Search Results (39)

The growing disposal of used tyres and plastic waste in landfills poses a significant environmental challenge. This study investigates the potential of utilizing used tyre rubber and macro-synthetic fibres (MSFs) made from recycled plastics in fibre-reinforced rubberized concrete (RuFRC). Various percentages of tyre rubber shreds were used to replace coarse aggregates, calculated as 10%, 20%, and 30% of the volume of fine aggregates; fibre dosages (0%, 0.25%, 0.5%, 0.75%, and 1% by volume) were incorporated into the mix, and a series of physical, mechanical, and durability properties were evaluated. The results show that, as the fibre and rubber content increased, the slump of RuFRC decreased, with the lowest value obtained for concrete with 1% fibre and 30% rubber. The density of RuFRC decreases as the rubber percentage increases due to air voids and increased porosity caused by the rubber. The strength properties of RuFRC were found to decline with the increase in the rubber content, with mixes containing 30% rubber exhibiting reductions of about 60% in compressive strength, 27% in tensile strength, and 13% in flexural strength compared to the control specimen. Durability testing revealed that an increased rubber content led to higher water absorption, water penetration, and chloride ion permeability, with 30% rubber showing the highest values. However, lower rubber content (10%) and higher fibre dosages improved the durability characteristics, with water absorption reduced by up to 5% and shrinkage strains lowered by about 7%, indicating better compaction and bonding. These results indicate that RuFRC with moderate rubber and higher fibre content offers a promising balance between sustainability and performance. Full article

This study investigates the impact of partially replacing cement with fly ash (FA) on the mechanical performance of fiber-reinforced rubberized concrete (FRRC) incorporating waste tyre rubber and recycled macro-synthetic fibers (MSF). FRRC mixtures were prepared with varying fly ash replacement levels (0%, 25%, and 50%), rubber aggregate contents (0%, 10%, and 20% by volume of fine aggregate), and macro-synthetic fiber dosages (0% to 1% by total volume). The fresh properties were evaluated through slump tests, while hardened properties including compressive strength, splitting tensile strength, and flexural strength were systematically assessed. Results demonstrated that fly ash substitution up to 25% improved the interfacial bonding between rubber particles, fibers, and the cementitious matrix, leading to enhanced tensile and flexural performance without significantly compromising compressive strength. However, at 50% replacement, strength reductions were more pronounced due to slower pozzolanic reactions and reduced cement content. The inclusion of MSF effectively mitigated strength loss induced by rubber aggregates, improving post-cracking behavior and toughness. Overall, an optimal balance was achieved at 25% fly ash replacement combined with 10% rubber and 0.5% fiber content, producing a more sustainable composite with favorable mechanical properties while reducing carbon and ecological footprints. These findings highlight the potential of integrating industrial by-products and waste materials to develop eco-friendly, high-performance FRRC for structural applications, supporting circular economy principles and reducing the carbon footprint of concrete infrastructure. Full article

The disposal of agro-industrial waste is a pressing environmental issue. At the same time, due to the high silica content in specific agricultural residues, their processed products can be utilised in various industrial sectors as substitutes for commercial materials. This study investigates the key technological, physico-mechanical, and viscoelastic properties of industrial elastomeric compounds based on synthetic styrene–butadiene rubber, intended for the tread of summer passenger car tyres, when replacing the commercially used highly reinforcing silica filler (SF), Extrasil 150VD brand (white carbon black), with a carbon–silica filler (CSF). The CSF is produced by carbonising a finely ground mixture of rice production waste (rice husks and stems) in a pyrolysis furnace at 550–600 °C without oxygen. It was found that replacing 20 wt.pts. of silica filler with CSF in industrial tread formulations improves processing parameters (Mooney viscosity increases by up to 5.3%, optimal vulcanisation time by up to 9.2%), resistance to plastic deformation (by up to 7.7%), and tackiness of the rubber compounds (by 31.3–34.4%). Viscoelastic properties also improved: the loss modulus and mechanical loss tangent decreased by up to 24.0% and 14.3%, respectively; the rebound elasticity increased by up to 6.3% and fatigue resistance by up to 2.7 thousand cycles; and the internal temperature of samples decreased by 7 °C. However, a decrease in tensile strength (by 10.7–27.0%) and an increase in wear rate (up to 43.3% before and up to 22.5% after thermal ageing) were observed. Nevertheless, the overall results of this study indicate that the CSF derived from the carbonisation of rice production waste—containing both silica and carbon components—can effectively be used as a partial replacement for the commercially utilised reinforcing silica filler in the production of tread rubber for summer passenger car tyres. Full article

This study explores the potential of using sustainable materials in brick manufacturing by designing a novel brick mix in the laboratory, incorporating sand, lime kiln dust (LKD) waste, tyre rubber, and ground granulated blast furnace slag (GGBFS) waste. These cementless bricks blended LKD–GGBFS wastes as the binder agent and fine crumb rubber from waste tyres as a partial replacement for sand in measured increments of 0%, 5%, and 10% by volume of sand. Ordinary Portland cement (OPC) and fired clay bricks were sourced from the industry, and their properties were compared to those of the laboratory bricks. Tests performed on the industry and laboratory bricks included compressive strength (CS), freeze-thaw (F-T), and water absorption (WA) tests for comparison purposes. Additionally, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analyses were performed on the bricks to assess the morphological and mineralogical changes responsible for the observed strengths and durability. The CS and WA values of the engineered bricks were 12, 6, and 4 MPa, and 7, 12, and 15%, respectively, for 0, 5, and 10% crumb rubber replacements. The industry bricks’ average CS and WA values were 13 MPa and 8%, respectively. From the results obtained, the green laboratory bricks passed the minimum strength requirements for load-bearing and non-load-bearing bricks, which can be used to construct small houses. Lastly, the engineered bricks demonstrated strength and durability properties comparable to those of the industry-standard bricks, indicating their potential as a sustainable alternative to help divert waste from landfills, reduce the pressure on natural fine sand extraction, and support eco-conscious brick production for a sustainable environment. Full article

Disposing of waste tyres in landfills poses significant environmental hazards, making recycling a crucial alternative. Rubberised concrete has been found to exhibit lower density and better thermal insulation performance than conventional concrete. In order to maximise the potential of thermal insulation of rubberised concrete, this study investigates the mechanical and thermal properties of foamed rubberised polypropylene fibre concrete (FRPFC). FRPFC was produced using a mix of crumb rubber (CR) granules, polypropylene fibres, and foam, targeting a density of 800 kg/m³, with CR substituting sand at varying levels. Compressive strength, flexural strength, splitting tensile strength, and thermal conductivity of FRPFC were evaluated. The results demonstrate that increasing CR granule content enhances compressive strength due to reduced porosity from lower foam usage. For instance, compressive strength improved by 55% (2.64 to 4.10 MPa) as CR granule content increased from 0% to 80%. Similarly, flexural strength and splitting tensile strength increased by 55% (1.61 MPa to 2.49 MPa) and 39% (0.41 MPa to 0.57 MPa), respectively, when CR content rose from 0% to 100% at a water-to-cement ratio of 0.50. Furthermore, thermal conductivity decreased by 34% (0.3608 W/mK to 0.2376 W/mK) when sand was fully replaced with CR granules, showcasing improved thermal insulation. Statistical analysis using ANOVA confirmed that the crumb rubber content significantly influences the mechanical and thermal properties of FRPFC, with higher CR content (80% and 100%) leading to superior performance. These findings highlight FRPFC’s potential as an environmentally sustainable and thermally efficient construction material, contributing to enhanced mechanical properties compared to conventional foamed polypropylene fibre concrete. Full article

In this study, numerical simulations using the Abaqus finite element model were performed to evaluate the effects of incorporating waste tyres of varying sizes into the base layer as part of a coupled tyre–pavement structure. The tyre-reinforced structure demonstrated superior deformation resilience, attributed to the hyperelastic properties of tyre rubber, underscoring its potential for applications where deformation recovery is essential. For achieving a uniform settlement, the entire tyre stacking scheme is recommended, whereas the one-third tyre configuration is ideal for minimising displacement. The one-half tyre configuration provides a balanced approach, optimising resource utilisation for structures with moderate performance requirements. The inclusion of tyres increases the equivalent stress within the cement-stabilised gravel layer beneath the tyre, and this effect is less pronounced with smaller tyre sizes. Notably, the projected portion of the tyre tread enhances the bearing capacity of the base structure, improving the load distribution and overall structural performance. The middle and bottom surface layers were identified as the most critical for controlling deformation and stress distribution, while a moderate modulus is advised for the surface course to achieve a balance between deformation control and stress uniformity. The integration of high-modulus layers with tyre reinforcement offers an optimised solution for both deformation management and stress distribution. This study highlights the potential of tyre-reinforced pavements as an innovative and sustainable construction practice, particularly suited for light to moderate traffic conditions. Further research is recommended to explore the long-term environmental and economic benefits, as well as the impacts of tyre composition and ageing on performance. Full article

This paper investigates the use of spent tyre rubber as a precursor for synthesising adsorbents to recover rare earth elements. Through pyrolysis and CO₂ activation, tyre rubber is converted into porous carbonaceous materials with surface properties suited for rare earth element adsorption. The study also examines the efficiency of leaching rare earth elements from NdFeB magnets using optimised acid leaching methods, providing insights into recovery processes. The adsorption capacity of the materials was assessed through batch adsorption assays targeting neodymium (Nd³⁺) and dysprosium (Dy³⁺) ions. Results highlight the superior performance of activated carbon derived from tyre rubber following CO₂ activation, with the best-performing adsorbent achieving maximum uptake capacities of 24.7 mg·g⁻¹ for Nd³⁺ and 34.4 mg·g⁻¹ for Dy³⁺. Column studies revealed efficient adsorption of Nd³⁺ and Dy³⁺ from synthetic and real magnet leachates with a maximum uptake capacity of 1.36 mg·g⁻¹ for Nd³⁺ in real leachates and breakthrough times of 25 min. Bi-component assays showed no adverse effects when both ions were present, supporting their potential for simultaneous recovery. Furthermore, the adsorbents effectively recovered rare earth elements from e-waste magnet leachates, demonstrating practical applicability. This research underscores the potential of tyre rubber-derived adsorbents to enhance sustainability in critical raw material supply chains. By repurposing waste tyre rubber, these materials offer a sustainable solution for rare earth recovery, addressing resource scarcity while aligning with circular economy principles by diverting waste from landfills and creating value-added products. Full article

High-Content Crumb Rubber Asphalt (HCRA) binder improves road performance and address waste tyre pollution, yet its ageing behaviour is not fully understood. In this study, 70# neat asphalt binder and HCRA with rubber contents of 35% and 50% were selected and aged through the Thin Film Oven Test (TFOT) and Pressure Ageing Vessel (PAV) tests. FTIR (Fourier Transform Infrared Spectroscopy) and DSR (Dynamic Shear Rheometer) were employed to investigate their chemical composition and rheological properties. The FTIR results show that HCRA’s chemical test results are similar to those of 70#, but HCRA is more susceptible to ageing. I(C=C) strength decreases with age. The DSR results show that HCRA outperforms 70# neat asphalt binder in terms of viscoelasticity, high temperature performance and fatigue resistance, and exhibits greater resistance to ageing. The ageing index (AI) was obtained through a calculation using the formula, and overall, 70# neat asphalt binder is more sensitive to ageing behaviour and less resistant to ageing, and HCRA is particularly outstanding for fatigue resistance. A strong correlation is observed between chemical composition and some rheological property indicators. Therefore, we are able to predict the rheological properties using chemical composition indicators. This study provides insight into the ageing behaviour of a neat asphalt binder and an HCRA binder and demonstrates that the HCRA binder outperforms conventional asphalt in several performance areas. It also provides theoretical support for the consumption of waste tyres to prepare high content crumb rubber asphalt. Full article

The integration of waste materials in extrudable cement mixtures has the potential to make the construction industry more sustainable by reducing carbon footprints and developing eco-friendly materials. This along with advancements in 3D concrete printing (3DCP) provides engineering and architectural benefits by reducing material waste and costs. In this paper, the impact of waste incorporation on properties of mortar and concrete is examined. The use of waste materials, such as pumice, coal slag, agricultural lignocellulosic residues, and recycled rubber tyres, to improve thermal insulation and durability of cementitious composites is discussed. In addition, the incorporation of air-entraining admixtures with surfactant activity is explored for their indirect effect on thermal behaviour, pore size reduction, and enhancement in concrete properties. This review includes important topics such as a strength resistance to freezing and thawing, fire resistance, plasticising effect, and delay in cement hydration. These findings highlight the benefits of using diverse waste materials in construction, providing a multidimensional approach to waste management, cost optimization, and enhanced construction materials in the context of 3DCP. Full article

The declining availability of natural sand resources and the significant carbon footprint associated with the extensive use of cement are posing severe limitations on the advancement and application of ultra-high-performance concrete (UHPC). In this study, waste tyre-derived recycled crumb rubber particles (CR) were employed to replace quartz sand, and an alkali-activated cementitious material was used to produce waste tyre-alkali-activated UHPC (T-UHPAC). The influence of different CR replacement ratios (0%, 5%, 20%, 35%, 50%) on the tensile and flexural performance of T-UHPAC was investigated, and a predictive model for the stress–strain response considering the CR replacement ratio was established. An optimization method for improving the tensile and flexural performance of T-UHPAC was proposed. The results indicate that the effect of rough-surfaced CR on the interfacial properties of concrete differs from that of smooth quartz sand. A CR replacement ratio exceeding 35% led to a reduction in both the tensile and flexural strengths of UHPAC, while a replacement ratio at or below 20% resulted in a superior tensile and flexural performance of T-UHPAC. The established predictive model for tensile performance accurately forecasts the stress–strain behaviour of T-UHPAC under varying CR replacement ratios, with the accuracy improving as the CR replacement ratio increases. By utilizing CR to replace quartz sand in proportions not exceeding 20%, the production of low-carbon UHPC with exceptional comprehensive mechanical properties is achievable. Moreover, the development of T-UHPAC through the comprehensive utilization of waste tyres presents a promising and innovative approach for the low-carbon and cost-effective production of UHPC, thereby facilitating the sustainable development of natural resources. This research represents a significant step towards the widespread adoption and application of UHPC and thus holds substantial importance. Full article

Recently, the feasibility of using bio-materials to reduce or completely replace the use of bitumen in asphalt mixture has gained increasing attention. Amongst others, an interesting solution is represented by the use of wood co-products with mineral or vegetable oils. This research focuses on the development of bio-binders using vegetable resin (VR) in unmodified form and waste olive oil (WOO) as the main components; in order to optimize the rheological properties of the blends, crumb rubber from end-of-life tyres (CR), Styrene-Butadiene-Styrene (SBS) and polyethylene waxes (PEW) are used as additives. In particular, this investigation focuses on studying different oil/rosin ratios and polymer contents to provide a clear framework on this bio-binder solution; conventional bituminous binders are taken as a reference. The alternative binders are characterized in terms of conventional properties such as penetration depth and softening point, as well as rheological response. Finally, two of the bio-binders studied are selected with the aim of assessing the mechanical properties of the resulting sustainable asphalt mixture using the Marshall Stability test and the Indirect Tensile Strength test, comparing the results with the threshold values set by an Italian road agency. Thus, this research represents a preliminary analysis of the potential application of bio-binder mixtures within the specification limits imposed by road agencies. Although this research represents a first attempt, the results are promising and prove to be worthy of further investigations. Full article

This study focuses on anti-trauma mats designed for buffaloes’ comfort, using as raw materials rubber powder from end-of-life tyres (ELTs) and an isocyanate-based polyurethane resin binder. The first part of the study focused on mat formulation. Whilst it was possible to select a unique combination of raw materials and design features, it was necessary to investigate the relationship between three critical parameters affecting mat consistency and therefore buffalo comfort: binder quantity, mat thickness, and desired final mat density (bulk). In order to quantitatively assess the variation in hardness, various combinations were investigated within well-defined ranges based on the relevant literature. The results obtained from nine selected combinations indicate that increases in the three critical parameters do not induce a real phase transition in the final product consistency, although the hardness suggests an increasing trend. The mats consistently exhibited a moderately soft/hard consistency, offering environmental benefits in terms of increased rubber usage and potentially reduced chemical binder, depending on the desired thickness. The selected mixture showed excellent resistance to heavy chemical loads, suggesting reliability for frequent cleaning operations. The second part of the study involved field trials of the mats with calves. This involved monitoring their weight gain and appetite levels over a 90-day period. The results showed excellent growth performance compared to uncoated grids (i.e., weight gain was approximately 20% higher at the end of the observation period); this was similar to that achieved with the use of straw bedding. However, compared to straw bedding, the mats (i) exhibit long-term durability, with no signs of wear from washing or trampling over the months of the trial, (ii) allow for quick and efficient cleaning, and (iii) enable companies to save on labour, material (straw), and waste disposal costs, while maintaining (or even improving) the same welfare levels associated with the use of straw. Full article

The incorporation of rubber recycled aggregates from end-of-life tyres (ELT) in the manufacturing process of sustainable building materials has gained great interest in recent decades as a result of the large volume of this waste being generated annually. In this work, the objective is to make a contribution towards the circularity of construction products by carrying out a physico-mechanical characterisation of new gypsum composites made with the incorporation of these recycled rubber aggregates. To this end, up to 30% by volume of the original raw material has been substituted, analysing the mechanical resistance to bending and compression. Although lower than those of traditional gypsum material, both properties exceed the limits set at 1 and 2 MPa, respectively, by the current regulations. In addition, water absorption by capillarity significantly decreases, and thermal conductivity is reduced by more than 35% with respect to the reference material. Finally, in order to provide the research with a practical application, a prefabricated plate design has been proposed that incorporates the gypsum materials studied and an agglomerated rubber band that increases the thermal resistance and improves the efficiency of the designed construction system. In this way, this research reflects the potential of these novel building materials and explores new avenues for their application in building construction. Full article

The current European standards demand more energy-efficient, comfortable, and sustainable buildings and encourage the incorporation of recycled materials in building construction. Timber buildings are successfully competing with traditional building materials in addressing these challenges; however, one of the weaknesses of timber systems is their limited sound insulation capacity. One material that can fit into the sustainability aims of timber construction and improve its acoustic performance is recycled ground tyre rubber (GTR), which, on top of this, is a serious environmental problem. This paper presents research on the use of GTR materials combined with timber systems in order to improve their acoustic performance. Three different types of GTR products (granulate, rolls, and sheets) of different thicknesses and densities are selected and are combined with different sound-absorbing materials (mineral wool, cellulose, and wood fibre) inside a lightweight timber sandwich system. In this study, the first qualitative approach, the acoustic performance of the different resulting systems is compared based on the sound pressure level difference measured in a custom-made reduced-size transmission chamber. Secondly, the sound reduction index of four selected specimens is measured in an accredited sound transmission laboratory. The results show that, for all the lightweight timber systems included in this research, introducing a GTR layer improves the acoustic performance of the system. Full article

Waste from scrap tyres, due to its high volume (17 million Mg per year) and durability resulting from the physical and chemical properties, requires innovative approaches for efficient and environmentally friendly management. In many countries, the landfilling of waste tyres is banned (e.g., EU, USA, UK); however, waste tyres can be a source of valuable materials such as carbon black, pyrolysis oil, hydrogen-rich syngas, tyre char, as well as energy. The purpose of this article is to provide a synthesis of the state of knowledge regarding the thermal conversion of waste tyres by pyrolysis and gasification, taking into account the use of different measurement techniques and reactor types. These technologies are forward-looking and have a high degree of flexibility in terms of product sourcing, depending on the process conditions. The properties of waste from used tyres were analysed, i.e., the composition of the content of individual components and the main chemical substances. The results encompassed ultimate and proximate analyses of rubber from tyres, as well as the physical and chemical parameters of the tyre char obtained through pyrolysis. This article compiles available literature data regarding the impact of process and raw material parameters, such as temperature and time conditions, pressure, particle size, and catalyst addition on the pyrolysis and gasification processes. It also explores the influence of these factors on the yield and properties of the products, including pyrolysis oil, gas, synthesis gas, and tyre char. Full article