Search Results (28)

Rainfall-induced landslides are widely distributed in many countries. Rainfall impacts the hydraulic dynamics of groundwater and, therefore, slope stability. We derive an analytical solution of slope stability considering effective rainfall based on the Richards equation. We define effective rainfall as the total volume of rainfall stored within a given range of the unsaturated zone during rainfall events. The slope stability at the depth of interest is provided as a function of effective rainfall. The validity of analytical solutions of system states related to effective rainfall, for infinite slopes of a granite residual soil, is verified by comparing them with the corresponding numerical solutions. Additionally, three approaches to global sensitivity analysis are used to compute the sensitivity of the slope stability to a variety of factors of interest. These factors are the reciprocal of the air-entry value of the soil α, the thickness of the unsaturated zone L, the cohesion of soil c, the internal friction angle ϕ related to the effective normal stress, the slope angle β, the unit weights of soil particles γ_s, and the saturated hydraulic conductivity K_s. The results show the following: (1) The analytical solutions are accurate in terms of the relative differences between the analytical and the numerical solutions, which are within 5.00% when considering the latter as references. (2) The temporal evolutions of the shear strength of soil can be sequentially characterized as four periods: (i) strength improvement due to the increasing weight of soil caused by rainfall infiltration, (ii) strength reduction controlled by the increasing pore water pressure, (iii) strength reduction due to the effect of hydrostatic pressure in the transient saturation zone, and (iv) stable strength when all the soil is saturated. (3) The large α corresponds to high effective rainfall. (4) The factors ranked in descending order of sensitivity are as follows: α > L > c > β > γ_s > K_s > ϕ. Full article

This research presents a proposal for alkali-activated permeable concrete composites with the use of industrial by-products, including ground granulated blast-furnace slag (GGBS) and waste-foundry sand, as well as agro-desecrate product, i.e., sugarcane bagasse ash (SBA). GGBS and SBA served as binders, with crushed granite as coarse aggregate and waste-foundry sand as fine aggregate. The novelty of this proposal is in examining the influence of SBA, in combination with slag, on the fresh- and hardened-state properties of the proposed permeable concretes. Experiments were conducted to optimize the SBA percentage based on hydraulic conductivity and compressive and tensile strength after 28 days of air curing. The hardened density, compaction factor (workability), and saturated water absorption were also measured for all the mixes. Furthermore, the control and optimal mixes were subjected to evaluate the microstructure analysis (EDX, XRD, and FESEM) after 28 days of air curing. The mix containing 100% GGBS and 0% SBA served as the reference, with the optimal 10% SBA mix (with 90% GGBS) used for comparative analysis to understand its effect on the properties of permeable composites. The results showed positive or acceptable mechanical performance at a mix ratio of 10% SBA to 90% GGBS as binders. This study aims to enhance the understanding of the engineering behavior of alkali-activated permeable composites, facilitating the rational design of permeable pavement systems through the effective use of agro-industrial waste products, thereby conserving ecosystems while meeting engineering requirements. Full article

Groundwater contamination with sub-lethal dissolved contaminants poses significant health risks globally, especially in rural India, where access to safe drinking water remains a critical challenge. This study explores the hydrogeochemical characterization and associated health risks of groundwater from shallow aquifers in the Marginal Ganga Alluvial Plain (MGAP) of northern India. The groundwater chemistry is dominated by Ca-Mg-CO₃ and Ca-Mg-Cl types, where there is dominance of silicate weathering and the ion-exchange processes are responsible for this solute composition in the groundwater. All the ionic species are within the permissible limits of the World Health Organization, except fluoride (F⁻) and nitrate (NO₃⁻). Geochemical analysis using bivariate relationships and saturation plots attributes the occurrence of F⁻ to geogenic sources, primarily the chemical weathering of granite-granodiorite, while NO₃⁻ contaminants are linked to anthropogenic inputs, such as nitrogen-rich fertilizers, in the absence of a large-scale urban environment. Multivariate statistical analyses, including hierarchical cluster analysis and factor analysis, confirm the predominance of geogenic controls, with NO₃⁻-enriched samples derived from anthropogenic factors. The spatial distribution and probability predictions of F⁻ and NO₃⁻ were generated using a non-parametric co-kriging technique approach, aiding in the delineation of contamination hotspots. The integration of the USEPA human health risk assessment methodology with the urbanization index has revealed critical findings, identifying approximately 23% of the study area as being at high risk. This comprehensive approach, which synergizes geospatial analysis and statistical methods, proves to be highly effective in delineating priority zones for health intervention. The results highlight the pressing need for targeted mitigation measures and the implementation of sustainable groundwater management practices at regional, national, and global levels. Full article

The genetic link between Weideshan-type rocks and gold mineralization in the Jiaodong Peninsula remains unclear. In this study, we examined the geochemical characteristics, water content, and oxidation states of Weideshan-type rocks and associated felsic dykes to assess the potential of a Weideshan-type batholith in directly contributing the fluids responsible for extensive gold mineralization. The findings reveal that the emplacement timing of Weideshan-type magmatic rocks in the Jiaodong Peninsula is slightly different from the timing of gold mineralization. Additionally, high zircon Eu/Eu* values indicate a relatively high water content within the Weideshan batholith. However, due to limited data on crystallization pressures, it remains equivocal whether water was saturated during the emplacement of the Weideshan batholith. Even if fluid saturation did occur, the magmatic oxidation states of Weideshan-type rocks are notably high (>FMQ + 1.5), which is incompatible with the reduced mineral assemblages typical of Jiaodong gold deposits. Therefore, our study suggests that the genetic link between gold mineralization and Weideshan-period granitic magmatism may be weak. Full article

We report the petrogenesis of arfvedsonite granites from the Dimra Pahar pluton in the Chhotanagpur Gneissic Complex based on petrology, whole-rock chemistry, mineral chemistry, and La-ICP-MS zircon U-Pb ages and Hf-Lu isotopic analyses. These granites are dominantly peralkaline, occasionally peraluminous, and demonstrate features of A1-type granites. The magma was emplaced at a shallow depth and had a high liquidus temperature, fO₂ (>NNO), and water saturation. The zircons exhibit three distinct U-Pb isotopic ages. The oldest (1324 ± 6 Ma), large-sized inherited zircons (εHf(t) = +1.65 to +7.64), show complex zoning and signs of partial resorption. The euhedral, prismatic-bipyramidal zircons displaying oscillatory zoning (εHf(t) = −3.43 to +1.43) reveal a crystallization age of 1046 ± 7 Ma. Their thin periphery (εHf(t) = −3.23 to +0.27) grew during retrograde metamorphism (995 ± 6 Ma). The whole-rock geochemistry and the Hf-isotope values imply that the parental magma of these granites resulted from the anatexis of metasomatized lithospheric mantle sources. These granites intruded in a syn-orogenic (syn-collisional exhumation) stage of the orogeny. Full article

The Taimyr Peninsula in the Russian High Arctic comprises a late Paleozoic-early Mesozoic collisional belt where several porphyry-type mineralization occurrences were identified during the last decade, making this area a potential exploration target for Cu-Mo deposits. In order to further evaluate the metallogenic potential of the poorly outcropped northeastern part of Taimyr, samples from seven granitoid intrusions were investigated in this study aimed to evaluate the granite fertility based on petrography, geochemistry, and composition of porphyry indicator minerals (zircon, apatite, and titanite). The studied intrusions represent small to moderate-sized bodies (40–800 km²) composed of biotite (±amphibole) quartz monzonites, granodiorites, granites, and biotite leucogranites that formed in the course of late Paleozoic-early Mesozoic tectono-magmatic events at the Siberian margins. The late Carboniferous Tessemsky massif represents suprasubduction granitoid series, while the Pekinskiy, Shirokinskiy, Dorozhinskiy, Kristifensenskiy, and Yuzhno-Lodochnikovskiy massifs are correlated with the early Triassic Siberian Traps LIP. The rocks of intrusions comprise a relatively uniform geochemically, predominantly magnesian, slightly peraluminous, calc-alkaline high-K amphibole-bearing I-type granitoid series with adakitic affinity, where Triassic plume-related granitoids inherit geochemical signatures of Carboniferous supra-subduction granitoids, and all rock types are marked by enrichment in LILE and negative Ta, Nb, and Ti anomalies. It is suggested that the adakitic geochemical characteristics of the Taimyr granites are a result of derivation from a relatively homogeneous mafic lower crustal source that formed at the stage of Carboniferous continental subduction and continued to produce granitic melts in the course of the early Mesozoic magmatic evolution. Whole rock geochemistry and composition of porphyry mineral indicators (zircon, apatite, and titanite) indicate that the Taimyr granites crystallized from oxidized water-saturated magmas at moderate temperatures, with the majority of samples showing characteristics typical for porphyry-fertile granites worldwide (fO₂ = ΔFMQ +1 to +3 with zircon Eu/Eu* > 0.4 and apatite SO₃ > 0.2 wt.%). Data from Dorozhinskiy, Kristifensenskiy, Pekinskiy, and Tessemskiy intrusions fully match geochemical criteria for porphyry-fertile granitoids, and these massifs are considered the most prospective for Cu-Mo mineralization. Granites from Shirokinskiy and Yuzhno-Lodochnikovskiy intrusions only partially match compositional constraints for fertile melts and can be considered as second-tier exploration targets. Finally, available data for the Simsovsky massif preclude its classification as a porphyry-fertile body. These conclusions are in line with previously developed exploration criteria for the northeastern Taimyr, showing that geochemical indicators of granite-fertility can be used on a regional scale in parallel with other exploration methods. Full article

The Neoproterozoic period in the Jabal Sayid and Dayheen areas is characterized by three distinct magmatic phases: an early magmatic phase of granodiorite–diorite association, a transitional magmatic phase of monzogranites, and a highly evolved magmatic phase of peralkaline granites and associated pegmatites. The presence of various accessory minerals in the peralkaline granites and pegmatites, such as synchysite, bastnaesite, xenotime, monazite, allanite, pyrochlore, samarskite, and zircon, plays an important role as contributors of REEs, Zr, Y, Nb, Th, and U. The geochemical characteristics indicate that the concentration of these elements occurred primarily during the crystallization and differentiation of the parent magma, with no significant contributions from post-magmatic hydrothermal processes. The obtained geochemical data shed light on the changing nature of magmas during the orogenic cycle, transitioning from subduction-related granodiorite–diorite compositions to collision-related monzogranites and post-collisional peralkaline suites. The granodiorite–diorite association is thought to be derived from the partial melting of predominantly metabasaltic sources, whereas the monzogranites are derived from metatonalite and metagraywacke sources. The peralkaline granites and associated pegmatites are thought to originate from the continental crust. It is assumed that these rocks are formed by the partial melting of metapelitic rocks that are enriched with rare metals. The final peralkaline phase of magmatic evolution is characterized by the enrichment of the residual melt with alkalis (such as sodium and potassium), silica, water, and fluorine. The presence of liquid-saturated melt plays a decisive role in the formation of pegmatites. Full article

Granite residual soil typically forms complex pore structures and exhibits high water sensitivity due to physical and chemical weathering processes. Changes in initial compaction conditions significantly affect the mechanical and hydraulic properties of in situ granite residual soil subgrades, with these variations fundamentally related to changes in pore structure and soil–water characteristics. This study investigates the pore structure and bimodal soil–water characteristic curve (SWCC) of a compacted granite residual soil through laboratory tests and mercury intrusion porosimetry tests. Nine initial conditions were selected based on potential in situ compaction conditions of subgrades, and their effects on the pore size distribution (PSD) and SWCC were thoroughly analyzed. The results show strong correlations between bimodal pore structure and SWCC. The size and volume of inter-aggregate pores exhibit noticeable changes with initial conditions, affecting SWCC within the low and middle suction range. Conversely, the intra-aggregate pores, which constitute over 60% of the pore structures, remain nearly intact across different initial conditions, resulting in similar SWCCs within the high suction range. As the compaction energy increases, the inter-aggregate pores are compressed and lead to a higher water retention capacity. In addition, as the compaction water content increases, the SWCC becomes less sensitive to compaction energy after the aggregates in the pore structure are fully saturated. Additionally, a three-dimensional bimodal SWCC equation is proposed and validated using test data with an R² value above 0.98. These findings offer valuable insights for the design and quality control of granite residual soil subgrades. Full article

The zircon from the pegmatite of the Adui granitic massif displays the unique the rare earth element (REE) distribution spectrum with the tetrad effect in REE fractionation. The tetrad effect often occurs in granitoid rocks, but it is rarely encountered in minerals, e.g., zircon. Fluid saturated with volatiles, water and trace elements is a factor responsible for the tetrad effect in the zircon. The detailed isotopic-geochemical study of the zircon has revealed several zones differing in internal structure (in the back-scattered electron (BSE) image), composition and REE distribution. The zones indicate changes in the crystallization environment provoked by the evolution of the pegmatite-forming melt. They occur as the gradually growing changes in composition from the unaltered zones that are light-colored in BSE to the altered zones that are dark-colored in BSE. The unaltered zones are consistent in composition and geochemical features with magmatic zircons. The high content of trace (U, Th, REE) and volatile elements (F, Cl) in water suggests its crystallization from the fluid-saturated magmatic melt. The altered zircon zones occur as recrystallized zones with high content of non-formula elements (Y, Ca, Sr, Nb, P), a non-differentiated REE distribution spectrum and an absent Ce anomaly. These features are consistent with those of hydrothermal-metasomatic zircon. Full article

This paper describes the impact of hydrothermal conditions on the strength properties and hydration processes of belite cement mortar samples. The belite-rich binder was synthesized by sintering the initial mixture of raw materials (granite cutting waste, the silica-gel waste from AlF₃ production, and natural materials) in a high-temperature furnace at a temperature of 1150 °C for 2 h. The prepared clinker consists of larnite, mayenite, srebrodolskite, ye’elimite, and gehlenite. To control hydration kinetics and optimize the hardening of belite cement mortar, the produced clinker was blended with 7.5% of gypsum. The mechanical properties were assessed by curing the standard prisms (following the EN 196-1 standard, cement/sand = 1:3, W/C= 0.67) under water-saturated conditions in a stainless steel autoclave. The curing process was performed in a temperature range of 90 °C to 200 °C at various hydrothermal curing durations (6–48 h). The results indicated that the curing conditions highly influence the compressive strength evolution of belite cement mortar and the formed mineralogy of hydrates. The highest compressive strength value (exceeded 20 MPa) was obtained at 200 °C, i.e., when the main belite cement mineral was entirely hydrated and recrystallized into 1.13 nm tobermorite. The microstructural evolution and the phase assemblage during the hydrothermal curing were determined by X-ray diffraction analysis and differential scanning calorimetry. Full article

In recent years, with the exploration and development of granite buried-hill oil and gas reservoirs, petrophysics research has played an important role in the study of reservoir characteristics and fluid identification. Through analysis of the relationship between the fluid-bearing petrophysical parameters and the reservoir, the seismic response changes caused by reservoir fluid changes can be determined. Mesozoic granites in the coastal area of Fujian Province in eastern China were investigated as the research object of this project. The mineral composition, density, porosity, P-wave velocity, and S-wave velocity of the granite were measured and analyzed by X-ray diffraction, rock density, rock porosity, and rock acoustics methods. Therefore, the granite’s petrophysical properties, fluid response characteristics, and gas sensitivity parameters were analyzed. The result of the study shows that the granite is predominantly monzogranite. According to the type of reservoir space assemblage, the samples can be divided into two types: those containing fracture-dissolution pores and those containing only dissolution pores. All the samples were characterized by medium to high densities and low to extra-low porosity. There was a linear correlation between the P-wave velocity and S-wave velocity under gas and water-saturated conditions. Factors such as P-wave to S-wave velocity ratio, Poisson’s ratio, Lame coefficient, and other parameters of the samples were analyzed, and the threshold values that distinguished the water and gas-saturated states of the samples were measured and determined. In addition, there were negative correlations between the P- and S-wave velocities and porosity. The sensitivities of the petrophysical parameters to the gas capacity from high to low are Ip² − 2.03 Is², λ − 0.03 μ, λ, λ/μ, E − 2.03 μ, σ, K/μ, K, Ip, Vp/Vs, Vp, E, μ, Vs, and Is. For granite-buried hill reservoirs, the variation ranges of the parameters, such as the density, porosity, and P-wave velocity, of the fracture-dissolution pore granite samples were larger than those of the dissolution pore samples. The bulk parameters (Ip, Vp, K, λ) and combination parameters (Ip² − 2.03 Is², K/μ, λ− 0.03 μ, E − 2.03 μ, λ/μ) of the dissolution pore samples were more sensitive to the gas capacity. The results of this study provide a basis for the geophysical identification of granite-buried hill reservoirs. Full article

Groundwater contamination by heavy metals (HMs) released by weathering and mineral dissolution of granite, gneisses, ultramafic, and basaltic rock composition causes human health concerns worldwide. This paper evaluated the heavy metals (HMs) concentrations and physicochemical variables of groundwater around enriched chromite mines of Malakand, Pakistan, with particular emphasis on water quality, hydro-geochemistry, spatial distribution, geochemical speciation, and human health impacts. To better understand the groundwater hydrogeochemical profile and HMs enrichment, groundwater samples were collected from the mining region (n = 35), non-mining region (n = 20), and chromite mines water (n = 5) and then analyzed using ICPMS (Agilent 7500 ICPMS). The ranges of concentrations in the mining, non-mining, and chromite mines water were 0.02–4.5, 0.02–2.3, and 5.8–6.0 mg/L for CR, 0.4–3.8, 0.05–3.6, and 3.2–5.8 mg/L for Ni, and 0.05–0.8, 0.05–0.8, and 0.6–1.2 mg/L for Mn. Geochemical speciation of groundwater variables such as OH⁻, H⁺, Cr⁺², Cr⁺³, Cr⁺⁶, Ni⁺², Mn⁺², and Mn⁺³ was assessed by atomic fluorescence spectrometry (AFS). Geochemical speciation determined the mobilization, reactivity, and toxicity of HMs in complex groundwater systems. Groundwater facies showed 45% CaHCO₃, 30% NaHCO₃, 23.4% NaCl, and 1.6% Ca-Mg-Cl water types. The noncarcinogenic and carcinogenic risk of HMs outlined via hazard quotient (HQ) and total hazard indices (THI) showed the following order: Ni > Cr > Mn. Thus, the HHRA model suggested that children are more vulnerable to HMs toxicity than adults. Hierarchical agglomerative cluster analysis (HACA) showed three distinct clusters, namely the least, moderately, and severely polluted clusters, which determined the severity of HMs contamination to be 66.67% overall. The PCAMLR and PMF receptor model suggested geogenic (minerals prospects), anthropogenic (industrial waste and chromite mining practices), and mixed (geogenic and anthropogenic) sources for groundwater contamination. The mineral phases of groundwater suggested saturation and undersaturation. Nemerow’s pollution index (NPI) values determined the unsuitability of groundwater for domestic purposes. The EC, turbidity, PO₄⁻³, Na⁺, Mg⁺², Ca⁺², Cr, Ni, and Mn exceeded the guidelines suggested by the World Health Organization (WHO). The HMs contamination and carcinogenic and non-carcinogenic health impacts of HMs showed that the groundwater is extremely unfit for drinking, agriculture, and domestic demands. Therefore, groundwater wells around the mining region need remedial measures. Thus, to overcome the enrichment of HMs in groundwater sources, sustainable management plans are needed to reduce health risks and ensure health safety. Full article

For economical and sustainable benefits, conventional retaining walls are being replaced by geosynthetic reinforced soil (GRS). However, for safety and quality assurance purposes, prior tests of pullout capacities of these materials need to be performed. Conventionally, these tests are conducted in a laboratory with heavy instruments. These tests are time-consuming, require hard labor, are prone to error, and are expensive as a special pullout machine is required to perform the tests and acquire the data by using a lot of sensors and data loggers. This paper proposes a data-driven machine learning architecture (MLA) to predict the pullout capacity of GRS in a diverse environment. The results from MLA are compared with actual laboratory pullout capacity tests. Various input variables are considered for training and testing the neural network. These input parameters include the soil physical conditions based on water content and external loading applied. The soil used is a locally available weathered granite soil. The input data included normal stress, soil saturation, displacement, and soil unit weight whereas the output data contains information about the pullout strength. The data used was obtained from an actual pullout capacity test performed in the laboratory. The laboratory test is performed according to American Society for Testing and Materials (ASTM) standard D 6706-01 with little modification. This research shows that by using machine learning, the same pullout resistance of a geosynthetic reinforced soil can be achieved as in laboratory testing, thus saving a lot of time, effort, and money. Feedforward backpropagation neural networks with a different number of neurons, algorithms, and hidden layers have been examined. The comparison of the Bayesian regularization learning algorithm with two hidden layers and 12 neurons each showed the minimum mean square error (MSE) of 3.02 × 10⁻⁵ for both training and testing. The maximum coefficient of regression (R) for the testing set is 0.999 and the training set is 0.999 for the prediction interval of 99%. Full article

The hydrological and mechanical properties of granitic residual soils can be significantly altered by periodical wetting and drying (W-D) cycles. The soil structure degradation induced by W-D cycles can lead to soil mass failure and collapsing gully erosion in granitic hilly slopes in south China. However, limited attempts have been made at a comprehensive investigation of the effects of W-D cycles on the structure degradation of granitic residual soils, especially at the pedon scale. The purpose of this paper is to investigate the structural degradation of granite soils induced by W-D cycles and explore its potential influence on the development of collapsing gully erosion. The granitic soil properties, including hydraulic properties, shear strength, and disintegration characteristics, were performed after W-D cycles. The results indicated that the W-D cycles altered the soil pore structure, leading to variations in soil hydraulic properties. Specifically, with increasing alternate W-D cycles, the initial saturated water content and residual water content decreased, while the saturated hydraulic conductivity increased. Meanwhile, increasing W-D cycles contributed significantly to variations in cohesion and internal friction strength by decreasing the shear strength variables, especially the soil cohesion strength. Correspondingly, soil disintegration was increased during W-D cycles. Furthermore, most degradation of soil structure was recorded within the first two cycles of W-D. The obtained results indicate that the W-D cycles weaken soil structure, increase rainwater infiltration, decrease soil shear strength and disintegration resistance, and accelerate soil erosion. A vicious cycle of granitic slope failure induced by W-D cycles is eventually formed. This study provides useful information about the mechanism of soil mass failure and collapsing gully erosion in granitic hilly slopes. Full article

In this study, we investigate GPR measurements in freshwater of less than 5 m at four different locations to derive rules of thumb in terms of depth penetration, resolution, and material contrasts of the method for 200 and 400 MHz antennas under field conditions. The objective is to improve the attractiveness of the method for archaeological issues in water, as there are hardly any studies on this subject so far. The depth penetration of 2–4 m is negligibly influenced by the choice of the 200 or 400 MHz antenna. Organic material in the water column also does not affect the water depth but offers new fields of applications for mapping and volume estimation of biomass in lakes with GPR. The horizontal resolution in the cm range in the direction of the profile and in the dm range across the profile could not be improved by the narrow antenna radiation pattern of <30° at the 3 dB level. In the crossline direction, the use of an antenna array would be necessary here. Still, the narrow antenna pattern reduces side reflections. Most common archaeological material contrasts can be resolved with the method. The method shows reflection coefficients >0.1 for materials of <80% porosity to the water column and for materials of <25% porosity and of >45% porosity to water-saturated sand. Large reflection coefficients also show, for example, granite to sand and gyttja to wood. The water column has a considerable effect on the data quality of the 400 MHz antenna from a depth of 2 m due to the antenna ringing. Furthermore, multiples must be expected in a water column <0.5 m. The method can especially complement the common geophysical methods of seismics and geoelectrics to exclude material ambiguities. The major advantage is the simple setting of the land equipment in the water. Full article