Search Results (126)

Moroccan oil shale ash (MOSA) represents an underutilized industrial by-product, particularly in the Rif region, where its high mineral content has often led to its neglect in value-added applications. This study highlights the successful conversion of MOSA into amorphous mesoporous silica (AS-Si) using a sol–gel process assisted by polyethylene glycol (PEG-6000) as a soft template. The resulting AS-Si material was extensively characterized to confirm its potential for environmental remediation. FTIR analysis revealed characteristic vibrational bands corresponding to Si–OH and Si–O–Si bonds, while XRD confirmed its amorphous nature with a broad diffraction peak at 2θ ≈ 22.5°. SEM imaging revealed a highly porous, sponge-like morphology composed of aggregated nanoscale particles, consistent with the nitrogen adsorption–desorption isotherm. The material exhibited a specific surface area of 68 m²/g, a maximum in the pore size distribution at a pore diameter of 2.4 nm, and a cumulative pore volume of 0.11 cm³/g for pores up to 78 nm. DLS analysis indicated an average hydrodynamic diameter of 779 nm with moderate polydispersity (PDI = 0.48), while a zeta potential of –34.10 mV confirmed good colloidal stability. Furthermore, thermogravimetric analysis (TGA) and DSC suggested the thermal stability of our amorphous silica. The adsorption performance of AS-Si was evaluated using methylene blue (MB) and ciprofloxacin (Cipro) as model pollutants. Kinetic data were best fitted by the pseudo-second-order model, while isotherm studies favored the Langmuir model, suggesting monolayer adsorption. AS-Si could be used four times for the removal of MB and Cipro. These results collectively demonstrate that AS-Si is a promising, low-cost, and sustainable adsorbent derived from Moroccan oil shale ash for the effective removal of organic contaminants from aqueous media. Full article

Torrefaction is a thermochemical pretreatment in which biomass is heated at 200–300 °C for 30–60 min in an inert atmosphere. Torrefaction has been previously used to improve the fuel properties of lignocellulosic biomass; however, the use of torrefaction for bioenergy generation represents a low-value final product as well as the dead end of the biomass value chain. Herein, we demonstrate the proof-of-concept for the utilisation of torrefaction as a pretreatment to convert low-value wood waste into biosurfactants, a high-value specialty biochemical. Wood waste was torrefied at 225 °C, 250 °C, 275 °C, and 300 °C and physicochemically characterised using proximate and ultimate analyses, FTIR, XRD, TGA–DTG, and SEM–EDX to assess its suitability as fermentation feedstock. Aspen waste torrefied at temperatures less than 250 °C was directly utilised by Burkholderia thailandensis DSM 13276 via semi-solid-state fermentation to yield biosurfactants, and 225 °C was selected for further experiments as it resulted in the production of biosurfactants which reduced the surface tension of the production medium to 36.8 mN/m and had an emulsification index of 64.1%. Tension and emulsification activities decreased with the increase in torrefaction temperature. The biosurfactant derived from torrefaction at 225 °C formed highly stable emulsions with diesel oil (lasting >40 days), in addition to low interfacial tension, suggesting potential applications in diesel bioremediation. This integrated, chemical-free strategy offers an alternative application for torrefied wood waste as well as a feasible solution for the cost-effective chemical-free production of biosurfactants, incorporating circular economy principles. Full article

Gamma oryzanol (GO) is a natural anti-oxidant found in rice bran with potential health benefits. Conventional isolation of GO from rice bran requires the use of non-eco-friendly solvents such as acetone, ethyl acetate and hexane due to its low aqueous solubility. Further, nanoencapsulation of GO is required for the enhancement of stability and bioavailability. Plant-derived nanovesicles (PDNVs) are natural/intrinsic exosome-mimetic vesicles isolated from edible plants using green methods. Washed/soaked rice water (SRW) is often discarded as waste prior to cooking rice. However, traditional knowledge indicates its health-promoting anti-oxidant benefit, probably contributed by the presence of GO. Herein, for the first time, we isolated PDNVs from SRW by the cost-effective Polyethylene glycol 6000(PEG) precipitation method and demonstrated the presence of GO in PDNVs. In our initial screen, PDNVs were isolated from both rice grains (RGs) as well as the SRW of four different rice varieties, in which we identified the copious presence of GO in black RGs and brown SRW PDNVs. Both RG and SRW PDNVs were non-toxic to keratinocytes. SRW PDNVs displayed distinct cellular uptake mechanisms compared to RG PDNVs in human keratinocytes. Compared to native GO, brown SRW PDNVs containing GO displayed superior anti-oxidant activity in HaCaT keratinocytes, likely due to its enhanced cellular uptake. Overall, we describe here a waste-to-wealth green approach using an economical PEG method for the extraction of GO in bioavailable form. Given that oxidative stress is a driving factor for inflammation and related diseases, SRW PDNVs provide an affordable natural formulation for the treatment of diseases with underlying oxidative stress and inflammation. Full article

Modern healthcare generates significant amounts of greenhouse gas emissions and waste, which pollute the global environment and damage human health. Healthcare firms could reduce these environmental emissions and waste by developing environmentally friendly technologies and production processes. However, the implementation of green innovations requires significant investments. Healthcare equity mutual funds could provide them financial resources whether this allows fund managers to comply with their fiduciary duties. Previous literature has examined the financial performance of healthcare mutual funds without considering the environmental practices that investees adopt. To understand this issue, we examined the effect of investees’ environmental business practices on healthcare fund financial performance by considering different states of the economy. To this end, we obtained a sample of 148 global healthcare equity mutual funds from December 2015 to December 2022. Adopting the Fama–French model, our findings indicate that mutual funds improve financial performance when investee firms are in the initial phase of greening their processes and activities. However, the mutual funds invested in healthcare firms with advanced environmental practices achieve risk-adjusted returns similar to those invested in healthcare firms that implement conventional business management strategies. Furthermore, the financial performance of healthcare mutual funds is not significantly affected by the COVID-19 pandemic crisis at the aggregate level. Therefore, adopting environmental practices in the healthcare sector will not result in a loss of investor wealth from 2016 to 2022. Full article

This study developed a microporous silica nanosilver antioxidant material (GT-Ag@MSN) from waste photovoltaic (PV) cells by incorporating plant polyphenols in the in situ synthesis. The biosynthesized GT-Ag@MSN had an average size of 296.5 nm, a pore size of 1.96 nm, and an Ag loading of 1.45%. The material was further evaluated through antibacterial tests, antioxidant capacity tests, and a reducing power assay. GT-Ag@MSN exhibited a minimum inhibitory concentration (MIC) of 20 mg/mL for Escherichia coli and Staphylococcus aureus, and a minimum bactericidal concentration (MBC) of 50 mg/mL for both of them, which will need further efforts to improve the performance. However, GT-Ag@MSN exhibited a notable 1,1-Diphenyl-2-picrylhydrazyl (DPPH) scavenging ability of 74.7 ± 1.6% at a concentration of 250 μg/mL, and its reducing power in the range of 10–100 mg was greater than that of ascorbic acid at 10–100 μg/mL. This study proposes a new waste-to-wealth strategy that utilizes purified silicon and silver from recycling used PV modules, encouraging the advancement of PV waste recycling and reuse technology. Full article

Objectives: the current study investigates the link between health insurance coverage and child nutritional status in Pakistan. Methods: Using data from the Pakistan Demographic and Health Survey (PDHS) 2017–18, encompassing 4499 children under 5, a binary logistic regression was applied to analyze the relationship between health insurance and child nutritional status. Due to the non-randomized sample, assessing health insurance continuously posed a practical challenge. To mitigate the sample selection bias, the cross-sectional-based propensity score matching (PSM) using the nearest neighbor method was utilized for the causal relationship, based on potential socio-economic covariates. Results: The prevalence rates of stunting, underweight, and wasting among children under five were 38.13%, 23.04%, and 8.05%, respectively. Malnutrition was found in 43.64% of non-insured children compared with 5% in insured children. The findings of PSM supported a causal relationship, given the cross-sectional nature and potential misplaced variables, as the PSM findings revealed that insured children had significantly better nutritional outcomes compared with non-insured children, with a significance level of 1%. The logistic regression outcomes for the covariates of child nutritional outcome indicated that health insurance coverage, higher wealth status, mother’s education, improved water and sanitation facilities, mother’s normal BMI, and urban residence reduced the likelihood of child malnutrition. The logistic regression results for the covariates of child health insurance depicted that factors such as higher birth order, mother’s low BMI, poor water and sanitation facilities, higher wealth status, women’s employment, higher education level, and child illnesses like diarrhea and malnutrition increased the likelihood of obtaining health insurance. The logistic results confirmed that health insurance coverage reduced the likelihood of child malnutrition, and, similarly, child malnutrition and other illnesses increased the chances of obtaining health insurance coverage. Conclusions: The findings underscore the critical need for health insurance, highlighting its role in enhancing child nutritional status. The government should expand health insurance programs, with a special emphasis on child nutrition and health. Full article

Metabolic syndrome (MetS) is a cluster of metabolic abnormalities that include insulin resistance, impaired glucose tolerance, dyslipidemia, hypertension, and abdominal obesity. Coffee production generates large quantities of waste products, which pose a serious threat to the environment. However, coffee by-products, such as coffee pulp (CP), possess an undeniable wealth of bioactive components. Based on this, we investigated whether a 10-week dietary intervention with 250 mg/kg/d of CP could prevent or ameliorate MetS in high-fructose-fed rats. Consumption of CP by rats fed a high-fructose diet reduced body weight gain, lowered systolic blood pressure (SBP), fasting plasma glucose and insulin levels, and improved insulin resistance compared to rats fed a high-fructose diet alone. At the hepatic level, CP attenuated the increase in lipid storage, reduced lipid peroxidation, and improved glutathione levels when combined with a high-fructose diet. CP also affected the expression of key genes related to glucose and lipid metabolism in hepatic and adipose tissues, in rats fed a fructose-rich diet. This study demonstrates that CP ameliorates several consequences of high-fructose-induced MetS in the rat (weight gain, hypertension, glucose intolerance, insulin resistance, changes in liver, and adipose tissue function). Hence, our data provide evidence that CP consumption in the context of a high-fructose diet can be used to improve MetS management. Full article

The increasing global demand for critical minerals, driven by rapid population growth and the widespread adoption of low-carbon technologies, electric vehicles, and clean energy systems, highlights the urgent need for sustainable resource management. Mine tailings, traditionally considered waste, are now being recognized as valuable secondary sources for mineral recovery. This paper compiles a comprehensive review of the four short- and mid-term critical minerals (lithium, cobalt, nickel, and rare earth elements) and provides insights regarding their recovery with a focus on the latest technological advancements. By exploring key innovations in separation processes, the review demonstrates how these technologies are addressing supply chain bottlenecks while simultaneously reducing the environmental footprint of mining operations. The paper also advocates for a holistic approach to mine waste management, integrating mineral recovery with environmental remediation. It emphasizes the dual benefits of recovering valuable resources while purifying contaminated water and mitigating pollution risks. The proposed circular economy model suggests a sustainable blueprint for managing mine tailings, emphasizing resource reuse, waste reduction, and economic viability. Full article

The construction sector is one of the largest creators and distributors of wealth, contributing to economic growth worldwide. However, this economic growth comes together with very high environmental impacts. Thus, rehabilitation solutions that can adapt the current building stock to today’s structural requirements are needed, increasing structural safety, while avoiding the production of demolition waste and the extraction of virgin raw materials, hence lowering the construction sector’s environmental impacts. Such rehabilitation solutions need to be environmentally and economically sound so that stakeholders can make informed decisions based on their needs and priorities. This paper presents a case study of an existing reinforced concrete beam, whose flexural resistance is increased using four alternative strengthening solutions: concrete jacketing, without and with increasing the cross-section size, and plate bonding, using either carbon fibre-reinforced polymer (CFRP) strips or steel plates. These solutions are studied via an environmental and economic cradle-to-gate life cycle assessment (LCA), resulting in a comprehensive comparison of their environmental and economic impacts, followed by a multicriteria and sensitivity analysis and eco-cost approach to determine the optimal solution. According to the criteria considered in the study, when environmental impacts are more valued, the concrete jacketing solution presents the best results and, when cost is dominant in the decision, the bonding of CFRP strips becomes the optimal solution. Full article

This study optimized the extraction conditions to maximize the recovery yields of quercetin and total flavonoids from red onion skin waste using sequential microwave/ultrasound-assisted extraction. Five effective factors of quercetin extraction yield were investigated using response surface methodology. The method was successfully performed under optimal 60 s microwave irradiation conditions followed by 15 min sonication at 70 °C with 70% (v/v, water) ethanol with a solvent-to-solid ratio of 30 mL/g. The variance analysis of the model for both quercetin (Y₁) and total flavonoid (Y₂) recovery from DOS demonstrated that ultrasound temperature (X₂) was the most highly significant and influential factor, with a p-value of <0.0001 for both responses. Additionally, three key interaction terms—X₁X₂, X₂X₄, and X₂X₅—were identified as highly significant, further underscoring the critical role of ultrasound temperature in optimizing the extraction process for both quercetin and total flavonoids. The maximum recovery yields of quercetin and total flavonoids from red onion skin were 10.32% and 12.52%, respectively. The predicted values for quercetin (10.05%) and total flavonoids (12.72%) were very close to the experimental results. The recovery yields obtained from different extraction methods under the identical experimental conditions mentioned earlier were ultrasound/microwave-assisted extraction (7.66% quercetin and 10.18% total flavonoids), ultrasound-assisted extraction (5.36% quercetin and 8.34% total flavonoids), and microwave-assisted extraction (5.03% quercetin and 7.91% total flavonoids). The ANOVA confirmed highly significant regression models (p-values < 0.0001), with an insignificant lack of fit (p = 0.0515 for quercetin, p = 0.1276 for total flavonoids), demonstrating the robustness and reliability of the optimization. This study provides valuable insights for improving the extraction of bioactive compounds, which is critical for developing effective cancer treatments and advancing medical research. Additionally, the model shows potential for scaling up food processing applications to recover valuable products from red onion skin waste. Full article

The decades after the Second World War have seen economic growth and prosperity on an unprecedented scale. Yet this incredible turnover of raw materials and energy into goods and eventually waste has brought our planetary systems close to their limits, as witnessed most prominently, yet not exclusively, by climate change and mass extinctions. Changing towards a greener, more sustainable and circular economy without limiting our economic wealth is attractive—yet this change does not seem to be easy or speedy enough to save the planet, its eco- and social systems, and its inhabitants. In contrast, moving towards an economy less demanding on energy and raw materials, and focusing more on the pursuit of immaterial forms of satisfaction and happiness, requires an alternative form of hedonism. By cerishing quality time rather than heaps of money, and social interactions rather than material goods, even a finite planet may allow sustainable and indeed infinite forms and amounts of prosperity. Full article

Corruption is a global problem that affects the fair distribution of wealth of every country to different degrees and represents a problem to be solved to prevent the diversion and waste of resources. Among the different efforts to first measure it and later reduce it by proposing strategies, there exist a variety of indices, such as the corruption perception index, and other related issues, such as the global impunity index, the laxness of anticorruption policies, etc., which are computed for different countries worldwide. Based on these indices, we propose a model for corruption using a system of ordinary differential equations, considering anticorruption policies. Those three factors were identified after analyzing the phenomenon and available data, particularly for Mexico. Also, we fit it to the reported data of this country and perform simulations expecting to predict the short term, and performed a sensitivity analysis. The model is capable of reproducing the observed oscillatory behavior of the phenomenon. The model fit can still be improved by including the data for the anticorruption policies, which were only studied for different scenarios. Moreover, the model is susceptible to application in other countries, as long as data are available, and then provides a computational tool to predict and visualize the effect of appropriate public policies to fight corruption. Full article

In this study, we propose an intelligent drinking water controller based on programmable logic controller (PLC) specifically designed for pig breeding, which significantly reduces the water waste caused by the use of traditional drinking bowls by regulating the frequency and flow of water release. In addition, the drinking water system has a tracking and recording function, which can record the frequency and duration with which fattening pigs drink water in each pen in detail, thus providing farmers with a wealth of pig health and behavior data to help optimize breeding management decisions. In order to deeply analyze the effects of the intelligent drinking water controller on the growth, resources environment and economic benefits of fattening pigs under the condition of large-scale breeding, a single factor comparison experiment was designed.In this experiment, 84 fattening pigs were selected and distributed in 12 pens. Among them, six pens were randomly designated as the control group;the pig in this group used ordinary drinking water bowls for the water supply. The other six pens were designated as the experimental group;the pigs in this group used the intelligent drinking water controller. The experimental results showed that in the experimental group with the intelligent drinking water controller, the average daily water waste per finishing pig was only 0.186 L (p < 0.05), accounting for only 25.98% of the average daily water waste per pig in the control group (p < 0.05). In terms of water quality, the intelligent drinking water controller also showed better performance, and the performance indicators were effectively reduced, with the highest reduction reaching 39.86%, which greatly reduced water pollution. Compared with the traditional drinking bowl, the average daily weight increment of fattening pigs in the pen using the intelligent drinking water controller was increased by 0.02 kg. In terms of long-term benefits, the PLC-based intelligent drinking water controller significantly improves the economic returns of the farm and has a positive impact on pig health. The high frequency data collection of the pigs’ drinking habits through the intelligent drinking water controller can also provide data support for the subsequent establishment of a pig water-drinking behavior analysis model. Full article

The purpose of this work is to examine the nature of the historically observed and empirically described by the Pareto law inequality in the distribution of wealth and income in an economic system. This inequality is presumed to be the result of unequal opportunity by its members. An analytical model of the economic system consisting of a large number of actors, all having equal access to its total wealth (or income) has been developed that is formally represented by a scale-free network comprised of nodes (actors) and links (states of wealth or income). The dynamic evolution of the complex network can be mapped in turn, as is known, into a system of quantum particles (links) distributed among various energy levels (nodes) in thermodynamic equilibrium. The distribution of quantum particles (photons) at different energy levels in the physical system is then derived based on statistical thermodynamics with the attainment of maximal entropy for the system to be in a dynamic equilibrium. The resulting Planck-type distribution of the physical system mapped into a scale-free network leads naturally into the Pareto law distribution of the economic system. The conclusions of the scale-free complex network model leading to the analytical derivation of the empirical Pareto law are multifold. First, any complex economic system behaves akin to a scale-free complex network. Second, equal access or opportunity leads to unequal outcomes. Third, the optimal value for the Pareto index is obtained that ensures the optimal, albeit unequal, outcome of wealth and income distribution. Fourth, the optimal value for the Gini coefficient can then be calculated and be compared to the empirical values of that coefficient for wealth and income to ascertain how close an economic system is to its optimal distribution of income and wealth among its members. Fifth, in an economic system with equal opportunity for all its members there should be no difference between the resulting income and wealth distributions. Examination of the wealth and income distributions described by the Gini coefficient of national economies suggests that income and particularly wealth are far off from their optimal value. We conclude that the equality of opportunity should be the fundamental guiding principle of any economic system for the optimal distribution of wealth and income. The practical application of this conclusion is that societies ought to shift focus from policies such as taxation and payment transfers purporting to produce equal outcomes for all, a goal which is unattainable and wasteful, to policies advancing among others education, health care, and affordable housing for all as well as the re-evaluation of rules and institutions such that all members in the economic system have equal opportunity for the optimal utilization of resources and the distribution of wealth and income. Future research efforts should develop the scale-free complex network model of the economy as a complement to the current standard models. Full article

The present paper explores the biological potential of bioactive compounds present in wine industry wastes, highlighting their valorization to promote sustainability and circular economy. Wine by-products, such as grape pomace and vine shoots, contain a high concentration of polyphenols, flavonoids, anthocyanins and other phytochemicals with antioxidant, anti-inflammatory and anticarcinogenic properties. Both conventional extraction methods, such as solid–liquid extraction, and emerging technologies, including enzyme-assisted extraction, ultrasound-assisted extraction, supercritical fluid extraction, microwave-assisted extraction, pressurized liquid extraction, high-hydrostatic-pressure extraction, and deep natural solvent-assisted extraction (NaDES), are discussed. In addition, the preservation of polyphenolic extracts by microencapsulation, a key technique to improve the stability and bioavailability of bioactive compounds, is addressed. The combination of advanced extraction methods and innovative preservation techniques offers a promising perspective for the valorization of bioactive compounds from wine residues, driving sustainability and innovation in the industry. Full article