Search Results (7)

Microplastics (MPs), defined as synthetic polymer particles ranging from 1 μm to 5 mm, originate from various sources, including synthetic textiles, tire wear, degraded plastic waste, etc. Their small size and chemical stability make them challenging to remove, collect and degrade, posing significant adverse effects to both ecosystems and human health. While efforts to develop sustainable alternatives and removal methods are ongoing, effective solutions remain limited. Catalytic degradation and upcycling present a promising route to mitigate MP pollution by enabling efficient breakdown into less harmful molecules and potential upcycling into valuable products with lower energy requirements. This review provides a comprehensive overview of recent advances in catalyst design and development specifically for MP degradation, highlighting photochemical, thermal, biological, electrochemical, and hybrid approaches. Key challenges, reaction mechanisms, and future directions are discussed, offering a timely reference for researchers in this emerging field. Full article

Rubberized concrete exhibits enhanced toughness and sustainability but suffers from reduced mechanical strength, limiting its applications. This study enhanced the compressive strength of rubberized concrete using hybrid steel/glass fibers. The results showed a positive synergy between the hybrid fibers, with improvements in compressive strength, elastic modulus, Poisson’s ratio, peak strain, and compressive toughness by 16.1%, 19.4%, 32.0%, 63.4%, and 101.7%, respectively, at a hybrid fiber content of 0.8% (steel fiber 0.6% and glass fiber 0.2%). A well-fitting stress–strain model was adopted for future constitutive simulations. This study advances the understanding of rubberized concrete with hybrid steel/glass fibers under axial compression and promotes its application in structural engineering. Full article

Waste rubber tires are an area of global concern in relation to reducing the consumption of petrochemical products and environmental pollution. Herein, eco-friendly high-performance thermoplastic polyurethane (PU) elastomers were successfully in-situ synthesized through the incorporation of ground tire rubber (GTR). The excellent wet-skid resistance of PU/GTR elastomer was achieved by using mixed polycaprolactone polyols with Mn = 1000 g/mol (PCL-1K) and PCL-2K as soft segments. More importantly, an efficient solution to balance the contradiction between dynamic heat build-up and wet-skid resistance in PU/GTR elastomers was that low heat build-up was realized through the limited friction between PU molecular chains, which was achieved with the help of the network structure formed from GTR particles uniformly distributed in the PU matrix. Impressively, the tanδ at 60 °C and the DIN abrasion volume (Δrel) of the optimal PU/GTR elastomer with 59.5% of PCL-1K and 5.0% of GTR were 0.03 and 38.5 mm³, respectively, which are significantly lower than the 0.12 and 158.32 mm³ for pure PU elastomer, indicating that the PU/GTR elastomer possesses extremely low rolling resistance and excellent wear resistance. Meanwhile, the tanδ at 0 °C of the above-mentioned PU/GTR elastomer was 0.92, which is higher than the 0.80 of pure PU elastomer, evidencing the high wet-skid resistance. To some extent, the as-prepared PU/GTR elastomer has effectively solved the “magic triangle” problem in the tire industry. Moreover, this novel research will be expected to make contributions in the upcycling of waste tires. Full article

Material design in shape memory polymers (SMPs) carries significant importance in attaining high performance and adjusting the interface between additive and host polymer matrix to increase the degree of recovery. Herein, the main challenge is to enhance the interfacial interactions to provide reversibility during deformation. The present work describes a newly designed composite structure by manufacturing a high-degree biobased and thermally induced shape memory polylactic acid (PLA)/thermoplastic polyurethane (TPU) blend incorporated with graphene nanoplatelets obtained from waste tires. In this design, blending with TPU enhances flexibility, and adding GNP provides functionality in terms of mechanical and thermal properties by enhancing circularity and sustainability approaches. The present work provides a scalable compounding approach for industrial applications of GNP at high shear rates during the melt mixing of single/blend polymer matrices. By evaluating the mechanical performance of the PLA and TPU blend composite composition at a 9:1 weight percentage, the optimum GNP amount was defined as 0.5 wt%. The flexural strength of the developed composite structure was enhanced by 24% and the thermal conductivity by 15%. In addition, a 99.8% shape fixity ratio and a 99.58% recovery ratio were attained within 4 min, resulting in the spectacular enhancement of GNP attainment. This study provides an opportunity to understand the acting mechanism of upcycled GNP in improving composite formulations and to develop a new perspective on the sustainability of PLA/TPU blend composites with an increased biobased degree and shape memory behavior. Full article

Homogeneous dispersion of graphene into thermoplastic polymer matrices during melt-mixing is still challenging due to its agglomeration and weak interfacial interactions with the selected polymer matrix. In this study, an ideal dispersion of graphene within the PA66 matrix was achieved under high shear rates by thermokinetic mixing. The flow direction of graphene was monitored by the developed numerical methodology with a combination of its rheological behaviors. Graphene nanoplatelets (GNP) produced from waste-tire by upcycling and recycling techniques having high oxygen surface functional groups were used to increase the compatibility with PA66 chains. This study revealed that GNP addition increased the crystallization temperature of nanocomposites since it acted as both a nucleating and reinforcing agent. Tensile strength and modulus of PA66 nanocomposites were improved at 30% and 42%, respectively, by the addition of 0.3 wt% GNP. Flexural strength and modulus were reached at 20% and 43%, respectively. In addition, the flow model, which simulates the injection molding process of PA66 resin with different GNP loadings considering the rheological behavior and alignment characteristics of GNP, served as a tool to describe the mechanical performance of these developed GNP based nanocomposites. Full article

The amount of elastomeric waste, especially from tires is constantly increasing on a global scale. The recycling of these residua should be considered a priority. Compounding the waste rubbers with other polymers can be an excellent alternative to reuse waste materials. This procedure requires solving the issue of the lack of compatibility between the waste rubber particles and other polymers. Simultaneously, there is a claim for introducing biodegradable plastics materials to reduce their environmental impact. In this work, reclaimed rubber/poly(ε-caprolactone) (RR/PCL) blends are proposed to enhance the recycling and upcycling possibilities of waste rubbers. The results show that the addition of PCL to the RR allows obtaining blends with improved mechanical properties, good thermal stability, and enhanced interfacial compatibility between the used components. Structure and properties of the proposed RR/PCL have been studied by means of static and dynamic mechanical testing, Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA)-FTIR analysis. Full article

Building energy efficiency and urban waste management are two focal issues for improving environmental status and reducing greenhouse gas emissions. The main aim of this paper is to compare economic costs of new building envelope structures designed by authors reusing and upcycling municipal waste in order to decrease energy demand from the building sector and, at the same time, improve eco-friendly waste management at the local scale. The reuse of waste for building envelope structures is one of the main principles of the Earthship buildings model, based on the use of passive solar principles in autonomous earth-sheltered homes. This Earthship principle has been analyzed in order to optimize buildings’ energy performance and reuse municipal waste for new building envelope structures in urban areas. Indeed, the elaborated structures have been designed for urban contexts, with the aim of reuse waste coming from surrounding landfills. The methods include an analysis of thermal performance of urban waste for designing new building envelope structures realized by assembling waste and isolating materials not foreseen in Earthship buildings. The reused materials are: cardboard tubes, automobile tires, wood pallets, and plastic and glass bottles. Finally, comparing economic costs of these new building envelope structures, the obtained results highlight their economic feasibility compared to a traditional structure with similar thermal transmittance. Full article