Search Results (14,737)

To address the challenges of winter pavement icing and the disposal of organic waste, this study developed a sustained-release deicing filler utilizing biochar derived from spent coffee grounds (SCGs). The material was synthesized through high-temperature carbonization, followed by physical adsorption of chloride salts and surface hydrophobic modification to control release rates. The study made asphalt mixtures and replaced normal mineral filler with the SCG material by volume at ratios of 0%, 50%, 75%, and 100% to test road and deicing performance. Wheel-tracking tests showed that the additive improved high-temperature stability and dynamic stability went up by 27.04% at the 75% replacement level. Salt dissolving created voids and slightly lowered water stability at high dosages, but all performance numbers still met the current engineering rules. Rutting slab tests at −5 °C showed the 100% replacement mix cut snow coverage to 11.43% in 60 min and proved it works for deicing. Pull-out tests measure the bond strength between ice and pavement at −5 °C, −7 °C, and −9 °C. The SCG deicing material weakens ice sticking and the bond strength for the 100% group at −5 °C was 0.35 kN, which is about 57.8% lower than the control asphalt. The bond strength of the deicing mix at −9 °C was still lower than the normal mix at −5 °C. This big drop in stickiness means the pavement stops ice from packing hard and makes mechanical removal easier. This study shows that the prepared deicing materials exhibit excellent sustained-release performance and snow-melting efficiency while ensuring satisfactory road performance. SCG deicing materials can effectively reduce snow accumulation on road surfaces in winter, lower the difficulty of ice-layer removal, and realize the sustainable utilization of SCGs. Full article

Magnesium phosphate cement (MPC) is a type of rapid-hardening inorganic cementitious material, which has important application value in rapid road repair, solidification of hazardous and radioactive waste, and other fields. However, it suffers from excessively fast setting and hardening and a short working time retention, which severely restrict its engineering application. Therefore, the development of high-efficiency set retarders is of great significance for optimizing MPC performance, enhancing its construction workability, and expanding its application scope. In this study, the effect of sodium polyacrylate (PAAS) on the setting and hardening of magnesium potassium phosphate cement (MKPC) was investigated by testing the setting time and fluidity at a low water-to-solid ratio (W/S = 0.18). Through pH and electrical conductivity measurements, combined with XRD, TG/DTG, and FTIR characterizations, we elucidated the retarding mechanism of PAAS on MKPC using a high water-to-solid ratio (W/S = 10). The results indicate that the setting time of MKPC is positively correlated with the PAAS dosage, whereas the fluidity and compressive strength exhibited a negative correlation with the PAAS dosage. Additionally, PAAS reduces the total heat release and the heat release rate of MKPC. The addition of PAAS increased the pH of the suspension, thereby reducing the solubility of MgO, but did not inhibit the dissolution of KH₂PO₄  The carboxylate groups in PAAS chemically reacted with Mg²⁺ on the surface of MgO to form magnesium carboxylate complexes (Mg-PAA), which remained as precipitates in the MKPC suspension system, thus reducing the amount of available Mg²⁺ participating in the hydration reaction. Furthermore, PAAS had no effect on the final precipitate composition at the end of hydration, which was composed of MgKPO₄·6H₂O  and Mg₃(PO₄)₂·22H₂O  in all cases. Full article

Activated sludge treatment is plagued by high secondary pollution risks, and ship antifouling paint particles (APPs) as hazardous heavy metal-rich solid wastes generated from hull derusting wastewater, pose severe environmental threats and intractable disposal dilemmas. This study developed a novel pilot-scale activated sludge reduction process coupling APPs-derived carbon-based catalysts with ultrasound-Fe²⁺/peroxydisulfate (PDS) advanced oxidation. Columnar catalysts were fabricated via direct carbonization-molding using waste APPs from an 82,000 deadweight bulk carrier were used as the sole raw material to prepare columnar catalysts via direct carbonization-molding; single-factor and orthogonal experiments optimized process parameters, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) characterized catalyst and sludge properties, free radical quenching experiments elucidated reaction mechanisms and a 90-day continuous pilot run assessed catalytic stability. The process achieved a 43.5% sludge removal rate under optimal conditions, accompanied by 100% toluene and 92.3% phenolic compound degradation, as well as efficient total phosphorus (TP) and total nitrogen (TN) removal. Mechanistic studies via characterization and quenching experiments confirmed the catalyst enhanced PDS activation through free/non-free radical synergy and accelerated Fe²⁺/Fe³⁺ redox cycling. A 90-day continuous pilot operation demonstrated excellent long-term catalytic stability, with sludge removal rate remaining above 38%. This “waste treating waste” technology realizes high-value APPs resource utilization, provides a low-carbon sludge disposal pathway, and offers a scalable solution for collaborative pollution control in the wastewater treatment and shipping industries. Full article

Four areas in the Kongo Central Province, western Democratic Republic of the Congo, with unexploited phosphate deposits were investigated to assess the composition of phosphatic materials and to evaluate pollution hazards, including radiological hazards arising from naturally occurring radionuclides. In those areas, phosphate rocks were sampled and analyzed for P₂O₅ content (by ED-XRF), and for the naturally occurring radionuclides ²³⁸U, ²²⁶Ra, ²³²Th, ⁴⁰K (by gamma-ray spectrometry). Phosphate rocks displayed P₂O₅ content ranging from 1.06 to 24.42% (dry weight) and exceptionally high ²³⁸U and ²²⁶Ra activity concentrations (up to 3069 and 2273 Bq kg⁻¹, respectively), significantly exceeding global averages in soils. Radiological hazard indices, including the radium equivalent (RaEq), annual effective dose and lifetime cancer risk, confirmed potential health risks associated with phosphate-rich rocks. With the upcoming development of phosphate deposits in DRC, such phosphate materials might become future sources of both geochemical contamination and radiological exposure, emphasizing the need for suitable radiation monitoring and waste management plans prior to and during mineral resource exploitation. Full article

The beneficial use of mining waste aligns with circular economy thinking: saving primary resources can extend their lifetime and maintain availability, reduce the volume of legacy mining waste and its environmental impacts, and develop a resource beneficiation industry that is less energy and water intensive; mining lower grades at larger scale inevitably requires more beneficial reuse. Existing classifications applicable to different types of mine waste were reviewed. These include factors such as the mode of origin during the mining operation, grain size, chemical composition and stability. The result shows that these factors also largely control their civil engineering applications, suitability for end use sectors and potential hazards. Long-term liabilities related to chemical stability were identified as the most difficult challenge. When developing a reuse project, either by the end users or by the mine operator, it is likely that resource screening covering a comprehensive range of factors will be required, as none of the existing schemes individually cover all of the aspects needed to fully assess suitability for beneficial use. In conclusion, there is a need for a systematic and structured approach to classification of mining waste to facilitate reuse as raw materials, such as that presented in our review. Full article

This study develops a unified multiscale–machine learning framework to interpret and predict thermo-mechanical wear regime transitions in MWCNT- and nanoclay-reinforced bio-based epoxy composites. A physics-informed master wear formulation integrating real contact mechanics, geometry-dependent shear transfer, interfacial adhesion energetics, and fracture-controlled matrix detachment was combined with interpretable machine learning analytics on a unified tribological dataset. In the CNT system, increasing loading from 0.1 to 0.4 wt.% enhanced interfacial adhesion energy density from 0.00813 to 0.01906 J/m², resulting in a monotonic reduction in the wear rate from 0.00918 to 0.00613 mm³/N·m (~33% reduction). In contrast, nanoclay exhibited an optimum behavior, with a minimum wear at 0.25 wt.% (0.000093 mm³/N·m; 7.9% reduction vs. neat clay baseline), followed by deterioration at a higher loading due to dispersion loss. The unified probabilistic regime classification of low-wear conditions (k < 0.007 mm³/N·m) achieved an ROC − AUC = 0.9256 and balanced accuracy = 94.3%, with thermo-mechanical severity identified as the dominant regime-switching driver. Reinforcement identity significantly modulated regime stability, confirming distinct shear transfer (Carbon Nano Tubes(CNT)) and confinement/tribofilm (clay) mechanisms within a common mathematical framework. By enabling the durability-oriented design of bio-based tribological systems and extending component service life through predictive stability mapping, this work contributes to resource-efficient materials engineering and reduced lifecycle waste, supporting Sustainable Development Goals SDG 9 (Industry, Innovation and Infrastructure), SDG 12 (Responsible Consumption and Production), and SDG 13 (Climate Action). Full article

Hazardous compounds from used batteries pose a great threat to the environment. To prevent pollution and to recover critical materials from battery waste, efficient recycling is required. Until now, battery recycling has focused on the recovery of valuable metals from cathode materials, while organic fractions have often been neglected due to their low material value. New approaches to battery recycling are therefore necessary, where recycling methods based on supercritical carbon dioxide (SC-CO₂) extraction show great potential. In this work, a SC-CO₂ method was implemented to extract electrolyte solvents for the purification and recovery of a separator waste material (SWM) sorted out from lithium-ion battery (LIB)-based black mass. In addition, two other separation routes (ultrasonic washing and thermal treatment) were used for comparison. Based on the results from the three routes, mass balances revealed the gravimetric composition of the SWM, which includes separator, electrolyte, and electrode powder. The composition of electrolyte solvents was determined via Gas Chromatography-Mass Spectroscopy analysis. Furthermore, the polymeric separator was analyzed using Fourier Transform Infrared Spectroscopy, Thermogravimetric Analysis, and Differential Scanning Calorimetry analysis to evaluate the effects of SC-CO₂ extraction on the physicochemical properties. The recovery of electrolyte by the SC-CO₂ route is more efficient than the others, with extraction yields of 162 mg of electrolyte per gram of SWM. Moreover, no changes are observed in the analyzed properties of the polymeric separator material due to the SC-CO₂ extraction. Thus, the SC-CO₂ process proves to be a promising method for an efficient and sustainable recycling of electrolyte solvent and purifying of separator material from LIB waste. Full article

Passive daytime radiative cooling (PDRC) is a promising thermal management technology, yet its widespread application is hindered by the high production costs and poor durability of traditional organic-based materials. Here, we presented a hierarchically porous, all-inorganic PDRC coating synthesized from industrial waste glass and alumina microparticles via low-temperature (600 °C) processing. Rather than serving merely as a cheap substitute, the alkali oxides inherent in waste glass act as natural fluxes, enabling partial melting. Concurrently, the steric hindrance of alumina restricts full densification, spontaneously constructing a highly scattering random photonic network. The optimized composite (50 wt.% waste glass/50 wt.% alumina) achieves 96% solar reflectance and 95% atmospheric window emittance. Field tests confirmed sub-ambient cooling of ~4.0 °C (day) and ~4.5 °C (night), yielding a peak net cooling power of 108.1 W/m². Accelerated weathering and thermal shock (1000 °C) tests demonstrated sustained optical stability under extreme environmental stress. Full article

This work investigates the physicochemical characteristics of waste tire pyrolysis char (WTP-char) produced at 500 °C in an industrial-scale auger reactor. The study uniquely combines material profiling with environmental safety assessment, specifically targeting organic contaminants and polymer stabilizers, evaluating WTP-char’s potential for circular economy applications. The samples underwent comprehensive analysis, including GC-MS, TGA, SEM-EDS, TXRF, and BET surface area measurements. The results revealed a high volatile matter content (13 wt.%), attributed to the thermal inertia typical of industrial-scale units. The organic fraction was dominated by n-alkanes (48.3%) and a significant concentration (6.97%) of the stabilizer Tris(2,4-di-tert-butylphenyl) phosphate (bDtBPP), posing potential environmental risks due to its cytotoxicity. Polycyclic aromatic hydrocarbon (PAH) analysis showed a prevalence of high-molecular-weight (HMW) compounds (79.7%), indicating high chemical stability. Although the specific surface area was low (28.9 m²/g), suggesting the need for activation, the material exhibits potential as a low-cost semi-reinforcing filler or solid fuel. By moving beyond laboratory-scale experiments to real industrial production, this study establishes a practical framework for evaluating both the performance and environmental safety of waste tire pyrolysis char. Full article

The research undertaken examines the impact of recycled tire steel fiber (RTSF) and waste aluminum (WAL) on the mechanical properties and freeze–thaw durability of sustainable fiber-reinforced concrete (FRC). RTSF (0.5%, 1.25%, and 2%) and WAL (10%) were added on their own and as hybrids. Findings revealed that 1.25% RTSF was the optimum content to use, as it enhanced compressive strength by 12.8% with high durability. Tensile and flexural strengths also increased for higher fiber contents with the help of good crack bridging and increased post-crack ductility; maximal gains of 52.6% and 11.8% were obtained at 2% RTSF. In contrast, the increase in porosity and the decrease in strength were demonstrated with WAL, whereas hybrid mixes delivered a balanced performance. Microstructural analysis ensured that there was an enhanced bonding between the fibers and the matrix, coupled with a refinement in the pore at the optimal fiber content. This study establishes the structural viability, durability improvement, and sustainability prospect of hybrid recycled material concrete as a construction material with eco-efficient and resilient applications. Full article

To enhance the early-age properties of steel slag cement mortar and promote the resource utilization of metallurgical solid waste, in this study, nano-SiO₂ (KH-NS) was modified using a KH550 silane coupling agent. The hydration kinetics and microstructure evolution were systematically analyzed by means of a macroscopic performance test (setting time and compressive strength) and multi-scale microscopic characterization (characterized by Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, X-ray Diffraction, Thermogravimetry-Differential Thermal Analysis, and isothermal calorimetry). The influence mechanism of its content on the early performance of the steel slag cement system was systematically studied. Research findings indicate that at a given dosage, increasing the proportion of KH-NS results in a shorter setting time for steel slag mortar. When the KH-NS dosage reaches 1.5%, the initial and final setting times of steel slag mortar decrease by 24.21% and 21.20%, respectively. The addition of KH-NS effectively enhances the compressive strength of mortar, with a particularly pronounced effect on early strength prior to 14 h of curing. At a KH-NS dosage of 1.5%, the onset of the accelerated phase of hydration heat release in steel slag cement mortar is advanced by 2.5 h. Mechanistic studies indicate that KH-NS accelerates cement hydration by promoting C₃S dissolution and C-S-H gel nucleation through interactions between surface silanol groups (Si-OH) and amino groups (-NH₂). Furthermore, KH-NS refines the pore structure via a micro-aggregate filling effect, reducing the number of harmful pores and improving the pore size distribution. KH-NS continuously consumes Ca(OH)₂ through pozzolanic reactions to generate C-S-H, with its reactivity increasing with higher dosage. Research confirms that KH-NS significantly enhances the early strength and density of steel slag mortar, providing both theoretical justification and technical support for developing low-carbon building materials based on solid waste with high dosage. Full article

Agricultural waste management is a strategic priority for reducing greenhouse gas emissions and transitioning to a circular bioeconomy. The thermochemical conversion of residual biomass into biochar offers a dual solution: waste recovery and the production of high-value functional materials. This narrative review summarizes the relationships among the composition of agricultural biomass, the conversion process parameters, and the structural properties of biochar, highlighting advanced modification strategies: controlled pyrolysis, physical and chemical activation, surface functionalization, and hybrid composite formation. Fundamental adsorption mechanisms, redox processes, and photocatalytic behavior are discussed, with a focus on applications in water treatment (heavy metals, dyes, emerging contaminants). The article proposes an integrative structure–property–performance framework and explores emerging concepts such as sequential use and post-use valorization of saturated biochar. Challenges related to reproducibility, industrial scaling, life cycle assessment, and carbon accounting are analyzed. Finally, a SWOT analysis is presented that highlights the potential of modified biochar as a strategic material in the circular economy. Full article

Thermally induced self-healing technology is regarded as an effective approach to mitigating the frequent occurrence of asphalt pavement distresses. Its efficiency, however, is highly dependent on the thermal conductivity of asphalt mixtures, which conventional aggregates can hardly satisfy. Meanwhile, high-titanium heavy slag (HTHS), an industrial solid waste rich in TiO₂, has been stockpiled in large quantities, and its large-scale resource utilization remains a critical challenge. Against this background, HTHS was employed in this study to replace limestone at equal mass ratios for the preparation of seven asphalt mastics (replacement rates of 0%, 20%, 40%, 60%, 80%, 100%, and neat asphalt) and four types of asphalt mixtures differentiated by coarse and fine aggregate compositions. The results indicate that with increasing HTHS content, the proportion of structural asphalt in the mastic increased markedly, leading to significant improvements in temperature susceptibility, high-temperature stability, and rutting resistance. Compared with the 100% limestone system, the penetration index (PI) of the 100% HTHS mastic increased by 8.4%, the softening point rose by 18.0%, and the rutting resistance factor at five temperatures from 46 °C to 70 °C increased by 21.8%, 56.8%, 79.2%, 171.7%, and 169.6%, respectively. Although low-temperature ductility decreased by 21.3% due to the reduction in free asphalt, it remained within acceptable limits. Regarding asphalt mixture performance, both high-temperature stability and low-temperature cracking resistance improved progressively with increasing HTHS replacement, showing increases of 75.56% and 11.75%, respectively, at full replacement. Water stability decreased by approximately 9% owing to the porous and water-absorptive nature of the slag, yet still satisfied specification requirements. In addition, the incorporation of HTHS significantly enhanced the thermal conductivity of the system, with increases of 0.125 W/(m·K) for asphalt mastics and 0.666 W/(m·K) for asphalt mixtures, corresponding to improvements of 33.7% and 32.2%, respectively. This study confirms that HTHS can serve as a viable asphalt pavement material capable of meeting the thermal conductivity requirements of thermally induced self-healing technology, while simultaneously providing a promising pathway for its large-scale resource utilization. Full article

Fibrous natural-origin materials are not only attractive as raw materials in various applications but are also often produced as waste products in some manufacturing processes. Despite their comprehensive implementation as thermal or noise isolation materials, their behavior under mechanical load is not yet fully understood, and there are no assignments of existing universal material models for the category of fibrous materials. The conducted experimental research provides a methodology with which to evaluate the structural behavior of fibrous materials under applied compression force and classify these materials according to their mechanical properties based on a certain material model. As a result of this research, we observed that the mechanical properties of the fibrous material during compression mode are determined by the fibrous structure, with insignificant influence from the physical nature of the material itself. This investigation provides an analysis of the application of a hyperelastic incompressible isotropic model to fibrous material of different origins. Hyperelastic material models of the Money–Rivlin, Ogden, Yeoh, and polynomial type were implemented. The fitting quality of the Yeoh third-order model obtained the best fitting results for animal wool and mineral wool. Cotton wool showed the best fitting results with the polynomial fifth-order model. The outcome of this research will help create finite element models for structural analysis, efficiently modelling structural responses to vibration or noise. For most animal and mineral wool samples, the best agreement with the experimental compression curves was obtained using the Yeoh third-order hyperelastic model, with coefficients of determination R² between 0.979 and 0.996, while fifth-order polynomial fits locally reached R² up to 0.9999 for aged cotton wool. Full article

Water-based drill cuttings generated during onshore natural gas development are complex solid wastes that may pose environmental risks if improperly managed. This study evaluates the feasibility of reutilizing water-based drill cuttings as pavement base materials after stabilization using a novel composite stabilizer composed of cement, stabilizer liquid agent, and water-reducing powder (CLP stabilizer). Mix proportion optimization was conducted through compaction and 7-day unconfined compressive strength tests, followed by evaluation of road performance, including strength, compressive rebound modulus, water stability, and temperature shrinkage, with stabilized powder stabilized soil as a control. Microstructural characteristics were analyzed using X-ray diffraction and scanning electron microscopy, and environmental safety was assessed through heavy metal leaching tests and background soil investigation. The results show that the optimal mixture ratio of curing agent (5% cement + 2% liquid stabilizer + 8% superplasticizer powder) satisfies the strength requirement for pre-drilling road bases, exhibiting superior performance compared to the control group. When the stabilizer dosage reaches 9%, the 7-day unconfined compressive strength achieves a maximum of 3.38 MPa, representing a 51% increase over the control group. At a stabilizer dosage of 12%, the splitting tensile strength reaches a peak value of 0.901 MPa, showing a 60.3% improvement. These results indicate enhanced deformation resistance, water stability, and reduced temperature shrinkage rates. Microstructural analysis indicates that the formation of calcium silicate hydrate (C-S-H) gel and ettringite (AFt phase) leads to a denser structure and enhanced durability. Heavy metal concentrations comply with relevant standards, demonstrating controllable environmental risks and supporting sustainable pavement base application. Full article