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Keywords = thermoplastic pipe

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19 pages, 6492 KB  
Article
Hydrogen Diffusion Behavior of Steel-Wire-Reinforced Thermoplastic Pipes with Stress–Hydrogen Coupled Finite Element Method
by Xin Li, Yifeng Guo, Tongshen Zheng, Hongxing Li, Jianghua Chen, Li Zhang, Yanjun Li and Chilou Zhou
Energies 2026, 19(14), 3425; https://doi.org/10.3390/en19143425 - 21 Jul 2026
Viewed by 455
Abstract
Hydrogen embrittlement of the steel reinforcement layers poses a critical threat to the safe operation of steel-wire-reinforced thermoplastic pipes (SRP) in hydrogen transport. However, the mechanisms governing hydrogen diffusion in SRP under stress conditions remain poorly understood. This study develops a two-dimensional finite [...] Read more.
Hydrogen embrittlement of the steel reinforcement layers poses a critical threat to the safe operation of steel-wire-reinforced thermoplastic pipes (SRP) in hydrogen transport. However, the mechanisms governing hydrogen diffusion in SRP under stress conditions remain poorly understood. This study develops a two-dimensional finite element model based on the theory of hydrogen diffusion under stress conditions. The model systematically examines the influence of four parameters on hydrogen diffusion in SRP: hydrogen pressure (1–20 MPa), steel wire diameter (1.0–2.0 mm), radial distance from the steel wire layer to the inner pipe wall (3.2–4.8 mm), and steel wire winding angle (8–15°). The key findings are as follows: (1) Increasing hydrogen pressure proportionally accelerates hydrogen diffusion and raises the local hydrogen concentration around the steel wires, thereby promoting hydrogen-induced crack initiation. (2) The effect of steel wire diameter is non-monotonic. Increasing the diameter from 1.0 mm to 1.2 mm lengthens diffusion paths and suppresses the local hydrogen concentration, whereas a further increase to 2.0 mm intensifies steric hindrance and hydrogen retention. Optimal hydrogen barrier performance is achieved at diameters of 1.2–1.4 mm. (3) Increasing the radial distance from the steel wire layer to the inner pipe wall strengthens the hydrogen concentration gradient across the inner and outer high-density polyethylene layers. This accelerates hydrogen diffusion and reduces the hydrogen concentration adjacent to the wires. (4) A winding angle of 9–10° minimizes the hydrogen concentration within the steel wire layer, thereby significantly improving resistance to hydrogen embrittlement. These findings elucidate the mechanisms governing hydrogen diffusion in SRP and provide quantitative design guidelines for mitigating hydrogen-induced damage in composite pipeline systems. Full article
(This article belongs to the Special Issue Advances in Hydrogen Energy Safety Technology, 2nd Edition)
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17 pages, 3346 KB  
Article
Investigation of Residual Stresses in Extruded Thermoplastic PE-RT Pipes
by Arun Biradar and Pierre Mertiny
Polymers 2026, 18(9), 1135; https://doi.org/10.3390/polym18091135 - 5 May 2026
Viewed by 972
Abstract
Polyethylene of Raised Temperature resistance (PE-RT) is a versatile polymer with an enhanced ability to withstand higher temperatures than other standard polyethylene-derived materials. The application scope of PE-RT pipes extends across a broad range of residential and industrial uses. However, the inherent residual [...] Read more.
Polyethylene of Raised Temperature resistance (PE-RT) is a versatile polymer with an enhanced ability to withstand higher temperatures than other standard polyethylene-derived materials. The application scope of PE-RT pipes extends across a broad range of residential and industrial uses. However, the inherent residual stresses developed during the fabrication processes of these pipes pose a significant challenge to their service performance. Moreover, the technical literature on residual stresses in PE-RT pipes is scarce. The investigations presented in this paper address this scientific and technical gap by experimentally quantifying the residual stresses present in different sizes of PE-RT pipes manufactured at the same plant. The slitting method was employed as the primary experimental procedure in these investigations. In addition to establishing experimental processes, this study aims to mitigate residual stresses in PE-RT pipes by investigating their sensitivity to varying annealing temperatures for one selected pipe size. Subsequently, the optimal annealing temperature (115 °C) was applied to the remaining pipe sizes to determine its efficacy in residual stress mitigation. Through the implementation of these procedures, the circumferential residual stresses in PE-RT pipes subjected to annealing at 115 °C were significantly reduced, with a minimum decrease of 78%. Furthermore, the longitudinal residual stresses were substantially diminished, reaching a state of near-complete elimination. Full article
(This article belongs to the Special Issue Advances in Thermal Behaviour of Polymers)
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28 pages, 3926 KB  
Article
Acoustic Emission and Machine Learning Approaches for Assessing Mechanical Degradation in Aged Unidirectional Glass Fiber-Reinforced Thermoplastics
by Jorge Palacios Moreno and Pierre Mertiny
Metrology 2026, 6(1), 11; https://doi.org/10.3390/metrology6010011 - 13 Feb 2026
Viewed by 911
Abstract
Unidirectional glass fiber-reinforced thermoplastic (UGFT) composite tapes are promising recyclable structural materials for applications such as composite pressure pipes. However, their durability under hydrothermal environments remains a critical concern. This study emphasizes metrology-driven evaluation of aging behavior in polypropylene-based UGFT tapes. Specimens were [...] Read more.
Unidirectional glass fiber-reinforced thermoplastic (UGFT) composite tapes are promising recyclable structural materials for applications such as composite pressure pipes. However, their durability under hydrothermal environments remains a critical concern. This study emphasizes metrology-driven evaluation of aging behavior in polypropylene-based UGFT tapes. Specimens were conditioned at 95 °C in a deionized-water environment for up to 4 weeks, and multiple complementary measurement techniques were applied to quantify degradation. Mass-change metrology was performed to characterize water uptake kinetics and establish diffusion-driven aging progression. Tensile testing enabled quantitative assessment of mechanical strength retention, defining a >25% reduction in strength as a threshold for significant deterioration. Acoustic emission (AE) acted as the central non-destructive monitoring method, capturing high-fidelity waveforms generated during loading. AE waveform descriptors, such as amplitude, rise time, and frequency content, served as measurable indicators of internal damage mechanisms including matrix cracking, interfacial debonding and fiber breakage. To process large AE datasets, principal component analysis was used for dimensionality reduction, followed by k-means clustering to group signals by damage type. Optical microscopy provided microstructural verification of these classifications. The integrated metrological framework demonstrates a reliable pathway to monitor, identify, and quantify damage evolution in hydrothermally aged UGFT structures. Full article
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138 KB  
Abstract
Low-Density Polyethylene Beads Integrity Disruption Induced by Native Fusarium oxysporum
by Maria Andrea Reyes Reyes, Brayan Danilo Vergel, Jorge Hernando Panqueva, Camila Andrea Rojas Florez, Yuly Andrea Prada Vargas, William Fernando Hidalgo Bucheli, Enrique Mejía Ospino, Sergio Marchant and Clara Inés Sánchez
Proceedings 2026, 136(1), 38; https://doi.org/10.3390/proceedings2026136038 - 14 Nov 2025
Viewed by 347
Abstract
Low-density polyethylene (LDPE) is a widely used thermoplastic polymer in the production of plastic bags and pipes due to its flexibility, chemical resistance, and low cost [...] Full article
(This article belongs to the Proceedings of The 3rd International Online Conference on Polymer Science)
19 pages, 7223 KB  
Article
Analysis of Failure Cause in Steel Wire-Reinforced Thermoplastic Composite Pipes for Sour Gas Field Water Transportation
by Zhiming Yu, Shaomu Wen, Jie Wang, Jianwei Lin, Chuan Xie and Dezhi Zeng
Materials 2025, 18(21), 4865; https://doi.org/10.3390/ma18214865 - 24 Oct 2025
Viewed by 1297
Abstract
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and [...] Read more.
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and primary contributing factors of the composite pipes, this study conducted a comprehensive analysis through microscopic morphology examination of different typical failure cases, differential scanning calorimetry, Fourier transform infrared spectroscopy, and mechanical property testing. The main failure mechanisms were investigated, and targeted protective measures are proposed. Key findings reveal that the typical failure modes are ductile cracking, aging-induced brittle cracking, and aging creep cracking. These failures follow a mechanism of degradation of the inner and outer polyethylene protective layers, penetration of the medium and corrosion of the steel wires, reduction in pressure-bearing capacity, and eventual structural damage or leakage propagation through the pipe wall. Notably, oxidation induction time values dropped as low as 1.4–17 min—far below the standard requirement of >20 min—indicating severe antioxidant depletion and material aging. The main controlling factors are poor material quality, external stress or mechanical damage, and long-term aging. The polyethylene used for the inner and outer protective layers is critical to the overall pipe performance; therefore, emphasis should be placed on evaluating its anti-aging properties and on protecting the pipe body during installation to ensure the long-term safety and stable operation of the pipeline system. Full article
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25 pages, 3353 KB  
Article
Thermo-Physical Behaviour of Thermoplastic Composite Pipe for Oil and Gas Applications
by Obinna Okolie, Nadimul Haque Faisal, Harvey Jamieson, Arindam Mukherji and James Njuguna
Polymers 2025, 17(8), 1107; https://doi.org/10.3390/polym17081107 - 19 Apr 2025
Cited by 6 | Viewed by 2774
Abstract
Thermoplastic composite pipes (TCP) consist of three distinct layers—liner, reinforcement, and coating—offering superior advantages over traditional industrial pipes, including flexibility, lightweight construction, and corrosion resistance. This study systematically characterises the thermal properties of TCP layers and their compositions using a multi-method approach. Thermal [...] Read more.
Thermoplastic composite pipes (TCP) consist of three distinct layers—liner, reinforcement, and coating—offering superior advantages over traditional industrial pipes, including flexibility, lightweight construction, and corrosion resistance. This study systematically characterises the thermal properties of TCP layers and their compositions using a multi-method approach. Thermal analysis was conducted through differential scanning calorimetry (DSC) for isothermal and non-isothermal crystallisation, thermogravimetric analysis (TGA) for thermal stability, and Fourier transform infrared spectroscopy (FTIR) for material identification. FTIR confirmed polyethylene as the primary component of TCP, with compositional variations across the layers. TGA results indicated that thermal degradation begins at approximately 200 °C, with complete decomposition at 500 °C. DSC analysis revealed a double melting peak, prompting further investigation into its mechanisms. On-isothermal crystallisation kinetics, analysed at cooling rates of 10 °C/min and 50 °C/min, revealed an anisotropic crystalline growth pattern. Although nucleation occurs uniformly, the subsequent three-dimensional crystalline growth is governed more by the degree of supercooling than by the crystallography of the glass fibres. This underscores the importance of precisely controlling the cooling rate during manufacturing to optimise the anisotropic properties of the reinforced layer. This study also demonstrates the value of FTIR, TGA, and DSC techniques in characterising the thermo-physical behaviour of TCP, offering critical insights into thermal expansion, shrinkage phenomena, and overall material stability. Given the limited body of research on this specific TCP formulation, the findings presented here lay a foundation for both quality enhancement and process optimisation. Moreover, the paper offers a distinctive perspective on the dynamic behaviour, thermal expansion, and long-term performance of TCP in demanding oil and gas environments. Full article
(This article belongs to the Section Polymer Applications)
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23 pages, 5246 KB  
Article
Integrated Non-Destructive Testing for Assessing Manufacturing Defects in Melt-Fusion Bonded Thermoplastic Composite Pipes
by Obinna Okolie, Nadimul Haque Faisal, Harvey Jamieson, Arindam Mukherji and James Njuguna
NDT 2025, 3(1), 6; https://doi.org/10.3390/ndt3010006 - 19 Mar 2025
Cited by 1 | Viewed by 2037
Abstract
The thermoplastic composite pipe (TCP) manufacturing process introduces defects that impact performance, such as voids, misalignment, and delamination. Consequently, there is an increasing demand for effective non-destructive testing (NDT) techniques to assess the influence of these manufacturing defects on TCP. The objective is [...] Read more.
The thermoplastic composite pipe (TCP) manufacturing process introduces defects that impact performance, such as voids, misalignment, and delamination. Consequently, there is an increasing demand for effective non-destructive testing (NDT) techniques to assess the influence of these manufacturing defects on TCP. The objective is to identify and quantify internal defects at a microscale, thereby improving quality control. A combination of methods, including NDT, has been employed to achieve this goal. The density method is used to determine the void volume fraction. Microscopy and void analysis are performed on pristine samples using optical micrography and scanning electron microscopy (SEM), while advanced techniques like X-ray computer tomography (XCT) and ultrasonic inspections are also applied. The interlayer between the reinforced and inner layers showed good consolidation, though a discontinuity was noted. Microscopy results confirmed solid wall construction, with SEM aligning with the XY axis slice, showing predominant fibre orientation around ±45° and ±90°, and deducing the placement orientation to be ±60°. Comparing immersion, 2D microscopy, and XCT methods provided a comparative approach, even though they could not yield precise void content values. The analysis revealed a void content range of 0–2.2%, with good agreement between microscopy and Archimedes’ methods. Based on XCT and microscopy results, an increase in void diameter at constant volume increases elongation and reduces sphericity. Both methods also indicated that most voids constitute a minority of the total void fraction. To mitigate manufacturing defects, understanding the material’s processing window is essential, which can be achieved through comprehensive material characterization of TCP materials. Full article
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22 pages, 6661 KB  
Article
Parametric Design of Easy-Connect Pipe Fitting Components Using Open-Source CAD and Fabrication Using 3D Printing
by Abolfazl Taherzadeh Fini, Cameron K. Brooks, Alessia Romani, Anthony G. Straatman and Joshua M. Pearce
J. Manuf. Mater. Process. 2025, 9(2), 65; https://doi.org/10.3390/jmmp9020065 - 19 Feb 2025
Cited by 3 | Viewed by 5658
Abstract
The amount of non-revenue water, mostly due to leakage, is around 126 billion cubic meters annually worldwide. A more efficient wastewater management strategy would use a parametric design for on-demand, customized pipe fittings, following the principles of distributed manufacturing. To fulfill this need, [...] Read more.
The amount of non-revenue water, mostly due to leakage, is around 126 billion cubic meters annually worldwide. A more efficient wastewater management strategy would use a parametric design for on-demand, customized pipe fittings, following the principles of distributed manufacturing. To fulfill this need, this study introduces an open-source parametric design of a 3D-printable easy-connect pipe fitting that offers compatibility with different dimensions and materials of pipes available on the market. Custom pipe fittings were 3D printed using a RepRap-class fused filament 3D printer, with polylactic acid (PLA), polyethylene terephthalate glycol (PETG), acrylonitrile styrene acrylate (ASA), and thermoplastic elastomer (TPE) as filament feedstocks for validation. The 3D-printed connectors underwent hydrostatic water pressure tests to ensure that they met the standards for residential, agricultural, and renewable energy production applications. All the printed parts passed numerous hydrostatic pressure tests. PETG couplings can tolerate up to 4.551 ± 0.138 MPa of hydrostatic pressure, which is eight times greater than the highest standard water pressure in the residential sector. Based on the economic analysis, the cost of 3D printing a pipe coupling is from three to seventeen times lower than purchasing a commercially available pipe fitting of a similar size. The new open-source couplings demonstrate particular potential for use in developing countries and remote areas. Full article
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20 pages, 16064 KB  
Article
The Application of High-Resolution, Embedded Fibre Optic (FO) Sensing for Large-Diameter Composite Steel/Plastic Pipeline Performance under Dynamic Transport Loads
by Nigel J. Cassidy, Paul O’Regan, Sha Luo, David N. Chapman and Ian Jefferson
Sensors 2024, 24(4), 1298; https://doi.org/10.3390/s24041298 - 17 Feb 2024
Cited by 4 | Viewed by 3054
Abstract
Distributed optical fibre sensing (DOFS)-based strain measurement systems are now routinely deployed across infrastructure health monitoring applications. However, there are still practical performance and measurement issues associated with the fibre’s attachment method, particularly with thermoplastic pipeline materials (e.g., high-density polyethylene, HDPE) and adhesive [...] Read more.
Distributed optical fibre sensing (DOFS)-based strain measurement systems are now routinely deployed across infrastructure health monitoring applications. However, there are still practical performance and measurement issues associated with the fibre’s attachment method, particularly with thermoplastic pipeline materials (e.g., high-density polyethylene, HDPE) and adhesive affixment methods. In this paper, we introduce a new optical fibre installation method that utilises a hot-weld encapsulation approach that fully embeds the fibre onto the pipeline’s plastic surface. We describe the development, application and benefits of the new embedment approach (as compared to adhesive methods) and illustrate its practical performance via a full-scale, real-world, dynamic loading trial undertaken on a 1.8 m diameter, 6.4 m long stormwater pipeline structure constructed from composite spiral-wound, steel-reinforced, HDPE pipe. The optical frequency domain reflectometry (OFDR)-based strain results show how the new method improves strain transference and dynamic measurement performance and how the data can be easily interpreted, in a practical context, without the need for complex strain transfer functions. Through the different performance tests, based on UK rail-road network transport loading conditions, we also show how centimetre- to metre-scale strain variations can be clearly resolved at the frequencies and levels consistent with transport- and construction-based, buried infrastructure loading scenarios. Full article
(This article belongs to the Special Issue Smart Sensing Technology and Infrastructure Health Monitoring)
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14 pages, 7608 KB  
Article
Bidirectional-Reinforced Carbon Fiber/Polyether-Ether-Ketone Composite Thin-Walled Pipes via Pultrusion-Winding for On-Orbit Additive Manufacturing
by Yuanhao Xia, Long Jiang, Yi Chen, Yiping Zhao, Lili Yang and Dengteng Ge
Materials 2024, 17(2), 293; https://doi.org/10.3390/ma17020293 - 6 Jan 2024
Cited by 14 | Viewed by 3845
Abstract
Benefitting from lightweight, high strength, long life, and green recyclability, continuous fiber reinforced thermoplastic composite (CFTPC) pipes have attracted extensive interest, especially in the on-orbit additive manufacturing of structural components. However, the preparation of CFTPC pipes remains challenging due to the on-orbit limited [...] Read more.
Benefitting from lightweight, high strength, long life, and green recyclability, continuous fiber reinforced thermoplastic composite (CFTPC) pipes have attracted extensive interest, especially in the on-orbit additive manufacturing of structural components. However, the preparation of CFTPC pipes remains challenging due to the on-orbit limited space and high processing temperature of thermoplastic resin. Here, we report an effective approach for high performance carbon fiber/polyether-ether-ketone (CF/PEEK) thin-walled pipes via bidirectional reinforcement using the pultrusion-winding technique. The continuous fabrication of thin-walled pipes can be achieved, but the limitation by the size of core mold is also broken. The compressive and shear performance of CF/PEEK pipes with different layer designs have been studied based on experiments and simulations. With the increase in axial prepreg tape layer, the resultant CF/PEEK pipes exhibit greatly improved axial compression strength. The finite element analysis indicates that the maximum axial stress is decreased due to the axial enhancement. The flexural strength is greatly proved with pultrusion–winding cycles. The simulation confirms that the circumferential strain is effectively reduced. The high performance of bidirectional reinforced CF/PEEK pipes and the facile controllability of this approach highlight their suitability for utilization in on-orbit manufacturing of large-scale structures. Full article
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14 pages, 5559 KB  
Article
A Method for Predicting the Load Interaction between Reinforced Thermoplastic Pipe and Sandy Soil Based on Model Testing
by Chuan Wang, Lianghai Liu, Ya Zhang and Min Lou
J. Mar. Sci. Eng. 2023, 11(12), 2353; https://doi.org/10.3390/jmse11122353 - 13 Dec 2023
Cited by 3 | Viewed by 2238
Abstract
This study aims to investigate the interaction between reinforced thermoplastic pipes (RTPs) and sandy soil. The mechanical properties of sandy soil in the South China Sea region were determined through shear tests to obtain fundamental data. Subsequently, a specialized experimental setup was designed [...] Read more.
This study aims to investigate the interaction between reinforced thermoplastic pipes (RTPs) and sandy soil. The mechanical properties of sandy soil in the South China Sea region were determined through shear tests to obtain fundamental data. Subsequently, a specialized experimental setup was designed and assembled to study the pipe–soil interaction, specifically measuring the lateral soil resistance of flexible pipes at varying burial depths. Data analysis revealed the relationship between soil resistance, lateral displacement, and initial burial depth. To simulate the mechanical behavior of the pipe–soil interaction, the coupled Eulerian–Lagrangian (CEL) method was employed for numerical simulations. The research findings indicate that the lateral soil resistance is influenced by the uplift height and accumulation width of the soil ahead of the pipe. Within a lateral displacement range of 0.5 times the pipe diameter (0.5D), the lateral soil resistance rapidly increases, resulting in a soil uplift along the circumferential direction of the pipe. This process not only enhances the load-bearing capacity of the pipe but also increases the accumulated soil resistance, consequently expanding the soil failure zone. Furthermore, the ultimate soil resistance exhibits an increasing trend with an increasing burial depth. Once the pipe reaches a certain burial depth, the uplift height of the soil reaches a critical state. To address the grid distortion caused by soil deformation, numerical simulations based on the CEL method effectively modeled the pipe–soil interaction forces under significant lateral displacements, exhibiting good agreement with the experimental results. This study provides a solution for investigating soil resistance in submarine pipelines, thereby contributing significantly to the design and performance prediction of underwater pipelines. Full article
(This article belongs to the Special Issue Advances in Marine Mechanical and Structural Engineering)
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27 pages, 5915 KB  
Article
A Numerical Investigation of Induced and Embedded Trench Installations for Large-Diameter Thermoplastic Pipes under High Fill Stresses
by Havvanur Kılıç, Perihan Biçer and Sercan Bozkurt
Appl. Sci. 2023, 13(5), 3040; https://doi.org/10.3390/app13053040 - 27 Feb 2023
Cited by 4 | Viewed by 3735
Abstract
The induced trench installation method is applied by placing material with high compressibility on rigid pipes to reduce the earth pressures acting on them. Although the performance of this method for rigid pipes has been investigated, research on thermoplastic pipes is very limited. [...] Read more.
The induced trench installation method is applied by placing material with high compressibility on rigid pipes to reduce the earth pressures acting on them. Although the performance of this method for rigid pipes has been investigated, research on thermoplastic pipes is very limited. In this study, induced trench installation (ITI) and embedded trench installation (ETI) of large-diameter thermoplastic pipes subjected to high fill stresses were investigated by numerical analysis. The numerical model has been verified by considering the field experiments, and a series of analyses were carried out by placing Expanded Polystyrene Foam (EPS Geofoam) in ITI and ETI models. Pipe stresses and deflections were evaluated by considering the pipe diameter, stiffness, and backfill properties. The ITI and ETI models in thermoplastic pipes reduced the stresses acting on the pipes and increased the positive arching regardless of the deflection of the pipe. For pipes with an inner diameter of 0.762 to 1.524 m under 30 m of fill stress, approximately 1.5 to 3.0% deflection occurred. In the ETI model, the horizontal earth pressure in the spring line of the pipe decreased from 65 to 40% depending on the backfill type, and an approximately uniform stress distribution was formed around the pipe. Full article
(This article belongs to the Special Issue Advances in Underground Pipeline Technology)
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25 pages, 9820 KB  
Article
Study on Mechanical Failure Behavior of Steel-Wire Wound Reinforced Thermoplastic Pipe under Combined Internal Pressure and Soil Landslide Conditions
by Jun Shi, Zhijie Hu, Li Zeng, Panlin Lu, Hanxin Chen, Nanming Yu and Xiang Li
Materials 2023, 16(2), 848; https://doi.org/10.3390/ma16020848 - 15 Jan 2023
Cited by 13 | Viewed by 3213
Abstract
A steel-wire wound reinforced thermoplastic pipe (SWW-RTP) has been widely utilized in many industrial areas, and a soil landslide is an inevitable hazardous extreme condition for the SWW-RTP as it is usually buried underground. It is imperative to study the mechanical failure behavior [...] Read more.
A steel-wire wound reinforced thermoplastic pipe (SWW-RTP) has been widely utilized in many industrial areas, and a soil landslide is an inevitable hazardous extreme condition for the SWW-RTP as it is usually buried underground. It is imperative to study the mechanical failure behavior and the failure criterion of the SWW-RTP under the combination of internal pressure and soil landslide conditions, and this paper is the first study to investigate the topic. In this paper, groups of stress–strain curves of high-density polyethylene (HDPE) and steel wires were obtained by uniaxial tensile tests at different strain rates, with the help of a Digital Image Correlation device (DIC). A rate-dependent constitutive model was employed to represent the mechanical behavior of the HDPE and to help deduce the stress–strain curve of the HDPE under the required strain rate, estimated from the static simplification of the dynamic soil landslide. Afterwards, a finite element model of the SWW-RTP, embedded in a cubic of soil, was established with the software ABAQUS. The SWW-RTP model was composed of HDPE solid elements, embedded with steel-wire truss elements, and the soil was characterized with the extended Drucker–Prager model. A quartic polynomial displacement distribution was applied to the soil model to represent the soil landslide. Then, the mechanical response of the SWW-RTP was analyzed. It was found that the failure criterion of the HDPE yield was more suitable for the pipe subjected to internal pressure and soil landslide conditions, instead of the steel-wire strength failure criterion always used in traditional research on the SWW-RTP. Further, the influence of landslide width, internal pressure and steel-wire number were discussed. The larger the width of the landslide area, the gentler the deformation of the pipeline; this resulted in an increase in the maximum landslide and a decrease in the maximum curvature with the width of the landslide area. The relatively high internal pressure was beneficial to the safety of the SWW-RTP under landslide, because the internal pressure could increase the stiffness of the pipeline. The number of steel wires had a limited influence on the maximum landslide required for the SWW-RTP’s failure. This work can be useful for the design and safe assessment of the SWW-RTP under internal pressure and soil landslide conditions. Full article
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11 pages, 3443 KB  
Article
The Aging Performance of PVDF in Acid Oil and Gas Medium
by Guoquan Qi, Hongxia Yan, Dongtao Qi, Houbu Li and Zhao Zhang
Polymers 2022, 14(19), 4244; https://doi.org/10.3390/polym14194244 - 10 Oct 2022
Cited by 6 | Viewed by 3347
Abstract
In the process of transporting oil and gas, the service performance of thermoplastic pipes will decline due to the multiple influences of medium, temperature, and pressure. In order to study the service performance changes of PVDF pipes under oil and gas transportation conditions, [...] Read more.
In the process of transporting oil and gas, the service performance of thermoplastic pipes will decline due to the multiple influences of medium, temperature, and pressure. In order to study the service performance changes of PVDF pipes under oil and gas transportation conditions, the high-temperature autoclave is used to simulate the service state of the pipe in the mediums. The PVDF samples are exposed to simulated oil and gas mediums for 1 week, 3 weeks, 5 weeks, and 7 weeks under 60 °C and 90 °C conditions. After the exposure test, the physical and chemical properties of the PVDF pipe are tested and compared with the initial samples. Compared with the initial sample, the sample quality after the exposure test has a slight increase, with growth rates of 2% and 3% at 60 °C and 90 °C, respectively. Meanwhile, the tensile strength of the samples is about 13% and 21% lower than that of the initial sample, respectively. According to the microscopic morphology analyses, there are some crack defects on the surface of the sample after the exposure test. Through infrared analysis, it is shown that no molecular chain breakage, crosslinking, or other reactions are found after the exposure test. The above analysis shows that the PVDF sample has slight penetration and swelling during the exposure test. However, due to the large force between the PVDF molecules, its mechanical properties have a small downward trend, showing excellent environmental stress crack resistance. Full article
(This article belongs to the Special Issue Development of Functional Polymer Composites)
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12 pages, 4986 KB  
Article
Permeation Characteristics of CH4 in PVDF with Crude Oil-Containing
by Xuemin Zhang, Huifang Chu, Houbu Li, Guoquan Qi, Jinmao Feng, Xiong Gao and Wenhui Yang
Polymers 2022, 14(13), 2723; https://doi.org/10.3390/polym14132723 - 3 Jul 2022
Cited by 5 | Viewed by 2684
Abstract
The liner of reinforced thermoplastic composite pipes (RTPs) used for oil and gas gathering and transportation experienced blister failure due to gas permeation. Few reports have appeared on the problem of gas permeation in thermoplastics with absorbed crude oil. Accordingly, the permeability of [...] Read more.
The liner of reinforced thermoplastic composite pipes (RTPs) used for oil and gas gathering and transportation experienced blister failure due to gas permeation. Few reports have appeared on the problem of gas permeation in thermoplastics with absorbed crude oil. Accordingly, the permeability of CH4 in polyvinylidene fluoride (PVDF) containing crude oil was studied at the normal service conditions by molecular simulations. The results showed that the solubility coefficients of CH4 in PVDF containing crude oil were much lower than those in pure PVDF. It can be concluded that the crude oil molecules absorbed into PVDF occupied certain adsorption sites, resulting in a decrease in the adsorption capacity of CH4 molecules in PVDF. The diffusion coefficients of CH4 in oil-containing PVDF were significantly greater than in PVDF. This is because the absorption of oil molecules leads to the volume swelling of PVDF and then increases the free volume for diffusion. The permeation process showed that CH4 molecules were selective-aggregate adsorbed in the region with low potential energy in oil-containing PVDF firstly, and then they vibrated within the holes of PVDF containing oil in most cases and jumped into the neighboring holes at high temperatures and pressures. Full article
(This article belongs to the Special Issue Polymer Composites for Water Treatment)
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