Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Installation
3.2. Materials
3.3. Laser Exposition
3.4. Methods of Characterization
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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No. | Medium Density, g/cm3 (T, °C; P, atm) | Ablation Time, min | Time of Ablation with a Stirrer, min | Wavelength λ, nm (Pulse Energy, mJ) | Pd Content, wt % | Proportion of Pd in Al2O3 Fraction > 0.25 mm, % |
---|---|---|---|---|---|---|
1 | 0.2 (70; 100) | 10 | 10 | 1064 (270) | 0.45 | 30 |
2 | 0.4 (70; 130) | 10 | 10 | 1064 (270) | 0.19 | 61 |
3 | 0.8 (50; 210) | 10 | 10 | 1064 (270) | 0.20 | 92 |
4 | 0.8 (50; 210) | 15 | 15 | 532 (110) | 0.35 | - |
Al2O3 Fractions, mm | Initial (Sample 5) | Fraction 0.25–0.5 (Sample 5-1) | Fraction 0.1–0.25 (Sample 5-2) | Fraction Less Than 0.1 |
---|---|---|---|---|
Mass of fraction, g | 1.5 | 1.0 | 0.3 | 0.2 |
Pd content, wt % | 0 | 0.1 | 0.47 | Not determined |
Fraction # | Fraction Size, mm | Pd Content, wt % | Wobserv. × 105, mol/min | TOF, s−1 | ||
---|---|---|---|---|---|---|
1st Stage | 2nd Stage | 1st Stage | 2nd Stage | |||
5-1 | 0.25–0.5 | 0.1 | 0.60 ± 0.15 | 0.08 ± 0.02 | 2.11 ± 0.2 | 0.28 ± 0.05 |
5-2 | 0.1–0.5 | 0.47 | 1.60 ± 0.20 | 0.15 ± 0.02 | 1.20 ± 0.15 | 0.12 ± 0.04 |
Sample Availability: Samples of the Al2O3:PdNP catalyst are available from the authors. |
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Parenago, O.; Rybaltovsky, A.; Epifanov, E.; Shubnyi, A.; Bragina, G.; Lazhko, A.; Khmelenin, D.; Yusupov, V.; Minaev, N. Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium. Molecules 2020, 25, 5807. https://doi.org/10.3390/molecules25245807
Parenago O, Rybaltovsky A, Epifanov E, Shubnyi A, Bragina G, Lazhko A, Khmelenin D, Yusupov V, Minaev N. Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium. Molecules. 2020; 25(24):5807. https://doi.org/10.3390/molecules25245807
Chicago/Turabian StyleParenago, Oleg, Alexey Rybaltovsky, Evgeniy Epifanov, Andrey Shubnyi, Galina Bragina, Alexey Lazhko, Dmitry Khmelenin, Vladimir Yusupov, and Nikita Minaev. 2020. "Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium" Molecules 25, no. 24: 5807. https://doi.org/10.3390/molecules25245807
APA StyleParenago, O., Rybaltovsky, A., Epifanov, E., Shubnyi, A., Bragina, G., Lazhko, A., Khmelenin, D., Yusupov, V., & Minaev, N. (2020). Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium. Molecules, 25(24), 5807. https://doi.org/10.3390/molecules25245807