Search Results (53)

This study demonstrated the effectiveness of using autoclaved aerated concrete AAC waste as a low-cost filtering material for removing hydrogen sulfide (H₂S) from gas streams. A long-term experiment (89 days) was conducted in a packed bed reactor to purify synthetic biogas composed of N₂, CO₂, H₂S, and O₂. Optimal H₂S removal efficiencies, reaching up to 100%, were achieved under highly acidic conditions (pH ≈ 1–3) and low oxygen concentrations (<1%). In the presence of oxygen, calcium oxides in the AAC waste react with H₂S to form gypsum (CaSO₄ 2H₂O). The simultaneous removal of both oxygen and H₂S by AAC waste, following an approximate 2:1 molar ratio, may be particularly beneficial for biogas streams containing unwanted traces of oxygen. The transformation and lifespan of AAC waste were monitored through sulfur accumulation in the material and pressure drop measurements, which indicated structural changes in the AAC waste. At the end of its lifespan, the AAC waste exhibited an H₂S removal capacity of 185 g_H2S kg_AAC⁻¹. This innovative and sustainable process not only provides a cost-effective and environmentally sound solution for the simultaneous removal of H₂S and O₂ from biogas, but also promotes waste valorization and aligns with circular economy principles. Full article

The use of paper sludge as a waste stream from industrial facilities represents a significant environmental challenge due to its quantity and heterogeneous composition. The aim of the study was to evaluate the adsorption characteristics of paper sludge in neutral mine effluents and aquatic solutions of metal ions: Cu(II), Zn(II), Cd(II), and Mn(II). The main novelty of the research is a comparison of the adsorption process in synthetically prepared aquatic solutions and neutral mine drainage from field sampling. The adsorption process of the monitored metals was evaluated in terms of adsorption capacity, parameters of the Freundlich and Langmuir adsorption isotherm, and the separation factor. The adsorption capacity of paper sludge of all metals is significantly lower in neutral mine drainage (NMD) compared to adsorption in aquatic solution. The adsorption capacity of Zn(II) in aqueous solution reaches equilibrium over time, similarly to Cu(II), with values ranging from 0.2 to 1.6 mg/g. For Cd(II), a slight increasing trend in the adsorption capacity of paper sludge is observed at higher initial concentrations (3–5 mg/L) over a contact time of 90–120 min. In general, aqueous solutions of metal ions exhibited higher adsorption capacities compared to NMD, with the highest value recorded for Cu(II) at 4.742 mg/g. As the concentration values in the original solution increased, a decline in K_R (from 268% to 137% at a C0 range of 4–20 mg/L) was observed. In the mine drainage with the addition of Zn(II), K_R values were also lower compared to those in aquatic solutions. The reduction in K_R became more pronounced with increasing initial concentration, showing a decrease of 29.9% to 38.9% at C0 levels ranging from 2 to 10 mg/L. The separation factors for Cu(II), Zn(II), and Cd(II) were lower in NMD, indicating better metal separation from real mine waters. The results confirm the potential of paper sludge as a low-cost adsorbent for the treatment of heavy metal contaminated waters. Full article

Backwater effects of the Feilaixia Reservoir caused frequent inundations in the reservoir tail and complicated flood regulations in the North River basin. Currently, how backwater effects impact wedge storages and flood stages in the Feilaixia Reservoir remains unknown. This study established the 1D HEC-RAS model to simulate the water level profile and dynamic storage capacity in the Feilaixia Reservoir during two flood events and in 25 regulation scenarios. The results show that the simulated water levels aligned well with the measured data during the flood events in June 2022 and April 2024. The impact of backwater effects on flood stages, i.e., the water level difference between reservoir regulation and natural river, gradually diminished from the dam to the reservoir tail. The larger flood flow and higher water levels in front of the dam triggered greater wedge storages and higher flood stages and inundation risks in the reservoir. The narrow Mangzaixia Gorge produced a secondary backwater effect in the reservoir tail, resulting in distinct water level profile patterns above the Lianjiangkou confluence in the main stream and in the Lian River tributary. The backwater effects on wedge storage and flood stages were exceptionally large, and the ratios of wedge storages to static water storages in the Feilaixia Reservoir were 125% and 147% during both flood events, and even up to 199% as inflow reaches 20,000 m³/s, which should be carefully considered in operational flood regulation and levee height design in the reservoir. Full article

This study presents a comprehensive flood-hazard assessment and mapping of the Messapios River catchment in Evia Island, Greece, utilizing a combination of Multi-Criteria Decision Analysis (MCDA) and Geographic Information Systems (GISs). Flood-prone zones were identified based on five critical factors, which were determined to be the most influential in the watercourse when excessive discharge overwhelms the drainage network’s capacity: slope, elevation, proximity to stream channels, geological formations, and land cover. The Analytic Hierarchy Process (AHP) was applied to assign weights to these factors, while the final flood-hazard map was generated using the Weighted Linear Combination (WLC) method. The analysis revealed that 17.8% of the catchment, approximately 39 km², falls within a very high flood-hazard zone, while 18.02% (38.91 km²) is classified as highly susceptible to flooding. The flood-prone areas are concentrated in the central, southern, and western parts of the study area, particularly at the lower reaches of the catchment, on both sides of the main streams’ channels, and within the gently sloping, low-lying fan delta of the river. The study area has high exposure to flood hazards due to the significant population of approximately 9000 residents living within the flood-prone zones, a fact that contributes to the area’s potential vulnerability. Additionally, critical infrastructure, including five industrial facilities, the Psachna General High School, the local Public Power Corporation substation, about 21 km of the road network, and 21 bridges are located within the zones classified as having high and very high flood-hazard levels. Furthermore, about 35 km² of economically vital agricultural areas (such as parts of the Psachna and Triada plains) are situated in highly and very highly prone to floods zones. MCDA proved to be an effective and reliable approach for assessing and mapping flood-hazard distribution in the Messapios River catchment. The results provide valuable insights to assist decision-makers in prioritizing intervention areas and efficiently allocate resources. Full article

Gravel coverage on slopes influences overland flow and soil erosion. However, the effect of different gravel sizes on the soil erosion process remains underexplored. In this study, a runoff scour test was performed to examine the effects of gravel coverage on the hydrodynamic characteristics of slope runoff and sediment transport capacity (T_c). The slope gradient varied from 18% to 84%, the unit flow discharge ranged from 0.27 × 10⁻³ to 1.11 × 10⁻³ m² s⁻¹, and gravel coverage was adjusted from 0% to 90%. The results reveal that water depth, shear stress, and stream power increased with gravel coverage. However, once coverage exceeded 20%, flow velocity and unit stream power decreased and stabilized. As gravel coverage increased, the hydraulic regimes transitioned from laminar to turbulent flow and shifted from supercritical to subcritical. Consequently, T_c first increased and then decreased with the increase in gravel coverage, reaching a peak at 20% coverage (1.66 kg m⁻¹ s⁻¹). Moreover, the degree of coverage indirectly influenced T_c through grain shear stress. The new equations, based on the Box–Lucas function, incorporated slope, grain shear stress, and flow velocity, thereby effectively simulating T_c for runoff on gravel-covered slopes (R² = 0.94, NSE = 0.94). These findings provide a basis for modeling soil erosion on gravel-covered slopes. Full article

Extreme flood events present a significant challenge for operators and managers of large drinking water reservoirs. Detailed flood response analysis can predict the hydrology response of a reservoir to changing climate conditions and can aid in managing the reservoir in anticipation of extreme events. Herein, the Soil and Water Assessment Tool (SWAT), a watershed model, was used in conjunction with a reservoir management model, the Operational Analysis and Simulation of Integrated Systems (OASIS) model, to evaluate extreme flood events across a set of initial reservoir storage capacities across various CMIP6 climate scenarios. The SWAT model was calibrated and validated with PRISM climate data in conjunction with land and soil cover data and multi-site gauged stream discharges. The validated model demonstrated satisfactory performance (NSE = 0.55 and R² = 0.56) for total reservoir inflow. The resulting inflow values from SWAT were utilized to set up a calibrated/validated OASIS model (NSE = 0.55 and R² = 0.68). OASIS was then used to assess alternative operating rules for the reservoir under varying climate scenarios (RCP4.5 and RCP8.5) and extreme events (synthetic hurricanes). Focusing on a major reservoir in the Northeastern United States, the analysis of the reservoir response was based on (1) reservoir volume–elevation curve, (2) daily reservoir inflow, (3) daily precipitation, (4) spillway flow, and (5) reservoir evaporation. Projected future scenarios indicate a >20% increase in precipitation in April compared to historical records, coupled with likely reduced runoff from November to March. With extreme conditions most likely in the month of April, RCP4.5 and RCP8.5 projections suggest that most scenarios result in a 10–15% increase in the mean of 3D30Y runoff volumes, and a 150% increase under the most extreme conditions. For 7D30Y runoff volumes in April, the RCP4.5 and RCP8.5 analyses reveal an increased likelihood of the reservoir elevation reaching overspill flow levels during the latter half of the simulation period (2020 to 2080). Our findings indicate that simulations with SWAT coupled with OASIS can assist reservoir managers in regulating water levels in anticipation of extreme precipitation events. Full article

Waste valorization is necessary in today’s society to achieve a sustainable economy and prosperity. In this work, a novel approach to the waste valorization of cuttlebone was investigated. This material was ground and calcined at 900 °C for 5 h in an inert atmosphere. The resulting calcined cuttlebone (CCB) was characterized using XRD, SEM, FTIR, BET, TGA, Zetasizer, and potential methods. The main phases in the CCB were determined to be CaO, MgO, Ca₃(PO₄)₂, and residual carbon. CCB was investigated as an adsorbent for the removal of dye from simulated wastewater streams. The maximum adsorption capacities for rhodamine B and crystal violet dyes were estimated to be 519 and 921 mg/g, respectively. For both dyes, the Avrami model was the best-fit model for representing adsorption kinetics. The study of adsorbent regeneration for CV as a representative example involved the use of several chemical solvents. Ethanol solvent was shown to have the highest adsorbent regeneration method efficiency, reaching 65.20%. In addition, CCB was investigated for methanol electro-oxidation for energy generation. As the methanol concentration increased, the maximum current density produced by the CCB increased, reaching approximately 50 mA/cm². This work paves the way toward waste valorization of natural matter for sustainable production and consumption of material, as per the requirements of the circular economy principles. Full article

Over the past decade, the production of biofuels from lignocellulosic biomass has steadily increased to offset the use of fuels from petroleum. To make biofuels cost-competitive, however, it is necessary to add value to the “ligno-” components (up to 30% by mass) of the biomass. The properties of lignin, in terms of molecular weight (MW), chemical functionality, and mineral impurities often vary from biomass source and biorefinery process, resulting in a challenging precursor for product development. Activated carbon (AC) is a feasible target for the lignin-rich byproduct streams because it can be made from nearly any biomass, and it has a market capacity large enough to use much of the lignin generated from the biorefineries. However, it is not known how the variability in the lignin affects the key properties of AC, because, until now, they could not be well controlled. In this work, various fractions of ultraclean (<0.6% ash) lignin are created with refined MW distributions using Aqueous Lignin Purification using Hot Agents (ALPHA) and used as precursors for AC. AC is synthesized via zinc chloride activation and characterized for pore structure and adsorption capacity. We show that AC surface area and the adsorption capacity increase when using lignin with increasing MW, and, furthermore, that reducing the mineral content of lignin can significantly enhance the AC properties. The surface area of the AC from the highest MW lignin can reach ~1830 m²/g (absorption capacity). Furthermore, single step activation carbonization using zinc chloride allows for minimal carbon burn off (<30%), capturing most of the lignin carbon compared to traditional burn off methods in biorefineries for heat generation. Full article

Net metering (NM) is among the potent regulatory tools used globally for supporting distributed generation and renewable energy sources. This paper examines the trajectory of NM in a developing country such as Pakistan, analyzing the impact of regulatory changes, confidence-building strategies, hindering factors, and technical/financial issues. The three-stage methodology involves three components, namely techno-economic analysis, stakeholder engagement surveys, and impact analysis of financing mechanisms. This study emphasizes the importance of clear regulatory and financial frameworks, grid upgrades, and public–private partnerships for technology distribution in the context of a developing country with weak grid utilities and an import–export energy ratio. It also explores the role of financial incentives, such as tax breaks and subsidies, to encourage investment in NM systems from the perspective of lucrative rates, impact on paybacks, and return on investments, and proposes concrete solutions to enhance financial inclusion for ambitious renewable energy goals. Until April 2023, over 56,000 NM/distributed generation facilities were commissioned, with an installed capacity of 950 MW. By May 2024, the number of NM consumers reached ~100,000, with a 1950 MW capacity, nearly doubling. However, the import and export ratio of IESCO changed most, with 61% exports and 39% imports, directly impacting the revenue stream. A total of 60% of banks have adopted actions linked with green banking criteria, aiming to limit their environmental impact. The change in tariff will result in reduced ROI for NM consumers to 20%, and increase the payback period from less than 4 years to 13 years. Government subsidies, tax breaks, and green financing frameworks are proposed to encourage investment, but have been abruptly halted, and were previously at a 6% interest rate. This research aims to provide insights into effective market evaluation methodologies for NM programs and offer policy recommendations to strengthen legislative and institutional frameworks governing NM. Full article

Rivers across the globe experience and respond to changes within the riparian corridor. Disturbance of the riparian corridor can affect warmwater, intermediate, and coldwater streams, which can negatively influence instream physical structure and biological communities. This study focused on assessing the influence of the riparian habitat on instream structure within the Whitewater River, a coldwater stream system within an agricultural watershed in southeastern Minnesota, USA. To understand the influence of the riparian zone on the physical instream habitat, twenty variables (riparian, n = 9; instream, n = 11) were measured at 57 sites across three forks of the Whitewater using a transect method every 10 m across a 150 m reach. We used a modified Wentworth scale approach to assess coarse and fine substrates to describe habitat conditions. Canonical correlation detected significant associations between riparian and instream variables across the river forks, and indicated that wider riparian buffers, more bank grass and shrubs, longer overhanging vegetation, limited bare soil, and more rocks on banks were significantly associated with increased instream cover, high levels of coarse substrates with reduced embeddedness, increased pool habitats, and reduced fine sediments. In contrast, excessive fine sediments, lack of riffle habitat, reduced coarse substrates, and high width to depth ratios indicative of an impaired instream habitat were associated with narrow riparian buffers and high percentages of bare soil on banks. Riparian corridors have the capacity to enhance and protect physical instream habitats and overall ecosystem health when managed properly. Wide, grassy riparian corridors with stable banks, overhanging vegetation, and limited shade from trees should protect and/or enhance the instream physical habitat, providing the structural diversity favored by aquatic communities. We recommend revising the current Best Management Practices to include monitoring for impairments in the riparia, while promoting and developing good land stewardship with private landowners which can be effective in improving river ecosystems in agricultural settings. Full article

The traffic flow parameters of the road network are most often evaluated through volumes, which are compared with its maximum volume (capacity) or speed and density. Capacity assessment was performed, considering horizontal and vertical orientation and characteristics of the traffic stream. This article presents the results of research on the identification of different states of creating congestion groups and their relationship to road capacity or decrease in speed. The following hypothesis was verified: when the capacity of the road is exceeded or almost reached, there is “always” a significant drop in the flow of traffic compared to when the capacity is not exceeded. The analysis showed that the average travel speed drops by 30% for the condition where groups of 25 or more vehicles are formed with a time interval of up to 4 s. The results make it possible to set traffic models in short time intervals according to real spatial conditions and to use them in the analysis of the environmental and safety impacts of road transport. Full article

Since the inception of the traffic flow theory, numerous traffic flow models have been formulated by scholars in an effort to more accurately delineate the relationships between various traffic flow parameters. However, only a limited number of studies have explored the distinctions between fundamental traffic diagrams, which characterize continuous and interrupted traffic flow conditions. Addressing this research lacuna, we compared twelve “speed–density” and “flow–density” models fitted to empirical data collected under continuous and interrupted traffic flow conditions on a selected regional road in Croatia. The empirical data used to develop these models were extracted from video footage captured by an unmanned aerial vehicle on two representative road segments during characteristic peak and off-peak hours on workdays. Our analysis reveals that, depending on the selected traffic flow model and prevailing traffic flow conditions, the practical capacity of the observed regional road is estimated to be in the range from 799 to 2333 veh/h/lane. It was also discovered that the considered models reach practical capacity at a significantly different density under continuous and interrupted traffic stream conditions, i.e., between 37 and 129 veh/km/lane. The conducted t-tests underscore the need to employ distinct “speed–density” and “flow–density” regression functions for modeling continuous and interrupted traffic stream conditions. Full article

Given the advantages of readily availability, low cost, convenient operation, and large adsorption capacity, brown seaweed has been studied extensively as a biosorbent for heavy metal remediation from aqueous media. Herein, raw Lessonia nigrescens and brown seaweed residue, a waste product from the manufacturing of alginate from L. nigrescens, were employed as low-cost and renewable adsorption materials for effective copper removal in wastewater streams. The influences of temperature, sample loadings, adsorption time, initial metal ion concentrations, and pH on the efficiency of the metal ions adsorption process were investigated. The thermodynamics and kinetics of Cu (II) adsorption for both the raw seaweed and seaweed residue were studied in order to determine the maximum removal efficiency and capacity. The characterization of the seaweed and seaweed residue before and after copper adsorption with SEM, FTIR, EDS, etc., coupled with the thermodynamics study, confirmed the ion exchange mechanism involved in the adsorption process. Under optimal conditions, the removal efficiencies were 75% and 71% for L. nigrescens and seaweed residue, respectively, and the adsorption capacities can reach 12.15 mg/g and 9.09 mg/g within 10 min for L. nigrescens and seaweed residue, respectively. The slight reduction in removal efficiency was because the active ion exchange sites were partially removed during the alginate extraction. The comparable metal ion removal efficiency between raw seaweed and seaweed residue suggesting the L. nigrescens residue is viable as bio-adsorbent and potential for industrial applications in adsorption process. The results provided a novel way to upgrade seaweed biomass in a biorefinery concept. Full article

Hazardous combustion and explosions during thermal runaway (TR) processes in lithium-ion batteries (LIBs) present a significant limitation to their widespread adoption. The objective of this study was to quantitatively reveal the eruption characteristics of LIBs. A commercially available prismatic cell with a capacity of 50 Ah was employed, featuring Li(Ni_0.6Co_0.2Mn_0.2)O₂ as the cathode material and graphite as the anode material. The investigation focused on the thermal runaway behavior at 100% state of charge (SOC). Three replicates of thermal runaway experiments were conducted within a 1000 L lithium battery adiabatic experimental chamber (AEC) under a nitrogen atmosphere, and the thermal runaway moments were captured using a high-speed camera. The ejection velocity of smoke during the opening of the safety valve was approximately 40 m/s; within an extremely short time frame following the opening of the safety valve, the jet stream temperature reached a peak value of 340.6 ± 42.0 °C; the duration of the ultra-high-speed jet was 12.0 ± 1.0 s, the high-speed jet lasted 9.9 ± 2.2 s, and the slow-speed jet persisted for 32.1 ± 3.0 s, resulting in an overall ejection duration of 53.9 ± 6.0 s. Full article

Floods often cause changes in the hydro-geomorphology of riverbeds and banks. These changes need to be closely monitored to find a balance and exchange between lateral and vertical erosion and deposition, upstream local sediment supply, and a stream’s transport capacity. Low-frequency cross-sectional field surveys cannot map hard-to-reach locations. Innovative techniques, such as small unmanned aerial vehicles (UAVs), must be employed to monitor these processes. This research compared historical data with a UAV survey and the Pix4DMapper structure-from-motion (SfM) program to assess the longitudinal, lateral, and vertical changes of Sidere Creek in the eastern Black Sea, Türkiye. Digitization was undertaken using 2011–2015–2017 Google Earth photographs, 1960s topographic maps, and 2023 orthomosaics. ArcGIS 10.6 was used to delineate the centerlines (thalweg), left/right banks, alluvial bars, active channel widths, and channel confinement layers. Channel Migration Toolbox and CloudCompare were utilized for analyzing lateral and vertical morphological changes, respectively. The active channel migrated 25.57 m during 1960–2011, 15.84 m during 2011–2015, 6.96 m during 2015–2017, and 5.79 m during 2017–2023. Left-bank channel confinement rose from 2.4% to 42% and right-bank channel confinement from 5.9% to 34.8% over 63 years. Neither stream meandering nor sinuosity index changed statistically. Active channel boundary widths varied from 149.79 m to 9.46 m, averaging 37.3 m. It can be concluded that UAV surveys can precisely measure and monitor the stream channel longitudinal, lateral, and vertical morphological changes at a lower cost and in less time than previous methods. Full article