Search Results (10)

2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) stands as one of the most potent halogenated polycyclic hydrocarbons, known to inflict substantial cytotoxic effects on both animal and human tissues. Its widespread presence and recalcitrance make it an environmental and health concern. Efforts are being intensively channeled to uncover strategies that could mitigate the adverse health outcomes associated with TCDD exposure. In the realm of counteractive agents, boron compounds are emerging as potential candidates. These compounds, which have found applications in a spectrum of industries ranging from agriculture to pharmaceutical and cosmetic manufacturing, are known to modulate several cellular processes and enzymatic pathways. However, the dose–response relationships and protective potentials of commercially prevalent boron compounds, such as boric acid (BA), ulexite (UX), and borax (BX), have not been comprehensively studied. In our detailed investigation, when peripheral blood mononuclear cells (PBMCs) were subjected to TCDD exposure, they manifested significant cellular disruptions. This was evidenced by compromised membrane integrity, a marked reduction in antioxidant defense mechanisms, and a surge in the malondialdehyde (MDA) levels, a recognized marker for oxidative stress. On the genomic front, increased 8-OH-dG levels and chromosomal aberration (CA) frequency suggested that TCDD had the potential to cause DNA damage. Notably, our experiments have revealed that boron compounds could act as protective agents against these disruptions. They exhibited a pronounced ability to diminish the cytotoxic, genotoxic, and oxidative stress outcomes instigated by TCDD. Thus, our findings shed light on the promising role of boron compounds. In specific dosages, they may not only counteract the detrimental effects of TCDD but also serve as potential chemopreventive agents, safeguarding the cellular and genomic integrity of PBMCs. Full article

Currently, Brazil is the largest producer and exporter of soybeans in the world. Most of this cultivation is concentrated in the Cerrado region, which has soils with low boron levels. Boron performs functions that are directly linked to plant performance. The objective of this study was to evaluate the agronomic performance of soybean cultivars with and without boron fertilization. Two field experiments were carried out in the agricultural years 2018/2019 and 2019/2020. Each experiment was carried out in a randomized block design with four replications and 10 soybean cultivars (Desafio, Foco, Bonus, Maracaí, 7067, 7110, 7739, 8372, 7100, and Population). Boron fertilization was carried out at the V3 stage of the crop using ulexite (10% of boron) at a rate of 3194 kg ha⁻¹ and 0.0 kg ha⁻¹ of B. The application of boron to the soil increased plant height, pod insertion height, number of branches, main stem diameter, and number of pods per plant, in addition to increasing the cycle of these cultivars. The cultivars 7110, 7739 and Desafio did not statistically differ in terms of grain yield in response to boron fertilization. The cultivars Foco, Bonus, Maracaí, 7067, 8372, 7100, and Population responded favorably to this fertilization. Furthermore, genetic breeding programs incorporate advanced strategies, such as the use of boron fertilization, in order to improve the performance of the selected genotypes. Implementing boron fertilization as an integral part of breeding programs helps not only to achieve high-yielding cultivars but also to optimize key agronomic traits. This integrated approach not only boosts breeding research but also provides a solid basis for sustainable and efficient agricultural practices. Full article

Cement is widely used for the solidification of low- and intermediate-level radioactive waste materials. Radioactive borate solution with a high concentration of boron is one of the main radioactive wastes produced in nuclear stations. It is difficult to solidify this solution by using cement because borate has a great inhibitory effect on the cement hydration process. In this study, the hydration kinetics, strength, durability, phase assemblage, and transportation and transformation of the silicon of the paste that blended Portland cement with 5 M borate solution were investigated. After the addition of sodium hydroxide and sodium metasilicate to the paste, the cement hydration process was restarted, and the 28-days strength of samples met the requirements of the Chinese standard. The mechanism of overcoming the retardation of cement hydration by the borate solution was attributed to the formation of calcium metaborate, ettringite, portlandite, and calcium silicate hydrate with the restarting of cement hydration, without the formation of ulexite. Full article

Fibers represent a type of structure of great interest in catalysis since they combine high area to volume ratio and can be fabricated from many types of materials, such as ceramic oxides, polymers, and alloys. They can be used in isolated form or structured, as in the case of the ceramic papers synthesized in this work, following a modified papermaking technique. The addition of cationic and anionic polyelectrolytes improved the retention of ceramic fibers during the ceramic paper formation stage by adsorption processes, through the formation of floccules. In the complex aqueous system containing charged macromolecules, the amounts of polyelectrolytes to be added were determined by titrations. To enhance mechanical properties of ceramic papers, different classes of nanoparticle suspensions can be used as binders. As a novel alternative, we have used different borate-type compounds. Among them, we selected natural ulexite, which was purified and used as a binder of ceramic fibers. In order to improve mechanical resistance and flexibility, measured from tensile indexes and elastic module, the amounts of NaCaB₅O₆(OH)₆.5H₂O and the calcination temperature were varied. In this contribution, to take advantage of the unique characteristics of the ulexite-containing ceramic papers, they were impregnated with Co,Ce and Co,Ba,K and tested for diesel soot combustion. Full article

Genetic, neuropathological and biochemical investigations have revealed meaningful relationships between aluminum (Al) exposure and neurotoxic and hematotoxic damage. Hence, intensive efforts are being made to minimize the harmful effects of Al. Moreover, boron compounds are used in a broad mix of industries, from cosmetics and pharmaceuticals to agriculture. They affect critical biological functions in cellular events and enzymatic reactions, as well as endocrinal and mineral metabolisms. There are limited dose-related data about boric acid (BA) and other boron compounds, including colemanite (Col), ulexite (UX) and borax (BX), which have commercial prominence. In this study, we evaluate boron compounds’ genetic, cytological, biochemical and pathological effects against aluminum chloride (AlCl₃)-induced hematotoxicity and neurotoxicity on different cell and animal model systems. First, we perform genotoxicity studies on in vivo rat bone marrow cells and peripheric human blood cultures. To analyze DNA and chromosome damage, we use single cell gel electrophoresis (SCGE or comet assay) and micronucleus (MN) and chromosome aberration (CA) assays. The nuclear division index (NDI) is used to monitor cytostasis. Second, we examine the biochemical parameters (superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GSH-Px), malondialdehyde (MDA), total antioxidant capacity (TAC) and total oxidative status (TOS)) to determine oxidative changes in blood and brain. Next, we assess the histopathological alterations by using light and electron microscopes. Our results show that Al increases oxidative stress and genetic damage in blood and brain in vivo and in vitro studies. Al also led to severe histopathological and ultrastructural alterations in the brain. However, the boron compounds alone did not cause adverse changes based on the above-studied parameters. Moreover, these compounds exhibit different levels of beneficial effects by removing the harmful impact of Al. The antioxidant, antigenotoxic and cytoprotective effects of boron compounds against Al-induced damage indicate that boron may have a high potential for use in medical purposes in humans. In conclusion, our analysis suggests that boron compounds (especially BA, BX and UX) can be administered to subjects to prevent neurodegenerative and hematological disorders at determined doses. Full article

The risk of resource depletion for future generations of humanity is often cited as an important issue. The choice of impact categories and characterization models for resource extraction in LCA is no more precise than other impact categories and models. This means that more discussion is needed on the use of resources. In this article, the potential depletion of Boron and Boron minerals (Colemanite, Ulexite, Tincal) are studied. These minerals have a big role for the world and for Turkey; however, this resource is limited. Using the life cycle assessment methodology, one can estimate the resource depletion through the indicator “abiotic resource depletion”. Several models can evaluate this indicator, but the most used models are ReCiPe and CML (that is the previous attempt of ReCiPe) methods. Here, we estimated the damage that is done to natural resource scarcity. The values that are calculated by these two methods were compared to identify the potential evolution of the model and to observe the gap between these two models. The ReCiPe method refers to the average amount of extra ore that is produced in the future to extract 1 kg of boron ore or boron minerals resource. On the other hand, The CML method depends on the final reserve amount in terms of depletion. The results show no depletion shortly for boron ore and boron minerals. Correlation coefficients were calculated in the ReCiPe method, and ‘high uncertainty’ was estimated since R² < 0.8. This research highlights the fact that there is the necessity to propose different impact factors for the various minerals and not only for boron (that is done today). Full article

Borate is an essential material to numerous industries and even to individual countries’ economies, defense, and politics. Almost all industries need borates for production, and almost everybody needs their products. Borate is a compound that contains or supplies boric oxide (B₂O₃). Among the minerals that contain boric oxide, there are only four minerals significant from an economic standpoint, namely borax (tincal), colemanite, ulexite, and kernite. Turkey has almost 70% of all known reserves in the world. Therefore, borates and their products could be one of the main topics for sustainable development in the whole world. The recent development and pursuit of new boron-consuming technologies and alternative products to existing borate-consuming products introduce additional uncertainty to the sustainability of boron minerals. Therefore, the European Union (EU) Commission also declared borate one of the 30 critical raw materials. Turkey is a prosperous country in terms of boron reserves, and it exports almost 96% of borates’ production. In order to better understand the relation between borate minerals and borate products, a material flow analysis (MFA) study has been carried out within the content of this work in order to update the data about the current status of boron. For this purpose, a system has been established that shows the flow of boron material. The extraction, enrichment, and refining processes of boron products are drawn. The results indicate that about 41% of extracted colemanite ore is converted into refined borate, about 31% of tincal ore is converted to refined borate, and 4% of tincal ore is converted to end-usage products, such as detergent. The correctness of the data and the sensitivity of the processes are all estimated values. The results can help in the development of boron sustainability and boron production strategies. The MFA study on tincal and colemanite ore may be an example of boron studies in different countries. Full article

Although there are a lot of studies in literature related to the life cycle assessment (LCA) of mining, there are only a few studies done on the boron mining industry. This paper presents an LCA of the boron mining industry including the extraction, beneficiation, and refinement processes. The main purpose is to identify and compare the environmental impacts associated with the production of 1 ton of refined products (boric acid, borax pentahydrate, borax decahydrate, and sodium perborate) starting from an open pit mine located in Turkey. The life cycle inventory (LCI) was obtained from the data collected from the related literature sources and the company’s reports. This cradle-to-gate analysis has been carried out using the commercial software called SimaPro employing the International Reference Life Cycle Data System (ILCD) 2011 Midpoint+ Life Cycle Impact Assessment (LCIA) method. The results showed that the environmental impact of the refinement process is critical compared to the mining and beneficiations processes. Sulphuric acid, steam, hydrogen peroxide, and sodium perborate which are used in refined boron production cause most of the impact and emission into the environment. Among the refined boron products investigated, the impact of sodium perborate is quite high. Full article

Life is a complex, open chemical system that must be supported with energy inputs. If one fathoms how simple early life must have been, the complexity of modern-day life is staggering by comparison. A minimally complex system that could plausibly provide pyrophosphates for early life could be the oxidation of reduced phosphorus sources such as hypophosphite and phosphite. Like all plausible prebiotic chemistries, this system would have been altered by minerals and rocks in close contact with the evolving solutions. This study addresses the different types of perturbations that minerals might have on this chemical system. This study finds that minerals may inhibit the total production of oxidized phosphorus from reduced phosphorus species, they may facilitate the production of phosphate, or they may facilitate the production of pyrophosphate. This study concludes with the idea that mineral perturbations from the environment increase the chemical complexity of this system. Full article

The modern boron applications have adsorbed the mineral processors’ attention to improve typical boron mineral’s (BM) beneficiation methods. In this regard, dry treatment and pretreatment processes—such as magnetic separation and calcination as environmentally friendly methods, due to their minimal or zero adverse effect on the environment—need more consideration. Over the years, anionic flotation has become the main technique for beneficiation of friable BMs; however, there is a gap in the investigation of cationic flotation separation since BMs’ surface negatively charges in a wide pH range. At present, enriching BMs’ flotation via surface modification is taking center stage, which can also be considered for reprocessing long-forgotten BM tailings. As a comprehensive review, this work is going to provide a synopsis of the processes, techniques, optimum parameters, and conditions—such as size reduction, zeta potential, pH, and reagents—which have been employed in the processing of BMs. Gaps in our understanding of BM’s flotation are presented in the context of addressing the existing processes, considering possibilities and rooms for efficiency improvement. Considering these gaps may improve the performance of existing methods for processing fine and ultrafine BMs, and help in the development of new technologies to improve flotation recoveries. Full article