/m
2 at furnace temperatures of 800 °C and up to 30 kW/m
2 at furnace temperatures of 1250 °C [
29]. On the other hand, MoSi
2-HEs can achieve wall loadings up to 160 kW/m
2 depending on the mode of installation [
30], achieving a much higher power density but still significantly lower compared to gas burners.
Inductive heating is a direct heating method that generates internal heat sources within the workpiece by inducing eddy currents through a strong, time-varying magnetic flux. This approach effectively eliminates technical limitations on the transport of thermal energy. Compared to gas burners, inductive heating can achieve power densities that are an order of magnitude higher [
31]. For strip workpieces, induction heating can be applied in form of longitudinal-field (LFH) or transversal-field (TFH) induction heating (
Figure 10).
LFH is a more robust and easier to design system compared to TFH. Therefore, it should be used whenever possible. The only significant limitation of LFH implementation is that it is constrained by the maximum frequency of the generator. As the strip becomes thinner, a higher frequency is required to achieve sufficient electrical efficiency.
To estimate the necessary frequency, the following equation can be used, where κ is the electrical conductivity [S/m], μ is the magnetic permeability [H/m], and d is the strip thickness [m]:
In contrast to LFH, the frequency of TFH is independent of strip thickness, allowing for similar heating efficiencies to be achieved at low frequencies. However, the heating profile of TFH is highly sensitive to the geometry of the inductor relative to the strip geometry. As a result, designing TFH systems requires extensive numerical simulations [
32].
3.2.2. Substitution Strategies
Considering the available technologies, two general substitution strategies can be formulated: 1. Substitute the heating and holding process with indirect resistive heating. 2. Use an inductive booster for the heating process in combination with an indirect resistive holding process. The first strategy is the most convenient to implement, it does not require numerical simulations, and the heat transfer mechanisms do not change. In the used practical scenario, the holding process can be easily electrified with indirect electric heating since only thermal losses need to be compensated there. The heating process, on the other hand, cannot be substituted by indirect electric heating. The radiative energy transfer is proportional to the difference in the fourth power of the temperatures of the heating element and workpiece (
Figure 11, left); even the use of MoSi
2-HEs will not provide sufficient energy transfer to heat up the steel strip over a 15 m furnace length to the required temperature of 1200 °C (
Figure 11, right).
Since neither the HE temperature nor the maximum wall load of a given HE type can be increased, the only way to enhance the heating performance is by extending the furnace length or reducing the throughput. If neither option is feasible, the second strategy must be employed. The strip thickness of 1 mm inhibits the use of LFH, as the optimal frequency would exceed 5 MHz in this scenario. Therefore, implementing a booster based on the TFH is necessary.
An analytic estimation of TFH heating performance is generally insufficient. The temperature profile, heating rate and process efficiency are dependent on the optimisation of codependent parameters which describe the geometry of the TFH inductor in relation to the respective strip (
Figure 12). In this case, numerical simulation is required.
Induction heating can be simplified as a combination of two coupled processes: first, the induction of eddy currents into the workpiece by the high-frequency electromagnetic field generated by the inductor; second, the propagation of the temperature field caused by the internal heating of the workpiece through joule heat losses. As the time constant of the thermal propagation is orders of magnitude higher than the time constant of the high-frequency electromagnetic field, the simulation can be implemented using two weakly coupled environments which solve the electromagnetic and the thermal part of the simulation independently.
To estimate the general performance of the TFH as a booster, a simulation of the regular zone is sufficient. In this case, the dimension of the simulation can be reduced from 3D to 2D to save computation resources.
Figure 13 shows the resulting simulation geometry.
A two-dimensional simulation model allows general parameter sweeps to estimate optimal process parameters.
Figure 14 shows the electric efficiency
and cos
as a function of frequency
and pole distance
for a stainless-steel strip with a 1 mm thickness. In the shown case, a constant coupling distance
and a constant conductor width
were used. The electric efficiency is calculated using the following formula, where
is the electric losses inside the stainless-steel strip and
is the electric losses inside the inductor:
Based on the results of the parameter sweep, a frequency of
and a pole distance
were used to approximate the heating performance of the TFH booster.
Figure 15 presents the simulation results for the estimated heating performance of the TFH booster. Within a mounting space of 1.4 m, the strip can be heated from room temperature to 1200 °C with an electric efficiency of 90% at a frequency of just 2 kHz.
3.2.3. Evaluation of the Economic Impact
The average lifespan of a thermoprocessing installation is typically planned to be between 20 and 40 years, with a focus on maintaining nearly continuous operation. Over the lifetime of such an installation, the running costs significantly outweigh the initial substitution costs. In high-temperature and high-power applications, the running costs are predominantly driven by energy prices. When considering substitution, these costs are especially determined by the price comparison between gas and electric energy, which is influenced by availability and local politics. Today, in most EU countries, the price of electricity still on average outweighs the gas price by at least a factor of two (
Figure 16, left), which on average leads to an increase in energy costs by over 100%. Poland presents an exception and a promising outlook for the future, where switching to electric heating does not affect energy costs, especially when the price of CO
2 certificates is factored in. Finland and Sweden, on the other hand, are a step further, where transitioning to electric heating can even reduce operational cost.
In summary, the implementation of inductive heating in the substitution of high-power processes, either as a complete replacement or as a booster in combination with indirect resistive heating, offers the safest way to fulfil the process requirements. This remains true even when considering the more complex process design involved. Although current energy prices suggest that replacing gas-powered installations with electric alternatives may not be advisable in most European countries in the short term, future changes in renewable energy production or CO2 pricing could quickly alter this condition. Therefore, a robust strategy for evaluating and designing a substitution concept will become increasingly important in the future.
3.3. Electrification of Melting Processes for Cast Iron and Aluminium
3.3.1. Introduction Preamble
The melting processes of metals are high-energy-consuming industrial processes, and the continuous improvement of the energy efficiency of competitive melting technologies is of increasing interest [
34]. Against this background, the CO
2 emissions of melting processes must now be considered alongside the evaluation of energy alone. The CO
2 balance of the entire process chain must be assessed and reduced in order to address future challenges in melting technologies [
35].
When comparing different melting processes, three groups of evaluation criteria are particularly important: application requirements, economic requirements, and ecological requirements (see
Figure 17).
Process requirements are the primary boundary conditions. Different melting technologies can only be considered as competing options if they meet the same process requirements, such as temperature level, furnace atmosphere, and production rate. If only one technology can satisfy these requirements, there is effectively no competition and the remaining criteria become secondary. If, however, two or more technologies can provide the same or similar process performance, the selection should ultimately be based on economic and ecological criteria. The most important economic aspects are investment costs, maintenance costs, and, in particular, the cost of the final energy used. In recent years, the total CO2 balance associated with the chosen final energy source has also become increasingly important, not only from an ecological perspective but also from an economic one because of CO2 emission trading schemes.
For a complete energy comparison, and for a consistent comparison of CO
2 emissions from different melting furnaces, the primary energy demand of each furnace must be considered in addition to its final energy demand. The evaluation of both primary energy use and CO
2 emissions therefore has to include the complete process chain [
36].
To describe the total energy demand of a melting process, the first step is to consider the direct energy demand, i.e., the specific energy required for the melting operation itself. The second step is to account for the embodied energy associated with material losses during the process, for example, due to oxidation. These losses must be compensated by additional material input and, from an energetic point of view, by the accumulated energy required to produce that material. This can be assessed through a complete process chain analysis in accordance with VDI 4600.
Depending on the final energy source used—electricity, gas, or coal—the corresponding process chains result in different CO2 emissions. Even when electric melting processes have primary energy demands similar to those of fuel-heated processes, their CO2 emissions are often already lower as of today. As the share of renewable electricity continues to increase, electric melting processes are expected to deliver even greater CO2 reductions in the future.
3.3.2. Melting of Cast Iron
Melting furnaces are widely used for melting of iron, steel and non-ferrous metals. For use in cast iron foundries, cupola, induction, and partly also gas- or oil-fired rotary furnaces are in competition; see
Figure 18.
From the criteria of the production requirements, the cupola furnace has substantial advantages for continuous melting and large throughputs. Induction furnaces are small, and their very flexible aggregates allow for making the optimal choice when often changing the alloy composition of the melt charge and for small batches of high-quality melting products [
37]. Nevertheless, energy consumption plays an important role in both cases.
Figure 19 shows the principal layout of a hot blast cupola furnace and typical energy consumption values for a modern large furnace. The melting rates of such large furnaces are 60 t/h. Cupola furnaces are used in large foundries with a small variety of different cast iron grades. The total energy consumption is in the range of 1000 to 1100 kWh per ton of molten cast iron, considering the impact of the oxidation losses in the energy balance. The main energy source of the hot blast cupola furnace is coke; small parts are gas and electricity. These energy sources cause total CO
2 emissions of about 810 kg/t cast iron, taking into account the electricity mix in Germany in 2022.
Figure 20 shows an induction crucible furnace, which is mostly used for flexible melting with a wide variety of different cast iron grades. The sizes of modern medium-frequency induction furnaces are smaller, and they have typically melting rates of 10 t/h to 20 t/h for cast iron [
38]. The energy consumption of modern furnaces is around 540 kWh/t in the case of the melting of cast iron (without holding operation losses) and is much lower than for the cupola furnace, but, due to electricity as the energy source, the energy costs are comparable or even higher. The total efficiency for the melting of cast iron is about 75%. In total, the melting and carburization process using the induction crucible furnace causes CO
2 emissions of about 220 kg/t cast iron, considering the electricity mix in Germany in 2022. But the total CO
2 emissions are only 20 kg/t if one hundred percent green electricity is used.
The electrification of the melting processes of cast iron offers significant potential to reduce CO2 emissions, especially when electric energy generated by renewable energy sources is used. In particular, experimental data relating to grey cast iron melting processes can be used to derive the substitution coefficient g in the transition from a process that uses fossil fuels to a fully electrified process.
In the process of melting one ton of grey cast iron in a cupola furnace, the energy consumption from fossil fuels, coke, and gas amounts to 930 kWh, or 3312 MJ, while the electricity consumption amounts to 30 kWh. The same melting process in an induction crucible furnace uses 420 kWh. With these values, we obtain
3.3.3. Melting of Aluminium
For the melting of aluminium, as of today, gas-fired furnaces are mostly used. These gas-fired furnaces (
Figure 21) are usually preferred because of their comparatively low operating energy costs.
In the gas-fired furnace, the open flame of the burner is directly oriented to the melt surface, which leads to considerable oxidation losses and inhomogeneous temperature distribution in the melt. The oxidation losses must be compensated by the very energy intensive production of primary aluminium. Therefore, the energy balance in
Figure 21 shows a very high amount of energy caused by the compensation of the oxidation losses.
For the electrification of the melting process for aluminium, the induction channel furnace (see
Figure 22) is a technology that fulfils all typical technical requirements of the foundry industry, such as high throughput and short melting cycles, melt homogenization by bath movement, and precise power and temperature control, as well as simple automatic process control, easy handling, and high flexibility [
38]. In addition, high electrical and thermal efficiency in connection with low oxidation losses and consequently the saving of raw materials lead to low specific energy consumption and environmental competitiveness.
Material losses from oxidation during the melting process play a significant role, especially from an energy and ecological point of view in the case of aluminium melting processes. These oxidation losses depend on the melting technology, the type and purity of the charged aluminium scrap, the temperature level and spatial distribution of the temperature in the melt, the melting time, the furnace atmosphere, and other factors. Practical investigations comparing fuel-fired and electrically heated aluminium melting have shown that induction furnaces can offer energy savings, lower oxidation losses, and environmental advantages. The comparison between the energy balance in
Figure 21 and
Figure 22 shows the great potential of lowering energy input and reducing CO
2 emissions for melting one ton of aluminium when using an induction channel furnace instead of a gas-fired furnace. The results highlight the influence of oxidation losses, which must be compensated by a highly energy intensive primary aluminium material.
Melting one ton of aluminium in a traditional furnace requires approximately 715 kWh or 2574 MJ of methane gas, while the same process in a channel induction furnace uses 520 kWh. In this case, the substitution coefficient is significantly lower and is equal to