Search Results (22)

The current work determines the physical properties of Cs₂HfCl₆ photovoltaic compounds including their structural, electronic, and optical behavior, utilizing the DFT approach. The simulated Cs₂HfCl₆ lattice constants, cell volumes, and bond lengths decrease as the pressure increases from 0 to 20 GPa. The band structure analysis reveals that the calculated under-pressure (0–20 GPa) of Cs₂HfCl₆ is semiconducting with a flexible indirect bandgap (5.44, 2.76, 2.02, 1.45, and 0.99) eV. The electronic bandgap diminishes (0–20 GPa), transitioning the compound from the UV to the visible spectra. This alteration improves the transition from the VBM to the CBM, hence augmenting the optical effectiveness. Concurrently, the dielectric function escalates, enhancing the absorption and conductivity, and causing a red shift in the optical spectra, while diminishing the reflection in the visible spectra. Our findings on the hydraulic pressure (0–20 GPa) and the electrical and optical properties indicate that Cs₂HfCl₆ may be utilized in the development of next-generation solar cells, LEDs, UV sensors, and high-pressure optical instruments. Full article

According to “The World Health Organization”, obesity during childhood is directly associated with multiple complications and with an increased risk of the installation of various pathologies. Considering the increase in this pathology among children and teenagers, new instruments of prevention are needed. Virtual reality is an innovative tool that offers several advantages over classical therapies, becoming important in various medical fields, starting from phobia treatment, pain relief, and body image perception to education. This technology has been successfully used to study the influence of virtual cues on behavioral responses and can be useful in nutritional education as well as understanding eating behavior. The objective of this scoping review study is to understand the impact of virtual supermarket exposure on individuals’ food choices and to explore the potential of technology on nutrition education in the general population. It seeks to explore purchasing based on product appearance and placement, food prices, nudging conditions and under-pressure decision making. A manual literature search was conducted using the databases Web of Science, SCOPUS and Google Scholar. Included articles were published between 2012 and 2024 using immersive virtual and augmented supermarket environments as a tool to understand food choices and education. The results showed that using higher immersion can be efficient in understanding food choices, rather than a lower immersive tool. The advantage of immersive virtual reality is highlighted by the sense of presence it offers, compared to other devices, providing a safe, controlled environment for users. Full article

This research aims to provide guidelines using probabilistic methods to understand better the dominant characteristics of the 824 under-pressure wetlands on 75 islands within Greece and to inform future conservation efforts. Identifying the characteristics and types of anthropogenic pressures is crucial for developing effective conservation strategies. The study employs power-law modeling to validate the natural size distribution of wetlands, naïve Bayesian inference to model human impacts, and the epsilon statistic to assess wetland sensitivity to specific pressures, addressing potential sampling biases. Power-law modeling reveals a natural heavy-tailed distribution of wetland sizes, highlighting the ecological significance of larger, rarer systems. Naïve Bayesian inference indicates that agriculture and transportation are the predominant pressures affecting natural coastal wetlands. The epsilon statistic further differentiates wetland sensitivity, identifying estuaries, lagoons, and marshes as particularly vulnerable. By profiling the most vulnerable wetlands using these methods, the research provides a framework for assessing anthropogenic impacts and informing targeted conservation and management strategies to protect these vital ecosystems. Full article

This study proposed a new method for homogenizing continuous casting blooms based on solidification simulation calculations and industrial tests. The text describes a theoretical analysis of the solidification route of a cast billet of high-carbon alloy steel (B300A) under different process conditions. It summarizes the changing law of different under-pressure process parameters and under-pressure efficiency. The text also presents a solution to the seriousness of center shrinkage defects in the continuous casting of a large square billet of high-carbon alloy steel with the synergistic control technology of mixed light and heavy mixing under pressure. The study indicates that the center carbon segregation index of a high carbon steel continuous casting billet is 1.05, with a carbon extreme difference of not more than 0.08% and a proportion of 98.4%. Additionally, the center shrinkage is not more than a 0.5 level with a proportion of 99.5%. Meanwhile, the internal quality of cast billets has been improved, allowing for the rolling of large-size bars with a low consolidation ratio. The pass rate for internal ultrasonic flaw detection using the GB/T4162A grade is now higher than 99.95%, significantly reducing process costs and improving production efficiency for continuous casting and rolling. Full article

The present report describes exposure to respirable silica and dust in the construction industry, as well as means to manage them. The average exposure in studied work tasks (n = 148) amounted to 64% of the Finnish OEL value of 0.05 mg/m³. While 10% of exposure estimates exceeded the OEL, the 60% percentile was well below 10% of the OEL, as was the median exposure. In other words, exposure was low in more than half of the tasks. Work tasks where exposure was low included construction cleaning, work management, installation of concrete elements, rebar laying, driving work machines equipped with cabin air intake filtration, and landscaping, in addition to some road construction tasks. Excessive exposure (>OEL) was related to not using respiratory protection at all or not using it for long enough after the dusty activity ceased. Excessive exposures were found in sandblasting, dismantling facade elements, diamond drilling, drilling hollow-core slabs, drilling with a drilling rig, priming of explosives, tiling, use of cabinless earthmoving machines, and jackhammering, regardless of whether the hammering took place in an underpressurized compartment or not. Even in these tasks, it was possible to perform the work safely, following good dust prevention measures and, when necessary, using respiratory protection suitable for the job. Furthermore, in all tasks with generally low exposure, one could be significantly exposed through the general air or by making poor choices in terms of dust control. Full article

Batch pressure-retarded osmosis (PRO) with varied-pressure and multiple-cycle operation using a pressurized variable-volume tank has been proposed as a high-efficiency osmotic energy harvesting technology, but it suffers scalability constraints. In this study, a more scalable batch PRO, namely, atmospheric batch PRO (AB-PRO), was proposed, utilizing an atmospheric tank to receive and store the intermediate diluted draw solution (DS) and a pressure exchanger to recover the pressure energy from the diluted DS before being recycled into the tank. Its performance was further compared with single-stage PRO (SS-PRO) at different flow schemes via analytic models. The results show that the AB-PRO with an infinitesimal per-cycle water recovery (r) approaches the thermodynamic maximum energy production under ideal conditions, outperforming the SS-PRO with lower efficiencies caused by under-pressurization (UP). However, when considering inefficiencies, a ~40% efficiency reduction was observed in AB-PRO owing to UP and entropy generation as the optimal r is no-longer infinitesimal. Nonetheless, AB-PRO is still significantly superior to SS-PRO at low water recoveries (R) and maintains a stable energy efficiency at various R, which is conducive to meeting the fluctuating demand in practice by flexibly adjusting R. Further mitigating pressure losses and deficiencies of energy recovery devices can significantly improve AB-PRO performance. Full article

The challenges posed by elevated rock hardness, deficient drillability, excessive friction torque, and significant underpressure in extended−reach horizontal wells are the primary factors that contribute to low ROP (Rate of Penetration) and limited horizontal reach during the drilling operation. Reducing drag and friction is one of the primary methods of addressing the aforementioned challenges. To augment the pulse output characteristics of the oscillating jet and bolster the energy of the hydrodynamic impact load, we developed and designed a multi−source impact oscillation speed−increasing tool coupled with blade rotation disturbance and multi−order oscillation cavity self−excitation. We utilized fluid dynamics software to model and conduct numerical analysis on the multi−source pulsed jet generator. Furthermore, we constructed a prototype and subjected it to testing. This paper examines the impact of dimensionless structural parameters on the pressure output characteristics of the multi−source pulse−jet generator. Specifically, we used three dimensionless quantities (cavity length ratios, cavity diameter ratios, and inner wall collision angle ratios) to study this effect. The findings indicate that the multi−source impact oscillation speed−increasing tool is capable of augmenting the pulse oscillation amplitude, and the frequency of pulse oscillation can be adjusted within the range of 5 Hz to 15 Hz. During the study, we determined that the optimal oscillation output characteristics can be achieved when the cavity diameter ratio is 0.8, the cavity length ratio is 1.0, and the inner wall collision angle ratio is 1.5. These findings present a novel approach for the development of downhole hydraulic impact oscillation speed−increasing tools. Full article

Insulating glass units (IGUs) are building components that show a particular structural behavior. Although such structures have many advantages from the point of view of thermal protection of buildings, they show particular structural behavior under climatic loads. The inability to equalize the pressure with the surrounding atmospheric air causes over- or under-pressure inside the gap. The phenomenon may result in the deformation of the panes under the influence of temporary or cyclical changes in weather conditions. This article presents the results of an experimental campaign with a representative IGU sample. The sample had dimensions of 500 mm × 500 mm and was composed of two 6 mm glass panes and a 16 mm wide spacer. The experiments were carried out using a rarely used methodology by inducing a controlled pressure change in the gap. Subsequently, analytical and numerical models were developed, and the results were compared with the experimental findings. The study found that the rapid injection/withdrawal of gas into/from the gap causes a sudden change in the pressure inside the gap, which decreases in absolute value and stabilizes after a few seconds. The decrease, on average, of 7% is due to adiabatic effects resulting from the high rate of gas exchange. The results from the numerical and analytical studies underestimate the pressure difference values obtained in the tests by an average of 8%. In terms of deflections and stresses, the results overestimate the experiments by 16% and 32%, respectively. This finding indicates the presence of a partial rotational restrain of the panes’ edges, which some researchers have also reported. This effect is usually ignored in engineering practice. Full article

Air pressure differences are a key factor in the behavior of building ventilation and air leakages through the building envelope. Field measurements of the air pressure differences over the building envelope were conducted in 24 Finnish municipal service buildings. The measured buildings were mainly schools and daycare centers, of which half were new buildings and half recently retrofitted. All buildings had mechanical ventilation. The measurements were conducted during 2016–2018. The total number of measurement points was 100, and the duration of individual time series varied. According to the results, the mean air pressure difference was within the range of national recommendations (small underpressure indoors) in 81–89% of measurement points, but some cases experienced either strong underpressure or overpressure conditions. In some cases, the air pressure difference showed a clear stepwise constant behavior, while other cases showed larger temporal variation. The conditions varied between different operating situations and the time of year. The study also supports the current recommendation that air pressure difference measurements should be done as continuous measurements of at least one week duration. Full article

This paper presents experimental studies on a controllable granular damper, whose dissipative properties are provided by the friction phenomenon occuring between loose granular material. In addition, in order to adjust to the current trends in vibration suppression, we built a semi-active device, controlled by a single parameter—underpressure. Such granular structures subjected to underpressure are called Vacuum-Packed Particles. The first section presents the state of the art. A brief description of the most often used intelligent and smart materials for the manufacture of dampers is presented. The main advantages of the proposed device are a simple structure, low construction cost, symmetrical principle of operation, and the ability to change the characteristics of the damper by quickly and suddenly changing the negative pressure inside the granular core. The second section provides a detailed description of the construction and operation principles of the original symmetrical granular damper. A description of its application in the laboratory research test stand is also provided. The third section presents the results of the experimental studies including the recorded damping characteristics of the investigated damper. The effectiveness of the ethylene–propylene–diene grains’ application is presented. The two parameters of underpressure and frequency of excitation were considered during the empirical tests. The influence of the system parameters on its global dissipative behavior is discussed in detail. The damper operation characteristics are close to linear, which is positive information from the point of view of the potential adaptive-passive control process. Brief conclusions and the prospective application of vacuum-packed particle dampers are presented in the final section. Full article

This article describes the cyclic loading of jammed granular systems represented by vacuum-packed particles in compression and tension, focusing on the influence of the properties of the granular material on the mechanical response. A jammed granular system is represented by a cylindrical sample filled with polymer granules (vacuum-packed particles) and is examined in symmetric cyclic compression and tension for up to 2000 cycles and at selected values of underpressure, i.e., 0.01, 0.04 and 0.07 MPa. Force and displacement are analyzed during the test, as well as changes in granule morphology by means of microscopic observations. The conducted tests indicate that it is possible to acquire repetitive results of maximum forces in the analyzed loading rage with the condition that granules do not plasticize during loading, i.e., they are resistant to damage during loading. Full article

There are significant levels of concern about both the safety assessment and financial evaluation of the whole hydropower system, especially at early project stages. In addition, there is a variety of reliable and accurate methods for analysis, design, and optimization of steel pressure liners in hydropower plants. Several countries have developed specific regulations and codes for the design, installation, and safety evaluation of under-pressure piping, as well as estimates of the potential risks associated with failure. This paper reviews the current methodologies and codes available for design and safety assessment of either unstiffened or stiffened pressure steel liners in hydropower plants. After examining the main guidelines and practical conclusions drawn from recent research in the field of liners subjected to either internal or external pressure, this article then discusses the relevant regulations and codes. The scope of this work is to summarize the advantages, disadvantages, and main characteristics of the existing design criteria, analysis methods, and other issues related to steel liners. Afterwards, this paper compares the main reliable formulations and modelling techniques, even the most recent or sophisticated ones. Lastly, we draw some conclusions regarding their accuracy and scope of applicability. Full article

Structural, electronic, and magnetic properties of Mn₂Co_1-xV_xZ (Z = Ga, Al, x = 0, 0.25, 0.5, 0.75, 1) Heusler alloys were theoretically investigated for the case of L2₁ (space group Fm$\overline{3}$m), L2_1b (L2₁ structure with partial disordering between Co and Mn atoms) and XA (space group F$\overline{4}$3m) structures. It was found that the XA structure is more stable at low V concentrations, while the L2₁ structure is energetically favorable at high V concentrations. A transition from L2₁ to XA ordering occurs near x = 0.5, which qualitatively agrees with the experimental results. Comparison of the energies of the L2_1b and XA structures leads to the fact that the phase transition between these structures occurs at x = 0.25, which is in excellent agreement with the experimental data. The lattice parameters linearly change as x grows. For the L2₁ structure, a slight decrease in the lattice constant a was observed, while for the XA structure, an increase in a was found. The experimentally observed nonlinear behavior of the lattice parameters with a change in the V content is most likely a manifestation of the presence of a mixture of phases. Almost complete compensation of the magnetic moment was achieved for the Mn₂Co_1-xV_xZ alloy (Z = Ga, Al) at x = 0.5 for XA ordering. In the case of the L2₁ ordering, it is necessary to consider a partial disorder of atoms in the Mn and Co sublattices in order to achieve compensation of the magnetic moment. Full article

Prior studies have noted that the principal stress orientations near the hydraulic fractures of well systems used for energy extraction may wander over time. Typically, the minimum and maximum principal stresses—in the horizontal map view—swap their respective initial directions, due to (1) fracture treatment interventions, and (2) pressure depletion resulting from production. The present analysis shows with stress trajectory visualizations, using a recently developed linear superposition method (LSM), that at least two generations of stress reversals around hydraulic fractures occur. The first generation occurs during the fracture treatment; the second occurs immediately after the onset of so-called flow-back. During each of these stress swaps in the vicinity of the hydraulic fractures, reservoir directions that were previously in compression subsequently exhibit extension, and directions previously stretching subsequently exhibit shortening. The pressure change in the hydraulic fractures—from over-pressured to under-pressured (only held open by proppant packs)—caused the neutral points that separate domains with different stress states to migrate from locations transverse to the fracture to locations beyond the fracture tips. Understanding such detailed geo-mechanical dynamics, related to the pressure evolution in energy reservoirs, is extremely important for improving both the fracture treatment and the well operation, as future hydrocarbon and geothermal energy extraction projects emerge. Full article

Shales are the most abundant class of sedimentary rocks, distinguished by being very fine-grained, clayey, and compressible. Their physical and chemical properties are important in widely different enterprises such as civil engineering, ceramics, and petroleum exploration. One characteristic, which is studied here, is a systematic reduction of porosity with depth of burial. This is due increases in grain-to-grain stress and temperature. Vertical stress in sediments is given by the overburden less the pore fluid pressure, $\sigma$, divided by the fraction of the horizontal area which is the supporting matrix, $(1-\phi )$, where $\phi$ is the porosity. It is proposed that the fractional reduction of this ratio, $\Lambda$, with time is given by the product of ${\phi }^{4m/3}$, ${(1-\phi )}^{4n/3}$, and one or more Arrhenius functions $Aexp(-E/RT)$ with m and n close to 1. This proposal is tested for shale sections in six wells from around the world for which porosity-depth data are available. Good agreement is obtained above 30–40 °C and fractional porosities less than 0.5. Single activation energies for each well are obtained in the range 15–33 kJ/mole, close to the approximate pressure solution of quartz, 24 kJ/mol. Values of m and n are in the range 1 to 0.8, indicating nearly fractal water-wet pore-to-matrix interfaces at pressure solution locations. Results are independent of over- or under-pressure of pore water. This model attempts to explain shale compaction quantitatively. For the petoleum industry, given porosity-depth data for uneroded sections and accurate activation energy, E, paleo-geothermal-gradient can be inferred and from that organic maturity, indicating better drilling prospects. Full article