Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
by
Maren Muntzeck and René Wilhelm *
Maren Muntzeck and René Wilhelm *
Department of Chemistry, University of Paderborn, Warburgerstr. 100, Paderborn 33098, Germany
*
Author to whom correspondence should be addressed.
Academic Editor: Andreas Taubert
Int. J. Mol. Sci. 2016, 17(6), 860; https://doi.org/10.3390/ijms17060860
Received: 30 March 2016 / Revised: 1 May 2016 / Accepted: 13 May 2016 / Published: 1 June 2016
(This article belongs to the Special Issue Ionic Liquids 2016 and Selected Papers from ILMAT III)
A three-component oxidative dehydrogenation tandem reaction via the coupling and hydroarylation of benzaldehyde, aniline and phenylacetylene to a quinoline derivate was catalyzed by an iron-containing ionic liquid. The reaction was air mediated and could be performed under neat conditions. The iron(III) of the ionic liquid was the oxidizing species.
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Keywords:
ionic liquid; C–H activation; oxidation; iron; catalysis; hydroarylation
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MDPI and ACS Style
Muntzeck, M.; Wilhelm, R. Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction. Int. J. Mol. Sci. 2016, 17, 860.
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