Search Results (8)

Superaustenitic stainless steels (SASSs) are one of the families of high-performance stainless steels, the so-called “super” grades. While sharing the face-centered cubic lattice structure typical of standard austenitic stainless steels, their chemical composition is significantly more complex. This enables them to offer an exceptional balance of superior corrosion resistance and high mechanical strength. However, the intricate chemical makeup of SASSs brings challenges, such as the phenomenon of segregation and precipitation of deleterious intermetallics. Consequently, this leads to several challenges in their processing and use. This work aims to present SASSs in detail, starting from their chemistry and metallurgy and ending with processing and applications. Hence, the first part will be dedicated to the analysis of chemistry, resulting grades, microstructure and secondary phases along with the conditions determining their formation. Afterwards, physical, mechanical and corrosion resistance characteristics will be set forth in such a way as to understand their origin and implications for processing and possible uses, with a focus on processability limitations. In fact, manufacturing and processing options significantly affect the types of products that can be developed, and, when considered alongside material attributes and costs, they help define the target markets for these alloys. Full article

The increasing demand for lightweight, high-performance materials in marine and offshore engineering has driven the development of hybrid solutions combining metals and composites. This study investigates the stress corrosion cracking (SCC) and tribocorrosion behaviour of a novel hybrid wire consisting of a superaustenitic stainless steel (6Mo) outer shell and a carbon fibre-reinforced polymer (CFRP) core. Microstructural analysis, residual stress measurement, and corrosion testing were performed to assess the integrity of the welded structure under harsh conditions. The results revealed that residual stresses and interdendritic segregation in the weld zone significantly contribute to SCC susceptibility, while the 6Mo steel showed improved corrosion resistance over 316L under tribocorrosion conditions but was more sensitive to the sliding frequency. These findings provide critical insights into the degradation mechanisms of metal composite hybrid wires and support the future design of corrosion-resistant components for offshore and structural applications. Full article

In situ X-ray diffraction has been used to investigate the stability of expanded austenite during annealing in vacuum for the austenitic stainless steel 316Ti, the super-austenitic stainless steel 904L, and the duplex steel 318LN. Expanded austenite has been formed using plasma immersion ion nitriding before. Time-of-flight secondary ion mass spectrometry before and after annealing yielded complementary information regarding nitrogen depth profiles and CrN precipitation using cluster analysis. The decay of expanded austenite during annealing was found to be thermally activated with an activation energy of 1.8 ± 0.3 eV, starting within five minutes at 550 °C and taking more than two hours below 450 °C. The decay occurs simultaneously throughout the whole nitrogen-containing zone—and not at the surface as during nitriding. Nitrogen diffusion occurring in parallel slightly complicates the data analysis. Further transmission electron microscopy investigations are necessary to understand the microstructure after annealing in vacuum. The limit for operating hard and wear-resistant expanded austenite layers at elevated temperatures of up to 350 °C is given, however, by nitrogen diffusion and not the decay into CrN. Full article

The cross-roll piercing and elongation (CPE) is a forming process performed at high temperatures and high strain rates. The final product quality is strongly dependent on its microstructure. In this study, a finite element method (FEM) model was developed to better understand plastic deformation effects on microstructure during CPE and to analyze alternative thermo-mechanical processing routes. Specific models were used to simulate dynamic and meta-dynamic recrystallization (DRX and MDRX) for the processing of superaustenitic stainless steel (SASS). In addition, the CPE of SASS was investigated experimentally. The microstructure, mechanical properties, and chemical changes of the final product were assessed using optical microscopy, hardness testing, X-ray diffraction, and SEM-EDS. The results revealed higher temperatures and strain rates in the exterior area of the shell after piercing, and MDRX occurred in the whole thickness. However, an average grain size reduction of 13.9% occurred only in the shell middle and inner diameters. During elongation, the highest values of the strain rate and DRX were observed in the inner region, exhibiting a grain size reduction of 38%. Spread in terms of grain size and grain shape anisotropy was found to be less accentuated for tube samples as compared to the pierced shells. Full article

Strain-induced precipitation (SIP) behaviors of 7Mo super-austenitic stainless steel (SASS) under various deformation conditions were studied by stress relaxation tests. The research demonstrates that sigma phases are the primary SIP phases of 7Mo SASS. Generally, SIP is mainly distributed in granular shape at the boundaries of deformed grains or recrystallized grains, as well as around the deformed microstructure, such as deformation twin layers/matrix interfaces. The variation of deformation parameters can lead to changes in microstructure, therefore influencing the distribution of SIP. For instance, with the temperature increases, the SIP distribution gradually evolves from deformed grain boundaries to recrystallized grain boundaries. The average size of SIP increases with increasing temperature and strain, as well as decreasing strain rate. The SIP content also increases with increasing strain and decreasing strain rate, while exhibiting an initial rise followed by a decline with increasing temperature, reaching its maximum value at 850 °C. The presence of SIP can promote recrystallization by particle-induced nucleation (PSN) mechanism during the hot deformation process. Moreover, the boundaries of these recrystallized grains can also serve as nucleation sites for SIP, therefore promoting SIP. This process can be simplified as $\mathrm{S}\mathrm{I}\mathrm{P}\stackrel{\mathrm{P}\mathrm{S}\mathrm{N}}{\to }\mathrm{R}\mathrm{e}\mathrm{c}\mathrm{r}\mathrm{y}\mathrm{s}\mathrm{t}\mathrm{a}\mathrm{l}\mathrm{l}\mathrm{i}\mathrm{z}\mathrm{a}\mathrm{t}\mathrm{i}\mathrm{o}\mathrm{n}\stackrel{\mathrm{N}\mathrm{u}\mathrm{c}\mathrm{l}\mathrm{e}\mathrm{a}\mathrm{t}\mathrm{i}\mathrm{o}\mathrm{n} \mathrm{s}\mathrm{i}\mathrm{t}\mathrm{e}\mathrm{s}}{\to }\mathrm{S}\mathrm{I}\mathrm{P}$. With the increase in holding time and the consumption of stored energy, the process gradually slows down, leading to the formation of a multi-layer structure, namely SIPs/Recrystallized grains/SIPs structure. Moreover, SIP at recrystallized grain boundaries can hinder the growth of recrystallized grains. Through this study, a comprehensive understanding of the SIP behaviors in 7Mo SASS under different deformation conditions has been achieved, as well as the interaction between SIP and recrystallization. This finding provides valuable insights for effective control or regulation of SIP and optimizing the hot working processes of 7Mo SASS. Full article

AISI 904L is a super-austenitic stainless steel that is remarkable for its mechanical properties and high corrosion resistance, which strictly depend on its chemical composition and microstructural features. The recrystallization process and grain growth phenomena play key roles in achieving high levels of material quality, as often requested by customers for specific applications. In this paper, the evolution of the microstructure and hardness values after cold rolling and subsequent annealing is reported, with the aim of optimizing the thermomechanical treatment conditions and improving the efficiency of the production process. The investigation was focused on three different cold reduction ratios (50%, 70% and 80%), while combining different annealing temperatures (950, 1050 and 1150 °C) and soaking times (in the range of 20–180 s. The test results were organized using a data analysis and statistical tool, which was able to show the correlation between the different variables and the impacts of these on recrystallization and grain growth processes. For low treatment temperatures, the tested soaking times led to partial recrystallization, making this condition industrially unattractive. Instead, for the higher temperature, full recrystallization was achieved over a short time (20–40 s), depending on the reduction ratio. Regarding the grain growth behavior, it was found to be independent of the reduction ratio; for each treatment temperature, the grain growth showed a linear trend as a function of the soaking time only. Moreover, the static recrystallization kinetics were analyzed using a statistical analysis software program that was able to provide evidence indicating the most and least influential parameters in the process. In particular, taking into consideration the hardness values as output data, the temperature and soaking time were revealed to have major effects as compared with the reduction ratio, which was excluded from the statistical analysis. The prediction approach allowed us to formulate a regression equation in order to correlate the response and terms. Moreover, a response optimizer was used to predict the best solution to get as close as possible to the hardness target required by the market. Full article

The properties of a cobalt-free cast superaustenitic stainless steel (SASS) is investigated comparatively to the commercial high-cobalt alloyed GX15CrNiCo21-20-20 (1.4957, N-155) steel regarding its global hardness and wear resistance at elevated temperature by means of in situ hot hardness tests and cyclic abrasive sliding wear tests against an Al₂O₃ (corundum) counter-body at 600 °C. In the aged condition, results show that the 1.4957 steel suffers a higher material loss due to brittle failure initiated by coarse eutectic Cr-rich carbides which are incorporated into a mechanically mixed layer during abrasive loading. In contrast, within the Co-free steel eutectic M₆(C,N) carbonitrides are distributed more homogeneously showing less tendency to form network structures. Due to the combination of primary Nb-rich globular-blocky MX-type carbonitrides and eutectic M₆(C,N) carbonitrides dispersed within an Laves phase strengthened austenitic matrix, this steel provides comparable hardness and significantly improved wear resistance at elevated temperature. Thus, it may be an adequate alternative material to commercial SASS and offers the possibility to save cobalt for future applications. Full article

The hot deformation behavior of a Fe–22Cr–25Ni–3.5W–3Cu–1.5Co super-austenitic stainless steel was investigated using isothermal compression tests with a wide range of temperatures (1173–1373 K) and strain rates (0.1–10 s−1). The results showed that all the flow curves gradually turned to balanced stress state without notable peak stress characteristics during the entire deformation, which indicated that the dynamic recovery behavior played a main restoration mechanism in the steel. Modeling constitutive equations relating to the temperature, strain rate and flow stress were proposed to determine the materials constants and activation energy necessary for deformation. In order to give the precise predicted values of the flow behavior, the influence of strain was identified using polynomial functions. The relationship of flow stress, temperature and strain rate was represented by the Zener-Hollomon parameter including the Arrhenius term. The predicted results validated that the developed constitutive equations can describe high temperature flow behavior well. Furthermore, a modified Zener-Hollomon parameter map of the studied steel was developed to clarify the restoration mechanism based on the constitutive modeling data and microstructural observation. Full article