Search Results (24)

This research aimed to characterise hydrocarbonoclastic bacteria isolated from naturally hydrocarbon-contaminated springs and the surrounding soils in the Agri Valley (Southern Italy) and to assess the effectiveness of bioaugmentation using a four-strain microbial consortium for removing hydrocarbons from artificially diesel-contaminated lake waters in mesocosm experiments. Four novel bacterial strains were selected for the experimentation: Gordonia amicalis S2S5, Rhodococcus erythropolis S2W2, Acinetobacter tibetensis S2S8, and Acinetobacter puyangensis S1W1. The four isolates can use diesel oil as their sole carbon source, and some exhibited a relatively high emulsifying capacity and ability to adhere to hydrocarbons. Furthermore, genome analyses revealed the presence of genes associated with the degradation, detoxification, and transport of various contaminants. Mesocosm experiments demonstrated that the bioaugmentation enhanced the capacities of the native lake microbial communities to remove hydrocarbons, although drastic changes in their composition (analysed through Next-Generation Sequencing—NGS) were observed. Taken together, these results suggest that naturally contaminated environments can serve as a valuable reservoir of microorganisms with significant biotechnological potential, particularly in the field of bioremediation. However, a complete understanding of the ability of the isolated bacterial strains to efficiently degrade contaminants requires further research to fully assess their capabilities and limitations across different settings. Full article

The search for alternative fuels is driven by increasing environmental and health concerns across the globe. Water-in-diesel emulsions (WiDEs) have been explored over the years as a potential fuel for diesel engines to mitigate emissions of greenhouse gases, especially nitrogen oxides and smoke. Researchers have been developing and testing different formulations of emulsified fuels with the common goal of stabilizing the mixture and minimizing pollutant emissions without significantly compromising engine performance. In this work, a novel approach is taken by developing a hydrophilic emulsion formulation optimized for engine operating temperatures, overcoming the storage-related stability issues that most studies focus on. Two different mixtures of WiDE were heated and supplied to a Hatz 1B40 single-cylinder diesel engine. The engine was coupled to an eddy current dynamometer to measure speed, torque, and power values. Emissions of carbon monoxide (CO), carbon dioxide (CO₂), hydrocarbons (HCs), nitric oxide (NO), and oxygen (O₂) were measured by an AVL DiGas 1000 exhaust gas analyzer. Smoke emissions were measured by an AVL DiSmoke 480. This study represents a contribution to the field of alternative fuels for diesel engines by providing experimental evidence that formulating WiDE for operating temperatures can be advantageous and significantly improve thermal efficiency and reduce emissions of NO and smoke at specific engine operating conditions, with a maximum reduction of 46.86% for NO emissions and a maximum reduction of 83.67% for smoke emissions obtained when compared to diesel. Full article

Managing chemical reactivity is crucial for sustainable chemistry and industry, fostering efficiency, reducing chemical waste, saving energy, and protecting the environment. Emulsification is used for different purposes, among them controlling the reactivity of highly reactive chemicals. Thermochemical fluids (TCFs), such as NH₄Cl and NaNO₂ salts, have been utilized in various applications, including the oil and gas industry. However, the excessive reactivity of TCFs limits their applications and consequently negatively impacts the potential success rates. In this study, an emulsification technique was employed to control the high reactivity of TCFs explored at 50% and 70% in diesel, using three distinct emulsifier systems at concentrations of 1%, 3%, and 5% to form water-in-oil emulsions. The reactivity of 4M neat TCFs and emulsified solutions was examined in an autoclave reactor as a function of triggering temperatures of 65–95 °C, volume fraction, and emulsifier type and concentration. Additionally, this study explores an alternative method for controlling TCF reactivity through pH adjustment. It investigates the impact of TCFs at pH values ranging from 6 to 10 and the initial pressure on the resulting pressure, temperature, and time needed to initiate the TCF’s reaction. The results revealed that both emulsification and pH adjustment have the potential to promote sustainability by controlling the reactivity of TCF reactions. The findings from this study can be utilized to optimize various downhole applications of TCFs, enhancing the efficiency of TCF reactions and success rates. This paper presents in detail the results obtained, and discusses the potential contributions of the examined TCFs’ reactivity control techniques to sustainability. Full article

Rhamnolipids (RLs) are widely used biosurfactants produced mainly by Pseudomonas aeruginosa and Burkholderia spp. in the form of mixtures of diverse congeners. The global transcriptional regulator gene irrE from radiation-tolerant extremophiles has been widely used as a stress-resistant element to construct robust producer strains and improve their production performance. A P_rhlA-irrE cassette was constructed to express irrE genes in the Pseudomonas aeruginosa YM4 of the rhamnolipids producer strain. We found that the expression of irrE of Deinococcus radiodurans in the YM4 strain not only enhanced rhamnolipid production and the strain’s tolerance to environmental stresses, but also changed the composition of the rhamnolipid products. The synthesized rhamnolipids reached a maximum titer of 26 g/L, about 17.9% higher than the original, at 48 h. The rhamnolipid production of the recombinant strain was determined to be mono-rhamnolipids congener Rha–C₁₀–C₁₂, accounting for 94.1% of total products. The critical micelle concentration (CMC) value of the Rha–C₁₀–C₁₂ products was 62.5 mg/L and the air-water surface tension decreased to 25.5 mN/m. The Rha–C₁₀–C₁₂ products showed better emulsifying activity on diesel oil than the original products. This is the first report on the efficient production of the rare mono-rhamnolipids congener Rha–C₁₀–C₁₂ and the first report that the global regulator irrE can change the components of rhamnolipid products in Pseudomonas aeruginosa. Full article

Diesel engines are known for their excellent efficiency and are therefore used in a variety of applications. However, they are also one of the main sources of hazardous emissions such as nitrogen oxides (NO_x) and smoke. Water-in-Diesel Emulsion (WiDE) is an alternative fuel that can possibly reduce some of the pollutant emissions without compromising engine performance. The surfactant formulation for WiDE usually follows the one used in water-in-oil (w/o) emulsions, where low hydrophilic–lipophilic balance (HLB) emulsifiers are preferred for better solubility in the diesel phase and stabilization at storage temperatures. However, by using a hydrophilic blend with a non-ionic surfactant, it is possible to develop an optimized formulation at higher fuel temperatures, which occur during an engine’s operating condition, achieving possibly higher benefits. Across the different speeds, the results for the emulsion show 7.57% mean improvement in specific fuel consumption (SFC), 19.14% mean improvement in thermal efficiency (TE), 5.54% mean reduction in carbon dioxide (CO₂), 20.50% mean reduction in nitric oxide (NO) and 75.19% mean reduction in smoke levels. However, carbon monoxide (CO) and hydrocarbons (HC) emissions were higher, with a mean increase of 81.09% and 93.83%, respectively. Full article

The quantum chemical properties of long-flame coal (LFC) and collectors (kerosene, diesel, diethyl phthalate (DEP), biodiesel collector (BDC), and emulsified biodiesel collector (EBDC)) were analyzed via the density functional theory (DFT). The molecular dynamics (MD) of the coal–collector–water system and the adsorption of collectors on LFC were conducted based on the first principles. The results showed that the frontier molecular orbitals of kerosene, diesel, DEP, and BDC were 0.38 eV, 0.28 eV, 0.27 eV, and 0.20 eV, respectively. The chemical reactivity order of the above mentioned collectors was BDC > DEP > diesel > kerosene. Kerosene, diesel, and DEP adsorbed with carbonyl, hydroxyl, and carboxyl groups in LFC, respectively. Carboxyl groups in BDC and carboxyl groups in LFC bilaterally adsorbed, while BDC repelled water molecules via hydrogen bonds on the LFC surface. In the systems of BDC and EBDC, the diffusion coefficients of a water molecule were 2.83 × 10⁻⁴ cm²/s and 3.73 × 10⁻⁴ cm²/s. The emulsifier that adsorbed onto the oil–water interface of the coal–BDC–water system improved the dispersion of BDC during flotation, while at the same time increasing the number of hydrogen bonds between BDC and LFC, which accelerated the migration of water molecules from the LFC surface. Full article

The development of cost-effective technologies for the treatment of water contaminated by petrochemicals is an environmental priority. This issue is of paramount importance for countries like Saudi Arabia owing to its scarce water resources. Of particular concern are automobile fuels, such as gasoline and diesel, that can contaminate water aquifers from leaking underground fuel storage tanks. Owing to the cost-effectiveness of adsorption-based technologies, low-cost high surface-area commercial activated carbon was used for the adsorptive removal of contaminants from the emulsified fuel-contaminated water. Batch equilibrium experiments showed a high efficacy of the adsorbent. Even with small amounts of the adsorbent, a removal efficiency of more than 97% was obtained for both gasoline as well as diesel. Three different well-known batch adsorption isotherm models, namely the Langmuir, Freundlich, and Temkin, were used for describing the experimental data. The best results were obtained using the Freundlich isotherm followed by the Langmuir model. The maximum capacity was found to be 8.3 g gasoline and 9.3 g diesel per gram of the adsorbent at ambient conditions for a neutral contaminated aqueous solution. Full article

Water-in-diesel (W/D) emulsion fuel is a potentially viable diesel fuel that can simultaneously enhance engine performance and reduce exhaust emissions in a current diesel engine without requiring engine modifications or incurring additional costs. In a consistent manner, the current study examines the impact of adding water, in the range of 5–30% wt. (5% increment) and 2% surfactant of polysorbate 20, on the performance in terms of brake torque (BT) and exhaust emissions of a four-cylinder four-stroke diesel engine. The relationship between independent factors, including water addition and engine speed, and dependent factors, including different exhaust released emissions and BT, was initially generated using machine learning support vector regression (SVR). Subsequently, a robust and modern optimization of the sea-horse optimizer (SHO) was run through the SVR model to find the optimal water addition and engine speed for improving the BT and lowering exhaust emissions. Furthermore, the SVR model was compared to the artificial neural network (ANN) model in terms of R-squared and mean square error (MSE). According to the experimental results, the BT was boosted by 3.34% compared to pure diesel at 5% water addition. The highest reduction in carbon monoxide (CO) and unburned hydrocarbon (UHC) was 9.57% and 15.63%, respectively, at 15% of water addition compared to diesel fuel. The nitrogen oxides (NOx) emissions from emulsified fuel were significantly lower than those from pure diesel, with a maximum decrease of 67.14% at 30% water addition. The suggested SVR-SHO model demonstrated superior prediction reliability, with a significant R-Squared of more than 0.98 and a low MSE of less than 0.003. The SHO revealed that adding 15% water to the W/D emulsion fuel at an engine speed of 1848 rpm yielded the optimum BT, CO, UHC, and NOx values of 49.5 N.m, 0.5%, 57 ppm, and 369 ppm, respectively. Finally, these outcomes have important implications for the potential of the SVR-SHO approach to minimize engine exhaust emissions while maximizing engine performance. Full article

Water-in-diesel (W/D) emulsion fuel is a potential alternative fuel that can simultaneously lower NOx exhaust emissions and improves combustion efficiency. Additionally, there are no additional costs or engine modifications required when using W/D emulsion fuel. The proportion of water added and engine speed is crucial factors influencing engine behavior. This study aims to examine the impact of the W/D emulsion diesel fuel on engine performance and NOx pollutant emissions using a compression ignition (CI) engine. The emulsion fuel had water content ranging from 0 to 30% with a 5% increment, and 2% surfactant was employed. The tests were performed at speeds ranging from 1000 to 3000 rpm. All W/D emulsion fuel was compared to a standard of pure diesel in all tests. A four-cylinder, four-stroke, water-cooled, direct-injection diesel engine test bed was used for the experiments. The performance and exhaust emissions of the diesel engine were measured at full load and various engine speeds using a dynamometer and an exhaust gas analyzer, respectively. The second purpose of this study is to illustrate the application of two optimizers, grey wolf optimizer (GWO) and intelligent grey wolf optimizer (IGOW), along with using multivariate polynomial regression (MPR) to identify the optimum (W/D) emulsion blend percentage and engine speed to enhance the performance, reduce fuel consumption, and reduce NO_X exhaust emissions of a diesel engine operating. The engine speed and proportion of water in the fuel mixture were the independent variables (inputs), while brake power (BP), brake thermal efficiency (BTE), brake-specific fuel consumption (BSFC), and NOx were the dependent variables (outcomes). It was experimentally observed that utilizing emulsified gasoline generally enhances engine performance and decreases emissions in general. Experimentally, at 5% water content and 2000 rpm, the BSFC has a minimal value of 0.258 kJ/kW·h. Under the same conditions, the maximum BP of 11.6 kW and BTE of 32.8% were achieved. According to the IGWO process findings, adding 9% water to diesel fuel and running the engine at a speed of 1998 rpm produced the highest BP (11.2 kW) and BTE (33.3%) and the lowest BSFC (0.259 kg/kW·h) and reduced NOx by 14.3% compared with the CI engine powered by pure diesel. The accuracy of the model is high, as indicated by a correlation coefficient R² exceeding 0.97 and a mean absolute error (MAE) less than 0.04. In terms of the optimizer, the IGWO performs better than GWO in determining the optimal water addition and engine speed. This is attributed to the IGWO has excellent exploratory capability in the early stages of searching. Full article

In this study, chitosan (CT) and naturally occurring acacia gum (AG) blends were employed as emulsifiers to form a series of emulsions developed from diesel and water. Effects of pH level (3, 5, 10, and 12) and various NaCl salt concentrations (0.25–1%) on the stability, viscosity, and interfacial properties of CT-(1%)/AG-(4%) stabilized Pickering emulsions were evaluated. Bottle test experiment results showed that the stability indexes of the CT/AG emulsions were similar under acidic (3 and 5) and alkaline (10 and 12) pH media. On the other hand, the effects of various NaCl concentrations on the stability of CT-(1%)/AG-(4%) emulsion demonstrated analogous behavior throughout. From all the NaCl concentrations and pH levels examined, viscosities of this emulsion decreased drastically with the increasing shear rate, indicating pseudoplastic fluid with shear thinning characteristics of these emulsions. The viscosity of CT-(1%)/AG-(4%) emulsion increased at a low shear rate and decreased with an increasing shear rate. The presence of NaCl salt and pH change in CT/AG solutions induced a transformation in the interfacial tension (IFT) at the diesel/water interface. Accordingly, the IFT values of diesel/water in the absence of NaCl/CT/AG (without emulsifier and salt) remained fairly constant for a period of 500 s, and its average IFT value was 26.16 mN/m. In the absence of salt, the addition of an emulsifier (CT-(1%)/AG-(4%)) reduced the IFT to 16.69 mN/m. When the salt was added, the IFT values were further reduced to 12.04 mN/m. At low pH, the IFT was higher (17.1 mN/M) compared to the value of the IFT (10.8 mN/M) at high pH. The results obtained will help understand the preparation and performance of such emulsions under different conditions especially relevant to oil field applications. Full article

The main target of the current research work is effectively eliminating fossil fuel dependency and improving the exhaust air quality of conventional Compression Ignition (CI) engines. This research paper demonstrates for the first time that a nanofluid (water without surfactant) stored in separate tanks can be quantified, collected, and immediately emulsified by a high shear mixer before transfer into the combustion chamber of a diesel engine. The experiment was carried out under different load states (25%, 50%, 75% and 100%) with a constant speed of 1500 rpm. Biofuel was extracted from citronella leaves using an energy-intensive process. The 5% water share was used for preparing the biofuel emulsion and nano-biofuel emulsion. A cobalt chromate nanoadditive was used to make the nanofluid. An experimental investigation was performed with prepared test fuels, namely, ultra-low sulphur diesel (ULSD), 100% Citronella (B100), surfactant-free Diesel emulsion (SDE), surfactant-free bioemulsion (SBE), and Surfactant free nano-bioemulsion (SNBE), in a test engine. The properties of the sample test fuels was ensured according to EN and ASTM standards. The observation performance results show that the SNBE blend exhibited lower BTE (by 0.5%) and higher SFC (by 3.4%) than ULSD at peak load. The emission results show that the SNBE blend exhibited lower HC, CO, NO_x, and smoke emissions by 23.86%, 31.81%, 2.94%, and 24.63%, respectively, compared to USD at peak load. The CP and HRR results for SNBE were closer to ULSD fuel. Overall, the novel concept of an RTEFI (Real-time emulsion fuel injection) system was proved to be workable and to maintain its benefits of better fuel economy and greener emissions. Full article

The impact of the constituent oxides of nitrogen, carbon, sulphur, and other particulate matter which make up the gas emissions from diesel engines has motivated several control techniques for these pollutants. Water-in-diesel emulsions provide a reliable solution, but the wear effects on the fuel injection system (FIS) still pose remarkable concerns. Because pressure signals from the common rail (CR) reflect the dynamics associated with varying emulsion compositions and at varying engine RPMs, an investigative (and diagnostic) study was conducted on a KIA Sorento 2004 four-cylinder line engine at various water-in-diesel emulsion compositions and engine speeds. Alongside visual/microscopic inspections and spectral analyses, the diagnostic framework proposed herein functions on the use of standardized first-order differentials of the CR pressure signals to generate reliable continuous wavelet coefficients (CWCs) which capture discriminative spectral and transient information for accurate diagnosis. The results show that by extracting the CWCs from the first-order CR pressure differentials up to the 512th scale on a Mexican hat wavelet, adequate fault parameters can be extracted for use by a deep neural network (DNN) whose hyperparameters were globally optimized following a grid search. With a test accuracy of 92.3% against other widely-used ML-based diagnostic tools, the proposed DNN-based diagnostics tool was empirically assessed using several performance evaluation metrics. Full article

Despite global patronage, diesel engines still contribute significantly to urban air pollution, and with the ongoing campaign for green automobiles, there is an increasing demand for controlling/monitoring the pollution severity of diesel engines especially in heavy-duty industries. Emulsified diesel fuels provide a readily available solution to engine pollution; however, the inherent reduction in engine power, component corrosion, and/or damage poses a major concern for global adoption. Notwithstanding, on-going investigations suggest the need for reliable condition monitoring frameworks to accurately monitor/control the water-diesel emulsion compositions for inevitable cases. This study proposes the use of common rail (CR) pressure differentials and a deep one-dimensional convolutional neural network (1D-CNN) with the local interpretable model-agnostic explanations (LIME) for empirical diagnostic evaluations (and validations) using a KIA Sorento 2004 four-cylinder line engine as a case study. CR pressure signals were digitally extracted at various water-in-diesel emulsion compositions at various engine RPMs, pre-processed, and used for necessary transient and spectral analysis, and empirical validations. Results reveal high model trustworthiness with an average validation accuracy of 95.9%. Full article

The article discusses the possibility of using blended biofuels from rapeseed oil (RO) as fuel for a diesel engine. RO blended diesel fuel (DF) and emulsified multicomponent biofuels have been investigated. Fuel physicochemical properties have been analyzed. Experimental tests of a diesel engine D-245 in the operating conditions of the external characteristic curve and the 13-mode test cycle have been conducted to investigate the effect of these fuels on engine performances. CFD simulations of the nozzle inner flow were performed for DF and ethanol-emulsified RO. The possibility of a significant improvement in brake thermal efficiency of the engine has been noted. The efficiency of using blended biofuels from RO as a motor fuel for diesel engines has been evaluated based on the experimental test results. It was shown that in comparison with the presence of RO in emulsified multicomponent biofuel, the presence of water has a more significant effect on NOx emission reduction. The content of RO and the content of water in the investigated emulsified fuels have a comparable influence on exhaust smoke reduction. Nozzle inner flow simulations show that the emulsification of RO changes its flow behaviors and cavitation regime. Full article

Diesel engine emissions contribute nearly 30% of greenhouse effects and diverse health and environmental problems. Amidst these problems, it is estimated that there will be a 75% increase in energy demand for transportation by 2040, of which diesel fuel constitutes a major source of energy for transportation. Being a major source of air pollution, efforts are currently being made to curb the pollution spread. The use of water-in-diesel (W/D)-emulsified fuels comes as a readily available (and cost-effective) option with other benefits including engine thermal efficiency, reduced costs, and NOx reduction; nonetheless, the inherent effects—power loss, component wear, corrosion, etc. still pose strong concerns. This study investigates the behavior and damage severity of a common rail (CR) diesel fuel injection system using exploratory and statistical methods under different W/D emulsion conditions and engine speeds. Results reveal that the effect of W/D emulsion fuels on engine operating conditions are reflected in the CR, which provides a reliable avenue for condition monitoring. Also, the effect of W/D emulsion on injection system components-piston, nozzle needle, and ball seat–are presented alongside related discussions. Full article