Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station
Abstract
1. Introduction
2. Mathematical Model
2.1. Numerical Methods
2.2. Control Equation
2.3. Mass Flow
2.4. Software Applicability Verification
3. Research Methodology
3.1. Geometric Model
3.2. Initial Condition Settings
3.3. Grid Independence Verification and Division
3.4. Leakage Diffusion Analysis
3.4.1. Influence of Leakage Direction
3.4.2. Influence of Seasonal Climate
3.5. Empirical Formula
4. Simulation Results and Analysis of Hydrogen Explosion
5. Analysis and Discussion
- Under the leakage scenarios analyzed in this work (considering specific leakage rates, directions, and environmental conditions), it can be seen that, in comparison with leakage from compressors and hydrogen storage tanks, leakage from dispensers poses lower risks to station equipment. However, the coupling between leakage direction and wind fields may still cause risks in station building areas. It is recommended to deploy multiple concentration sensors around compressors and storage tanks.
- Southeast/south winds during spring and summer promote outward migration of hydrogen clouds, reducing on-site risks, but may cause localized accumulation near storage tanks. Conversely, north/northwest winds in autumn and winter significantly increase hydrogen concentrations near compressors and station buildings. Special attention should be paid to strengthening ventilation measures.
- Downward (−Z direction) leaks from storage tanks generate ground-hugging clouds with the largest diffusion range. If an ignition source is encountered, such scenarios exhibit explosion overpressure peaks of 0.25 barg and flame temperatures exceeding 2500 K, requiring priority prevention and control. We recommend installing ground ventilation slots near the storage tanks to accelerate the diffusion of ground-hugging hydrogen gas, and adding rapid-response explosion suppression systems.
- An empirical formula integrating climatic parameters and leakage directions was proposed to address the insufficient generalizability of traditional models. This formula can be used to predict the hydrogen concentration distribution under different seasons and leakage directions in similar HRSs (with the same equipment layout and environmental conditions), providing a reference for the risk assessment of HRSs. In addition, this method can also be applied to other HRSs. In the actual construction of HRSs, it is suggested to optimize ground ventilation facilities, dynamically adjust the sensor layout based on the empirical formula and seasonal wind field characteristics, and optimize equipment spacing to enhance risk prevention and control capabilities.
- Although small-scale experiments (such as wind tunnel tests) can provide valuable supplementary verification, conducting full-scale, multi-season, and multi-parameter coupled experiments has significant limitations in terms of cost and safety. This study ensured the reliability of the research results through three means: strict verification of grid independence, systematic multi-scenario coupling analysis covering 72 working conditions, and construction of empirical formulas (prediction error < 20%).
- However, this work focused on single-leakage scenarios; future studies should extend dynamic analysis to multi-leakage scenarios and complex meteorological conditions. In addition, the impact of long-term hydrogen exposure on leakage rate and explosion severity has not been studied either. Future studies can further introduce a leakage rate correction coefficient after long-term hydrogen exposure of materials (such as obtaining the variation law of the leakage aperture under different exposure durations through fatigue experiments), and analyze the impact of leakage rate changes on explosion overpressure and flame temperature in combination with explosion dynamics models, so as to more comprehensively evaluate the long-term operation risks of hydrogen refueling stations.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Model | Accuracy for High-Velocity Jets | Computational Cost | Key Limitations | Applicability to HRS Scenarios |
---|---|---|---|---|
k − ε | Moderate (empirical constants limit transient precision) | Low (efficient for large-scale geometries) | Under-predicts strong shear/curvature effects | Suitable for full-scale HRS models |
LES | High (resolves large-scale turbulence) | Very high (10–50 × k − ε cost) | Requires fine grids; subgrid model dependence | Limited to small domains/single scenarios |
DNS | Highest (resolves all turbulent scales) | Extremely high (prohibitive for industry cases) | Restricted to simple geometries/low Re | Not feasible for full-scale HRS models |
Season | Average Wind Speed (m/s) | Wind Direction | Average Temperature (°C) | ||
---|---|---|---|---|---|
Spring (March to May) | −2.12 | 2.12 | 0 | Southeast | 20 |
Summer (June to August) | 0 | 2 | 0 | South | 25 |
Autumn (September to November) | 0 | −2.5 | 0 | North | 18 |
Winter (December to February) | 1.63 | −1.63 | 0 | Northwest | 10 |
Point | Coordinates (m) | Point | Coordinates (m) | Point | Coordinates (m) | Point | Coordinates (m) |
---|---|---|---|---|---|---|---|
M1 | (16.25, 13.75, 0.25) | M10 | (16.25, 13.75, 3.25) | M19 | (16.25, 13.75, 6.25) | M28 | (16.25, 13.75, 9.25) |
M2 | (30.55, 13.75, 0.25) | M11 | (30.55, 13.75, 3.25) | M20 | (30.55, 13.75, 6.25) | M29 | (30.55, 13.75, 9.25) |
M3 | (48.75, 13.75, 0.25) | M12 | (48.75, 13.75, 3.25) | M21 | (48.75, 13.75, 6.25) | M30 | (48.75, 13.75, 9.25) |
M4 | (16.25, 27.55, 0.25) | M13 | (16.25, 27.55, 3.25) | M22 | (16.25, 27.55, 6.25) | M31 | (16.25, 27.55, 9.25) |
M5 | (30.55, 27.55, 0.25) | M14 | (30.55, 27.55, 3.25) | M23 | (30.55, 27.55, 6.25) | M32 | (30.55, 27.55, 9.25) |
M6 | (48.75, 27.55, 0.25) | M15 | (48.75, 27.55, 3.25) | M24 | (48.75, 27.55, 6.25) | M33 | (48.75, 27.55, 9.25) |
M7 | (16.25, 41.25, 0.25) | M16 | (16.25, 41.25, 3.25) | M25 | (16.25, 41.25, 6.25) | M34 | (16.25, 41.25, 9.25) |
M8 | (30.55, 41.25, 0.25) | M17 | (30.55, 41.25, 3.25) | M26 | (30.55, 41.25, 6.25) | M35 | (30.55, 41.25, 9.25) |
M9 | (48.75, 41.25, 0.25) | M18 | (48.75, 41.25, 3.25) | M27 | (48.75, 41.25, 6.25) | M36 | (48.75, 41.25, 9.25) |
Number | Wind Conditions | Compressor Leakage Location | Leak Direction | Core-Region Grid Size (m) | Grid Count |
---|---|---|---|---|---|
#1 | No wind | (13.25, 22.05, 0.95) | +X | 0.15 | 62,100 |
#2 | No wind | (13.25, 22.05, 0.95) | +X | 0.2 | 51,772 |
#3 | No wind | (13.25, 22.05, 0.95) | +X | 0.3 | 36,504 |
#4 | No wind | (13.25, 22.05, 0.95) | +X | 0.4 | 25,725 |
#5 | No wind | (13.25, 22.05, 0.95) | +X | 0.5 | 21,780 |
A | a | b | c | d | e | f | g | h | α | B | |
---|---|---|---|---|---|---|---|---|---|---|---|
Hydrogen storage tank | −0.0651 | 0.264 | 0.1488 | 0.1 | 0.7602 | 0.7422 | 0.682 | 0.1 | 0.1 | 0.3459 | 0.0587 |
Compressor | −0.8181 | 0.1001 | 0.1 | 0.1001 | 0.3986 | 0.2777 | 0.576 | 0.1 | 0.1 | 0.0307 | 0.6538 |
Hydrogen dispenser | 3.0738 | 0.1 | 18.223 | 0.1 | 30 | 0.9209 | 2.4717 | 0.1 | 0.1 | 0.7485 | 0.0058 |
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Liu, Y.; Zeng, Y.; Zhao, G.; Hou, H.; Song, Y.; Ding, B. Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station. Energies 2025, 18, 4172. https://doi.org/10.3390/en18154172
Liu Y, Zeng Y, Zhao G, Hou H, Song Y, Ding B. Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station. Energies. 2025; 18(15):4172. https://doi.org/10.3390/en18154172
Chicago/Turabian StyleLiu, Yaling, Yao Zeng, Guanxi Zhao, Huarong Hou, Yangfan Song, and Bin Ding. 2025. "Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station" Energies 18, no. 15: 4172. https://doi.org/10.3390/en18154172
APA StyleLiu, Y., Zeng, Y., Zhao, G., Hou, H., Song, Y., & Ding, B. (2025). Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station. Energies, 18(15), 4172. https://doi.org/10.3390/en18154172