Search Results (75)

Submarine groundwater discharge (SGD) is an important pathway of dissolved matter transport to coastal ecosystems, yet its identification in methane seep environments remains challenging because chemical signals are modified by sedimentary biogeochemical processes. This study evaluated hydrochemical tracers of SGD in methane seep sites, bacterial mat areas, and background sediments along the southern coast of Crimea (Black Sea). The studied settings exhibited distinct water chemical characteristics. Chloride concentrations decreased from 10.6 to 11.2 g L⁻¹ in background waters, to 8.7–9.3 g L⁻¹ in bacterial mat pore waters and to 7.7 g L⁻¹ in sediment–water interface waters, indicating the presence of a low-salinity water component. Dissolved silica increased by approximately one order of magnitude relative to background values at methane-associated sites. Methane concentrations ranged from 0.025 to 1058 μM, with the highest values occurring in bacterial mat areas. These zones were further characterized by sulfate depletion (down to 0.9 g L⁻¹), elevated normalized alkalinity, ammonium concentrations reaching 8000 μg L⁻¹, high sulfide contents, and low dissolved Fe concentrations consistent with iron sulfide precipitation. The results demonstrate that no single hydrochemical parameter is sufficient to identify SGD in methane-affected coastal sediments. Instead, the combined use of conservative tracers (Cl⁻ and DSi) and reactive constituents (SO₄²⁻, alkalinity, NH₄⁺, HS⁻, TDFe, and Mn²⁺) provides a robust hydrochemical framework for recognizing groundwater influence and evaluating associated biogeochemical transformations. Full article

Although recent studies have significantly improved our understanding of submerged landscapes along the karstified eastern Adriatic coast, many aspects of their evolution and response to post-glacial relative sea-level rise remain poorly understood. Thus, the present study offers new insights into the Late Quaternary paleoenvironmental history of Pirovac Bay, a submerged coastal karst basin in the central Adriatic, by integrating high-resolution seismic data with chronologically constrained sediment cores. The results revealed the existence of two morphologically distinct karst depressions that provided accommodation space for the formation of diverse depositional environments. The Late Glacial and Holocene sedimentary succession documents an evolution from subaerial and fluvially influenced settings to lacustrine and ultimately fully marine environmental conditions. The identified fluvio-karst valley highlights the largely unexplored role of fluvio-karst processes in the development of coastal karst basins, while the discovered Pirovac paleolake is the youngest submerged Holocene lake known along the eastern Adriatic coast. The present-day embayment appears to be characterized by erosional processes and active submarine groundwater discharge, reflecting highly dynamic hydrological conditions. These findings contribute to a better understanding of the interactions between karstification, sea-level rise, sedimentary processes, and groundwater dynamics in coastal karst basins. They also provide an important framework for future paleoenvironmental and hydrogeological investigations along the eastern Adriatic coast. Full article

Submarine groundwater discharge (SGD) is an important pathway for water and solute exchange between coastal aquifers and the ocean, but its spatial detection remains challenging because field methods have limited coverage and remotely sensed anomalies may also reflect other coastal processes. This study developed a hydrodynamically constrained remote sensing framework for SGD identification by integrating optical and thermal indicators with hydrogeological constraints. Sentinel-2 imagery was used to derive the Normalized Difference Chlorophyll Index (NDCI) and Normalized Difference Turbidity Index (NDTI), while Landsat thermal data were used to quantify seasonal sea surface temperature variability using the 90th–10th percentile amplitude. These indicators were combined in a K-means clustering framework, and the classification results were further constrained using year-specific maximum offshore distances estimated from groundwater level observations with a Dupuit–Glover-based scaling approach and hydraulic time-lag correction. Applied to the north shore of Long Island, New York, the framework identified coherent nearshore SGD patches that were broadly consistent with field observation locations and showed both temporally persistent discharge zones and interannual variability in spatial extent. These results indicate that incorporating physically based constraints can improve the robustness and interpretability of remote sensing-based SGD detection. Full article

Unconfined coastal karst aquifers are highly susceptible to contamination from anthropogenic activities, particularly in regions lacking adequate wastewater treatment. Their open hydrological structure facilitates the input and dispersion of contaminants from both point and non-point sources. Furthermore, groundwater exerts a significant influence on coastal water quality through submarine discharge that could impact vulnerable ecosystems like seagrasses, mangroves, and coral reefs. Seasonal hydrological variability—especially between dry and rainy periods—affects contaminant transport, with increased groundwater flux potentially enhancing spatial dispersion. Additionally, the balance between the contributions from the coastal karst aquifer and the hydrodynamics of the coastal zone determines the extent and degree of salinization occurring at the interface between these two systems, which in turn influences aquifer water quality. This study presents a five-year dataset of metal and nutrient concentrations measured during dry and rainy seasons in surface waters (0.5 m depth) from 24 cenotes within the Ring of Cenotes (RC), Yucatán Peninsula, Mexico. The RC functions as a preferential groundwater flow path from inland to the coast via underwater conduits and submarine groundwater discharge (SGD), transporting contaminants present in groundwater into highly vulnerable coastal ecosystems. While most parameters remained below regulatory thresholds, concentrations of total Al, Cr, Pb, and N-NH₃ exceeded limits established by NOM-127-SSA1-2021 at several sites measured within the RC. Spatial heterogeneity was observed across seasons and years, driven by groundwater flux dynamics, land use, and individual sinkhole characteristics. Notably, N-NH₃ concentrations were higher during the dry season, particularly near agricultural and peri-urban zones. These findings underscore the need for mandatory wastewater treatment and integrated coastal karstic aquifer management to protect the region’s sole freshwater resource and the vulnerable ecosystems in the coastal area. Full article

Mixing zones in carbonate coastal aquifers are dynamic interfaces where freshwater and seawater converge, triggering complex biogeochemical processes. This study investigates diagenetic barite (BaSO₄) precipitation within such a mixing zone in the dolomitic aquifer of the Sierra de Gádor (SE Spain). Three sectors were analyzed: two active mixing zones—one associated with submarine discharge and the other affected by marine intrusion—and an uplifted, fossilized Pleistocene mixing zone. Mineralogical, petrographic, and geochemical analyses reveal extensive dissolution of the dolomitic bedrock, forming polygonal voids and fracture-controlled porosity, frequently covered by Fe and Mn oxides. Barite crystals were identified exclusively in the Fe oxide precipitates at depths where 80% of seawater is reached. The saturation index for barite in groundwater suggests near-equilibrium conditions across the fresh–brackish–saline transition; however, barite precipitation is localized where Fe oxides act as a geochemical barrier, concentrating Ba and enabling nucleation. SEM imaging shows well-formed euhedral barite crystals up to 100 µm in size. This form of crystallization would be similar to the marine diagenetic barite formation models involving organic matter degradation and Ba remobilization, translated to a coastal aquifer setting in this study. Trace metal analyses show significant enrichment of Pb (up to 20 wt%) and other elements (Zn, Ni, and Co), suggesting potential for ore-forming processes if redox conditions shift. This work proposes a conceptual model for diagenetic barite formation in coastal aquifers, emphasizing the role of Fe and Mn oxides as reactive substrates in metal cycling at the land–sea interface. Full article

The objective of this study is to detect the locations of submarine groundwater discharge (SGD) in the coastal area of the El Jebha region, located in northwestern Morocco. It is hypothesized that this zone is fed by one of the most rain-rich karstic aquifers in Morocco (the Dorsale Calcaire). The region’s geology is complex, characterized by multiple faults and fractures. Thermal remote sensing is used in this study to locate potential SGD zones, as groundwater emerging from karst systems is typically cooler than surrounding ocean water. Landsat satellite imagery was used to assess temperature variations and detect anomalies associated with the presence of freshwater in the marine environment. El Jebha’s geographical location, with a direct interface between limestone and sea, makes it an ideal site for the appearance of submarine groundwater discharges. This study constitutes the first use of Landsat-8/9 thermal-infrared imagery, processed with a multi-temporal fuzzy-overlay method, to detect SGD. Out of 107 Landsat scenes reviewed, 16 cloud-free images were selected. The workflow identified 18 persistent cold anomalies, of which three were classified as high-probability SGD zones based on recurrence and spatial consistency. The results highlight several potential SGD zones, confirming the cost-effectiveness of thermal remote sensing in mapping thermal anomalies and opening up new perspectives for the study of SGD in Morocco, where these phenomena remain rarely documented. Full article

Pockmarks are globally distributed geomorphic features exhibiting diverse morphologies. Their geometric characteristics are commonly quantified by the radius-to-depth ratio. The evolutionary process of these features typically follows a cyclical pattern comprising initiation, expansion, stabilization, and decline. Submarine groundwater discharge (SGD), a seasonally modulated land–sea exchange process, exerts a significant influence on the formation and evolution of pockmarks. This influence is mediated through hydrodynamic forcing effects, sediment redistribution, and coupled chemical–biological interactions. This review systematically examines the formation mechanisms, evolutionary patterns, and primary controlling factors of pockmarks induced by SGD. It integrates recent research developments and global case studies to elucidate the dynamic interplay of multiple influencing factors. This study emphasizes the significance of interdisciplinary approaches in marine geological research and identifies key areas for future investigation. These insights aim to enhance risk assessment frameworks for marine hazards and inform marine spatial planning strategies. Full article

Natural radioactivity was measured and analyzed at the Nice Slope for over a month using radon daughters in order to trace groundwater movement from a coastal aquifer to a nearshore continental shelf. Such groundwater movement may have resulted in submarine groundwater discharge (SGD) and potentially sediment weakening and slope failure. The relationship among major hydrological parameters (precipitation, Var discharge, groundwater level, salinity and water origin) in the area is demonstrated in this study. Time series analyses also helped to detect tidal fluctuations in freshwater input, highlighting the crucial role SGD plays in the slope stability of the still failure-prone Nice Slope, parts of which collapsed in a tsunamigenic submarine landslide in 1979. Earlier deployments of the underwater mass spectrometer KATERINA showed that SGD is limited to the region of the 1979 landslide scar, suggesting that the spatially heterogenous lithologies do not support widespread groundwater charging. The calculated volumetric activities from groundwater tracing isotopes revealed peaks up to ca. 150 counts ²¹⁴Bi, which is similar to those measured at other prominent SGD sites along the Mediterranean shoreline. Therefore, this rare long-term radioisotope dataset is a valuable contribution to the collaborative research at the Nice Slope and may not remain restricted to the unconfined landslide scar but may charge permeable sub-bottom areas nearby. Hence, it has to be taken into account for further slope stability studies. Full article

This study combines field and laboratory analyses from seven shallow wells (ZK1 to ZK7) positioned perpendicular to the coastline to investigate groundwater discharge and dynamics in the coastal unconfined aquifer of the intertidal zone at Yazhou Bay, Sanya, Hainan Province. The research highlights spatial variations in N₂O concentration, temperature, electrical conductivity (EC), pH, and the distribution of CFCs and CCl₄ in shallow groundwater, utilizing samples from wells ZK1 to ZK7 and seawater collected near ZK1. Key findings indicate that groundwater temperature decreases toward the ocean, while EC exhibits a stepwise increase from land to sea, with a sharp transition near ZK3 marking the freshwater–saltwater mixing zone. pH values are lowest in ZK3 and ZK4, gradually rising both inland and seaward. N₂O concentrations in the shallow wells (ZK1–ZK7) are divided into two distinct groups: higher concentrations (9.69–57.77 nmol/kg) in ZK5–ZK7 and lower concentrations (6.63–23.03 nmol/kg) in ZK1–ZK4. Wells ZK3 and ZK4 show minimal variation in CFC-11 and CFC-113 concentrations, suggesting they represent a transition zone that likely delineates groundwater flow paths. In contrast, significant concentration differences in wells ZK5–ZK7 (north) and ZK1–ZK2 (south) reflect the influence of aquifer structure variability, recharge sources, and local hydrogeochemical conditions. CFC-12 concentrations exhibit a clear freshwater–saltwater mixing gradient between ZK3 and ZK1, with higher concentrations in freshwater-dominated areas (ZK3–ZK7) and lower concentrations near seawater (ZK1). CCl₄ concentrations at ZK7 and ZK3 differ markedly from other wells, indicating unique hydrogeochemical conditions or localized anthropogenic influences. A model for the formation of upper saline plumes (USP) under tidal forcing at the low tidal line was established previously. Here, we establish a new model that accounts for the absence of USP driven by hydrological processes influenced by artificial sandy beach topography, and a fresh groundwater wedge is identified, which can serve as a significant fast-flow pathway for terrestrial water and nutrients to the ocean. Full article

The number of studies on submarine groundwater discharge (SGD) and the evidence of its significance in biogeochemical cycling and potential impacts on the chemical and ecological status of coastal waters is increasing globally. Here, we briefly present SGD studies from the Baltic Sea identified along the coastlines of Denmark, Finland, Germany, Poland, Sweden and Russia in the southwestern, southern and north–northeastern parts of the Baltic Sea. We introduce a digital SGD map viewer and information platform enabling easy overview and access to information on identified SGD sites in the coastal areas of the Baltic Sea. SGDs potentially transport critical pollutants from urban and agricultural areas on land to the marine environment. The pollutants include nutrients, dissolved organic and inorganic carbon, metals, pharmaceuticals, and other emerging contaminants, potentially harming marine ecosystems and biodiversity and possibly contributing to the poor chemical or ecological status of coastal waters, affecting human and environmental health. We focus on case studies from Finland, Germany, Poland and Denmark that include the results and interpretations from the applied geochemical, geophysical and geological methods, as well as bionic autonomous underwater vehicles (AUVs) for locating, investigating, modelling and visualizing SGD sites in 2D and 3D. The potential Pan-European or even global SGD information platform established within the European Geological Data Infrastructure (EGDI) enables the easy combination and comparison of map layers such as seabed sediment types and coastal habitats. The EGDI map viewer provides easy access to information from SGD studies and may serve as an entry point to relevant information on SGDs, including contents of pollutants, for the scientific community and policy-makers. The information potentially includes the results of model simulations, data from near real-time sensors at permanently installed monitoring stations and surveys in time and space conducted by AUVs. The presented digital SGD information platform is particularly pertinent to the UN Sustainable Development Goal (SDG) No. 14, which focuses on the conservation and sustainable use of oceans and marine resources. Full article

Submarine groundwater discharge (SGD) refers to the flow of groundwater that enters seawater through the seabed surface at the edge of the coastal shelf. During this discharge process, seepage and initiation can easily trigger seabed instability, which significantly influences the breeding, occurrence, and evolution of marine geological events. The narrow distribution of land near the coastline and the substantial flux of groundwater discharge are closely associated with typical seabed geological events, such as submarine landslides and collapse pits, which are prevalent in the sea area. This paper analyzes the current research status of SGD both domestically and internationally, elucidates the interaction mechanisms between groundwater discharge and the seabed, and integrates existing studies on discharge-induced slope instability, collapse pit formation, and seabed erosion and resuspension. It summarizes and evaluates the existing research on the influence of seabed groundwater discharge on the evolution of seabed geological structures, identifies key scientific problems that urgently need to be addressed, and proposes future research directions that require further emphasis. Additionally, the paper conducts research on the mechanisms by which groundwater discharge affects seabed stability, providing valuable insights for the study of coastal zones in China. It also offers a scientific basis for enhancing the understanding of the generation mechanisms of marine geological events and improving the technological capabilities for their prevention and control. Full article

Coral reefs experience numerous natural and anthropogenic environmental gradients that alter biophysical conditions and affect biodiversity. While many studies have focused on drivers of reef biodiversity using traditional diversity metrics (e.g., species richness, diversity, evenness), less is known about how environmental variability may influence functional diversity. In this study, we tested the impact of submarine groundwater discharge (SGD) on taxonomic and functional diversity metrics in Mo‘orea, French Polynesia. SGD is the expulsion of terrestrial fresh or recirculated seawater into marine environments and is associated with reduced temperatures, pH, and salinity and elevated nutrient levels. Using a regression approach along the SGD gradient, we found that taxon and functional-entity richness displayed unimodal relationships to SGD parameters, primarily nitrate + nitrite and phosphate variability, with peak richness at moderate SGD for stony coral and the full benthic community. Macroalgae showed this unimodal pattern for functional-entity but not taxonomic richness. Functional community composition (presence and abundance of functional entities) increased along the gradient, while taxonomic composition showed a nonlinear relationship to SGD-related parameters. SGD is a common feature of many coastal ecosystems globally and therefore may be more important to structuring benthic functional diversity than previously thought. Further, studying community shifts through a functional-trait lens may provide important insights into the roles of community functions on ecosystem processes and stability, leading to improved management strategies. Full article

Aquifer storage and recovery have gained attention as a solution that utilizes submarine groundwater discharge (SGD) as a surrogate water resource to alleviate water scarcity and fill the demand gap. Characterizing SGD is crucial for using coastal groundwater and improving understanding of the interaction between continental water and seawater. This study employs fiber-optical distributed temperature sensing (FODTS) and the heat tracer to quantify the groundwater flux in a coastal aquifer in northern Taiwan. The fluxes in different sections along the borehole were estimated from the temperature response caused by the active heating tests and campier groundwater flux under different tidal conditions, providing information on potential water resources for water resource planning and management. According to the active heating tests, the material of the sections with high-temperature response mainly consists of a gravel–sand mixture. Based on the estimations of groundwater fluxes along the well, the sections with low sensitivity of temperature response have low hydraulic conductivity and low groundwater flux. The estimated thermal parameters at the site are consistent with those obtained from the borehole samples in the laboratory tests. The groundwater fluxes in different sections are calculated based on the temperature response observed from the FODTS. The groundwater fluxes along the well vary between 0.02 and 1.77 m/day. There are considerable differences between the estimated fluxes during the tidal cycle in a heterogeneous coastal aquifer, indicating the high uncertainty of estimated SGD along coastlines. Full article

Laboratory-scale experiments were conducted on Carboniferous Limestone gravels from the Mendip Hills area, England; sandstones from the Pirambóia and Botucatu formations, Paraná sedimentary basin, Brazil; samples of schist and quartzite from Caldas Novas Hydrothermal Complex, Brazil; and the minerals tantalite, cassiterite, and columbite from mining areas at Rio Grande do Norte State, Brazil, with the purpose of evaluating the release of ²²²Rn to the water phase. The specific surface area of the samples corresponded to 1.69–81.36 cm²g⁻¹, which provided values of 0.001–1.68 dpm/g and 3.18 × 10⁻⁶ to 0.59 for the radon released and radon emanation coefficient, respectively. These results allowed us to calculate the radon flux with respect to the radon leakage, which corresponded to values of 0.00016–0.00158 Bq/m²/d for the denser materials and 0.018–0.43 Bq/m²/d for limestones and sandstones. They also permitted us to find an inverse, significant relationship between the radon generated by the minerals/rocks and the radon flux into the water phase, which was tested for sediments in coastal and inland Brazilian areas, demonstrating utility for evaluating the diffusive radon flux from the sediments, which is an important parameter to monitor submarine groundwater discharge (SGD) by means of radon as a natural tracer. Full article

While the biogeochemical properties of the Israeli coastal shelf (ICS) are similar to adjacent pelagic waters, the external sources of inorganic nitrogen (N) are very different. The main source of ‘new’ N to the pelagic zone is deep winter mixing, with minor contributions from atmospheric deposition and eddy diffusion across the nutricline. For the ICS, major N sources include offshore water advection (260 × 10⁶ mol N y−¹), atmospheric input (115 × 10⁶ mol N y−¹), and riverine input (138 × 10⁶ mol N y−¹), which primarily consists of treated wastewater and stormwater runoff. Direct pollutant discharge from sewage outfalls and submarine groundwater discharge are relatively minor. Key N sinks are new production (420 × 10⁶ mol N y−¹) and sediment deposition and uptake (145 × 10⁶ mol N y−¹). Inputs of nitrate and ammonium were similar and dominant in winter. Unlike temperate shelves, where riverine input is dominant, here it was only slightly higher than atmospheric input, with net N advection onto the shelf being significant. External N inputs did not change net primary production (NPP) by more than ~30% or affect dominant pico and nanophytoplankton genera, except in localized patches. This study offers baseline values for future climate and environmental change assessments. Full article