Search Results (7)

Airborne wind energy systems using flexible membrane wings have the advantages of a low weight, small packing volume, high mobility and rapid deployability. This paper investigates the aero-structural deformation of a leading edge inflatable kite for airborne wind energy harvesting. In the first step, a triangular two-plate representation of the wing is introduced, leading to an analytical description of the wing geometry depending on the symmetric actuation state. In the second step, this geometric constraint-based model is refined to a multi-segment wing representation using a particle system approach. Each wing segment consists of four point masses kept at a constant distance along the tubular frame by linear spring-damper elements. An empirical correlation is used to model the billowing of the wing’s trailing edge. The linear spring-damper elements also the model line segments of the bridle line system, with each connecting two point masses. Three line segments can also be connected by a pulley model. The aerodynamic force acting on each wing segment is determined individually using the lift equation with a constant lift coefficient. The particle system model can predict the symmetric deformation of the wing in response to a symmetric actuation of the bridle lines used for depowering the kite (i.e., changing the pitch angle). The model also reproduces the typical twist deformation of the wing in response to an asymmetric line actuation used for steering the kite. The simulated wing geometries are compared with photogrammetric information taken by the onboard video camera of the kite control unit, focusing on the wing during flight. The results demonstrate that a particle system model can accurately predict the geometry of a soft wing at a low computational cost, making it an ideal structural building block for the next generation of soft wing kite models. Full article

A high cost of high-purity materials is one of the major factors that limit the application of ceramic membranes. Consequently, the focus was shifted to using natural and abundant low-cost materials such as zeolite, clay, sand, etc. as alternatives to well-known pure metallic oxides, such as alumina, silica, zirconia and titania, which are usually used for ceramic membrane fabrication. As a contribution to this area, the development and characterization of new low-cost ultrafiltration (UF) membranes made from natural Tunisian kaolin are presented in this work. The asymmetric ceramic membranes were developed via layer-by-layer and slip-casting methods by direct coating on tubular supports previously prepared from sand and zeolite via the extrusion process. Referring to the results, it was found that the UF kaolin top layer is homogenous and exhibits good adhesion to different supports. In addition, the kaolin/sand and kaolin/zeolite membranes present an average pore diameter in the range of 4–17 nm and 28 nm, and water permeability of 491 L/h·m²·bar and 182 L/h·m²·bar, respectively. Both membranes were evaluated in their treatment of electroplating wastewater. This was done by removing oil and heavy metals using a homemade crossflow UF pilot plant operated at a temperature of 60 °C to reduce the viscosity of the effluent, and the transmembrane pressure (TMP) of 1 and 3 bar for kaolin/sand and kaolin/zeolite, respectively. Under these conditions, our membranes exhibit high permeability in the range of 306–336 L/h·m²·bar, an almost total oil and lead retention, a retention up to 96% for chemical oxygen demand (COD), 96% for copper and 94% for zinc. The overall data suggest that the developed kaolin membranes have the potential for remediation of oily industrial effluents contaminated by oil and heavy metals. Full article

Ceramic membrane contactors hold great promise for CO₂ desorption due to their high mass transfer area as well as the favorable characteristics of ceramic materials to resist harsh operating conditions. In this work, a hydrophobic tubular asymmetric alpha-alumina (α-Al₂O₃) membrane was prepared by grafting a hexadecyltrimethoxysilane ethanol solution. The hydrophobicity and permeability of the membrane were evaluated in terms of water contact angle and nitrogen (N₂) flux. The hydrophobic membrane had a water contact angle of ~132° and N₂ flux of 0.967 × 10⁻⁵ mol/(m²∙s∙Pa). CO₂ desorption from the aqueous monoethanolamine (MEA) solution was conducted through the hydrophobic tubular ceramic membrane contactor. The effects of operating conditions, such as CO₂ loading, liquid flow rate, liquid temperature and permeate side pressure, on CO₂ desorption flux were investigated. Moreover, the stability of the membrane was evaluated after the immersion of the ceramic membrane in an MEA solution at 373 K for 30 days. It was found that the hydrophobic α-Al₂O₃ membrane had good stability for CO₂ desorption from the MEA solution, resulting in a <10% reduction of N₂ flux compared to the membrane without MEA immersion. Full article

Asymmetric tubular ceramic–ceramic (cercer) membranes based on La₂₇W_3.5Mo_1.5O_55.5−δ-La_0.87Sr_0.13CrO_3−δ were fabricated by a two-step firing method making use of water-based extrusion and dip-coating. The performance of the membranes was characterized by measuring the hydrogen permeation flux and water splitting with dry and wet sweep gases, respectively. To explore the limiting factors for hydrogen and oxygen transport in the asymmetric membrane architecture, the effect of different gas flows and switching the feed and sweep sides of the membrane on the apparent hydrogen permeability was investigated. A dusty gas model was used to simulate the gas gradient inside the porous support, which was combined with Wagner diffusion calculations of the dense membrane layer to assess the overall transport across the asymmetric membrane. In addition, the stability of the membrane was investigated by means of flux measurements over a period of 400 h. Full article

Thin-film membrane layers coated onto porous supports is widely considered as an efficient way to obtain high-performance oxygen transport membranes with both good permeability and high mechanical strength. However, conventional preparation methods of membrane supports usually result in highly tortuous channels with high mass transfer resistance. Tubular porous MgO and MgO/CGO supports were fabricated with a simple phase inversion casting method. Long finger-like channels were obtained inside the dual-phase supports by adjusting the ceramic loading, polymer concentration and particle surface area, as well as by introducing ethanol inside the casting slurries. Slurries that exhibit lower viscosity in the zero-shear viscosity region resulted in more pronounced channel growth. These supports were used to produce thin supported CGO membranes for possible application in O₂ separation. Similar shrinkage speeds for the different layers during the sintering process are crucial for obtaining dense asymmetric membranes. The shrinkage of the support tube at a high temperature was greatly affected by the polymer/ceramic ratio and compatible shrinkage behaviours of the two layers were realized with polymer/ceramic weight ratios between 0.175 and 0.225. Full article

An original asymmetric tubular membrane for oxygen production applications was manufactured in a two-step process. A 3 mol% Y₂O₃ stabilized ZrO₂ (3YSZ) porous tubular support was manufactured by the freeze-casting technique, offering a hierarchical and radial-oriented porosity of about 15 µm in width, separated by fully densified walls of about 2 µm thick, suggesting low pressure drop and boosted gas transport. The external surface of the support was successively dip-coated to get a Ce_0.8Gd_0.2O_2−δ – 5mol%Co (CGO-Co) interlayer of 80 µm in thickness and an outer dense layer of La_0.6Sr_0.4Co_0.2Fe_0.8O_3−δ (LSCF) with a thickness of 30 µm. The whole tubular membrane presents both uniform geometric characteristics and microstructure all along its length. Chemical reactivity between each layer was studied by coupling X-Ray Diffraction (XRD) analysis and Energy Dispersive X-Ray spectroscopy (EDX) mapping at each step of the manufacturing process. Cation interdiffusion between different phases was discarded, confirming the compatibility of this tri-layer asymmetric ceramic membrane for oxygen production purposes. For the first time, a freeze-cast tubular membrane has been evaluated for oxygen permeation, exhibiting a value of 0.31 mL·min⁻¹·cm⁻² at 1000 °C under air and argon as feed and sweep gases, respectively. Finally, under the same conditions and increasing the oxygen partial pressure to get pure oxygen as feed, the oxygen permeation reached 1.07 mL·min⁻¹·cm⁻². Full article

Palladium-based catalytic membrane reactors (CMRs) effectively remove H₂ to induce higher conversions in methane steam reforming (MSR) and water-gas-shift reactions (WGS). Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H₂, CO and CO₂. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H₂O, CO₂ and H₂. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H₂ and induce higher methane and CO conversions while yielding ultrapure H₂ and compressed CO₂ ready for dehydration. Experimental results involving (i) a conventional packed bed reactor packed (PBR) for MSR, (ii) a PBR with five layers of two catalysts in series and (iii) a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD) model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H₂ permeance and purity, high CH₄ conversion levels and reduced CO yields. Full article