Search Results (74)

Optimisation of the anti-skid properties of tyres is a significant area of composite applications. For investigating the wet slip friction characteristics, the wet slip friction test of tread rubber and road surface was carried out using the comprehensive tire friction testing machine. The wet slip properties of different formulated rubbers under various working conditions such as different slip speeds, water film thicknesses and vertical loads were compared through the test. Subsequently, an orthogonal test programme was designed to investigate the degree of significant influence of each factor on the wet slip performance. A three-dimensional finite element model of tread rubber and road surface with water film was established in order to facilitate analysis of the wet slip properties. The simulation results were utilised to elucidate the pattern of the effects of different loads on the wet slip friction characteristics. Results indicate that the wet slip friction coefficient is subject to decrease in proportion to the magnitude of the vertical load; the friction coefficient of rubber block in wet slip condition exhibits a decline of approximately 26% in comparison with that of dry condition; the factor that exerts the most significant influence on the coefficient of friction is the vertical load, while the water film thickness exerts the least influence. The results obtained can serve as a reference source for the design of tire anti-skid performance enhancement. Full article

The inclusion of adsorption thermodynamic analysis and performance benchmarking with existing adsorbents reinforces both the theoretical significance and practical applicability of this study. The modified rubber-derived carbon demonstrated a remarkably high DBT adsorption capacity of 254.45 mg/g. These results establish it as a promising alternative to conventional materials such as commercial activated carbon, zeolites, and even metal–organic framework materials. In addition to confirming the superior performance of the adsorbent, the findings provide a deeper understanding of the DBT adsorption mechanism and offer a solid scientific basis for large-scale fuel desulfurization applications. This research highlights the potential of transforming end-of-life tire waste into value-added functional materials and contributes to the advancement of sustainable and efficient desulfurization technologies. Future work should focus on optimizing surface functionalization and regeneration strategies to further improve long-term adsorption stability and practical deployment. Full article

The iron and steel industry generates large quantities of iron-bearing dust (IBD), contributing to resource inefficiency and environmental concerns. This study investigates heating methods and the use of organic solid waste, specifically waste tire carbon (WTC), as a reductant for the recovery of Fe from sintering machine tail dust (SMTD) and steelmaking gravity dust. The results indicate that the optimal reduction conditions occurred at 1000 °C, with a 2:1 ratio of SMTD to WTC, and 0% O₂ holding for 45 min. WTC is the best material, and heating methods affect it limitedly. The leaching behavior of seven metals was measured, showing an increase in the leaching of Ca and Al compared to the raw materials. The study shows that WTC provides a promising alternative reductant for IBD reduction, offering an energy-saving and low-carbon alternative to conventional fossil fuel injections in blast furnaces. The risk of Cr leaching should be paid attention to while enhancing Fe recovery. Full article

This study focuses on the production and characterization of activated carbons derived from the carbonaceous residue obtained through the catalytic pyrolysis of waste tires. A catalytic pyrolysis process was conducted at 450 °C and 575 °C, employing two zeolitic catalysts, the commercial ZSM-5 and a synthesized zeolite (PZ2), developed from natural pozzolan, which played a key role in the pyrolysis performance and the quality of the resulting carbons. After pyrolysis, the solid residues were chemically activated using KOH to improve their porous structure and surface characteristics. Comprehensive characterization was carried out, including textural properties (BET surface area and porosity) and morphological (SEM) analysis of the activated carbons, as well as crystallinity evaluation (XRD) of the zeolitic catalysts. The BET surface areas of activated carbons PZ2-T1-AK and PZ2-T2-AK reached 608.65 m²/g and 624.37 m²/g, respectively, values that surpass those reported for similar materials under comparable activation conditions. The developed porous structure suggests strong potential for applications in adsorption processes, including pollutant removal. These findings demonstrate the effectiveness of zeolite-catalyzed pyrolysis, particularly using PZ2, as a sustainable strategy for transforming tire waste into high-performance adsorbent materials. This approach supports circular economy principles through innovative waste valorization and offers a promising solution to an environmental challenge. Full article

To address the challenges of unclear thermo-mechanical coupling mechanisms and unpredictable multi-field synergistic effects in segmented tire molds during vulcanization, this study focuses on segmented tire molds and proposes a multi-physics coupling numerical model. This model integrates fluid flow dynamics into heat transfer mechanisms. It systematically reveals molds’ heat transfer characteristics, stress distribution and deformation behavior under combined high-temperature and mechanical loading. Based on a fluid-solid-thermal coupling framework and experimental validations, simulations indicate that the internal temperature field of the mold is highly uniform. The global temperature difference is less than 0.13%. The temperature load has a significant dominant effect on the deformation of key components such as the guide ring and installation ring. Molding forces play a secondary role in total stress. The error between multi-field coupling simulation results and experimental results is controlled within 6%, verifying the model’s reliability. This research not only provides a universally applicable multi-field coupling analysis method for complex mold design but also highlights the critical role of temperature fields in stress distribution and deformation analysis. This lays a theoretical foundation for the intelligent design and process optimization of high-temperature, high-pressure forming equipment. Full article

To reduce solid waste production and enable the synergistic conversion of solid waste into high-value-added products, we introduce a novel, sustainable, and ecofriendly method. We fabricate nanofiber and nanosheet silicon carbides (SiC) through a carbothermal reduction process. Here, the calcined coal gangue, converted from coal gangue, serves as the silicon source. The carbon sources are the carbonized waste tire residue from waste tires and the pre-treated kerosene co-refining residue. The difference in carbon source results in the alteration of the morphology of the SiC obtained. By optimizing the reaction temperature, time, and mass ratio, the purity of the as-made SiC products with nanofiber-like and nanosheet-like shapes can reach 98%. Based on the influence of synthetic conditions and the results calculated from the change in the Gibbs free energy of the reactions, two mechanisms for SiC formation are proposed, namely the reaction of intermediate SiO with CO to form SiC-nuclei-driven nanofibrous SiC and the SiO-deposited carbon surface to fabricate nuclei-induced polymorphic SiC (dominant nanosheets). This work provides a constructive strategy for preparing nanostructured SiC, thereby achieving “turning trash into treasure” and broadening the sustainable utilization and development of solid wastes. Full article

Dimer and trimer acids are interesting viscous liquids produced from fatty acids derived from renewable sources. The chemical structures of dimer and trimer acids are known and quite complex and are presented here, discussed and further elucidated through electronic absorption spectroscopy, FT-IR and Raman spectroscopy. Dimer and trimer acids have a number of applications in their original form or in the form of derivatives. In the present study, a series of esters of dimer and trimer acids with alcohols from renewable sources were synthesized for use as plasticizers for rubber and plastics. The polarity of the dimer and trimer acids as well as their esters with alcohols from renewable sources (dimerates and trimerates) were systematically studied using a Nile red solvatochromic probe. The resulting E(NR) values were compared with the E(NR) values of the most common types of rubber and plastics. Compatibility and other physical properties expected from the E(NR) scale were studied and successfully confirmed in tire tread rubber compound formulations and in nitrile rubber and PVC matrices, confirming once again the sensitivity and the validity of the Nile red solvatochromic polarity scale for the development of new plasticizers. The validity of the liquids polarity measured with the Nile Red dye is supported by the correlation found between the E(NR) scale and the dielectric constants (ε) of carboxylic acids (including dimer and trimer acids, hydrogenated dimer acids and isostearic acid) and alcohols. A correlation was even found linking the E(NR) values the with the ε values of thin solid films of rubbers and plastics. In the case of the esters the correlation of their E(NR) values was found with the length of the aliphatic chains of the alcohols used in the esterification. Full article

Aedes aegypti is a key vector in the transmission of arboviral diseases in the Colombian Amazon. This study aimed to characterize microbiota composition using DNA extracted from water in artificial breeding sites, immature stages, and adults of Ae. aegypti in Leticia, Amazonas. Additionally, the physicochemical water variables were correlated with the bacterial communities present. Eight artificial breeding sites were identified, with bucket, plant pot, and tire being the most frequent. The breeding sites exhibited similar physicochemical profiles, with significant temperature and salinity differences (p-value < 0.03). The most representative bacterial genera included Ottowia (82%), Xanthobacter (70.59%), and Rhodocyclaceae (92.78%) in breeding site water; Aquabacterium (61.07%), Dechloromonas (82.85%), and Flectobacillus (58.94%) in immature stages; and Elizabethkingia (70.89%) and Cedecea (39.19%) in males and females of Ae. aegypti. Beta diversity analysis revealed distinct clustering between adults and the water and immature communities (p-value < 0.001). Multivariate analysis showed strong correlations among bacterial communities, breeding sites, and physicochemical variables such as tire and drum cover which exhibited high levels of total dissolved solids, conductivity, and salinity associated with Flectobacillus, Leifsonia, Novosphingobium, Ottowia, and Rhodobacter. Bacterial genera such as Mycobacterium, Escherichia, Salmonella, and Clostridium, present in artificial breeding sites, are associated with public health relevance. This study provides insights into bacterial community dynamics across Ae. aegypti’s life cycle and underscores the importance of water physicochemical and biological characteristics for developing new vector control strategies. Full article

To reduce dependence on fossil fuels, cope with the growing energy demand, and reduce greenhouse gas emissions, this paper innovatively designs a novel integrated energy system integrating anaerobic digestion of animal manure, fuel cell technology, gas turbine, and tire pyrolysis. The system maximizes the energy potential of biogas while synergistically treating waste tires, improving waste management’s flexibility, efficiency, and economic viability through multiple outputs such as electricity and by-products, subsystem synergies, equipment sharing, and economies of scale. Thermodynamic performance and economic feasibility are analyzed using Aspen Plus V14 simulation modeling, ensuring the system’s technical and economic viability. In this study, the simulation model of the system is established, and the techno-economic benefits of the system are analyzed. The simulation results show that the net electric power output of the system is 444.79 kW. Combined with the contribution of pyrolysis products, the system’s total efficiency reaches 70.88%. In only 4.79 years, the initial investment can be recovered, and in its 25-year service life, the system has realized a profit of 2,939,130 USD. The system realizes the energy and quality matching between different thermal processes through indirect collaborative treatment of different solid wastes, improves the conversion efficiency of biogas energy, co-treats waste tires, and reduces environmental pollution. Full article

The energy crisis and environmental degradation are pressing challenges, intensified by population growth and the excessive generation of solid waste. Converting waste into energy, especially through pyrolysis, is a viable and sustainable alternative. This thermal process transforms waste such as banana peels and used tires into high-value products, such as gas, char, and bio-oil. This study aims to evaluate the production of bio-oil from the pyrolysis and co-pyrolysis of these materials, considering different proportions and temperatures, as well as using an Artificial Neural Network (ANN) to predict the composition of the bio-oils. The pyrolysis tests with 100% banana peel and 75% banana peel mixed with 25% tire showed a decrease in bio-oil yield with increasing temperature, with a drop of around 30% when comparing 500 °C to 400 °C. In contrast, co-pyrolysis with 50% of each material and 100% of the tire resulted in increases in bio-oil yield as the temperature rose. A Fourier Transform Infrared Spectroscopy (FTIR) analysis of the bio-oils showed the presence of relevant functional groups, while an elemental analysis and ANN provided accurate predictions of carbon, hydrogen, and nitrogen content. The results suggest that the co-pyrolysis of waste tires and banana peels is a viable alternative for the production of bio-oil. Full article

Solketal, a widely used glycerol-derived solvent, can be efficiently synthesized through heterogeneous catalysis, thus avoiding the significant product losses typically encountered with aqueous work-up in homogeneous catalysis. This study explores the catalytic synthesis of solketal using solid acid catalysts derived from recovered carbon blacks (rCBs), which are obtained through the pyrolysis of end-of-life tires. This was further converted into solid acid catalysts through the introduction of acidic functional groups using concentrated H₂SO₄ or 4-benzenediazonium sulfonate (BDS) as sulfonating agents. Additionally, post-pyrolytic rCB treated with glucose and subsequently sulfonated with sulfuric acid was also prepared. Comprehensive characterization of the initial and modified rCBs was performed using techniques such as elemental analysis, powder X-ray diffraction, thermogravimetric analysis, a back titration method, and both scanning and transmission electron microscopy, along with X-ray photoelectron spectroscopy. The catalytic performance of these samples was evaluated through the batch mode glycerol acetalization to produce solketal. The modified rCBs exhibited substantial catalytic activity, achieving high glycerol conversions (approximately 90%) and high solketal selectivity (around 95%) within 30 min at 40 °C. This notable activity was attributed to the presence of -SO₃H groups on the surface of the functionalized rCBs. Reusability tests indicated that only rCBs modified with glucose demonstrated acceptable catalytic stability in subsequent acetalization cycles. The findings underscore the potential of utilizing end-of-life tires to produce effective acid catalysts for glycerol valorization processes. Full article

The continuous increase in solid waste materials, such as waste tires, underscores the critical importance of recycling them to mitigate environmental impact and promote sustainable resource management. This research study evaluated the effectiveness of utilizing waste tire pyrolysis oils (WTPOs) as recycling agents for asphalt materials. The chemical composition and thermal behavior of WTPO were analyzed using Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). Mechanically, the prepared WTPO binders were assessed by measuring dynamic viscosity and changes in high- and intermediate-temperature performance grades. Additionally, the cracking susceptibility of the binders was evaluated using the Glover-Rowe (G-R) parameter. The findings indicated that WTPOs might contain water and light aromatics in varying percentages, depending on the pyrolysis process. Incorporating WTPOs enhanced the workability of asphalt mixtures and ensured a high degree of blending between recycled/aged asphalt and raw binder. A 12% WTPO dosage was identified as the most effective for enhancing fatigue and low-temperature cracking resistance, facilitating improved interactions between the virgin binder and recycled asphalt materials. Finally, utilizing WTPOs as rejuvenating agents in pavement construction supports sustainable practices by recycling waste materials and significantly improving the performance and durability of asphalt mixtures. Full article

This research assesses the effect of carbonated pyrolysis oil (CPO) derived from scrap car tires on the metallurgical efficiency of coal flotation as a flotation additive. Using a statistical experimental design, the influence of various operational variables, including solid percent of feed pulp and dosages of reagents, i.e., CPO as an additive, diesel oil as a collector, and pine oil as a frother, on the ash content and yield of the final concentrate were investigated. Experimental data vary significantly based on operational conditions, ranging from 6.6% ash content with a 15% yield to 19.1% ash content with a 76.8% yield. The composition of the pyrolysis oil was identified by using Fourier transform infrared spectroscopy (FTIR). The analysis of variance (ANOVA) of experimental results demonstrated that almost all variables had a substantial effect on the flotation responses, positive or negative, depending on the variable or variable interaction. It was discovered that the usage of CPO intensified the total yield and ash content of concentrate in a nonlinear fashion in a range of 15% and 4%, respectively. The results revealed a non-selective interaction effect between CPO and pine oil, as well as competitive adsorption between diesel oil and CPO, which contributed to the curved behavior of flotation measurements. The detrimental effect of CPO on the flotation response of the studied coal sample was also related to the interaction of the hydrophilic groups in the CPO structure and the oxide groups of ash material in coal particles. This work shows the potential of carbonated pyrolysis oil to enhance coal flotation performance and sheds light on the underlying mechanisms. Full article

The purpose of this study was to investigate the effect of the use of rubber powder from tire recovery on the dynamic loading performance of CPB. Finally, it is concluded that using recycled rubber material to backfill mine paste is helpful in reducing waste tire pollution and improving the impact resistance of the backfill body. The dynamic compressive strength, Dynamic Increase Factor (DIF), peak dynamic load strain, and dynamic load elastic modulus of the samples composed of slag, Portland cement, wastewater, and rubber powder were determined. Through the analysis of the experimental data, it can be seen that the recycled rubber reduces the dynamic compressive strength and DIF of the specimen but increases the peak dynamic load strain and dynamic load elastic modulus and other characteristics, and enhances the ability of the filled body to absorb elastic strain energy. The results show that recycled rubber can increase the deformation ability of the filler and improve the impact resistance of the filler. The results of this study provide valuable information and industrial applications for the effective management of solid waste based on sustainable development and the circular economy. Full article

Over one billion rubber tires are disposed of worldwide annually as a major component of the solid waste stream, posing a significant environmental risk. Therefore, recycling and taking advantage of the rubber component in End-of-Life Tires (ELTs) presents an advantageous opportunity to produce environmentally friendly and cost-effective products. This work studied multiple properties of oil extracted from ELTs using thermal pyrolysis (i.e., pyro-oil) as a potential candidate for industrial lubrication applications. First, pyro-oil was characterized by studying its morphological and chemical properties. Then, rheological studies were conducted to explore the oil properties at different temperatures and shear rates. A tribometer was also used to assess pyro-oil’s tribological performance at different temperatures and speeds. Finally, wettability and thermal analyses were performed to understand the wetting and thermal stability properties. The results revealed that pyro-oil has chemical properties similar to conventional engine oil with slightly higher sulfur content. Furthermore, the pyro-oil exhibited lower viscosity and lubrication performance than conventional engine oil, but this difference was smaller at higher temperatures. Thermal stability and wetting properties of pyro-oil were found to be significantly lower than those of conventional engine oil. Based on the properties found and compared with engine oil, pyro-oil presents itself as a suitable liquid lubricant for low-speed, low-load applications operating in temperatures below 61 °C. This work presents a comprehensive study of pyro-oil properties extracted from end-of-life waste tires, offering a feasible route to obtain sustainable and low-cost products. Full article