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Department of Chemistry, Life Sciences and Environmental Sustainability (SCVSA), University of Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy
Author to whom correspondence should be addressed.
Molbank 2018, 2018(1), M988;
Received: 20 February 2018 / Revised: 9 March 2018 / Accepted: 10 March 2018 / Published: 12 March 2018
(This article belongs to the Special Issue Molecules from Catalytic Processes)
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The title compound—cis,exo-1,2,3,4,4a,13b-hexahydro-1,4-methano-5-isopropoxy-9H-tribenzo[b,f]azepine—was synthesized in 83% isolated yield by a palladium-catalyzed one-pot strategy from 1-iodo-2-isopropoxybenzene and ortho-bromoaniline. The azepine derivative was fully characterized (FT-IR, MS, 1H and 13C-NMR, elemental analysis) and all proton and carbon signals have been completely assigned by 2D NMR experiments. View Full-Text
Keywords: palladium; norbornene; benzo[b,f]azepine; C-C and C-N couplings; multicomponent; one-pot reaction palladium; norbornene; benzo[b,f]azepine; C-C and C-N couplings; multicomponent; one-pot reaction

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Casnati, A.; Motti, E.; Ca’, N.D. Cis,exo-1,2,3,4,4a,13b-hexahydro-1,4-methano-5-isopropoxy-9H-tribenzo[b,f]azepine. Molbank 2018, 2018, M988.

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