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Keywords = zero-gap conductors

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20 pages, 4299 KB  
Article
Establishment Mechanism of Power-Frequency Follow-Current Arc on Medium-Voltage Insulated Conductors Under Lightning Overvoltage
by Xin Ning, Rui Yu, Longchen Liu, Jiayi Wang, Jingxin Zou, Hao Wang, Tian Tan, Huajian Peng and Xin Yang
Inventions 2026, 11(2), 28; https://doi.org/10.3390/inventions11020028 - 18 Mar 2026
Cited by 1 | Viewed by 630
Abstract
Lightning-induced breaking accidents of medium-voltage insulated conductors pose a serious threat to the safety of distribution networks, and the key cause lies in the establishment and sustained combustion of the power-frequency follow-current arc after lightning overvoltage breakdown. This paper systematically investigates the formation [...] Read more.
Lightning-induced breaking accidents of medium-voltage insulated conductors pose a serious threat to the safety of distribution networks, and the key cause lies in the establishment and sustained combustion of the power-frequency follow-current arc after lightning overvoltage breakdown. This paper systematically investigates the formation mechanism and critical conditions of power-frequency follow-current arcs using combined simulation and experimental approaches. Based on the streamer discharge theory, a lightning breakdown model was established and combined with the arc energy balance equation, revealing that the establishment of power-frequency follow-current arcs is essentially determined by the post-breakdown energy competition process. The simulation results show that the required anode electric field strength for lightning breakdown is not less than 3 kV/mm. When the power-frequency voltage reaches 10 kV, Joule heating of the arc continuously exceeds heat dissipation loss, enabling restrike after zero-crossing and sustaining stable burning. Experiments verified this voltage threshold and further revealed that the arc establishment rate exhibits nonlinear growth with increasing power-frequency voltage, exceeding 90% at power-frequency voltages ≥ 10 kV. The study also reveals that increased gap distance reduces the arc establishment rate, while the introduction of insulators can enhance it by approximately 20%. This study clarifies the energy criterion for power-frequency follow-current arc establishment and the influence patterns of key parameters, providing theoretical basis and engineering reference for lightning protection design and arc suppression in medium-voltage insulated lines. Full article
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13 pages, 4784 KB  
Article
New Organic Crystalline Material Close to Nodal-Line Materials: α′-STF2IBr2
by Koki Funatsu, Ryuhei Oka, Naoya Tajima and Toshio Naito
Crystals 2023, 13(11), 1606; https://doi.org/10.3390/cryst13111606 - 20 Nov 2023
Cited by 3 | Viewed by 2156
Abstract
Recently, topological materials (TMs) have attracted attention from various scientists. Their electronic properties are governed by relativistic particles called Dirac fermions which, in some cases, possess no masses and move in solids with the speed of light. In addition to the unique particles, [...] Read more.
Recently, topological materials (TMs) have attracted attention from various scientists. Their electronic properties are governed by relativistic particles called Dirac fermions which, in some cases, possess no masses and move in solids with the speed of light. In addition to the unique particles, such materials exhibit unprecedented electronic properties because of the quantum effects (interference between wavefunctions). Examples include nodal-line materials (NLMs), where metallic or even superconducting properties may appear only at the surface of the single crystals of insulators. Thus far, whether they be organic or inorganic compounds, TMs have hardly been discovered except for the zero-gap conductors (ZGCs), because there is no guideline on how to develop such unusual materials. In this work, we prepared a new organic charge–transfer complex, α′-STF2IBr2 (STF = bis(ethylenedithio)diselenadithiafulvalene), which measured the electrical and magnetic properties and calculated the band structure and intermolecular interactions. A close comparison with those of α-STF2I3, being established as a ZGC at p > 12–15 kbar, revealed that α′-STF2IBr2 is also closely related to it, but belongs to a different type of TMs, namely NLMs. This finding will accelerate the successive findings of NLMs to elucidate the mechanism of their unique electronic properties. Full article
(This article belongs to the Special Issue Charge-Transfer Complexes (CTCs) and Related Interactions)
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16 pages, 6112 KB  
Article
Exploiting Surface Plasmon with Dielectric Coating in Copper Wires Waveguide for the Propagation of Terahertz Waves
by Arslan Ahmed Sohoo, Fauziahanim Che Seman, Ahmed Jamal Abdullah Al-Gburi, Hamza Ahmad, Yee See Khee, Nurul Syafeeqa Binti Ishak, Thamer A. H. Alghamdi and Moath Alathbah
Coatings 2023, 13(11), 1857; https://doi.org/10.3390/coatings13111857 - 29 Oct 2023
Cited by 2 | Viewed by 2621
Abstract
Recently, metallic wires have gained popularity for utilization as waveguides in propagating sub-THz and THz waves through surface plasmonic polaritons (SPPs). Single and double metallic wire waveguides have demonstrated the ability to propagate these high frequencies with minimal loss and nearly zero dispersion. [...] Read more.
Recently, metallic wires have gained popularity for utilization as waveguides in propagating sub-THz and THz waves through surface plasmonic polaritons (SPPs). Single and double metallic wire waveguides have demonstrated the ability to propagate these high frequencies with minimal loss and nearly zero dispersion. However, wires typically installed commercially are often coated with dielectric material. Therefore, this paper investigated the effects of using two and four metallic copper wires, both with and without dielectric coating. The impact of various gap distances on different propagation characteristics was also analyzed. Computer Simulation Technology (CST) Microwave Studio was employed in this study for electromagnetic simulations of both uncoated and coated configurations of two and four wires. The introduction of a dielectric coating led to an enhancement in reducing conductor losses and improving energy confinement, with the goal of enhancing the overall efficiency of waveguide signal propagation. Full article
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31 pages, 1744 KB  
Review
Recent Advances in Membrane-Based Electrochemical Hydrogen Separation: A Review
by Leandri Vermaak, Hein W. J. P. Neomagus and Dmitri G. Bessarabov
Membranes 2021, 11(2), 127; https://doi.org/10.3390/membranes11020127 - 13 Feb 2021
Cited by 113 | Viewed by 15546
Abstract
In this paper an overview of commercial hydrogen separation technologies is given. These technologies are discussed and compared—with a detailed discussion on membrane-based technologies. An emerging and promising novel hydrogen separation technology, namely, electrochemical hydrogen separation (EHS) is reviewed in detail. EHS has [...] Read more.
In this paper an overview of commercial hydrogen separation technologies is given. These technologies are discussed and compared—with a detailed discussion on membrane-based technologies. An emerging and promising novel hydrogen separation technology, namely, electrochemical hydrogen separation (EHS) is reviewed in detail. EHS has many advantages over conventional separation systems (e.g., it is not energy intensive, it is environmentally-friendly with near-zero pollutants, it is known for its silent operation, and, the greatest advantage, simultaneous compression and purification can be achieved in a one-step operation). Therefore, the focus of this review is to survey open literature and research conducted to date on EHS. Current technological advances in the field of EHS that have been made are highlighted. In the conclusion, literature gaps and aspects of electrochemical hydrogen separation, that require further research, are also highlighted. Currently, the cost factor, lack of adequate understanding of the degradation mechanisms related to this technology, and the fact that certain aspects of this technology are as yet unexplored (e.g., simultaneous hydrogen separation and compression) all hinder its widespread application. In future research, some attention could be given to the aforementioned factors and emerging technologies, such as ceramic proton conductors and solid acids. Full article
(This article belongs to the Special Issue Polymer Membranes for Gas Separation)
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13 pages, 6884 KB  
Article
Band Structure and Physical Properties of α-STF2I3: Dirac Electrons in Disordered Conduction Sheets
by Toshio Naito and Ryusei Doi
Crystals 2020, 10(4), 270; https://doi.org/10.3390/cryst10040270 - 2 Apr 2020
Cited by 13 | Viewed by 3667
Abstract
The compound being investigated is an organic charge-transfer complex of the unsymmetrical donor STF with I3 [STF = bis(ethylenedithio)diselenadithiafulvalene], which is isostructural with α-ET2I3 and α-BETS2I3 [ET = bis(ethylenedithio)tetrathiafulvalene, BETS = bis(ethylenedithio)tetraselenafulvalene]. According to recent studies, [...] Read more.
The compound being investigated is an organic charge-transfer complex of the unsymmetrical donor STF with I3 [STF = bis(ethylenedithio)diselenadithiafulvalene], which is isostructural with α-ET2I3 and α-BETS2I3 [ET = bis(ethylenedithio)tetrathiafulvalene, BETS = bis(ethylenedithio)tetraselenafulvalene]. According to recent studies, the calculated band structure should represent a zero-gap semiconductor at 1 bar that is similar to α-ET2I3 under high pressure (>15 kbar). Such materials have attracted extensive interest because the electrons at the Fermi level can be massless Dirac fermions (MDFs), with relativistic behaviors like those seen in graphene. In fact, α-STF2I3 exhibited nearly temperature-independent resistivity, ρ, (~100–300 K), a phenomenon that is widely observed in zero-gap semiconductors. The non-Arrhenius-type increase in ρ (<~100 K) was consistent with the characteristics of interacting MDFs. The paramagnetic susceptibility, χ, (2–300 K)—as well as the reflectivity, R and optical conductivity, σ, (25–300 K; 400–25,000 cm−1)—were also almost temperature independent. Furthermore, σ was practically independent of wavenumber at ~6000–15,000 cm−1. There was no structural transition based on X-ray studies (90–300 K). Considering all the electrical, magnetic, optical and structural properties of α-STF2I3 at 1 bar, it was concluded that the salt possesses a band structure characterized with Dirac cones, which was consistent with the calculation. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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17 pages, 5087 KB  
Review
Effects of Carrier Doping on the Transport in the Dirac Electron System α-(BEDT-TTF)2I3 under High Pressure
by Naoya Tajima
Crystals 2018, 8(3), 126; https://doi.org/10.3390/cryst8030126 - 8 Mar 2018
Cited by 12 | Viewed by 5587
Abstract
A zero-gap state with a Dirac cone type energy dispersion was discovered in an organic conductor α-(BEDT-TTF)2I3 under high hydrostatic pressures. This is the first two-dimensional (2D) zero-gap state discovered in bulk crystals with a layered structure. Moreover, the Dirac [...] Read more.
A zero-gap state with a Dirac cone type energy dispersion was discovered in an organic conductor α-(BEDT-TTF)2I3 under high hydrostatic pressures. This is the first two-dimensional (2D) zero-gap state discovered in bulk crystals with a layered structure. Moreover, the Dirac cones are highly tilted in a k-space. This system, thus, provides a testing ground for the investigation of physical phenomena in the multilayered, massless Dirac electron system with anisotropic Fermi velocity. Recently, the carrier injection into this system has been succeeded. Thus, the investigations in this system have expanded. The recent developments are remarkable. This effect exhibits peculiar (quantum) transport phenomena characteristic of electrons on the Dirac cone type energy structure. Full article
(This article belongs to the Special Issue Advances in Organic Conductors and Superconductors)
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19 pages, 3580 KB  
Review
Transport Phenomena in Multilayered Massless Dirac Fermion System α-(BEDT-TTF)2I3
by Naoya Tajima, Yutaka Nishio and Koji Kajita
Crystals 2012, 2(2), 643-661; https://doi.org/10.3390/cryst2020643 - 11 Jun 2012
Cited by 9 | Viewed by 8073
Abstract
A zero-gap state with a Dirac cone type energy dispersion was discovered in an organic conductor α-(BEDT-TTF)2I3 under high hydrostatic pressures. This is the first two-dimensional (2D) zero-gap state discovered in bulk crystals with a layered structure. In contrast to [...] Read more.
A zero-gap state with a Dirac cone type energy dispersion was discovered in an organic conductor α-(BEDT-TTF)2I3 under high hydrostatic pressures. This is the first two-dimensional (2D) zero-gap state discovered in bulk crystals with a layered structure. In contrast to the case of graphene, the Dirac cone in this system is highly anisotropic. The present system, therefore, provides a new type of massless Dirac fermion system with anisotropic Fermi velocity. This system exhibits remarkable transport phenomena characteristic to electrons on the Dirac cone type energy structure. Full article
(This article belongs to the Special Issue Molecular Conductors)
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18 pages, 705 KB  
Review
Theory of Dirac Electrons in Organic Conductors
by Yoshikazu Suzumura and Akito Kobayashi
Crystals 2012, 2(2), 266-283; https://doi.org/10.3390/cryst2020266 - 20 Apr 2012
Cited by 12 | Viewed by 8042
Abstract
The dynamical property of electrons with the tilted Dirac cone was examined using the tilted Weyl equation. The polarization function exhibits cusps and nonmonotonic structures by varying both the frequency and the momentum. A pair of tilted Dirac cones exhibits a new plasmon [...] Read more.
The dynamical property of electrons with the tilted Dirac cone was examined using the tilted Weyl equation. The polarization function exhibits cusps and nonmonotonic structures by varying both the frequency and the momentum. A pair of tilted Dirac cones exhibits a new plasmon for the intermediate magnitude of momentum owing to the combined effects of two tilted cones. Dirac electrons with the zero-gap state (ZGS) in organic conductor α-(BEDT-TTF)2I3 are examined by calculating the Berry curvature, which displays the peak structure for a pair of Dirac particles between the conduction band and the valence band. The ZGS is theoretically predicted for α-(BEDT-TTF)2NH4Hg(SCN)4 under uniaxial pressure. Examining the band structure of the stripe charge ordered state of α-(BEDT-TTF)2I3 under pressure, we have found a topological transition from a conventional insulator to a new phase of a pair of Dirac electrons with a finite mass. Further, investigating the zero-energy (N = 0) Landau level under a strong magnetic field, we propose ferromagnetism breaking the SU(2) valley-pseudo-spin symmetry, and the phase fluctuations of the order parameters leading to Kosterlitz-Thouless transition at lower temperatures. Full article
(This article belongs to the Special Issue Molecular Conductors)
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