Study on Time-Varying Mechanism of Reservoir Properties During Long-Term Water Flooding
Abstract
1. Introduction
2. Experimental Evaluation
2.1. Methodology
2.2. Cores Selection
3. Results
3.1. Porosity and Permeability
3.2. Pore Throat
3.3. Clay Content
3.4. Oil Recovery
3.5. Evolution Mechanism
3.6. Threshold-Based Polarization Model for Time-Varying Permeability
3.7. Model Interpretation and Fitting
4. Discussion
5. Conclusions
- (1)
- Permeability exhibits a distinct polarization trend. Under prolonged water injection (up to 500 PV), high-permeability cores experience a significant permeability enhancement (average +27.3%), whereas low-permeability cores suffer a severe permeability reduction (average −22%). This divergent evolution fundamentally amplifies reservoir heterogeneity after long-term water flooding.
- (2)
- Porosity demonstrates a synchronous and uniform increase. Contrary to the polarization of permeability, porosity increased consistently across all core types, with an average gain of 21%. This indicates that matrix dissolution and clay volume redistribution are universal processes during long-term water-rock interaction.
- (3)
- The evolution is governed by the pore-throat network polarization mechanism. Microscopic analysis reveals that this paradox is primarily driven by differential clay migration: In high-permeability zones, sufficient flow velocity mobilizes and transports clay particles (especially kaolinite), leading to pore-throat enlargement and enhanced connectivity. In low-permeability zones, inadequate flow velocity allows migrating clays to aggregate and bridge at narrow pore throats, resulting in occlusion and increased flow resistance.
- (4)
- Clay content and composition undergo significant alterations. The overall clay content decreased by 7.34% on average, with kaolinite being the most mobilized mineral. The redistribution of these detached clays from high-permeability to low-permeability zones creates a positive feedback loop that intensifies the heterogeneity of the reservoir.
- (5)
- A threshold-based polarization model was developed, unifying the macroscopic observations. This model identifies a critical pore-throat radius as the key threshold dictating the divergent evolution of permeability. It successfully decouples the universal porosity increase from the permeability polarization, providing a predictive tool for long-term reservoir performance.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Abbreviations
| HP | High Permeability |
| RHP | Relatively High Permeability |
| MP | Medium Permeability |
| RLP | Relatively Low Permeability |
| LP | Low Permeability |
| SEM | Scanning Electron Microscopy |
| XRD | X-ray Diffraction |
| WC | Water Cut |
| and ) | Permeability and porosity after injection |
| and | Initial permeability and porosity |
| Dynamic polarization factor | |
| Ultimate polarization factor | |
| Kinetic coefficient for polarization | |
| RO | Oil recovery |
References
- Zendehdel, P.; Karimian Torghabeh, A.; Jowkar, H.; Pimentel, N. Comprehensive Petrophysical Assessment of Carbonate Reservoirs in the Shanul Gas Field (SW Iran): A Case Study with Implications for Hydrocarbon Exploration and Production. Fuels 2025, 6, 77. [Google Scholar] [CrossRef]
- Ni, H.; Boon, M.; Garing, C.; Benson, S.M. Coreflooding Data on Nine Sandstone Cores to Measure CO2 Residual Trapping. Data Brief 2019, 25, 104249. [Google Scholar] [CrossRef]
- Sarlak, M.; Reed, J.; Law, S.; McCue, A.J.; Tanino, Y. Water and Oil Volume Measurement Using UV–Visible Spectroscopy. Transp. Porous Media 2024, 152, 5. [Google Scholar] [CrossRef]
- Mostakhdeminhosseini, F.; Rafiei, Y.; Sharifi, M. Visual Investigation of Swelling and Migration Behavior of Bentonite and Kaolinite Clays at Elevated Temperature Using Micromodels. Sci. Rep. 2025, 15, 16763. [Google Scholar] [CrossRef]
- Wang, S.-C.; Zhang, N.; Tang, Z.-H.; Zou, X.-F.; Sun, Q.; Liu, W. Time-Dependent Model for Two-Phase Flow in Ultra-High Water-Cut Reservoirs: Time-Varying Permeability and Relative Permeability. Pet. Sci. 2024, 21, 2536–2553. [Google Scholar] [CrossRef]
- Zhang, N.; Guo, S.; Wang, S.; Tong, Y.; Li, Z.; Wu, J. Fractal and Multifractal Characteristics on Pore Structure of Coal-Based Sedimentary Rocks Using Nuclear Magnetic Resonance. SPE J. 2024, 29, 2624–2637. [Google Scholar] [CrossRef]
- Konoshonkin, D.; Shishaev, G.; Matveev, I.; Volkova, A.; Rukavishnikov, V.; Demyanov, V.; Belozerov, B. Machine Learning Clustering of Reservoir Heterogeneity with Petrophysical and Production Data. In Proceedings of the SPE Europec, Virtual, 1–3 December 2020. [Google Scholar]
- Zeng, L.; Li, X.; Jiang, F.; Yin, M.; Dang, Z.; Zhang, L.; Huang, W.; Yi, X. The Effect of Kaolinite on Ferrihydrite Colloid Migration in Soil: Molecular-Scale Mechanism Study. Environ. Sci. Nano 2023, 10, 2754–2766. [Google Scholar] [CrossRef]
- Zheng, X.; Shen, X.; Bourg, I.C. Coarse-Grained Simulation of Colloidal Self-Assembly, Cation Exchange, and Rheology in Na/Ca Smectite Clay Gels. J. Colloid Interface Sci. 2025, 693, 137573. [Google Scholar] [CrossRef] [PubMed]
- Masoudi, M.; Nooraiepour, M.; Deng, H.; Hellevang, H. Reevaluating Traditional Porosity-Permeability Relationships: Investigating the Influence of Crystallite Distribution on Pore Geometry and Permeability Evolution in Porous Media. In Proceedings of the 17th Greenhouse Gas Control Technologies Conference (GHGT-17), Calgary, AB, Canada, 20–24 October 2024. [Google Scholar]
- Graham, G.M.; Kidd, S.; Stalker, R.; Wright, R. Effect of Coreflood Test Methodology on Appropriate Simulation of Field Treatments. In Proceedings of the SPE International Symposium and Exhibition on Formation Damage Control, Lafayette, LA, USA, 15–17 February 2012. [Google Scholar]
- Jouini, M.S.; Alabere, A.O.; Alsuwaidi, M.; Morad, S.; Bouchaala, F.; Al-Jallad, O.A. Experimental and Digital Investigations of Heterogeneity in Lower Cretaceous Carbonate Reservoir Using Fractal and Multifractal Concepts. Sci. Rep. 2023, 13, 20306. [Google Scholar] [CrossRef] [PubMed]
- Cihan, A.; Petrusak, R.; Bhuvankar, P.; Alumbaugh, D.; Trautz, R.; Birkholzer, J.T. Permeability Decline by Clay Fines Migration around a Low-Salinity Fluid Injection Well. Groundwater 2022, 60, 87–98. [Google Scholar] [CrossRef] [PubMed]
- Sell, K.; Enzmann, F.; Kersten, M.; Spangenberg, E. Microtomographic Quantification of Hydraulic Clay Mineral Displacement Effects During a CO2 Sequestration Experiment with Saline Aquifer Sandstone. Environ. Sci. Technol. 2013, 47, 198–204. [Google Scholar] [CrossRef] [PubMed]










| Core # | Weight, g | Length, cm | Diameter, cm | Pore Volume | Porosity, % | Permeability, mD |
|---|---|---|---|---|---|---|
| A1 | 31.94 | 3.13 | 2.52 | 3.09 | 19.86 | 300.28 |
| A2 | 29.81 | 2.91 | 2.51 | 2.80 | 19.46 | 245.86 |
| A3 | 32.83 | 3.08 | 2.52 | 2.62 | 17.10 | 139.60 |
| B1 | 31.59 | 3.02 | 2.52 | 2.77 | 18.43 | 73.61 |
| B2 | 33.52 | 3.19 | 2.51 | 2.94 | 18.59 | 68.53 |
| B3 | 33.20 | 3.18 | 2.50 | 2.89 | 18.56 | 66.27 |
| B4 | 32.33 | 3.04 | 2.52 | 2.81 | 18.57 | 50.50 |
| C1 | 34.70 | 3.12 | 2.52 | 2.15 | 13.85 | 28.77 |
| C2 | 33.37 | 3.01 | 2.52 | 2.22 | 14.86 | 25.95 |
| C3 | 34.14 | 3.07 | 2.52 | 2.16 | 14.11 | 15.26 |
| D1 | 35.21 | 3.14 | 2.52 | 1.95 | 12.51 | 6.36 |
| D2 | 34.99 | 2.99 | 2.52 | 1.57 | 10.49 | 5.72 |
| D3 | 34.64 | 3.05 | 2.52 | 1.90 | 12.43 | 4.17 |
| D4 | 32.74 | 3.05 | 2.51 | 2.40 | 15.97 | 3.64 |
| E1 | 35.28 | 3.06 | 2.52 | 1.68 | 11.00 | 0.81 |
| E2 | 36.97 | 3.23 | 2.52 | 1.76 | 10.87 | 0.69 |
| E3 | 35.31 | 2.88 | 2.52 | 0.88 | 6.13 | 0.69 |
| Stage | Core # | Non-Clay | Clay | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| Quartz | Siderite | Calcite | Albite | Orthoclase | Total | Chlorite | Illite | Kaolinite | Total | ||
| After flooding | A1 | 68.40% | 4.40% | 12.00% | 5.40% | 90.20% | 2.86% | 2.94% | 4.00% | 9.80% | |
| C1 | 74.00% | 0.30% | 4.90% | 9.20% | 3.70% | 92.10% | 2.91% | 2.39% | 2.60% | 7.90% | |
| D1 | 72.50% | 0.50% | 2.80% | 12.20% | 4.80% | 92.80% | 1.84% | 2.36% | 3.10% | 7.30% | |
| Average | 65.43% | 0.47% | 5.78% | 13.15% | 5.90% | 91.70% | 2.54% | 2.56% | 3.23% | 8.33% | |
| Before flooding | A1 | 22.10% | 0.30% | 3.10% | 41.10% | 13.80% | 80.40% | 1.99% | 5.36% | 12.35% | 19.70% |
| C1 | 33.80% | 0.40% | 2.50% | 35.00% | 11.80% | 83.50% | 6.45% | 4.65% | 5.40% | 16.50% | |
| D1 | 39.60% | 0.20% | 3.40% | 37.30% | 8.70% | 89.20% | 3.97% | 3.43% | 3.40% | 10.80% | |
| Average | 31.83% | 0.30% | 3.00% | 37.80% | 11.43% | 84.33% | 4.14% | 4.48% | 7.05% | 15.67% | |
| Core Group | (μm) | |||
|---|---|---|---|---|
| High-Permeability (HP) | ~21.5 | 1.12 | 0.022 | 1.2 |
| Low-Permeability (LP) | ~8.5 | 0.67 | 0.008 | 0.5 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
An, X.; Zhu, Y.; Tan, X.; Bi, J.; Tan, C. Study on Time-Varying Mechanism of Reservoir Properties During Long-Term Water Flooding. Energies 2025, 18, 6488. https://doi.org/10.3390/en18246488
An X, Zhu Y, Tan X, Bi J, Tan C. Study on Time-Varying Mechanism of Reservoir Properties During Long-Term Water Flooding. Energies. 2025; 18(24):6488. https://doi.org/10.3390/en18246488
Chicago/Turabian StyleAn, Xiaoping, Yufen Zhu, Xiqun Tan, Jingyi Bi, and Chengqian Tan. 2025. "Study on Time-Varying Mechanism of Reservoir Properties During Long-Term Water Flooding" Energies 18, no. 24: 6488. https://doi.org/10.3390/en18246488
APA StyleAn, X., Zhu, Y., Tan, X., Bi, J., & Tan, C. (2025). Study on Time-Varying Mechanism of Reservoir Properties During Long-Term Water Flooding. Energies, 18(24), 6488. https://doi.org/10.3390/en18246488
