Comparative Study between Direct and Pseudomorphic Transformation of Rice Husk Ash into MFI-Type Zeolite
AbstractPre-shaped mesoporous amorphous rice husk ash (RHA) and MCM-41 derived from RHA as a silica source were transformed into MFI-type zeolites using two different structure-directing agents. Tetrapropylammonium hydroxide (TPAOH) was utilized as an alkali source for silica dissolution and structure control during the direct transformation of RHA into zeolite. A monopropylamine (PA)-containing alkaline solution (NaOH) was used for the pseudomorphic transformation of RHA or MCM-41 into zeolite. The hydrothermal conversion of RHA or MCM-41 into MFI-type zeolites was investigated as a function of reaction time at 175 °C. With PA as template, the crystallization took place inside and on the outer surface of RHA or MCM-41 without losing the original shape of the initial silica sources, while TPAOH led to the formation of conventional MFI-type zeolite crystals due to the complete dissolution of RHA. The final products were characterized by X-ray diffraction, nitrogen adsorption, scanning electron microscopy, and optical emission spectroscopy. View Full-Text
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Alyosef, H.A.; Roggendorf, H.; Schneider, D.; Inayat, A.; Welscher, J.; Schwieger, W.; Münster, T.; Kloess, G.; Ibrahim, S.; Enke, D. Comparative Study between Direct and Pseudomorphic Transformation of Rice Husk Ash into MFI-Type Zeolite. Molecules 2018, 23, 1.
Alyosef HA, Roggendorf H, Schneider D, Inayat A, Welscher J, Schwieger W, Münster T, Kloess G, Ibrahim S, Enke D. Comparative Study between Direct and Pseudomorphic Transformation of Rice Husk Ash into MFI-Type Zeolite. Molecules. 2018; 23(1):1.Chicago/Turabian Style
Alyosef, Hallah A.; Roggendorf, Hans; Schneider, Denise; Inayat, Alexandra; Welscher, Julia; Schwieger, Wilhelm; Münster, Tom; Kloess, Gert; Ibrahim, Suzan; Enke, Dirk. 2018. "Comparative Study between Direct and Pseudomorphic Transformation of Rice Husk Ash into MFI-Type Zeolite." Molecules 23, no. 1: 1.
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