1. Introduction
The present work deals with the analysis of the coupled mechanism of thermophoretic transportation and mixed convection around the surface of a sphere. In this study, a sphere is working as a heat source with a constant surface temperature, and the exact velocity components at the solid surface of a sphere are considered to be zero and approach an ambient condition far from the surface.
The sphere is a source of heat, which transmits its energy to its surroundings, where submicron particles are in motion and have low energy. These small particles receive energy from the sphere and gain momentum through the temperature gradient and this phenomenon is termed as thermophoretic motion. The force by which these particles are repelled far from the surface of a sphere is called thermophoretic force. Carl Ludwig was the first one to observe thermophoresis in liquid mixtures and in gas mixtures; it was reported by John Tyndall. The phenomenon of heat convection around the surface of a sphere takes place due to a temperature difference and thermophoretic motion.
There are several applications of the thermophoresis phenomenon in industrial processes, like in the removal of minor-sized particles from streams of gas and identification of the channel of exhaust from the devices used in combustion processes. Its significance can be seen in particle deposition on the blades of turbines, the blackening of a gas glob of a kerosene lantern, and the filtration of impure gas. The disgusting of tools of gas turbines, corrosion occurring in heat exchangers, and clotting of condensing/evaporating fine mist is the contribution of thermophoretic deposition. In many of these applications, soot and combustion products deposit on cooled surfaces, which reduces the heat transfer efficiency by a considerable amount and may lead to pollution and fouling of the flow passages.
The depositions of submicron particles drop the pressure and decrease the engine efficiency and enhance the fuel consumption. Some submicron particles like soot particles are acidic and can cause corrosion on surfaces. Experiments show that water droplets in turbines have a larger size range and are more than 90% of the vapor in the form of fog, which has a very small diameter. In cooled gas turbines, the blades are 300–400 K colder than the flow, and so thermophoresis phenomena are very significant in droplet deposition. Aircraft engines experience many difficulties when passing through suspended volcanic ash clouds as deposited particles can block the cooling holes of the turbines blades which are diverse applications of thermophoretic motion. Very similar problems can occur in heavily particle-driven flows, such as explosive eruption and sandstorms, which may damage airplane engines significantly.
The thermophoresis mechanism has vast applications in the engineering field, such as a micro-scale thermophoresis instrument, which is specifically based on thermophoresis and measures the equilibrium binding events; it has been shown to have potential in drug discovery. It is used for the separation of different polymer particles in field flow fractionation. It is used in the manufacturing of optical fibers in vacuum deposition processes. Thermophoresis is used for the sampling of aerosol particles. Thermophoresis removes small gas particles from combustion devices and turbine blades to avoid accidents in nuclear reactors. It is used in electrostatic precipitators. It serves as a transport mechanism in fouling. Engineers use the thermophoresis phenomenon while they are designing air cleaning devices. Its uses are seen in chemical vapor deposition. Due to the variety of applications of mixed convection and thermophoretic motion, many researchers have presented this phenomenon in different flow geometries.
The salient features of the material properties of fluid erupting from the boundary layer and in the plume region above the sphere were examined by Potter and Riley [
1]. The analysis of thermophoretic force and natural convection flow by encompassing the particles’ deposition on a vertical surface was performed numerically in [
2]. Riley [
3] provided qualitative and reliable theoretical observations about convection flow around the heated sphere. He performed a numerical simulation of the governing equations for several finite several values of Prandtl as well as the Grashof number. Loyalka [
4] investigated the effects of thermophoretic transportation on a single particle by solving the linearized Boltzmann equation numerically. Kang and Greif [
5] found that there is a wide reduction in the deposition efficiency when there is no alignment of the torch with the target during the vapor deposition process.
A rigorous mathematical treatment of unsteady conjugate heat and the fluid flow mechanism about a solid sphere was achieved by Nguyen et al. [
6], and the Chebyshev-Legendre spectral method has been implemented for the numerical results of the governing model. A technical note on the effects of thermophoresis for spheres made up of solid and liquid in air was presented by Li and Davis [
7]. The influence of the surface mass through mixed convection over a vertical heated porous surface with a thermophoresis process was investigated by Selim et al. [
8]. They computed the numerical results of the flow by employing the implicit finite difference and perturbation techniques. Chamkha and Pop [
9] predicted the convective heat and fluid flow mechanism over the surface considered vertically fixed in porous medium and observed deposition effects on heat and mass transfer phenomenon. Chamkha et al. [
10] encountered the influences of heat generation and absorption combined with thermophoresis on convective flow on a vertical flat plate.
The convective flow phenomenon through the sphere under the action of the generation of heat and variable viscosity were investigated numerically in [
11,
12]. Postelnicu [
13] extended the work of Chamkha and Pop [
9] by considering the thermophoretic deposition along a normal direction from the surface of the proposed geometry. He found that the general behavior of heat and fluid flow mechanisms in both studies is synchronized.
The analytical solutions of the Soret and Dufour phenomenon by considering the thermophoretic particle deposition with the inclusion of chemical reactions were simulated by Siva Raman et al. [
14] by using a group theoretic method. They observed that the effects of thermophoresis are dominant as compared with thermal and mass diffusion. Musong and Feng [
15] proposed the problem of heat and fluid flow about a heated sphere by incorporating the different ranges of the Richardson as well as the Reynolds’ number. They found that the relationship between the heat transfer rate and the Richardson number is very linear for wide ranges of arbitrary incident flow angles in the laminar flow regime. Malai et al. [
16] concluded that the dependency factor of the thermophoretic force and velocity on the average temperature of the particle is nonlinear. Gompper et al. [
17] elaborated the fascination, significance, and diverse physical aspects of the self-propelled particles’ motion.
The viscous dissipation influences on mixed convection with periodic behavior of physical properties around the sphere were explored in [
18] numerically. Burelbach et al. [
19] measured the thermophoretic force on various polystyrene particles of a varying surface coating, negative charge, and size by using the bright field and came to the conclusion that colloids with the weakest zeta potential show the strongest thermophoretic effect.
Theoretical investigations of the thermophoretic forces on nano-cylinders suspended in gas and a mixture of gases were performed by Wang et al. [
20]. The comparison of the various forms of correction on the first-order derivative of the smooth particle hydrodynamics method is given in [
21]. The authors’ main focus was to determine the one optimal kernel approximation. Chang and Keh [
22] produced analytical results of the thermophoretic force induced by a spherical-shaped particle suspended in gas that has a uniform temperature gradient for a small Peclet number with the help of the asymptotic expansion method.
Yu et al. [
23] devoted their efforts to focus on the phenomenon of thermophoresis produced by the nano-spherical-shaped convex particle. The gas considered by them had a non-uniform temperature filled in the region of the free molecule. The thermophoresis transportation of spherical particles suspended in gas within a spherical-shaped cavity along with its material properties were examined by Li and Keh [
24] analytically. The characteristics of the shear stress and heat transfer rate around the surface of a sphere are discussed in [
25].
Juan et al. [
26] investigated the mixed convection heat transfer mechanism numerically and experimentally about a rectangular geometry whose sides were all adiabatic except the front, which was an isothermal side. The surface heating effects on a mixed convective fluid flow in a cylindrical geometry were examined by Osman et al. [
27].
Niu and Palberg [
28] proposed the study of the establishment and development of a modular approach regarding micro swimming. Xiong et al. [
29] proposed the study of particle deposition caused by thermophoretic force by using a modified Markov model. Karim et al. [
30] discussed the molten salt nanofluid as high-temperature fluid in a direct absorption solar collector system. They considered a two-dimensional computational fluid dynamics model of a direct absorption high-temperature molten salt nano-fluid concentrating solar receiver.
Minakov and Schick [
31] presented analytical solutions of the heat transfer problem for local fast thermal perturbations around carbon nano tube CNT-polymer. Investigators have presented analytical and numerical studies of the phenomena of thermophoresis in different fluids considering different geometries in [
32,
33,
34,
35,
36,
37].
Khan et al. [
38] performed a detailed analysis on the model and applications of nonofluid flow between infinite parallel plates suspended by micro cantilever sensors by adopting the effective Prandtl model.
Gompper et al. [
39] addressed the researchers of the present era about the different physical aspects and significance of the self-propulsion mechanism and motility of a huge number of identical agents by the help of the 2020 self-motile active matter roadmap.
Based on the above literature review, in the current study, a parametric analysis was conducted to analyze the effect of the dimensionless parameters involved in the flow model on the velocity distribution, temperature distribution, and mass concentration, as well as their derivatives along with the thermophoretic velocity. For this purpose, the finite difference method and a built-in numerical scheme boundary value problem of fourth order code BVP4C was used and the main numerical findings are displayed graphically and in a tabular form.
4. Results and Discussion
In the current analysis, simulation was performed for different values of the controlling parameters, including the Prandtl number Pr, mixed convection parameter
λt, Schmidt number Sc, thermophoresis parameter
Nt, thermophoretic coefficient κ, and modified mixed convection parameter
λC on the velocity field
U, temperature field θ, concentration distribution φ, and thermophoretic velocity
Vt around different positions of the surface of the sphere. Additionally, under the effect of these parameters, the numerical solutions of skin friction, the rate of heat transfer, and the rate of mass transfer are displayed in graphical as well tabular forms. The details of the obtained numerical solutions along with the physical behavior are given in the subsequent paragraphs. Additionally, the numerical solutions of the governing problem obtained by FDM were validated by the MATLAB built-in numerical solver BVP4C. Comparison of the numerical solutions obtained by both methods is given in
Table 1,
Table 2,
Table 3,
Table 4,
Table 5 and
Table 6 for different values of the different dimensionless parameters.
Figure 2a–c display the characteristics of the fluid velocity, the temperature of the domain, and the mass concentration for various values of the Prandtl number Pr around the surface of a sphere. From given plots, it is deduced that the velocity of the fluid flow is maximum at position
X = 1.5 radian. We can infer that the temperature and mass concentrations are well behaved at position
X = π radian for Pr = 0.71 and 7.0, respectively.
Figure 2a–c, show that the phenomena of fluid velocity, temperature distribution, and mass concentration are vice versa; that is, the fluid velocity and temperature distribution are reduced but the opposite attitude for the case of the mass concentration is noted. It was expected because an enhancement in Pr leads to a rise in the viscous force and reduces the thermal diffusion, which causes the fluid velocity and temperature of the domain to decrease. Physically, it is true when Pr increases, the momentum diffusion is actually increased, and thermal diffusion is decreased. The momentum and thermal diffusions act like retarding forces, which causes the above said phenomenon in
Figure 2a–c.
The impact of the various values of the modified mixed convection parameter,
λC, on the concentration, velocity, and temperature distributions is given through the results illustrated in
Figure 3a–c. The considered range for the modified mixed convection parameter is
λC = 10.0 and
λC = 50.0, and very much spans over a wide range of possible operating conditions, which were observed.
The figures show that the velocity profile is prominent at position X = 1.5 radian and has maximum motion for λC = 50.0 radian. It is also noticed that the temperature and mass distributions have a maximum magnitude at position X = π radian and minimum magnitude at position X = 1.5 radian.
Mathematically speaking, it can be noticed that the boundary condition in the figures is highly satisfied at the surface and far from the surface asymptotically. It is concluded that with an increase of
λC, the mass concentration difference is increased so the velocity of the fluid is enhanced and, consequently, the temperature and mass concentration decrease.
Figure 4a–b present the typical velocity, temperature, and mass concentration profiles for three different positions around a sphere for Sc = 1.0 and 10.0, respectively.
From the graphical results, it is predicted that an augmentation in Sc implies a significant decrease in the velocity and mass profiles and an increase in the temperature profile is observed. By viewing the behavior of the velocity, temperature, and mass profiles at several circumferential points around a sphere, it can be concluded that the velocity distribution attains a higher magnitude at X = 1.5 radian but the temperature and mass profiles achieve their higher magnitude at X = π radian. One noticeable point is that no difference is found in the velocity profile at X = π radian. The above said phenomenon takes place because with the increase of the Schmidt number, molecular diffusion is reduced, and viscous force is increased. It is predicted that with the increase of Sc, the viscosity of the fluid flow domain dominates the mass diffusion per unit volume, which reduces the fluid velocity at each position of the sphere.
Figure 5a,b displays the effect of the mixed convection parameter,
λt, at different circumferential stations around the sphere on velocity, temperature, and mass profiles, respectively. The plots indicate that by increasing the values of the mixed convection parameter,
λt, from 10.0 to 50.0 by keeping the other parameters fixed, the velocity profile increases but the temperature and mass profiles decrease. It can be observed that the fluid velocity approaches its highest value at
X = 1.5 radian, but the temperature and mass profiles approach maximum values at
X = π radian.
The results provide information indicating that no difference in the temperature profile and mass concentration is observed at position X = π radian corresponding to increasing values of λt. In this mechanism, we noticed that the buoyancy force is working as a controlling parameter and is responsible for delaying or speeding up the fluid’s motion.
In
Figure 6a–c, the behavior of the skin friction, heat transfer rate, and mass transfer rate for several values of the mixed convection parameter,
λt = 10.0, 100.0, when the other parameters remain fixed is highlighted. We can see that as
λt is enhanced, the slopes of the velocity, temperature, and mass concentration profiles increase at positions
X = 0.1 radian and
X = 1.5 radian around a sphere, but at position
X = π radian, all of the three physical quantities show no reasonable change corresponding to an increase in
λt.
It can be observed that all three quantities are magnified at position
X = 1.5 radian, and lower magnifications are noted at
X = π radian.
Figure 7a–b depict that for the Prandtl number Pr = 0.71 and 7.0, by keeping the other parameters fixed, skin friction decreases at
X = 0.1 radian and
X = 1.5 radian, but no change is observed at
X = π radian.
On the other hand, the heat transfer rate and the mass transfer rate increase and decrease, respectively, with the augmentation in Pr. It can be noted that all three quantities secure their highest values at position
X = 1.5 radian around a sphere.
Figure 8a,b reveal the typical variations in skin friction, and the heat transfer rate along with the mass transfer rate at the expense of distinct Schmidt number values when the rest of the physical parameters are kept constant.
As Sc is increased, it gives rise to a loss of skin friction and the rate of heat transfer, and an increase in the rate of mass transfer is observed. It is shown that skin friction at position
X = 1.5 radian achieves its maximum value and minimum value at
X = π radian, and similar results are observed for the heat and mass transfer rates.
Figure 9a–c elaborate on the effect of various estimations of
λC on the skin friction, heat transfer rate, and mass transfer rate.
From the graphical demonstration, it is shown that the effect of modified mixed convection on skin friction along with the heat and mass transfer rates is more profound at position X = 1.5 radian. Further, in all cases, the amount of skin friction with the heat and mass transfer rate is dominated at position X = π radian.
The behavior of the skin friction, rate of heat, and mass transfer under the influence of different values of the thermophoresis parameter,
Nt, when other parameters involved in the flow model are kept fixed is highlighted in
Figure 10a–c. It can be viewed that around different positions of a sphere, when the thermophoresis parameter increases, the skin friction and rate of heat transfer are enhanced but the mass transfer rate decreases.
By observing the variations in the skin friction and the heat and mass transfer rate around three different positions of a sphere, it is revealed that all of the aforementioned thermo physical quantities attain the highest values at X = 1.5 radian.
Figure 11a,b depict the influence of the thermophoresis parameter,
Nt, and thermophoretic coefficient, κ, on the thermophoretic velocity,
Vt, at three different stations around the surface of a sphere against the volume fraction of the submicron particles. In these figures, it is shown that the thermophoretic velocity at the surface of the sphere is higher at position
X = 1.5 radian, and in both cases, it approaches zero as the fraction or particle size is increased. Further, the curves in the graph intersect at a horizontal axis due to the mixing attitude of the thermophoresis particles.
Table 1,
Table 2,
Table 3,
Table 4,
Table 5 and
Table 6 show a comparison of the results for the skin friction, rate of heat transfer, and rate of mass transfer for different values of the mixed convection parameter,
λt, and thermophoretic coefficient, κ, when the rest of the physical parameters are kept constant at a favorable point
X = 1.5 radian. It is observed that there is good agreement between the results of the present problem obtained by FDM and the built-in numerical solver BVP4C technique.
The numerical solutions of the proposed model by FDM were obtained on the entire surface of the flow geometry. On the other hand, solutions by the built-in numerical solver BVP4C were obtained only at the leading edge of the surface of the proposed geometry for a similar form of the equations given in Equations (22)–(24) with the boundary conditions of Equation (25). Therefore, the results computed by the finite difference method were validated by the built-in numerical solver BVP4C at the leading edge. The comparison of the results by both methods supports the argument that main proposed method, which is FDM, applied for the current problem is accurate.
Table 1,
Table 2 and
Table 3 depict the numerical solutions for the skin friction, the rate of heat transfer, and the rate of mass transfer, respectively, computed by FDM and BVP4C at the leading edge for several values of the mixed convection parameter,
λt, at
X = 1.5 radian when the rest of the dimensionless numbers are kept constant. From these tables, it is seen that increasing values of
λt lead to an enhancement of the skin friction, rate of heat transfer, and rate of mass transfer.
Physically, it is endorsed that augmentation in
λt is basically due to an increase in the buoyancy force. The increase in buoyancy force causes an enhancement of the thermal expansion and temperature difference between the temperature of the surface of the sphere and the ambient temperature, due to which the temperature gradient increases and the slopes of the velocity and mass concentration increase. The percentage error at each value of
λt was calculated, and it is concluded that there are many favorable values of
λt where FDM and BVP4C are very close, which shows the agreement of the physical reasoning.
Table 4,
Table 5 and
Table 6 display the behavior of the abovementioned quantities for different values of the thermophoretic coefficient, κ, at
X = 1.5 radian when the remaining pertinent parameters are taken at their fixed values. From
Table 4,
Table 5 and
Table 6, it is concluded that the skin friction and the rate of heat transfer increases, but the rate of mass transfer decreases. Again, the percentage error for each value of κ appears to be very small, t which shows the validation of FDM at the leading edge.