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Keywords = ultrasonic particle manipulation

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24 pages, 3935 KB  
Article
PSO Trajectory Optimization of Robot Arm for Ultrasonic Testing of Complex Curved Surface
by Rao Yao, Yahui Lv, Kai Wang, Yan Gao and Dazhong Wang
Coatings 2026, 16(3), 332; https://doi.org/10.3390/coatings16030332 - 8 Mar 2026
Viewed by 466
Abstract
In ultrasonic nondestructive testing, maintaining the ultrasonic sensor in normal contact with curved surfaces is pivotal for acquiring valid defect signals. Replacing manual operation with a robotic arm ensures stable signal collection, while stable and fast trajectory planning for complex curved-surface tracking remains [...] Read more.
In ultrasonic nondestructive testing, maintaining the ultrasonic sensor in normal contact with curved surfaces is pivotal for acquiring valid defect signals. Replacing manual operation with a robotic arm ensures stable signal collection, while stable and fast trajectory planning for complex curved-surface tracking remains a key challenge. This research investigates gesture-driven robotic trajectory planning and impact optimization via the particle swarm optimization (PSO) algorithm in the robot joint space for rapid and smooth movement. Gesture trajectories are acquired via a Leap Motion device, with unified mapping established through spatial transformations among gesture, simulation, and experimental robot spaces. PSO is utilized to optimize trajectories, enhancing accuracy and controllability. Median filtering is applied to trajectory coordinate data to suppress errors from hand tremor and sensor limitations, followed by introducing a surface normal offset to generate pose matrices at each trajectory point. Systematic comparison of interpolation methods (polynomial, cubic spline, circular, cubic B-spline) reveals that cubic B-spline interpolation achieves the shortest execution time under angular acceleration constraints. The results show that PSO optimizes point-to-point trajectories based on 5-5-5 polynomial interpolation, with impact force and execution time as objectives, yielding the optimal trajectory with minimal time under acceleration constraints. This research provides valuable methodological references for robotic manipulator trajectory planning and optimization in complex curved-surface ultrasonic testing. Full article
(This article belongs to the Section Surface Characterization, Deposition and Modification)
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35 pages, 37297 KB  
Article
Heterogeneous Acoustofluidic Distributions Induced by Different Radiation Surface Arrangements in Various Pseudo-Sierpiński-Carpet-Shaped Chambers
by Qiang Tang, Boyang Li, Chen Li, Junjie Wang, Huiyu Huang, Yulong Hu, Kan Zhu, Hao Chen, Xu Wang and Songfei Su
Micromachines 2026, 17(2), 259; https://doi.org/10.3390/mi17020259 - 16 Feb 2026
Viewed by 894
Abstract
In this research, an innovative scheme to generate heterogeneous acoustofluidic distributions in various pseudo-Sierpiński-carpet-shaped chambers with different filling fractions and cross-sectional configurations has been proposed and calculated for topographical manipulation of large-scale micro-particles. All of the structural components positioned in the pseudo-fractal chambers [...] Read more.
In this research, an innovative scheme to generate heterogeneous acoustofluidic distributions in various pseudo-Sierpiński-carpet-shaped chambers with different filling fractions and cross-sectional configurations has been proposed and calculated for topographical manipulation of large-scale micro-particles. All of the structural components positioned in the pseudo-fractal chambers are symmetrically distributed in space, and all ultrasonic radiation surfaces hold the unified settings of input frequency point, oscillation amplitude, and initial phase distribution along their respective normal directions. A large number of fascinating acoustofluidic patterns can be generated in the originally-static pseudo-Sierpiński-carpet-shaped chambers at different recursion levels without complicated vibration parameter modulation. The simulation results of acoustofluidic distributions and particle motion trajectories under different radiation surface arrangements further demonstrate the manipulation performance of these specially designed devices, and indicate that controllable spatial partitioning and intensity modulation of the acoustofluidic field can be achieved by adjusting the hierarchical order, cross-sectional configuration and combination mode of the radiation surfaces. Unlike the existing device construction method of miniaturized microfluidic systems, the artificial introduction of fractal elements like Sierpiński carpet/triangle, Koch snowflake, Mandelbrot set, Pythagoras tree, etc., can provide extraordinary perspectives and expand the application range of the acoustofluidic effect, which also makes ultrasonic micro/nano-scale manipulation technology more abundant and diversified. This exploratory research indicates the potential possibility of applying fractal structures as alternative component parts to purposefully customize acoustofluidic distributions for the further research of patterned manipulation of bio-organisms and navigation of micro-robot swarms in brand new ways that cannot be achieved through traditional methods. Full article
(This article belongs to the Special Issue Acoustic-Microfluidic Integration and Biological Applications)
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14 pages, 4550 KB  
Article
Tunable Acoustic Tweezer System for Precise Three-Dimensional Particle Manipulation
by Jiyun Nan, Hiep Xuan Cao, Jong-Oh Park, Eunpyo Choi and Byungjeon Kang
Micromachines 2024, 15(10), 1240; https://doi.org/10.3390/mi15101240 - 8 Oct 2024
Cited by 3 | Viewed by 3184
Abstract
This study introduces a tunable acoustic tweezer system designed for precise three-dimensional particle trapping and manipulation. The system utilizes a dual-liquid-layer acoustic lens, which enables the dynamic control of the focal length through the adjustable curvature of a latex membrane. This tunability is [...] Read more.
This study introduces a tunable acoustic tweezer system designed for precise three-dimensional particle trapping and manipulation. The system utilizes a dual-liquid-layer acoustic lens, which enables the dynamic control of the focal length through the adjustable curvature of a latex membrane. This tunability is essential for generating the acoustic forces necessary for effective manipulation of particles, particularly along the direction of acoustic wave propagation (z-axis). Experiments conducted with spherical particles as small as 1.5 mm in diameter demonstrated the system’s capability for stable trapping and manipulation. Performance was rigorously evaluated through both z-axis and 3D manipulation tests. In the z-axis experiments, the system achieved a manipulation range of 33.4–53.4 mm, with a root-mean-square error and standard deviation of 0.044 ± 0.045 mm, which highlights its precision. Further, the 3D manipulation experiments showed that particles could be accurately guided along complex paths, including multilayer rectangular and helical trajectories, with minimal deviation. A visual feedback-based particle navigation system significantly enhanced positional accuracy, reducing errors relative to open-loop control. These results confirm that the tunable acoustic tweezer system is a robust tool for applications requiring precise control of particles with diameter of 1.5 mm in three-dimensional environments. Considering its ability to dynamically adjust the focal point and maintain stable trapping, this system is well suited for tasks demanding high precision, such as targeted particle delivery and other applications involving advanced material manipulation. Full article
(This article belongs to the Special Issue Acoustic Transducers and Their Applications, 2nd Edition)
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14 pages, 8720 KB  
Article
A Microchannel Device for Droplet Classification by Manipulation Using Piezoelectric Vibrator
by Ao Fujioka, Shoko Seo, Takefumi Kanda, Shuichi Wakimoto and Daisuke Yamaguchi
Actuators 2024, 13(3), 95; https://doi.org/10.3390/act13030095 - 28 Feb 2024
Cited by 2 | Viewed by 2487
Abstract
Emulsion formulations should be monodispersed in terms of their stability. Therefore, there is a need for a device that can classify droplets of the desired size from polydispersed emulsions in a fluidized bed manufacturing system. In the previous study, we evaluated the fabrication [...] Read more.
Emulsion formulations should be monodispersed in terms of their stability. Therefore, there is a need for a device that can classify droplets of the desired size from polydispersed emulsions in a fluidized bed manufacturing system. In the previous study, we evaluated the fabrication of a droplet manipulation device using acoustic radiation forces through simulation using the finite element method. In this study, particle manipulation experiments using 1, 6, and 10 µm polystyrene particles were first estimated and evaluated in comparison with their theoretical particle behavior. Based on the results we obtained, the driving conditions and droplet behavior were derived, and the droplet manipulation device using ultrasonic waves to shrink monodisperse emulsions was evaluated. As a result, the droplet classification effect in the microchannel was confirmed to be consistent with the droplet behavior prediction, and the microchannel structure with a constriction component improved its classification effect. Full article
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21 pages, 4030 KB  
Review
Review of Ultrasonic Particle Manipulation Techniques: Applications and Research Advances
by Shuai Wang, Xuewei Wang, Fucheng You and Han Xiao
Micromachines 2023, 14(8), 1487; https://doi.org/10.3390/mi14081487 - 25 Jul 2023
Cited by 28 | Viewed by 8277
Abstract
Ultrasonic particle manipulation technique is a non-contact label-free method for manipulating micro- and nano-scale particles using ultrasound, which has obvious advantages over traditional optical, magnetic, and electrical micro-manipulation techniques; it has gained extensive attention in micro-nano manipulation in recent years. This paper introduces [...] Read more.
Ultrasonic particle manipulation technique is a non-contact label-free method for manipulating micro- and nano-scale particles using ultrasound, which has obvious advantages over traditional optical, magnetic, and electrical micro-manipulation techniques; it has gained extensive attention in micro-nano manipulation in recent years. This paper introduces the basic principles and manipulation methods of ultrasonic particle manipulation techniques, provides a detailed overview of the current mainstream acoustic field generation methods, and also highlights, in particular, the applicable scenarios for different numbers and arrangements of ultrasonic transducer devices. Ultrasonic transducer arrays have been used extensively in various particle manipulation applications, and many sound field reconstruction algorithms based on ultrasonic transducer arrays have been proposed one after another. In this paper, unlike most other previous reviews on ultrasonic particle manipulation, we analyze and summarize the current reconstruction algorithms for generating sound fields based on ultrasonic transducer arrays and compare these algorithms. Finally, we explore the applications of ultrasonic particle manipulation technology in engineering and biological fields and summarize and forecast the research progress of ultrasonic particle manipulation technology. We believe that this review will provide superior guidance for ultrasonic particle manipulation methods based on the study of micro and nano operations. Full article
(This article belongs to the Special Issue Acoustic Micro/Nano Manipulation and Its Applications)
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13 pages, 10178 KB  
Article
Formation of a 3D Particle Array Actuated by Ultrasonic Traveling Waves in a Regular Polygon Resonator
by Fei Wan, Kai Xu, Hongcheng Wang, Haihao Xu, A’long Huang, Zihao Bai, Linan Zhang and Liqun Wu
Micromachines 2022, 13(11), 2003; https://doi.org/10.3390/mi13112003 - 17 Nov 2022
Cited by 1 | Viewed by 2436
Abstract
Acoustic radiation forces have been extensively studied regarding static particles, cell patterning, and dynamic transportation. Compared with standing wave manipulation, traveling wave manipulation can be more easily modulated in real time and has no matching requirement between the size of the resonant cavity [...] Read more.
Acoustic radiation forces have been extensively studied regarding static particles, cell patterning, and dynamic transportation. Compared with standing wave manipulation, traveling wave manipulation can be more easily modulated in real time and has no matching requirement between the size of the resonant cavity and the sound frequency. In this work, we present an efficient, multi-layer microparticle pattern technique in a 3D polygon cavity with a traveling bulk acoustic wave. There are two types of excitation modes: the interval excitation mode (IEM) and the adjacent excitation mode (AEM). We conducted theoretical and simulation analyses, and our results show that both of these modes can form particle arrays in the resonant cavity, which is in accordance with the experimental results. The array spacings in the IEM and AEM were about 0.8 mm and 1.3 mm, respectively, while the acoustic frequency was 1MHz. Double-layer particle patterns were arrayed by a double in the resonant cavity. The spacing between the two layers was set at 3.0 mm. The line spacings were about 0.4 mm in both layers. The line width was 0.2 mm, which was larger than the single layer. The results show that ultrasonic traveling waves are a feasible method to manipulate particles and cells that form 3D patterns in particle–fluid flows. Full article
(This article belongs to the Special Issue Acoustofluidics: Applications, Phenomena and Fabrication Technique)
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12 pages, 4040 KB  
Article
Particle Manipulation in 2D Space Using a Capacitive Micromachined Ultrasonic Transducer
by Chang Hoon Lee, Beom Hoon Park, Young Hun Kim, Hyeong Geun Jo and Kwan Kyu Park
Micromachines 2022, 13(4), 534; https://doi.org/10.3390/mi13040534 - 29 Mar 2022
Cited by 3 | Viewed by 3516
Abstract
Ultrasonic particle manipulation is a noncontact method for controlling microscale objects, such as cells or microparticles, using an acoustic field. In this study, a 2D array of capacitive micromachined ultrasonic transducers (CMUTs), placed horizontally in immersion, generated ultrasonic waves in the vertical direction, [...] Read more.
Ultrasonic particle manipulation is a noncontact method for controlling microscale objects, such as cells or microparticles, using an acoustic field. In this study, a 2D array of capacitive micromachined ultrasonic transducers (CMUTs), placed horizontally in immersion, generated ultrasonic waves in the vertical direction, and the oil’s surface increased due to the radiation force of the ultrasonic waves. In addition, the radiation force directly exerted a force on a floating particle. By measuring the movement of the reflected laser light by the moving oil surface, the height of the oil’s surface deformed by the acoustic radiation force (ARF) was measured. The ARF made a floating particle, as well as the oil’s surface, move. The particle moved radially away from the surface position above the transducer, and its velocity was determined by its position on the fluid’s surface. When a single channel was operated, it moved 0.4 mm at an average speed of 90 μm/s, and when two adjacent channels were operated, it moved 1.2 mm at a speed of 272 μm/s. The particles moved in any direction on the surface of the oil by controlling the actuation channel using an electrical switch. Full article
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12 pages, 6039 KB  
Article
Study on Particle Manipulation in a Metal Internal Channel under Acoustic Levitation
by Yaxing Wang, Liqun Wu and Yajing Wang
Micromachines 2022, 13(1), 18; https://doi.org/10.3390/mi13010018 - 24 Dec 2021
Cited by 6 | Viewed by 3646
Abstract
In order to study the acoustic levitation and manipulation of micro-particles in the heterogeneous structures inside metal, a test system for internal levitation in three-dimensional space is designed, establishing the 3D motion model of ultrasonic levitation and manipulation of micro-particles. The relationship between [...] Read more.
In order to study the acoustic levitation and manipulation of micro-particles in the heterogeneous structures inside metal, a test system for internal levitation in three-dimensional space is designed, establishing the 3D motion model of ultrasonic levitation and manipulation of micro-particles. The relationship between levitation force, particle diameter, internal channel size, and transmission thickness is established through the motion manipulation tests of multi-configuration channel levitation micro-particles in components. The results show that the proposed method can realize the following movement of levitation micro-particles at a higher speed and the control of motion accuracy in three-dimensional space. The micro-particles can be reliably suspended and continuously moved inside the components along a predesigned motion trajectory. The results provide an effective and feasible processing scheme for direct processing through the internal spatial structure. Full article
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12 pages, 3793 KB  
Article
Evolvable Acoustic Field Generated by a Transducer with 3D-Printed Fresnel Lens
by Danfeng Wang, Pengfei Lin, Zeyu Chen, Chunlong Fei, Zhihai Qiu, Qiang Chen, Xinhao Sun, Yan Wu and Lei Sun
Micromachines 2021, 12(11), 1315; https://doi.org/10.3390/mi12111315 - 26 Oct 2021
Cited by 4 | Viewed by 3959
Abstract
Evolvable acoustic fields are considered an effective method for solving technical problems related to fields such as biological imaging, particle manipulation, drug therapy and intervention. However, because of technical difficulties and the limited technology available for realizing flexible adjustments of sound fields, few [...] Read more.
Evolvable acoustic fields are considered an effective method for solving technical problems related to fields such as biological imaging, particle manipulation, drug therapy and intervention. However, because of technical difficulties and the limited technology available for realizing flexible adjustments of sound fields, few studies have reported on this aspect in recent years. Herein, we propose a novel solution, using a Fresnel lens-focused ultrasonic transducer for generating excited-signal-dependent acoustic pressure patterns. Finite element analysis (FEA) is used to predict the performance of a transducer with a Fresnel lens. The Fresnel lens is printed using 3D additive manufacturing. Normalized intensity maps of the acoustic pressure fields are characterized from the Fresnel lens-focused transducer under various numbers of excited-signal cycles. The results demonstrate that under different cycle excitations, a temporal evolution acoustic intensity can be generated and regulated by an ultrasound transducer with a 3D Fresnel lens. This acoustical pattern control method is not only simple to realize but also has considerable application prospects. Full article
(This article belongs to the Special Issue Advances in Piezoelectric Sensors, Transducers and Harvesters)
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23 pages, 10444 KB  
Review
Ultrasonic Particle Manipulation in Glass Capillaries: A Concise Review
by Guotian Liu, Junjun Lei, Feng Cheng, Kemin Li, Xuanrong Ji, Zhigang Huang and Zhongning Guo
Micromachines 2021, 12(8), 876; https://doi.org/10.3390/mi12080876 - 26 Jul 2021
Cited by 24 | Viewed by 14544
Abstract
Ultrasonic particle manipulation (UPM), a non-contact and label-free method that uses ultrasonic waves to manipulate micro- or nano-scale particles, has recently gained significant attention in the microfluidics community. Moreover, glass is optically transparent and has dimensional stability, distinct acoustic impedance to water and [...] Read more.
Ultrasonic particle manipulation (UPM), a non-contact and label-free method that uses ultrasonic waves to manipulate micro- or nano-scale particles, has recently gained significant attention in the microfluidics community. Moreover, glass is optically transparent and has dimensional stability, distinct acoustic impedance to water and a high acoustic quality factor, making it an excellent material for constructing chambers for ultrasonic resonators. Over the past several decades, glass capillaries are increasingly designed for a variety of UPMs, e.g., patterning, focusing, trapping and transporting of micron or submicron particles. Herein, we review established and emerging glass capillary-transducer devices, describing their underlying mechanisms of operation, with special emphasis on the application of glass capillaries with fluid channels of various cross-sections (i.e., rectangular, square and circular) on UPM. We believe that this review will provide a superior guidance for the design of glass capillary-based UPM devices for acoustic tweezers-based research. Full article
(This article belongs to the Special Issue Miniature Ultrasonic Devices and Their Applications)
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16 pages, 12537 KB  
Review
Recent Development and Perspectives of Optimization Design Methods for Piezoelectric Ultrasonic Transducers
by Dongdong Chen, Linwei Wang, Xingjun Luo, Chunlong Fei, Di Li, Guangbao Shan and Yintang Yang
Micromachines 2021, 12(7), 779; https://doi.org/10.3390/mi12070779 - 30 Jun 2021
Cited by 37 | Viewed by 8651
Abstract
A piezoelectric ultrasonic transducer (PUT) is widely used in nondestructive testing, medical imaging, and particle manipulation, etc., and the performance of the PUT determines its functional performance and effectiveness in these applications. The optimization design method of a PUT is very important for [...] Read more.
A piezoelectric ultrasonic transducer (PUT) is widely used in nondestructive testing, medical imaging, and particle manipulation, etc., and the performance of the PUT determines its functional performance and effectiveness in these applications. The optimization design method of a PUT is very important for the fabrication of a high-performance PUT. In this paper, traditional and efficient optimization design methods for a PUT are presented. The traditional optimization design methods are mainly based on an analytical model, an equivalent circuit model, or a finite element model and the design parameters are adjusted by a trial-and-error method, which relies on the experience of experts and has a relatively low efficiency. Recently, by combining intelligent optimization algorithms, efficient optimization design methods for a PUT have been developed based on a traditional model or a data-driven model, which can effectively improve the design efficiency of a PUT and reduce its development cycle and cost. The advantages and disadvantages of the presented methods are compared and discussed. Finally, the optimization design methods for PUT are concluded, and their future perspectives are discussed. Full article
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13 pages, 6213 KB  
Article
Generating Airborne Ultrasonic Amplitude Patterns Using an Open Hardware Phased Array
by Rafael Morales, Iñigo Ezcurdia, Josu Irisarri, Marco A. B. Andrade and Asier Marzo
Appl. Sci. 2021, 11(7), 2981; https://doi.org/10.3390/app11072981 - 26 Mar 2021
Cited by 53 | Viewed by 20886
Abstract
Holographic methods from optics can be adapted to acoustics for enabling novel applications in particle manipulation or patterning by generating dynamic custom-tailored acoustic fields. Here, we present three contributions towards making the field of acoustic holography more widespread. Firstly, we introduce an iterative [...] Read more.
Holographic methods from optics can be adapted to acoustics for enabling novel applications in particle manipulation or patterning by generating dynamic custom-tailored acoustic fields. Here, we present three contributions towards making the field of acoustic holography more widespread. Firstly, we introduce an iterative algorithm that accurately calculates the amplitudes and phases of an array of ultrasound emitters in order to create a target amplitude field in mid-air. Secondly, we use the algorithm to analyse the impact of spatial, amplitude and phase emission resolution on the resulting acoustic field, thus providing engineering insights towards array design. For example, we show an onset of diminishing returns for smaller than a quarter-wavelength sized emitters and a phase and amplitude resolution of eight and four divisions per period, respectively. Lastly, we present a hardware platform for the generation of acoustic holograms. The array is integrated in a single board composed of 256 emitters operating at 40 kHz. We hope that the results and procedures described within this paper enable researchers to build their own ultrasonic arrays and explore novel applications of ultrasonic holograms. Full article
(This article belongs to the Special Issue Holography in Acoustics and Ultrasonics)
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13 pages, 6138 KB  
Article
Micromotor Manipulation Using Ultrasonic Active Traveling Waves
by Hiep Xuan Cao, Daewon Jung, Han-Sol Lee, Gwangjun Go, Minghui Nan, Eunpyo Choi, Chang-Sei Kim, Jong-Oh Park and Byungjeon Kang
Micromachines 2021, 12(2), 192; https://doi.org/10.3390/mi12020192 - 13 Feb 2021
Cited by 33 | Viewed by 4772
Abstract
The ability to manipulate therapeutic agents in fluids is of interest to improve the efficiency of targeted drug delivery. Ultrasonic manipulation has great potential in the field of therapeutic applications as it can trap and manipulate micro-scale objects. Recently, several methods of ultrasonic [...] Read more.
The ability to manipulate therapeutic agents in fluids is of interest to improve the efficiency of targeted drug delivery. Ultrasonic manipulation has great potential in the field of therapeutic applications as it can trap and manipulate micro-scale objects. Recently, several methods of ultrasonic manipulation have been studied through standing wave, traveling wave, and acoustic streaming. Among them, the traveling wave based ultrasonic manipulation is showing more advantage for in vivo environments. In this paper, we present a novel ultrasonic transducer (UT) array with a hemispherical arrangement that generates active traveling waves with phase modulation to manipulate a micromotor in water. The feasibility of the method could be demonstrated by in vitro and ex vivo experiments conducted using a UT array with 16 transducers operating at 1 MHz. The phase of each transducer was controlled independently for generating a twin trap and manipulation of a micromotor in 3D space. This study shows that the ultrasonic manipulation device using active traveling waves is a versatile tool that can be used for precise manipulation of a micromotor inserted in a human body and targeted for drug delivery. Full article
(This article belongs to the Special Issue Micro/Nanorobotics)
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16 pages, 32209 KB  
Article
Inter-Particle Effects with a Large Population in Acoustofluidics
by Kun Jia, Yulong Wang, Liqiang Li, Jian Chen and Keji Yang
Actuators 2020, 9(4), 101; https://doi.org/10.3390/act9040101 - 10 Oct 2020
Cited by 2 | Viewed by 3348
Abstract
The ultrasonic manipulation of cells and bioparticles in a large population is a maturing technology. There is an unmet demand for improved theoretical understanding of the particle–particle interactions at a high concentration. In this study, a semi-analytical method combining the Jacobi–Anger expansion and [...] Read more.
The ultrasonic manipulation of cells and bioparticles in a large population is a maturing technology. There is an unmet demand for improved theoretical understanding of the particle–particle interactions at a high concentration. In this study, a semi-analytical method combining the Jacobi–Anger expansion and two-dimensional finite element solution of the scattering problem is proposed to calculate the acoustic radiation forces acting on massive compressible particles. Acoustic interactions on arrangements of up to several tens of particles are investigated. The particle radius ranges from the Rayleigh scattering limit (ka«1) to the Mie scattering region (ka≈1). The results show that the oscillatory spatial distribution of the secondary radiation force is related to the relative size of co-existing particles, not the absolute value (for particles with the same radius). In addition, the acoustic interaction is non-transmissible for a group of identical particles. For a large number of equidistant particles arranged along a line, the critical separation distance for the attraction force decreases as the number of particles increases, but eventually plateaus (for 16 particles). The range of attraction for the formed cluster is stabilized when the number of aggregated particles reaches a certain value. Full article
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17 pages, 5462 KB  
Article
Synthesis and Characterization of Amorphous Iron Oxide Nanoparticles by the Sonochemical Method and Their Application for the Remediation of Heavy Metals from Wastewater
by Virendra Kumar Yadav, Daoud Ali, Samreen Heena Khan, Govindhan Gnanamoorthy, Nisha Choudhary, Krishna Kumar Yadav, Van Nam Thai, Seik Altaf Hussain and Salim Manhrdas
Nanomaterials 2020, 10(8), 1551; https://doi.org/10.3390/nano10081551 - 7 Aug 2020
Cited by 155 | Viewed by 11836
Abstract
Nanoparticles have gained huge attention in the last decade due to their applications in electronics, medicine, and environmental clean-up. Iron oxide nanoparticles (IONPs) are widely used for the wastewater treatment due to their recyclable nature and easy manipulation by an external magnetic field. [...] Read more.
Nanoparticles have gained huge attention in the last decade due to their applications in electronics, medicine, and environmental clean-up. Iron oxide nanoparticles (IONPs) are widely used for the wastewater treatment due to their recyclable nature and easy manipulation by an external magnetic field. Here, in the present research work, iron oxide nanoparticles were synthesized by the sonochemical method by using precursors of ferrous sulfate and ferric chloride at 70 °C for one hour in an ultrasonicator. The synthesized iron oxide nanoparticles were characterized by diffraction light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), electron diffraction spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM) and vibrating sample magnetometer (VSM). The FTIR analysis exhibits characteristic absorption bands of IONPs at 400–800 cm−1, while the Raman spectra showed three characteristic bands at 273, 675, and 1379 cm−1 for the synthesized IONPs. The XRD data revealed three major intensity peaks at two theta, 33°, 35°, and 64° which indicated the presence of maghemite and magnetite phase. The size of the spherical shaped IONPs was varying from 9–70 nm with an average size of 38.9 nm while the size of cuboidal shaped particle size was in microns. The purity of the synthesized IONPs was confirmed by the EDS attached to the FESEM, which clearly show sharp peaks for Fe and O, while the magnetic behavior of the IONPs was confirmed by the VSM measurement and the magnetization was 2.43 emu/g. The batch adsorption study of lead (Pb) and chromium (Cr) from 20% fly ash aqueous solutions was carried out by using 0.6 mg/100 mL IONPs, which exhibited maximum removal efficiency i.e., 97.96% and 82.8% for Pb2+ and Cr ions, respectively. The fly ash are being used in making cements, tiles, bricks, bio fertilizers etc., where the presence of fly ash is undesired property which has to be either removed or will be brought up to the value of acceptable level in the fly ash. Therefore, the synthesized IONPs, can be applied in the elimination of heavy metals and other undesired elements from fly ash with a short period of time. Moreover, the IONPs that have been used as a nanoadsorbent can be recovered from the reaction mixture by applying an external magnetic field that can be recycled and reused. Therefore, this study can be effective in all the fly ash-based industries for elimination of the undesired elements, while recyclability and reusable nature of IONPs will make the whole adsorption or elimination process much economical. Full article
(This article belongs to the Special Issue Nanomaterials and Nanotechnology in Wastewater Treatment)
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