Search Results (23)

This study employs a plasma-coupled calcium peroxide (CaO₂) system to degrade tetracycline (TC) and remove phosphorus from emergency wastewater in a chemical industry park. The plasma/CaO₂ system achieves optimal performance when the CaO₂ dosage reaches 0.13 g/L. Higher degradation efficiencies of TC were observed at increased discharge voltages, frequencies, and under weakly acidic and weakly alkaline conditions. Variations in discharge voltage and frequency have no significant impact on the phosphorus removal efficiency, but weakly alkaline conditions favor phosphorus removal. The reactive species (·OH, ¹O₂, O₂·⁻) within the plasma/CaO₂ system were identified, and their roles were elucidated using radical scavengers. Subsequently, the degradation process was characterized by measuring changes in total organic carbon (TOC), chemical oxygen demand (COD), and ammonia nitrogen during the reaction, along with three-dimensional fluorescence analysis and ultraviolet-visible spectroscopy (UV-Vis). Eight intermediate products were identified through LC-MS, and two degradation pathways were clarified based on density functional theory. The toxicity analysis of the intermediate products demonstrated that the plasma/CaO₂ system is an efficient, feasible, and environmentally friendly method for the synchronous removal of organic pollutants and phosphorus from emergency wastewater in a chemical industry park. Full article

Pore structure plays a critical role in evaluating shale “sweet spots”. Compared to marine shale, lacustrine shale has more diverse lithofacies types and greater heterogeneity in pore structure due to frequently changing environmental conditions. Using methods such as mercury intrusion porosimetry (MIP), field emission scanning electron microscopy (FE-SEM), nuclear magnetic resonance (NMR), and X-ray diffraction (XRD), this study investigates the micropore structures and heterogeneity of different lithofacies in the Jurassic Dongyuemiao Member lacustrine shale. Image processing and multifractal theory were employed to identify the controlling factors of pore structure heterogeneity. The key findings are as follows. (1) Based on mineral content and laminae types, the lithofacies types of Dongyuemiao lacustrine shale are classified into four types: shell–laminae mixed shale (SLMS), silty–laminae clay shale (SLCS), clast–laminae clay shale (CLCS), and clay shale (CS). (2) Based on genesis, shale reservoirs’ pore and permeability space are categorized into inorganic pores, organic pores, and micro-fractures. Inorganic pores consist of inter-particle pores and intra-particle pores. Pore size distribution curves for all four lithofacies exhibit two main peaks, with pore sizes concentrated in the ranges of 2–10 nm and 50–80 nm. Mesopores and macropores dominate, accounting for over 80% of the total pore volume. Mesopores are most developed in CLCS, representing 56.3%. (3) Quartz content is positively correlated with the multifractal dimension, while clay content shows a negative correlation. Higher quartz content, coupled with lower clay content, weakens pore structure heterogeneity. A negative correlation exists between total organic carbon (TOC) and the multifractal dimension, indicating that higher organic matter content enhances organic pore development and increases microscopic heterogeneity. (4) Porosity heterogeneity in SLMS is effectively characterized by D₀-D_max, while in the other three lithofacies, it is characterized by D_min-D₀. Permeability across all lithofacies correlates with D₀-D_max. In CS, SLMS, and SLCS, permeability is positively correlated with D₀-D_max, with higher values indicating greater permeability heterogeneity. In CLCS, permeability is negatively correlated with D₀-D_max, such that lower values reflect stronger heterogeneity. Full article

As the issue of global climate change becomes increasingly severe, governments worldwide have implemented carbon reduction policies, such as carbon taxes and industrial low-carbon transitions, to effectively control total carbon emissions. This study applies a multi-objective programming approach and uses the plastic raw material manufacturing process in the petrochemical industry as an example to explore how companies can balance profit maximization with minimizing production-related carbon emissions. By integrating Activity-Based Costing (ABC) and the Theory of Constraints (TOC), this study develops a production decision-making model and employs the ε-constraint method to impose carbon emission constraints, analyzing the resulting changes in corporate profitability. The model considers three different policy scenarios: basic carbon tax costs (including the use of renewable energy), continuous incremental progressive carbon tax costs, and discontinuous incremental progressive carbon tax costs. The results indicate that adopting renewable energy effectively reduces carbon emissions during production, while the discontinuous incremental carbon tax model provides better control over emissions. Under different carbon emission constraints, significant variations in optimal profits and production volumes are observed across the models, offering valuable insights for governments and enterprises in formulating carbon reduction strategies. Full article

The contradiction between ecological environment protection and economic development in the Yangtze River Basin has become increasingly prominent in recent years, which seriously limits the sustainable development of the basin. Research on water environment changes of the main tributaries of the Yangtze River helps explore measures to improve the ecological environment of the Yangtze River Basin. In this study, based on the theory of behavioral science in modern management, water quality data in the field were collected, and the farmers’ garbage stacking behavior was also investigated in the water source area of the Dabie Mountains. The results showed that ammonia nitrogen (AN), chemical oxygen demand (COD), total organic carbon (TOC), and total dissolved solids (TDS) in the water bodies showed an overall negative correlation with the distance of water quality collection sites from the garbage stacking point. AN was the most important pollution element affecting the rural water quality in the water source area of the Dabie Mountains. The unsuitable garbage stacking locations and the farmers’ behavior of dumping garbage along the riverbanks were the important causes of water pollution. The garbage stacking locations were optimized and designed by using a GIS spatial analysis tool and a developed suitability evaluation model for the garbage stacking points. The optimized garbage stacking locations were more suitable for improving the local water environment, and their average suitability values increased to 2.01 times and 2.94 times that of the original stacking locations in Kanxiawan and Lengshuigou, respectively. This study can be used as a scientific and methodological reference for improving the rural water environment in the water source area of the Dabie Mountains and in other similar regions in the world. Full article

Diabase intrusion is a common geological phenomenon in lacustrine shale formations in continental basins in China, which has important effects on the physical and chemical properties of shale oil reservoirs. In this paper, we systematically analyzed the pore structure of diabase-intruded lacustrine shale in the Gaoyou sag of the Subei Basin using geochemical tests, thin-section observation, argon ion polishing scanning electron microscopy (SEM), low-temperature nitrogen adsorption experiments (LTNA), and other methods combined with monofractal and multifractal theories. The results show that the intrusion metamorphic segments are a diabase zone, hornfels zone, slate zone, and normal shale zone from the intrusion center. The pores of hornfels and slate are mostly oriented and dissolution is obvious. Many microfractures and secondary minerals such as quartz and chlorite are observed. The pore volumes of diabase and hornfels are small, while those of slate and normal shale are larger. The monofractal dimensions D₁ and D₂ of the intrusion segment show a general trend of decreasing first and then increasing from the intrusion center to the shale zone. The multifractal parameters’ H index decreases gradually from the lower normal shale to the upper metamorphic zone hornfels, while Δα and Rd increase gradually. The total organic carbon (TOC) content of the intrusion zone has little effect on the pore structure, and the fractal characteristics fluctuate weakly, while the vitrinite reflectivity (R_o) value change has a significant impact on the monofractal characteristics of the shale pore. Pore volume also affects the pore heterogeneity; the larger the specific surface area (SSA) and total pore volume (TPV), the lower the pore heterogeneity and the higher the surface roughness and pore connectivity. The diabase intrusion caused three modification mechanisms of mechanical squeezing, the thermal effect, and chemical action on the shale surrounding rocks, resulting in different degrees of pore formation or change. The pore evolution model of the metamorphic belt with the combined action of “mechanical-thermal-chemical” is established, and the influence of diabase intrusion on the pore types and pore size distribution (PSD) of shale reservoirs is quantitatively described, providing a new perspective and method for understanding the impact of diabase intrusion on the characteristics and exploration potential of shale oil reservoirs. Full article

The pore structure and mineral characteristics affect the accumulation and migration of hydrocarbons in shale, which determines the production capacity of shale oil. In this study, shale samples from the Chang 7 member of the Ordos Basin in China were selected to investigate the pore space characteristics, the effect of hydrocarbon accumulation on pore heterogeneity, and the hydrocarbon migration changes based on fractal theory, and a series of experiments were conducted involving X-ray diffraction (XRD), total organic carbon (TOC), Soxhlet extraction, and low-temperature nitrogen (N₂) and carbon dioxide (CO₂) adsorption. Then, the factors affecting extraction efficiency in shale pores were discussed. The interparticle pores contributed most to the accumulation of shale oil, and the organic matter (OM) pores contributed positively to the adsorption of hydrocarbons. The accumulation of hydrocarbons in the pore space did not increase the heterogeneity of the shale pore structure. The contents, states, and positions of hydrocarbons changed during the extraction process. Hydrocarbons were redistributed on the pore surface after Soxhlet extraction, and the heterogeneity of hydrocarbon adsorption and pore surface roughness were improved. Some heavy hydrocarbons and adsorbed components were pyrolyzed, resulting in the gradual escape of the adsorbed layer in the large pores. However, the free oil in the small pores diffused to the large pores and reaggregated on the surface, restoring a stable adsorption layer. The extraction rate was closely related to the pore throat structure and the wettability of mineral surfaces. The configuration between pores and throats had a crucial influence on the extraction rate. A high proportion of meso-pores, which effectively connect micro- and macro-pores, had a higher diffusion efficiency and a higher extraction rate. The OM pores with high energy adsorption were located in the micro-pores, and the shale oil existed in a dissolved state with high mobile capacity. The wettability of mineral surfaces affected the adsorption behavior during extraction, and strong oil wetting promoted hydrocarbon re-adsorption in clay minerals, so that the volume of micro-pores was smaller after extraction. Full article

Cities are facing challenges in adaptation to, and mitigation of climate change. Urban Green Spaces (UGS) have a pivotal role in this transformative process and are almost always coupled with digital tools. The deployment of digital solutions, encompassing Information and Communication Technology (ICT) and the Internet of Things (IoT), seeks to increase awareness of UGS benefits across a wider range of users. This study is part of a Horizon 2020 project that aims to measure the social impact of Visionary Solutions (VS), i.e., combined Nature Based Solutions (NBSs) and Digital Solutions (DSs), in UGSs located in seven European cities. The project proposes a novel application of the Social Return on Investment (SROI) methodology to forecast the impact of VS implementation in the case of an Italian demonstration. The three main objectives are: (i) establishing a causal chain for transformation through the Theory of Change (ToC) tool; (ii) quantifying the expected change by developing two monetary alternatives; and (iii) comparing these alternatives to assess which is more influential in stakeholders’ decision-making. The authors reviewed a range of financial proxies of social outcomes from other SROI case studies. The result of the Italian demonstration is that, for each euro invested in project solutions, two euros of social return are generated. The analysis reveals these monetized intangible outcomes. Full article

This study investigated the influence of movable oil on the pore structure of various shale types, analyzing 19 shale samples from Well X in the Mahu Sag of the Junggar Basin. Initially, X-ray diffraction (XRD) analysis classified the shale samples. Subsequently, the geochemical properties and pore structures of the samples, both pre and post oil Soxhlet extraction, were comparatively analyzed through Total Organic Carbon (TOC) content measurement, Rock-Eval pyrolysis, and nitrogen adsorption experiments. Additionally, fractal theory quantitatively described the impact of movable oil on the pore structure of different shale types. Results indicated higher movable oil content in siliceous shale compared to calcareous shale. Oil extraction led to a significant increase in specific surface area and pore volume in all samples, particularly in siliceous shale. Calcareous shale predominantly displays H2–H3 type hysteresis loops, indicating a uniform pore structure with ink-bottle-shaped pores. Conversely, siliceous shale exhibited diverse hysteresis loops, reflecting its complex pore structure. The fractal dimension in calcareous shale correlated primarily with pore structure, exhibiting no significant correlation with TOC content before or after oil extraction. Conversely, the fractal dimension changes in siliceous shale samples do not have a clear correlation with either TOC content or pore structure, suggesting variations may result from both TOC and pore structure. Full article

To clarify the contribution of the bridging effect from three metal cations (K⁺, Mn²⁺, and Fe³⁺) on the humification of lignin-rich Tilia wood shavings and further enrich the theory of lignin humification, an indoor incubation method with constant temperature and humidity was adopted. K⁺, Mn²⁺, and Fe³⁺ served as additives, with CK as the control for studying the differential influence of metal cations with different valences on the humus composition of dark-brown soil mixed with Tilia wood shavings. The change in the C contents of water-soluble substance (C_WSS), humic-extracted acid (C_HE) and humin (C_Hu), ∆logK value of HE, atomic ratio and FTIR spectra of humic acid (HA), and the ratio of C content of humic acid to fulvic acid (C_HA/C_FA) of dark-brown soil mixed with Tilia wood shavings were analyzed after 0, 30, 80, and 150 days of incubation, and the following conclusions were reached: (1) The addition of metal cations, regardless of their valence, could effectively improve the microbial utilization and consumption of WSS, and the effect was as follows: Fe³⁺ > Mn²⁺ > K⁺. The addition of three metal cations could effectively inhibit mineralization and reduce the loss of TOC, and the effect could be seen as follows: Fe³⁺ > Mn²⁺ > K⁺. (2) Although the C_HE content first decreased and then increased with incubation, the addition of Fe³⁺ and Mn²⁺ ions increased the C_HE content, showing that Fe³⁺ > Mn²⁺, and K⁺ ions had no significant effect. Throughout the incubation, the structure of HE molecules changed first via a complex process and then through a simple process. Comparing the change before and after the incubation, the overall structure of HE molecules tended to be simpler with the CK control, and HE became more complicated with the addition of Fe³⁺ and Mn²⁺; however, the addition of K⁺ had little effect on the structure of HE molecules. (3) At the end of the incubation, the addition of Fe³⁺, Mn²⁺, and K⁺ ions strengthened the molecular condensation of HA and its aromatization degree, while the CK control without any added metal cations caused HA molecules to decompose and obtain a greater aliphatic degree. In addition, the number of O-containing functional groups and N-containing compounds in HA molecules increased to varying degrees regardless of which metal cation was added. The decomposition of Tilia wood chips led to a partial entry of the decomposition products into the HA component, which was then reconsumed by continuous mineralization. After incubation, the polysaccharides in HA molecules were consumed only with the addition of Mn²⁺ ions. Fe³⁺ and Mn²⁺ ions had greater advantages in increasing the C_HA/C_FA ratio and improving the humus quality than K⁺ ions. (4) The addition of metal cations could effectively inhibit the mineralization and decomposition of the Hu component, among which Fe³⁺ ions had the most significant effect, followed by Mn²⁺ ions. Compared to monovalent cations (K⁺), polyvalent cations (Fe³⁺ and Mn²⁺) had the advantage of a bridging effect, and their addition promoted the microbial utilization of WSS, effectively reduced the loss of TOC, increased the C_HE content, complicated its molecular structure, improved the humus quality, and inhibited the decomposition of Hu. Regardless of which metal cation was added, the degree of molecular polycondensation and aromatization of HA was enhanced, and the number of O-functional groups and N-containing compounds in HA molecules increased. Full article

The United States Department of Agriculture’s Gus Schumacher Nutrition Incentive Program (GusNIP) supports nutrition incentive (NI) and produce prescription programs (PPRs). PPRs allow healthcare providers to “prescribe” fruits and vegetables (FVs) to patients experiencing low income and/or chronic disease(s) and who screen positive for food insecurity. We developed a Theory of Change (TOC) that summarizes how and why PPRs work, identifies what the programs hope to achieve, and elucidates the causal pathways necessary to achieve their goals. We created the PPR TOC through an iterative, participatory process that adapted our previously developed GusNIP NI TOC. The participatory process involved food and nutrition security experts, healthcare providers, PPR implementors, and PPR evaluators reviewing the existing NI TOC and suggesting modifications to accurately reflect PPRs. The resulting TOC describes the mechanisms, assumptions, rationale, and underpinnings that lead to successful and equitable outcomes. Modifications of the NI TOC centered around equity and focused on inclusion of healthcare as an additional partner and the importance of health and healthcare utilization as outcomes. The TOC describes how the GusNIP PPR program reaches its goals. This understanding will be useful for PPR developers, implementers, funders, and evaluators for describing the pathways, assumptions, and foundations of successful PPRs. Full article

South Africa is a water-stressed country with significant water management challenges. In response, progressive and advanced water management policy and legislation have been developed that include the regulation of water uses through a water use license application (WULA) system. In recent years, the effective functioning of the WULA system has come under increased scrutiny. However, a comprehensive systematic evaluation of the effectiveness of the WULA system has not yet been conducted. This paper aims to identify key risks to the effectiveness of the WULA system in South Africa through the application of a theory of change (ToC) methodology. Workshops with more than 60 participants were held with different stakeholder groups. Ultimately, a total of 21 key risks to the effectiveness of the WULA system were identified. The results suggest that various risks have already been realized and that the WULA system is not functioning as intended and is not achieving its outcomes. It is recommended that the identified key risks provide the basis for a comprehensive system evaluation to inform a more effective WULA system design. Full article

In this study, we aimed to develop a theoretical framework for a multimodal, integrative, exercise, anti-inflammatory and dietary counselling (MMIEAD) intervention for patients with renal cachexia with reference to how this addresses the underlying causal pathways for renal cachexia, the outcomes anticipated, and how these will be evaluated. We used a Theory of Change (ToC) approach to guide six steps. Step 1 included inputs from a workshop to obtain key stakeholder views on the potential development of a multimodal intervention for renal cachexia. Step 2 included the findings of a mixed-methods study with Health Care Practitioners (HCPs) caring for individuals with End Stage Kidney Disease (ESKD) and cachexia. Step 3 included the results from our systematic literature review on multimodal interventions for cachexia management. In step 4, we used the body of our research team’s cachexia research and wider relevant research to gather evidence on the specific components of the multimodal intervention with reference to how this addresses the underlying causal pathways for renal cachexia. In steps 5 and 6 we developed and refined the ToC map in consultation with the core research team and key stakeholders which illustrates how the intervention components of MMIEAD interact to achieve the intended long-term outcomes and anticipated impact. The results of this study provide a theoretical framework for the forthcoming MMIEAD intervention for those with renal cachexia and in subsequent phases will be used to determine whether this intervention is effective. To the best of our knowledge no other multimodal intervention trials for cachexia management have reported a ToC. Therefore, this research may provide a useful framework and contribute to the ongoing development of interventions for cachexia management. Full article

Increased fruit and vegetable (FV) intake is associated with decreased risk of nutrition-related chronic diseases. Sociodemographic disparities in FV intake indicate the need for strategies that promote equitable access to FVs. The United States Department of Agriculture’s Gus Schumacher Nutrition Incentive Program (GusNIP) supports state and local programs that offer nutrition incentives (NIs) that subsidize purchase of FVs for people participating in the Supplemental Nutrition Assistance Program (SNAP). While a growing body of research indicates NIs are effective, the pathways through which GusNIP achieves its results have not been adequately described. We used an equity-focused, participatory process to develop a retrospective Theory of Change (TOC) to address this gap. We reviewed key program documents; conducted a targeted NI literature review; and engaged GusNIP partners, practitioners, and participants through interviews, workshops, and focus groups in TOC development. The resulting TOC describes how GusNIP achieves its long-term outcomes of increased participant FV purchases and intake and food security and community economic benefits. GusNIP provides NIs and promotes their use, helps local food retailers develop the capacity to sell FVs and accept NIs in accessible and welcoming venues, and supports local farmers to supply FVs to food retailers. The TOC is a framework for understanding how GusNIP works and a tool for improving and expanding the program. Full article

The relevance of the circular economy for climate change is still a developing area of research that needs to be explored. This paper aims to provide an overview of the relevance of the circular economy for climate change through the theory of change approach framework. For this purpose, we analysed 96 articles from the Scopus and WoS databases in the “Arts and Humanities, Business, Management and Accounting, Economics, Econometrics and Finance and Social Sciences,” with the keywords “Circular economy” and “Climate Change”. Our analysis shows that 87% of the reviewed articles showed a strong relevance of the circular economy for climate change. However, most of the articles focused on the mitigation aspect of climate change. The circular economy is widely practised in countries such as the United Kingdom, Italy, Belgium, and China. Our main theoretical contribution is in developing a logical framework through the theory of change, which is a novel approach in social science research apart from monitoring and evaluation studies. Full article

Digitalization is widely recognized as a transformative power for sustainable development. Careful alignment of progress made by digitalization with the globally acknowledged Sustainable Development Goals (SDGs) is crucial for inclusive and holistic sustainable development in the digital era. However, limited reference has been made in SDGs about harnessing the opportunities offered by digitalization capabilities. Moreover, research on inhibiting or enabling effects of digitalization considering its multi-faceted interlinkages with the SDGs and their targets is fragmented. There are only limited instances in the literature examining and categorizing the impact of digitalization on sustainable development. To overcome this gap, this paper introduces a new Digitainability Assessment Framework (DAF) for context-aware practical assessment of the impact of the digitalization intervention on the SDGs. The DAF facilitates in-depth assessment of the many diverse technical, social, ethical, and environmental aspects of a digital intervention by systematically examining its impact on the SDG indicators. Our approach draws on and adapts concepts of the Theory of Change (ToC). The DAF should support developers, users as well policymakers by providing a 360-degree perspective on the impact of digital services or products, as well as providing hints for its possible improvement. We demonstrate the application of the DAF with the three test case studies illustrating how it supports in providing a holistic view of the relation between digitalization and SDGs. Full article