Search Results (11)

This study investigates the hydrogen permeability of injection-molded polyamide 6 (PA6) nanocomposites reinforced with organo-modified montmorillonite (OMMT) at varying concentrations (1, 2.5, 5, and 10 wt. %) for potential use as Type IV composite-overwrapped pressure vessel (COPV) liners. While previous work examined their mechanical properties, this study focuses on their crystallinity, morphology, and gas barrier performance. The precise inorganic content was determined using thermal gravimetry analysis (TGA), while differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and scanning electron microscopy (SEM) were used to characterize the structural and morphological changes induced by varying filler content. The results showed that generally higher OMMT concentrations promoted γ-phase formation but also led to increased agglomeration and reduced crystallinity. The PA6/OMMT-1 wt. % sample stood out with higher crystallinity, well-dispersed clay, and low hydrogen permeability. In contrast, the PA6/OMMT-2.5 and -5 wt. % samples showed increased permeability, which corresponded to WAXD and SEM evidence of agglomeration and DSC results indicating a lower degree of crystallinity. PA6/OMMT-10 wt. % showed the most-reduced hydrogen permeability compared to all other samples. This improvement, however, is attributed to a tortuous path effect created by the high filler loading rather than optimal crystallinity or dispersion. SEM images revealed significant OMMT agglomeration, and DSC analysis confirmed reduced crystallinity, indicating that despite the excellent barrier performance, the compromised microstructure may negatively impact mechanical reliability, showing PA6/OMMT-1 wt. % to be the most balanced candidate combining both mechanical integrity and hydrogen impermeability for Type IV COPV liners. Full article

Type IV composite overwrapped pressure vessels (COPVs) store hydrogen at pressures up to 70 MPa and must meet stringent safety standards through physical testing. However, full-scale burst, plug torque, axial compression, impact, and drop tests are time-consuming and costly. This study proposes a unified finite element analysis (FEA) workflow that replicates these mandatory tests and predicts failure behavior without physical prototypes. Axisymmetric and three-dimensional solid models with reduced-integration elements were constructed for the polyamide liner, aluminum boss, and carbon/epoxy composite. Burst simulations showed that increasing the hoop-to-axial stiffness ratio shifts peak stress to the cylindrical region, promoting a longitudinal rupture—considered structurally safer. Plug torque and axial load simulations revealed critical stresses at the boss–composite interface, which can be reduced through neck boss shaping and layup optimization. A localized impact with a 25 mm sphere generated significantly higher stress than a larger 180 mm impactor under equal energy. Drop tests confirmed that 45° oblique drops cause the most severe dome stresses due to thin walls and the lack of hoop support. The proposed workflow enables early-stage structural validation, supports cost-effective design optimization, and accelerates the development of safe hydrogen storage systems for automotive and aerospace applications. Full article

Due to environmental concerns and increasing energy needs, hydrogen is increasingly seen as a promising alternative to fossil fuels. Its advantages include minimal greenhouse gas emissions (depending on origin), high efficiency, and widespread availability. Various storage methods have been developed, with high-pressure storage being currently among the most common due to its cost-effectiveness and simplicity. Composite high-pressure vessels are categorized as type III or IV, with type III using an aluminum alloy liner and type IV utilizing a polymer liner. This paper investigates damage mechanisms in filament wound carbon fiber composite pressure vessels subjected to low-velocity impacts, focusing on two types of impactors (with different geometries) with varying impact energies. The initial section features experimental trials that capture various failure modes (e.g., matrix damage, delamination, and fiber breakage) and how different impactor geometries influence the damage mechanisms of composite vessels. A numerical model was developed and validated with experimental data to support the experimental findings, ensuring accurate damage mechanism simulation. The research then analyzes how the shape and size of impactors influence damage patterns in the curved vessel, aiming to establish a relationship between impactor geometry features and damage, which is crucial for the design and applications of carbon fiber composites in such an engineering application. Full article

Hydrogen is one of the critical components to address global challenges such as climate change, environmental pollution and global warming. It is a renewable source of energy that has many advantages compared to other renewables. Even though it may not be a “silver bullet” solution for the polluted world, there is still a big expectation that it can solve some of the energy crisis and challenges in the transportation, domestic and industry sectors. This study reviews the latest advancements in materials science, especially in the composite materials used for energy storage/transportation tanks. Special attention is given to towpreg material structures as the most promising ones for hydrogen storage. Various types of storage vessels are reviewed with emphasis on the most advanced type IV and type V vessels for energy (hydrogen) storage. The manufacturing processes, mainly filament winding (FW) and automatic fiber placement (AFP), are reviewed with their pros and cons. The sustainability aspects for the most promising hydrogen technologies, limitations and future challenges are also discussed. Full article

This study focuses on polyamide 6/organo-modified montmorillonite (PA6/OMMT) nanocomposites as potential liner materials, given the growing interest in enhancing the performance of type IV composite overwrapped hydrogen storage pressure vessels. The mechanical properties of PA6/OMMT composites with varying filler concentrations were investigated across a temperature range relevant to hydrogen storage conditions (−40 °C to +85 °C). Liner collapse, a critical issue caused by rapid gas discharge, was analyzed using an Ishikawa diagram to identify external and internal factors. Mechanical testing revealed that higher OMMT content generally increased stiffness, especially at elevated temperatures. The Young’s modulus and first yield strength exhibited non-linear temperature dependencies, with 1 wt. per cent OMMT content enhancing yield strength at all tested temperatures. Dynamic mechanical analysis (DMA) indicated that OMMT improves the storage modulus, suggesting effective filler dispersion, but it also reduces the toughness and heat resistance, as evidenced by lower glass transition temperatures. This study underscores the importance of optimizing OMMT content to balance mechanical performance and thermal stability for the practical application of PA6/OMMT nanocomposites in hydrogen storage pressure vessels. Full article

The seal and weight of the Type IV hydrogen storage vessel are the key problems restricting the safety and driving range of fuel cell vehicles. The boss, as a metal medium connecting the inner liner of the Type IV hydrogen storage vessel with the external pipeline, affects the sealing performance of the Type IV hydrogen storage vessel, and there is no academic research on the weight of the boss. Therefore, according to the force characteristics of the boss, this paper divides the upper and lower areas (valve column and plate). The valve column with seal optimization and light weight is manufactured with a 3D printing additive, while the plate bearing and transferring the internal pressure load is manufactured by forging. Firstly, a two-dimensional axisymmetric simulation model of the sealing ring was established, and the effects of different compression rates on its seal performance were analyzed. Then, the size and position of the sealing groove were sampled, simulated, and optimized based on the Latin Hypercube method, and the reliability of the optimal seal structure was verified by experiments. Finally, the Solid Isotropic Material with Penalization (SIMP) topology method was used to optimize the weight of the boss with optimal sealing structure, and the reconstructed model was checked and analyzed. The results show that the weight of the optimized boss is reduced by 9.6%. Full article

Currently, large-volume type IV composite vessel tube trailers garner significant attention and development within the hydrogen energy storage and transportation industry due to their cost-effectiveness and practicality. This study aims to assess the static strength and sealing performance of the boss structure in order to optimize its design. Firstly, a model of the mouth structure of type IV vessels was constructed to analyze the stress distributions in the boss and liner. Subsequently, innovative boss and liner structures were developed based on the primary mouth structure to investigate the impact of geometric dimensions through finite element analysis. This study revealed that changes in geometrical dimensions led to significant alterations in the stresses of the plastic liner in comparison to metallic bosses. Building upon these findings, the structural safety and sealing performance of the boss and liner structure were further validated through finite element analysis. The outcomes of this research can serve as a reference for guiding the structural design of bosses and aiding in the development of hydrogen storage vessels. Full article

Compressed gas storage of hydrogen has emerged as the preferred choice for fuel cell vehicle manufacturers, as well as for various applications, like road transport and aviation. However, designers face increasing challenges in designing safe and efficient composite overwrapped pressure vessels (COPVs) for hydrogen storage. One challenge lies in the development of precise software programs that consider a multitude of factors associated with the filament winding process. These factors include layer thickness, stacking sequence, and the development of particularly robust models for the dome region. Another challenge is the formulation of predictive behavior and failure models to ensure that COPVs have optimal structural integrity. The present study offers an exploration of numerical methods used in modeling COPVs, aiming to enhance our understanding of their performance characteristics. The methods examined include finite element analysis in Abaqus, involving conventional shell element, continuum shell element, three-dimensional solid element, and homogenization techniques for multilayered composite pressure vessels. Through rigorous comparisons with type-III pressure vessels from the literature, the research highlights the most suitable choice for simulating COPVs and their practicality. Finally, we propose a new design for type-IV hydrogen composite pressure vessels using one explored method, paving the way for future developments in this critical field. Full article

Hydrogen as an energy carrier could help decarbonize industrial, building, and transportation sectors, and be used in fuel cells to generate electricity, power, or heat. One of the numerous ways to solve the climate crisis is to make the vehicles on our roads as clean as possible. Fuel cell electric vehicles (FCEVs) have demonstrated a high potential in storing and converting chemical energy into electricity with zero carbon dioxide emissions. This review paper comprehensively assesses hydrogen’s potential as an innovative alternative for reducing greenhouse gas (GHG) emissions in transportation, particularly for on-board applications. To evaluate the industry’s current status and future challenges, the work analyses the technology behind FCEVs and hydrogen storage approaches for on-board applications, followed by a market review. It has been found that, to achieve long-range autonomy (over 500 km), FCEVs must be capable of storing 5–10 kg of hydrogen in compressed vessels at 700 bar, with Type IV vessels being the primary option in use. Carbon fiber is the most expensive component in vessel manufacturing, contributing to over 50% of the total cost. However, the cost of FCEV storage systems has considerably decreased, with current estimates around 15.7 $/kWh, and is predicted to drop to 8 $/kWh by 2030. In 2021, Toyota, Hyundai, Mercedes-Benz, and Honda were the major car brands offering FCEV technology globally. Although physical and chemical storage technologies are expected to be valuable to the hydrogen economy, compressed hydrogen storage remains the most advanced technology for on-board applications. Full article

This study focuses on the critical connection area between type IV hydrogen storage vessels and external valves, which is commonly referred to as the BOSS structure. The novel BOSS structures were proposed to further ensure the safety of pressure vessels. In order to identify optimal structure that meet industrial requirements, finite element models were performed to analyze and compare the effectiveness of the proposed models in terms of strength, fatigue, and sealing performance. Some influences were discussed, including the angle of inclination of the stop-rotation platform and the number of sealing grooves in the BOSS structures. The results showed that the fatigue life of the proposed BOSS structures can exceed the design life of 30,000 cycles using austenitic stainless steel S31603. The maximum contact stresses were higher than the operating pressure of 58 MPa. Additionally, The BOSS structure model designed with a stop-rotation platform featuring a 65° tilt angle and two sealing grooves had the lowest mean square deviation of contact stress, which was 13.47 MPa, indicating reliable sealing performance. Full article

The rapid development of hydrogen fuel cells has been paralleled by increased demand for lightweight type IV hydrogen storage vessels with high hydrogen storage density, which raises the performance requirements of internal plastic liners. An appropriate manufacturing process is important to improve the quality of polymer liners. In this paper, DSC, WAXD, a universal testing machine and a differential pressure gas permeameter were used to investigate the effect of the cooling rate of the rotational molding polyamide 11 on the thermal, crystallization, mechanical and barrier properties. The cooling rate is formulated according to the cooling rate that can be achieved in actual production. The results suggest that two PA11 liner materials initially exhibited two-dimensional (circular) growth under non-isothermal crystallization conditions and shifted to one-dimensional space growth due to spherulite collision and crowding during the secondary crystallization stage. The slower the cooling process, the greater the crystallinity of the specimen. The increase in crystallinity significantly improved the barrier properties of the two PA11 liner materials, and the gas permeability coefficient was 2-3-fold higher than at low crystallinity. Moreover, the tensile strength, the tensile modulus, the flexural strength, and the flexural modulus increased, and the elongation at break decreased as the crystallinity increased. Full article