Constitutive Behavior and Mechanical Failure of Internal Configuration in Prismatic Lithium-Ion Batteries under Mechanical Loading

Internal short circuits and thermal runaway in lithium-ion batteries (LIBs) are mainly caused by deformation-induced failures in their internal components. Understanding the mechanisms of mechanical failure in the internal materials is of much importance for the design of LIB pack safety. In this work, the constitutive behaviors and deformation-induced failures of these component materials were tested and simulated. The stress-strain constitutive models of the anode/cathode and the separator under uniaxial tensile and compressive loads were proposed, and maximum tensile strain failure criteria were used to simulate the failure behaviors on these materials under the biaxial indentations. In order to understand the deformation failure mechanisms of ultrathin and multilayer materials within the prismatic cell, a mesoscale layer element model (LEM) with a separator-cathode-separator-anode structure was constructed. The deformation failure of LEM under spherical punches of different sizes was analyzed in detail, and the results were experimentally verified. Furthermore, the n-layer LEM stacked structure numerical model was constructed to calculate the progressive failure mechanisms of cathodes and anodes under punches. The results of test and simulation show the fracture failure of the cathodes under local indentation will trigger the failure of adjacent layers successively, and the internal short circuits are ultimately caused by separator failure owing to fractures and slips in the electrodes. The results improve the understanding of the failure behavior of the component materials in prismatic lithium-ion batteries, and provide some safety suggestions for the battery structure design in the future.