Search Results (5)

The limited availability of high-quality ore deposits and the environmental hazards of metallurgical wastes highlight the importance of developing resource-efficient metal recovery technologies. Zinc kiln slag (ZKS), also known as Waelz slag, a by-product material enriched in non-ferrous metals, was processed through oxidative HCl leaching with H₂O₂ as an oxidant. Thermodynamic simulation and laboratory experiments were applied to determine optimal leaching conditions to dissolve copper, zinc, and iron. Optimal leaching efficiency was achieved with consumptions of 0.8 g HCl and 0.1 g H₂O₂ per gram of ZKS, a liquid-to-solid (L/S) ratio of 5 mL/g, a temperature of 70 °C, and a duration of 180 min, which resulted in recoveries of 96.3% Cu, 93.6% Fe, and 76.8% Zn. The solid residue with 43.5 wt.% C is promising for reuse as a reductant material in pyrometallurgical processes. Copper and arsenic were separated from the leachate via cementation with iron powder, achieving recovery rates of 98.9% and 91.2%, respectively. A subsequent two-step iron precipitation produced ferric hydroxide with 52.2 wt.% Fe and low levels of impurities. As a result, the developed novel hydrochloric acid oxidative leaching and metal precipitation route for ZKS recycling provides an efficient and sustainable alternative to conventional treatment methods. Full article

Millions of tons of slag and clinker can be found in the dumps of enterprises across the Republic of Kazakhstan. The goal of this project is to create a technology that conserves energy in waste treatment. The novelty of the work is the discovery of a new phenomenon, which shows that in the melt layer, there are two reactions opposite in direction and intensity: slow reactions of the decomposition of complex components into simple molecules and rapid responses of the formation of complex components from simple molecules. The dominance of one of the two reactions affects the process’s fuel consumption. Using this phenomenon, a melting reactor was created, which will reduce specific fuel consumption by 3–4 times compared to a Waelz kiln. It is shown that using a new method of CO₂ decarbonization by zinc, it is possible to ensure the production of zinc sublimates and cast stone products and the full neutralization of CO₂. The lowest market potential only for Achisai dump clinker would be around USD 125,600,000 if the cost of commercial clinker sublimates is USD 800/t. The expected net profit would be USD 4,466,039/y. Full article

The harmless treatment of historical lead smelting slag (LSS) is of significance to ecological and environmental protection, but it is still challenging in terms of the economic feasibility of alone processing due to the low content of valuable metals. Here, we performed an industrialized test with a co-treatment of LSS and zinc oxide ore in a rotary kiln to evaluate the economic feasibility and solidification effect of harmful elements. The results revealed that more than 70% of Zn and Pb were recovered from LSS in the form of dust, while the nonvolatile part of Pb, Zn, and Cd were solidified in gangue as complex silicate phases. The nonvolatile part of As came into being Fe-As intermetallic compound which was encapsulated by gangue particles or was solidified in silicate phases. The entirely enclosed structure of water-quenched slag plays an important role in the stability of slag. The TCLP and SNAL leaching tests demonstrated the high stability of water-quenched slag. A zinc oxide ore addition of 20% was recommended for energy consumption and processing capacity. Our findings highlight that the valuable metals not only can be effectively recovered but also harmful elements are solidified in gangue, providing an economical and feasible technical route for the treatment of historical LSS. Full article

(1) Background: The importance of Zinc in today’s world can hardly be exaggerated—from anticorrosion properties, to its durability, aesthetic, and even medicinal uses—zinc is ever-present in our daily lives ever since its discovery in ancient times. The natural, essential, durable, and recyclable features of zinc make it a prized material with uses in many applications across a wide array of fields. The purpose of this study was to compare two life cycle impact assessments of zinc production by using two different main raw materials: (A) zinc concentrates (sulfide ore) and (B) Waelz oxides (obtained through recycling existing imperial smelting process furnace slags). The Waelz oxide scenario was based on a case study regarding the existing slag deposit located in Copsa Mica town, Sibiu county, Romania. (2) Methods: consequential life cycle impact assessment methods were applied to each built system, with real process data obtained from the case study enterprise. (3) Results: Overall, the use of slags in the Waelz kiln to produce zinc oxides for use in the production of zinc metal is beneficial to the environment in some areas (acidification, water, and terrestrial eutrophication), whereas in other areas it has a slightly larger impact (climate change, photochemical ozone formation, and ozone depletion). (4) Conclusions: The use of slags (considered a waste) is encouraged to produce zinc metal, where available. The results are not absolute, suggesting the further need for fine-tuning the input data and other process parameters. Full article

This work deals with the influence of zinc on cement hydration. The amount of zinc in cement has increased over recent years. This is mainly due to the utilization of solid waste and tires, which are widely used as a fuel in a rotary kiln. Zinc can also be introduced to cement through such secondary raw materials as slag, due to increased recycling of galvanized materials. The aim of this work was to determine the effect of zinc on the hydration of Portland cement, blended with ground blast furnace slag (GBFS). This effect was studied by isothermal and isoperibolic calorimetry. Both calorimetry methods are suitable for measurements during the first days of hydration. Isoperibolic calorimetry monitors the hydration process in real-life conditions, while isothermal calorimetry does so at a defined chosen temperature. Zinc was added to the cement in the form of two soluble salts, namely Zn(NO₃)₂, ZnCl₂, and a poorly soluble compound, ZnO. The concentration of added zinc was chosen to be 0.05, 0.1, 0.5, and 1mass percent. The amount of GBFS replacement was 15% of cement dosage. The newly formed hydration products were identified by X-ray diffraction method (XRD). Full article