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Keywords = waste car tires

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21 pages, 3080 KiB  
Review
Use of Alternative Materials in Sustainable Geotechnics: State of World Knowledge and Some Examples from Poland
by Małgorzata Jastrzębska
Appl. Sci. 2025, 15(6), 3352; https://doi.org/10.3390/app15063352 - 19 Mar 2025
Cited by 2 | Viewed by 773
Abstract
Geotechnical engineering projects carried out within the framework of the low-emission economy and the circular economy are the subject of many publications. Some of these studies present the use of various waste materials, as soil additives, for improving geomechanical behavior/properties. Many of these [...] Read more.
Geotechnical engineering projects carried out within the framework of the low-emission economy and the circular economy are the subject of many publications. Some of these studies present the use of various waste materials, as soil additives, for improving geomechanical behavior/properties. Many of these materials are eagerly used in geoengineering applications, primarily to strengthen weak subsoil or as a base layer in road construction. Information on individual applications and types of these materials is scattered. For this reason, this article briefly discusses most of the major waste materials used for achieving weak-soil improvement in geoengineering applications, and highlights pertinent bibliographic sources where relevant details can be found. The presented list includes waste from mines, thermal processes, end-of-life car tires, chemical processes (artificial/synthetic fibers), and from construction, renovation and demolition works of existing buildings and road infrastructure. The presentation of various applications is supplemented with three dynamically developing innovative technologies based on nanomaterials, microorganisms (MICP, EICP) and lignosulfonate. In addition to the positive impact of using waste (or technologies) instead of natural and raw materials, the paper encourages the reader to ponder whether the waste used really meets the criteria for ecological solutions and what is the economic feasibility of the proposed implementations. Full article
(This article belongs to the Special Issue Natural and Artificial Fibers in Geoengineering Applications)
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26 pages, 10736 KiB  
Article
Experimental Evaluation of Under Slab Mats (USMs) Made from End-of-Life Tires for Ballastless Tram Track Applications
by Cezary Kraśkiewicz, Piotr Majnert, Anna Al Sabouni-Zawadzka, Przemysław Mossakowski and Marcin Zarzycki
Materials 2024, 17(21), 5388; https://doi.org/10.3390/ma17215388 - 4 Nov 2024
Viewed by 940
Abstract
The growing population of urban areas results in the need to deal with the noise pollution from the transportation system. This study presents experimental test results of static and dynamic elastic characteristics of under slab mats (USMs) according to the procedure of DIN [...] Read more.
The growing population of urban areas results in the need to deal with the noise pollution from the transportation system. This study presents experimental test results of static and dynamic elastic characteristics of under slab mats (USMs) according to the procedure of DIN 45673-7. Prototype USMs based on recycled elastomeric materials, i.e., SBR granules and fibres produced from waste car tires, are analysed. Vibration isolation mats with different thicknesses (10, 15, 20, 25, 30, and 40 mm), densities (500 and 600 kg/m3), and different degrees of space filling (no holes, medium holes, large holes) are considered. Moreover, a practical application of the laboratory test results of USMs in the design of ballastless track structures of two different types (with a concrete slab and longitudinal beams) is presented. Deflections of the rail and the floating slab system, as well as stresses acting on the mat, are determined according to EN 16432-2. The use of shredded rubber from recycled car tires as a material component of sustainable and environmentally friendly tram track structures may be one of the most effective ways to manage rubber waste within the current trend toward a circular economy, and this study intends to introduce methods for experimental identification and analytical selection of basic static and dynamic parameters of prototype USMs. Full article
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12 pages, 5284 KiB  
Article
The Input of Nanoclays to the Synergistic Flammability Reduction in Flexible Foamed Polyurethane/Ground Tire Rubber Composites
by Aleksander Hejna, Paulina Kosmela, Adam Olszewski and Wiktoria Żukowska
Materials 2024, 17(21), 5344; https://doi.org/10.3390/ma17215344 - 31 Oct 2024
Viewed by 1308
Abstract
Currently, postulated trends and law regulations tend to direct polymer technology toward sustainability and environmentally friendly solutions. These approaches are expressed by keeping materials in a loop aimed at the circular economy and by reducing the environmental burdens related to the production and [...] Read more.
Currently, postulated trends and law regulations tend to direct polymer technology toward sustainability and environmentally friendly solutions. These approaches are expressed by keeping materials in a loop aimed at the circular economy and by reducing the environmental burdens related to the production and use of polymers and polymer-based materials. The application of recycled or waste-based materials often deals efficiently with the first issue but at the expense of the final products’ performance, which requires various additives, often synthetic and petroleum-based, with limited sustainability. Therefore, a significant portion of research is often required to address the drawbacks induced by the application of secondary raw materials. Herein, the presented study aimed to investigate the fire performance of polymer composites containing highly flammable matrix polyurethane (PU) foam and filler ground tire rubber (GTR) originating from car tire recycling. Due to the nature of both phases and potential applications in the construction and building or automotive sectors, the flammability of these composites should be reduced. Nevertheless, this issue has hardly been analyzed in literature and dominantly in our previous works. Herein, the presented work provided the next step and investigated the input of nanoclays to the synergistic flammability reduction in flexible, foamed PU/GTR composites. Hybrid compositions of organophosphorus FRs with expandable graphite (EG) in varying proportions and with the addition of surface-modified nanoclays were examined. Changes in the parameters obtained during cone calorimeter tests were determined, discussed, and evaluated with the fire performance index and flame retardancy index, two parameters whose goal is to quantify the overall fire performance of polymer-based materials. Full article
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20 pages, 71851 KiB  
Article
Thinking Green on 3D Printing: Sustainable Polymer Compositions of Post-Consumer Polypropylene and Tire Rubber Crumbs Intended for Industrial Applications
by Sandra Paszkiewicz, Jacek Andrzejewski, Daniel Grochała, Kamil Adamczyk, Paweł Figiel, Elżbieta Piesowicz and Katarzyna Pokwicka-Croucher
Materials 2024, 17(21), 5209; https://doi.org/10.3390/ma17215209 - 25 Oct 2024
Cited by 2 | Viewed by 1643
Abstract
Year by year, more and more plastic is used worldwide. A large part of post-consumer waste is still stored in landfills instead of being reused. The solution to this problem may be recycled materials (recyclates) or biodegradable materials. The method of 3D printing, [...] Read more.
Year by year, more and more plastic is used worldwide. A large part of post-consumer waste is still stored in landfills instead of being reused. The solution to this problem may be recycled materials (recyclates) or biodegradable materials. The method of 3D printing, regarded as a clean processing technology, can significantly contribute to addressing global plastic pollution by utilizing post-consumer recycled polymers to create new components and parts. Therefore, this study focuses on the assessment of various properties and characteristics of 3D-printed compositions based on post-consumer polypropylene (PP) and rubber crumbs, recycled from packages foils and car tires, respectively. Moreover, within this study, we compared the mechanical performance of the injection molding material with the one obtained from 3D printing. A characterization was made considering the thermal and mechanical properties as well as the “print quality” through the microscopic and tomographic analysis of subsequent print passes, the number of free spaces, and imperfections in the polymer melt. Samples obtained using the FDM and injection methods exhibited comparable melting temperatures, while the samples obtained by injection molding exhibited slightly better mechanical performance, higher hardness, and impact strength. Full article
(This article belongs to the Special Issue Advances in Bio-Polymer and Polymer Composites)
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16 pages, 8867 KiB  
Article
Structural, Thermal and Mechanical Assessment of Green Compounds with Natural Rubber
by Xavier Colom, Jordi Sans, Frederic de Bruijn, Fernando Carrillo and Javier Cañavate
Macromol 2024, 4(3), 566-581; https://doi.org/10.3390/macromol4030034 - 7 Aug 2024
Cited by 2 | Viewed by 1276
Abstract
The inadequate disposal of tires poses a significant threat to human health and requires effective recycling solutions. The crosslinked structure of rubber, formed through sulfur bridges during vulcanization, presents a major challenge for recycling because it prevents the rubber scraps from being reshaped [...] Read more.
The inadequate disposal of tires poses a significant threat to human health and requires effective recycling solutions. The crosslinked structure of rubber, formed through sulfur bridges during vulcanization, presents a major challenge for recycling because it prevents the rubber scraps from being reshaped thermoplastically. Reclaiming or devulcanization aims to reverse this crosslinking, allowing waste rubber to be transformed into products that can be reprocessed and revulcanized, thereby saving costs and preserving resources. Microwave technology shows promise for devulcanization due to its ability to break sulfur crosslinks. In this study, we investigate the devulcanization of ground tire rubber (GTR) through a combined process applied to samples from both car and truck tires subjected to varying periods of microwave irradiation (0, 3, 5 and 10 min). The devulcanized GTR was then blended with natural rubber (NR) and underwent a new vulcanization process, simulating recycling for novel applications. The GTR was mixed with NR in proportions of 0, 10, 30 and 50 parts per hundred rubber (phr). This study also examines the differences between the GTR from car tires and GTR from truck tires. The results showed that the treatment effectively breaks the crosslinks in the GTR, creating double bonds (C=C) and improving the mechanical properties of the revulcanized samples. The crosslinking density and related properties of the samples increased with treatment time, reaching a maximum at 5 min of microwave treatment, followed by a decrease at 10 min. Additionally, the incorporation of GTR enhanced the thermal stability of the resulting materials. Full article
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17 pages, 6413 KiB  
Article
Performance of a Diesel Engine Fueled by Blends of Diesel Fuel and Synthetic Fuel Derived from Waste Car Tires
by Mirosław Jakubowski, Artur Jaworski, Hubert Kuszewski and Krzysztof Balawender
Sustainability 2024, 16(15), 6404; https://doi.org/10.3390/su16156404 - 26 Jul 2024
Cited by 3 | Viewed by 1695
Abstract
Waste car tires are a significant burden on the environment. One way to manage them is through energy recovery by burning them in the furnaces of combined heat and power plants or cement plants, which from an environmental point of view is not [...] Read more.
Waste car tires are a significant burden on the environment. One way to manage them is through energy recovery by burning them in the furnaces of combined heat and power plants or cement plants, which from an environmental point of view is not a favorable solution. Another way to use waste tires is to produce liquid fuels, which can be used as pure fuels or components added to conventional fuels. Therefore, it is necessary to conduct research aimed at evaluating the physical and chemical properties of tire-derived fuels relative to conventional fuels. It is also important to determine the impact of feeding engines with synthetic fuels, regarding their operational and environmental performance. In this article, the physicochemical properties of typical diesel fuel, synthetic fuel derived from waste tires (WT) and its blends with diesel fuel (DF) in shares of 5, 10, 15, 20 and 25% v/v were studied. Tests were also conducted on an internal combustion engine with a common rail injection system (CR IC) engine to determine operational and emission parameters. The results showed, among other things, a deterioration relative to diesel fuel of such parameters as cold filter plugin point (CFPP) and flash point (FP). At the same time, a favorable effect of synthetic fuel addition was noted on hydrocarbon (HC) and nitrogen oxide (NOx) emissions. Full article
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14 pages, 9347 KiB  
Article
Torsional Behavior of Waste Fiber-Reinforced Concrete
by Artur Sanok, Jacek Domski, Janusz Kobaka and Dominik Logoń
Materials 2024, 17(13), 3269; https://doi.org/10.3390/ma17133269 - 2 Jul 2024
Viewed by 907
Abstract
Factory made steel fiber and steel fiber derived from worn tires was used to develop cement concrete, which was subjected to torsional forces. A dedicated stand for torsion tests, allowing for the measurement of force, deflection, and torsion angle, was used. The test [...] Read more.
Factory made steel fiber and steel fiber derived from worn tires was used to develop cement concrete, which was subjected to torsional forces. A dedicated stand for torsion tests, allowing for the measurement of force, deflection, and torsion angle, was used. The test results showed that both the factory-made fiber and the waste steel fiber significantly improved torsional properties of the concrete matrix. The test results of specimens made with waste fiber were characterized by slightly worse results compared to factory-made fibers, but there was a significant improvement in torsional properties compared to samples without fibers. Taking into account the financial and environmental benefits, the application of waste steel fiber recovered from car tires could be an interesting alternative to using commercially sold steel fiber applied for the production of construction elements subjected to torsional forces. Full article
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22 pages, 5171 KiB  
Article
Flash Pyrolysis of Waste Tires in an Entrained Flow Reactor—An Experimental Study
by Balan Ramani, Arqam Anjum, Eddy Bramer, Wilma Dierkes, Anke Blume and Gerrit Brem
Polymers 2024, 16(12), 1746; https://doi.org/10.3390/polym16121746 - 20 Jun 2024
Cited by 2 | Viewed by 2733
Abstract
In this study, a flash pyrolysis process is developed using an entrained flow reactor for recycling of waste tires. The flash pyrolysis system is tested for process stability and reproducibility of the products under similar operating conditions when operated continuously. The study is [...] Read more.
In this study, a flash pyrolysis process is developed using an entrained flow reactor for recycling of waste tires. The flash pyrolysis system is tested for process stability and reproducibility of the products under similar operating conditions when operated continuously. The study is performed with two different feedstock materials, i.e., passenger car (PCT) and truck tire (TT) granulates, to understand the influence of feedstock on the yield and properties of the pyrolysis products. The different pyrolytic products i.e., pyrolytic carbon black (pCB), oil, and pyro-gas, are analyzed, and their key properties are discussed. The potential applications for the obtained pyrolytic products are discussed. Finally, a mass and energy balance analysis has been performed for the developed pyrolysis process. The study provides insight into the governing mechanisms of the flash pyrolysis process for waste tires, which is useful to optimize the process depending on the desired applications for the pyrolysis products, and also to scale up the pyrolysis process. Full article
(This article belongs to the Special Issue Recycling of Plastic and Rubber Wastes)
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20 pages, 9474 KiB  
Article
Analysis of the Impact of Rubber Recyclate Addition to the Matrix on the Strength Properties of Epoxy–Glass Composites
by Daria Żuk, Norbert Abramczyk and Adam Charchalis
Polymers 2023, 15(16), 3374; https://doi.org/10.3390/polym15163374 - 11 Aug 2023
Cited by 1 | Viewed by 1237
Abstract
Currently, there is a noticeable trend of modifying new materials by using additives from the recycling of harmful waste. This is to protect the environment by using waste to produce composites and at the same time to reduce the cost of their production. [...] Read more.
Currently, there is a noticeable trend of modifying new materials by using additives from the recycling of harmful waste. This is to protect the environment by using waste to produce composites and at the same time to reduce the cost of their production. The article presents an analysis of the impact of the use of rubber recyclate obtained from the utilization of car tires as a sandwich layer of epoxy–glass composites and its impact on the strength parameters of the composite. The presented research is an extension of the previously conducted analyses on composite materials modified with the addition of rubber recyclate. The four variants of the materials produced contained the same percentage amount of rubber recyclate, but differed in the way it was distributed and the number of layers. Static tensile tests as well as impact strength and kinetics of damage to samples made with and without the addition of recyclate were carried out. Observation of the structures of the materials with the use of SEM was also performed. A significant influence of the method of distributing the recyclate in layers on the strength parameters of the materials was found. In the case of composites with three and two sandwich layers of recyclate, more favorable results were obtained compared to the blank sample. In addition, the values of the impact strength measurements were subjected to statistical analysis at the significance level of α = 95%. The distributions were tested for normality with the Shapiro–Wilk test, differences between pairs were tested with the Student’s t-test for dependent groups, and ANOVA differences were tested for independent groups. Using the Student’s t-test, it was confirmed that between the pairs of variables in the configurations reference sample and modified sample, there were significant statistical differences in the distribution of impact strength measurement results for all the analyzed materials. Statistical analysis showed a significant usefulness in the selection of the material with the best strength parameters and a significant role of statistical methods in the study of anisotropic materials. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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14 pages, 4390 KiB  
Article
Influence of the Addition of Recycled Aggregates and Polymer Fibers on the Properties of Pervious Concrete
by Oskar Mitrosz, Marzena Kurpińska, Mikołaj Miśkiewicz, Tadeusz Brzozowski and Hakim Salem Abdelgader
Materials 2023, 16(15), 5222; https://doi.org/10.3390/ma16155222 - 25 Jul 2023
Cited by 8 | Viewed by 2154
Abstract
The aim of the study was to check the possibility of reusing aggregate from recycled concrete waste and rubber granules from car tires as partial substitution of natural aggregate. The main objective was to investigate the effects of recycled waste aggregate modified with [...] Read more.
The aim of the study was to check the possibility of reusing aggregate from recycled concrete waste and rubber granules from car tires as partial substitution of natural aggregate. The main objective was to investigate the effects of recycled waste aggregate modified with polymer fibers on the compressive and flexural strength, modulus of elasticity and permeability of pervious concrete. Fibers with a multifilament structure and length of 54 mm were deliberately used to strengthen the joints among grains (max size 31.5 mm). Eight batches of designed mixes were used in the production of pervious concrete at fixed water/binder ratio of 0.34 with cement content of 350 kg/m3. Results showed that the use of recycled concrete aggregate (8/31.5 mm) with replacement ratio of 50% (by weight of aggregate) improved the mechanical properties of pervious concrete in all analyzed cases. Whereas the replacement of 10% rubber waste aggregate (2/5 mm) by volume of aggregate reduced the compressive strength by a maximum of 11.4%. Addition of 2 kg/m3 of polymer fibers proved the strengthening effect of concrete structure, enhancing the compressive and tensile strengths by a maximum of 23.4% and 25.0%, respectively. The obtained test results demonstrate the possibility of using the recycled waste aggregates in decarbonization process of pervious concrete production, but further laboratory and field performance tests are needed. Full article
(This article belongs to the Section Construction and Building Materials)
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19 pages, 4967 KiB  
Article
Durability of Polymer-Modified Asphalt Mixture with Wasted Tire Powder and Epoxy Resin under Tropical Climate Curing Conditions
by Kyung-Nam Kim and Tri Ho Minh Le
Polymers 2023, 15(11), 2504; https://doi.org/10.3390/polym15112504 - 29 May 2023
Cited by 16 | Viewed by 3131
Abstract
The quality of pavements in tropical climates is negatively affected by the frequent wet and dry cycles during the rainy season, as well as by issues related to overloading from heavy trucks and traffic congestion. Contributing to this deterioration are factors such as [...] Read more.
The quality of pavements in tropical climates is negatively affected by the frequent wet and dry cycles during the rainy season, as well as by issues related to overloading from heavy trucks and traffic congestion. Contributing to this deterioration are factors such as acid rainwater, heavy traffic oils, and municipal debris. In light of these challenges, this study aims to assess the viability of a polymer-modified asphalt concrete mixture. This study investigates the feasibility of a polymer-modified asphalt concrete mixture with the addition of 6% crumb rubber powder from waste car tires and 3% epoxy resin to counter the harsh conditions of tropical climate weather. The study involved subjecting test specimens to five to 10 cycles of contaminated water (100% rainwater + 10% used oil from trucks), curing for 12 h, and air drying in a chamber of 50 °C for 12 h to simulate critical curing conditions. The specimens underwent fundamental laboratory performance tests such as the indirect tensile strength test, dynamic modulus test, four points bending test, and Cantabro test, as well as the double load condition in the Hamburg wheel tracking test to determine the effectiveness of the proposed polymer-modified material in actual conditions. The test results confirmed that the simulated curing cycles had a critical impact on the durability of the specimens, with the greater curing cycles leading to a significant drop in the strength of the material. For example, the TSR ratio of the control mixture dropped from 90% to 83% and 76% after five and 10 curing cycles, respectively. Meanwhile, the modified mixture showed a decrease from 93% to 88% and 85% under the same conditions. The test results revealed that the effectiveness of the modified mixture outperformed the conventional condition in all tests, with a more prominent impact observed under overload conditions. Under double conditions in the Hamburg wheel tracking test and a curing condition of 10 cycles, the maximum deformation of the control mixture sharply increased from 6.91 to 22.7 mm, whereas the modified mixture increased from 5.21 to 12.4 mm. Overall, the test results confirm the durability of the polymer-modified asphalt concrete mixture under harsh tropical climate conditions, promoting its application for sustainable pavements, especially in Southeast Asian countries. Full article
(This article belongs to the Special Issue Application of Polymeric Materials in the Building Industry II)
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15 pages, 4780 KiB  
Article
Comparative Analysis of Waste, Steel, and Polypropylene Microfibers as an Additive for Cement Mortar
by Mateusz Zakrzewski, Mateusz Gancarz, Katarína Tvrdá, Joanna Laskowska-Bury and Jacek Domski
Materials 2023, 16(4), 1625; https://doi.org/10.3390/ma16041625 - 15 Feb 2023
Cited by 6 | Viewed by 1991
Abstract
This study presents the results of laboratory experiments conducted to determine the mechanical parameters for cement mortar with various quantities of waste fibers, polypropylene microfibers, and steel microfibers. Waste fibers were used as samples and obtained using an end-of-life car tire recycling process. [...] Read more.
This study presents the results of laboratory experiments conducted to determine the mechanical parameters for cement mortar with various quantities of waste fibers, polypropylene microfibers, and steel microfibers. Waste fibers were used as samples and obtained using an end-of-life car tire recycling process. For comparison, samples with the addition of steel and polypropylene microfibers were tested. The same degrees of fiber reinforcement were used for all types of fibers. Ultimately, 22 mixtures of cement mortar were prepared. The aim of this study is therefore to present and compare basic mechanical parameter values. Compressive strength, flexural strength, fracture toughness, and flexural toughness were of particular interest. A three-point bending test was performed on three types of samples, without a notch and with a notch of 4 and 8 mm. The results show that the use of steel microfibers in the cement mortar produces a product with better properties compared to a mixture with steel cord or polypropylene fibers. However, the cement mortar with the steel cord provides better flexural strength and greater flexural toughness factors compared to the cement mortar with polypropylene fibers. This means that the steel cord is a full-value ecological replacement for different fibers. Full article
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14 pages, 1227 KiB  
Article
Experimental Production of Iron-Bearing Sinters Using Chars from Waste Car Tires
by Marian Niesler, Janusz Stecko, Damian Gierad, Martyna Nowak and Sławomir Stelmach
Processes 2023, 11(1), 231; https://doi.org/10.3390/pr11010231 - 10 Jan 2023
Cited by 3 | Viewed by 2047
Abstract
The metallurgical industry is seeking raw material substitutes more and more intensively in order to replace materials traditionally used in pig iron production. Research has been conducted on the use of char obtained from waste car tires via a pyrolysis process in an [...] Read more.
The metallurgical industry is seeking raw material substitutes more and more intensively in order to replace materials traditionally used in pig iron production. Research has been conducted on the use of char obtained from waste car tires via a pyrolysis process in an iron ore sintering process. The char obtained from car tires could be a potential substitute for some of the coke breeze used in the iron ore sintering process. However, the Zn and S content of the char is a major technological issue. This paper presents the results of research conducted to assess the possibility of substituting coke breeze with a commercial char from waste tires. The experiments were carried out in a laboratory stand capable of sintering 200 kg of sintering blend. The results obtained show that it is possible to replace 10 %m/m of coke breeze with waste tire char without any technological danger for sintering lines. The application of waste tire char in metallurgical processes is an example of actions that form part of the circular economy and also of the appropriate use of anthropogenic resources that are technologically available. Full article
(This article belongs to the Special Issue Solid Waste and Resource Recycling)
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20 pages, 9434 KiB  
Article
Impact of Shredded Rubber Waste (SRW) on the Range of Elastic Work of Road Construction Mixtures Containing Industrial Waste Bound with a Binder
by Konrad Walotek, Joanna Bzówka and Adrian Ciołczyk
Materials 2022, 15(23), 8503; https://doi.org/10.3390/ma15238503 - 29 Nov 2022
Cited by 2 | Viewed by 1538
Abstract
The paper presents the results of research on a composite mixture intended for use in road construction. The purpose of developing the mixture is to be able to use large amounts of industrial waste to produce building material. The waste used are coal [...] Read more.
The paper presents the results of research on a composite mixture intended for use in road construction. The purpose of developing the mixture is to be able to use large amounts of industrial waste to produce building material. The waste used are coal slate from the mining industry, shredded rubber waste from used passenger car tires and fly ash from power plants. The mixture (SRFC) consists of unburnt coal-mining slate (S), shredded rubber waste (R), fly ash (F) and cement(C). A test under cyclic loading conditions was carried out on samples prepared from the SRFC mixture, in which the global deformations and local strains caused on the samples were measured. A measurement system using digital image correlation was used for the research. On the basis of the conducted research, it was found that the content of shredded rubber waste significantly influences the deformability of the tested mixtures and allows for the extension of the scope of elastic deformation in which the tested samples work. Full article
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20 pages, 5725 KiB  
Article
Comprehensive Enhancement of Prepolymer-Based Flexible Polyurethane Foams’ Performance by Introduction of Cost-Effective Waste-Based Ground Tire Rubber Particles
by Wiktoria Żukowska, Paulina Kosmela, Paweł Wojtasz, Mariusz Szczepański, Adam Piasecki, Roman Barczewski, Mateusz Barczewski and Aleksander Hejna
Materials 2022, 15(16), 5728; https://doi.org/10.3390/ma15165728 - 19 Aug 2022
Cited by 13 | Viewed by 3662
Abstract
Material innovations in polyurethane (PU) foams should ideally combine performance enhancement, environmental impact limitation, and cost reduction. These goals can be achieved by applying recycled or waste-based materials without broader industrial applications, implicating their low price. Herein, from 5 to 20 parts by [...] Read more.
Material innovations in polyurethane (PU) foams should ideally combine performance enhancement, environmental impact limitation, and cost reduction. These goals can be achieved by applying recycled or waste-based materials without broader industrial applications, implicating their low price. Herein, from 5 to 20 parts by weight of ground tire rubber (GTR) particles originated from the recycling of postconsumer car tires were incorporated into a flexible foamed PU matrix as a cost-effective waste-based filler. A two-step prepolymer method of foams manufacturing was applied to maximize the potential of applied formulation changes. The impact of the GTR content on the foams’ processing, chemical, and cellular structure, as well as static and dynamic mechanical properties, thermal stability, sound suppression ability, and thermal insulation performance, was investigated. The introduction of GTR caused a beneficial reduction in the average cell diameter, from 263.1 µm to 144.8–188.5 µm, implicating a 1.0–4.3% decrease in the thermal conductivity coefficient. Moreover, due to the excellent mechanical performance of the car tires—the primary application of GTR—the tensile performance of the foams was enhanced despite the disruption of the cellular structure resulting from the competitiveness between the hydroxyl groups of the applied polyols and on the surface of the GTR particles. The tensile strength and elongation at break were increased by 10 and 8% for 20 parts by weight GTR addition. Generally, the presented work indicates that GTR can be efficiently applied as a filler for flexible PU foams, which could simultaneously enhance their performance, reduce costs, and limit environmental impacts due to the application of waste-based material. Full article
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