Search Results (70)

Efficient soil fertility monitoring is essential for sustainable agriculture, food security, and environmental management across Africa, yet conventional laboratory methods remain prohibitively costly and slow for continental-scale applications. Soil spectroscopy is considered as a rapid, non-destructive alternative with transformative potential. This review provides a systematic synthesis of spectroscopic applications across Africa, encompassing laboratory, field, airborne, and satellite-based platforms, while examining major data sources including the Africa Soil Information Service (AfSIS) and GEO-CRADLE spectral libraries. We critically evaluate the evolution of modeling approaches, revealing that Partial Least Squares Regression (PLSR) dominates, but a shift toward advanced frameworks like hybrid physically based models, ensemble learning and deep neural networks is essential. Critically, we identify a pronounced imbalance wherein laboratory spectroscopy prevails while imaging and satellite-based approaches remain comparatively underutilized, despite their unparalleled potential for scaling point measurements to continental extents. The review consolidates findings on key soil properties, demonstrating consistent successes for primary constituents with direct spectral responses (i.e., organic carbon), while revealing relative uncertainty for properties inferred indirectly via covariance (e.g., available phosphorus, potassium). Despite significant local and regional progress, the absence of a standardized pan-African spectral library and the intractable transferability problem remain formidable barriers. Future research must pivot decisively toward imaging spectroscopy and satellite platforms, mitigating PLSR dominance through systematic adoption of ensemble methods, transfer learning, and model harmonization frameworks to fully operationalize these technologies in support of Africa’s sustainable development goals. Full article

Municipal solid waste management remains a major environmental challenge across Africa, where rapid urbanisation has outpaced formal waste infrastructure and routine landfill monitoring is often absent. Rather than proposing a classification algorithm, this study investigates whether spaceborne hyperspectral imagery can reveal robust spectral fingerprints of landfill surfaces suitable for automated detection. Eight landfill sites across seven African countries were analysed using Hyperspectral Imager Suite (HISUI) data (400–2500 nm, 20 m resolution). A segment-based framework was applied after masking low signal-to-noise regions, combining brightness analysis, L2-normalised spectral shape comparison using Spectral Contrast Angle (SCA), and derivative spectroscopy across 109,275 pixels from six land-cover classes. Brightness-based discrimination exhibited strong inter-site variability, limiting its general applicability. In contrast, shape-based metrices revealed consistent separability between landfill-active surfaces and soil or urban classes in the shortwave infrared (SWIR), particularly within the 1538–1750 nm and 2075–2474 nm regions. Derivative analysis further identified stable extrema near approximately 1700 nm and 2200–2300 nm across all sites, indicating reproducible curvature-based fingerprints associated with exposed municipal solid waste. These results demonstrate that landfill surfaces exhibit intrinsic SWIR spectral characteristics that persist across diverse African environments. This study establishes the first multi-site hyperspectral library of African landfill surfaces, providing a physical basis for developing generalised landfill detection frameworks. Full article

Hyperspectral remote sensing (HRS) is gaining widespread adoption within the geoscience and Earth observation communities. It fosters diverse applications, including precision agriculture, soil science, mineral exploration, and carbon detection, to name a few. Recent technological advancements facilitated a growing number of satellite missions as well as an increase in the availability of commercial sensors and platforms, such as drones. A significant challenge in deploying the varied platforms and sensors is the design and optimization of the hyperspectral surveys. Forward modelling simulators are valuable for optimizing mission parameters and estimating imaging performance. Limited accessibility of open-source simulators presents an obstacle for users who seek to benefit from such tools. To bridge this gap, HySIMU (Hyperspectral SIMUlator) was developed and described herein. It is an open-source, forward modelling toolkit that combines and integrates a primary processing pipeline with various open-source packages into a transparent and modular workflow. It offers a cost-effective approach to evaluating the performance of hyperspectral surveys. HySIMU is designed to simulate hyperspectral imagery based on user-defined targets, platforms, and sensor parameters. Features include (i) a ground truth data cube builder for customizable input parameters, (ii) a terrain-based solar and view geometry calculator for illumination modelling, (iii) integrated open-source radiative transfer models for incorporating atmospheric effects, and (iv) spatial resampling filters. In this manuscript, the initial framework for HySIMU is presented with some example applications, including two validation studies with real hyperspectral images. As remote sensing technologies advance, forward modelling toolkits such as HySIMU play a crucial role in refining mission designs and assessing survey feasibility. The scalability for arbitrary hyperspectral sensors, platforms, and spectral libraries ensures broad applicability. Of particular importance is support for parameter optimization for both scientific and commercial HRS campaigns. Full article

Timely and accurate soil property information is critical for sustainable agriculture and precision nutrient management. Conventional laboratory methods are accurate but costly and labor-intensive, restricting their feasibility for high-density soil mapping. Low-cost, portable near-infrared (NIR) spectroscopy presents a promising alternative for rapid, on-site, and non-destructive soil analysis. This study aimed to evaluate the potential of a low-cost, portable NIR sensor (NeoSpectra) for the quantitative prediction of key soil properties in paddy fields from Southeastern China. The target properties were soil organic matter (SOM), total nitrogen (TN), pH, and particle size fractions (clay, silt, and sand). A total of 995 soil samples were collected from representative paddy fields in the region and spectra measurements were conducted in the laboratory on air-dried samples. We developed and compared the performance of multiple machine learning algorithms, including partial least squares regression (PLSR), Cubist, random forest (RF) and memory-based learning (MBL), to build robust calibration models. The predictive models showed substantial performance for SOM and TN, indicating high accuracy (R² > 0.75, LCCC > 0.85, RPD > 2) for quantitative prediction. Predictions for pH, silt, sand, and clay were less accurate (R² of 0.48–0.53, LCCC of 0.67–0.71, RPD of 1.39–1.49), suggesting the sensor’s utility is limited to indicating general trends for these properties. Among the tested algorithms, MBL consistently provided the most accurate and robust predictions across the majority of soil properties. Our findings demonstrate that the low-cost portable NIR sensor, when coupled with appropriate machine learning algorithms, is a powerful and viable tool for the rapid and reliable estimation of critical paddy soil fertility properties (SOM and TN). This technology has significant potential to support field-level soil health monitoring, precision fertilization strategies, and sustainable land management in the agricultural systems of Southeastern China. Full article

Demand for rapid and cost-effective soil analysis has increased the use of spectroscopy, particularly in the visible–near-infrared (Vis–NIR) and mid-infrared (MIR) regions. Using 8304 soil samples from the United States Department of Agriculture spectral library, this study evaluated the effects of raw and preprocessed spectra on the prediction accuracy of eleven key soil properties across Vis–NIR and MIR regions using multiple machine learning algorithms. Spectral preprocessing, combining baseline correction and standard normal variate transformation, consistently improved prediction accuracy compared to the raw spectra. Overall, MIR-based models consistently outperformed Vis–NIR across all soil properties, with the largest performance gains observed for potassium, bulk density, and nitrate nitrogen. Among the machine learning approaches evaluated, artificial neural networks and categorical boosting algorithms provided the strongest and most consistent predictive performance across both spectral regions. These findings demonstrate that combining appropriate spectral preprocessing, spectral region selection, and advanced machine learning algorithms can substantially improve soil property prediction using spectroscopy. Full article

Non-photosynthetic vegetation fractional cover (f_NPV) is a key indicator of vegetation decline and ecological health. Traditional inversion models assume identical spectral signatures for the same vegetation cover class across entire study areas. Spectral variations occur among regions due to divergent soil properties and vegetation types. To address this limitation, extensive ground sampling was conducted; ground observation data from multiple regions were utilized to establish localized spectral libraries, thereby enhancing spectral variability representation within the study area while concurrently optimizing vegetation indices across different sensor systems. The results reveal that, within the optimized spectral mixture analysis model, the coefficient of determination (R²) for f_NPV using the NPV soil separation index (NSSI) for Sentinel sensor is 0.6258, and that of f_PV using the modified soil adjusted vegetation index (MSAVI) is 0.8055. The MSAVI-NSSI achieved an R² of 0.7825 for f_NPV and 0.8725 for photosynthetic vegetation fractional cover (f_PV). Optimized vegetation indices also yielded favorable validation results. Landsat’s theoretical predictions improved by 0.1725, with validated results up by 0.1635. MODIS showed improvements of 0.1365 and 0.1923, respectively. This enhancement significantly improves the accuracy of NPV fractional cover identification, providing critical insights for vegetation ecological health assessment in arid and semi-arid regions under global warming. Furthermore, by optimizing the spectral constraint weights in remote sensing images, a solution is provided for the long-term monitoring of vegetation health status. Full article

Visible near-infrared (VNIR) spectroscopy offers a cost-effective solution to quantify the spatiotemporal dynamics of soil organic carbon (SOC), especially in the context of rapid advances in spectra-based local modeling approaches using large-scale soil spectral libraries. And yet, direct temporal transferability of VNIR spectroscopic modeling (applying historical models to new spectral data) and its capability to monitor temporal changes in SOC remain underexplored. To address this gap, this study uses the LUCAS Soil dataset (2009 and 2015) from France to evaluate the effectiveness of localized spectral models in detecting SOC changes. Two local learning algorithms, memory-based learning (MBL) and GLOBAL-LOCAL algorithms, were adapted to integrate spectral and soil property similarities during local training set selection, while also incorporating LUCAS 2009 soil measurements (clay, silt, sand, CEC) as covariates. These adapted local learning algorithms were then compared against global partial least squares regression (PLSR). The results demonstrated that localized models substantially outperformed global PLSR, with MBL achieving the highest accuracy for croplands, grasslands, and woodlands (R² = 0.72–0.79, RMSE = 4.73–20.92 g/kg). Incorporating soil properties during the local learning procedure reduced spectral heterogeneity, leading to improved SOC prediction accuracy. This improvement was particularly pronounced after excluding organic soils from grasslands and woodlands, as evidenced by 13.3–21.1% decreases in the RMSE. Critically, for SOC monitoring, spectrally predicted SOC successfully identified over 70% of samples experiencing significant SOC changes (>10% loss or gain), effectively capturing the spatial patterns of SOC changes. This study demonstrated the potential of localized spectral modeling as a cost-effective tool for monitoring SOC dynamics, enabling efficient and large-scale assessments critical for sustainable soil management. Full article

Soils serve as critical carbon reservoirs, playing an essential role in climate change mitigation and agricultural sustainability. Accurate soil property determination relies on soil spectral reflectance data from Earth observation (EO), but current vegetation models often oversimplify soil conditions. This study introduces a novel approach that combines radiative transfer models (RTMs) with open-access soil spectral libraries to address this challenge. Focusing on conditions of low soil moisture content (SMC), photosynthetic vegetation (PV), and non-photosynthetic vegetation (NPV), the coupled Marmit–Leaf–Canopy (MLC) model is used to simulate early crop growth stages. The MLC model, which integrates MARMIT and PRO4SAIL2, enables the generation of mixed soil–vegetation scenarios. A simulated EO disturbed soil spectral library (DSSL) was created, significantly expanding the EU LUCAS cropland soil spectral library. A 1D convolutional neural network (1D-CNN) was trained on this database to predict Soil Organic Carbon (SOC) content. The results demonstrated relatively high SOC prediction accuracy compared to previous approaches that rely only on RTMs and/or machine learning approaches. Incorporating soil moisture content significantly improved performance over bare soil alone, yielding an R² of 0.86 and RMSE of 4.05 g/kg, compared to R² = 0.71 and RMSE = 6.01 g/kg for bare soil. Adding PV slightly reduced accuracy (R² = 0.71, RMSE = 6.31 g/kg), while the inclusion of NPV alongside moisture led to modest improvement (R² = 0.74, RMSE = 5.84 g/kg). The most comprehensive model, incorporating bare soil, SMC, PV, and NPV, achieved a balanced performance (R² = 0.76, RMSE = 5.49 g/kg), highlighting the importance of accounting for all surface components in SOC estimation. While further validation with additional scenarios and SOC prediction methods is needed, these findings demonstrate, for the first time, using radiative-transfer simulations of mixed vegetation-soil-water environments, that an EO-DSSL approach enhances machine learning-based SOC modeling from EO data, improving SOC mapping accuracy. This innovative framework could significantly improve global-scale SOC predictions, supporting the design of next-generation EO products for more accurate carbon monitoring. Full article

Soil spectroscopy offers a rapid, cost-effective alternative to traditional soil analyses for characterization and classification. Previous studies have mainly focused on predicting soil categories using single sensors, particularly visible–near-infrared (vis–NIR) or mid-infrared (MIR) spectroscopy. In this study, we evaluated the performance of vis–NIR, MIR, and their combined spectra for soil classification by partial least-squares discriminant analysis (PLSDA) and random forest (RF). Utilizing 60 typical soil profiles’ data of four soil classes from the global soil spectral library (GSSL), our results demonstrated that in PLSDA models, direct combination (optimal overall accuracy: 70.6%, kappa coefficient: 0.60) and outer product analysis (OPA) fused spectra (optimal overall accuracy: 68.1%, kappa coefficient: 0.57) outperformed vis–NIR (optimal overall accuracy: 62.2%, kappa coefficient: 0.49) but underperformed compared to MIR (optimal overall accuracy: 71.4%, kappa coefficient: 0.62). In RF models, classification accuracy using fused spectra was inferior to single spectral ranges, with MIR achieving the highest classification accuracy (optimal overall accuracy: 89.1%, kappa coefficient: 0.85). Therefore, MIR alone remains the most effective spectral range for accurate soil class discrimination. Our findings highlight the potential of MIR spectroscopy for enhancing global soil classification accuracy and efficiency, with important implications for soil resource management and agricultural planning across diverse environments. Full article

An attempt was made to quantify soil properties using hyperspectral remote-sensing techniques and machine-learning algorithms. In total, 100 soil samples representing various locations and soil-nutrient statuses were collected, and the samples were analyzed for soil pH, EC, soil organic carbon, available nitrogen (AN), available phosphorus (AP), and available potassium (AK) by following standard methods. Soil had a wide range of properties, i.e., pH varied from 5.62 to 8.49, EC varied from 0.08 to 1.78 dS/m, soil organic carbon varied from 0.23 to 0.94%, available nitrogen varied from 154 to 344 kg/ha, available phosphorus varied from 9.5 to 25.5 kg/ha, and available potassium varied from 131 to 747 kg/ha. The same set of soil samples were subjected to spectral reflectance measurement using SVC GER 1500 Spectroradiometer (spectral range: 350 to 1050 nm). The measured spectral signatures of various soils were organized for developing a spectral library and for deriving various spectral indices to correlate with soil properties to quantify the nutrients. The soil samples were partitioned into 60:40 ratios for training and validation, respectively. In order to select optimum bands (wavelength) from the soil spectra, we have employed metaheuristic algorithms i.e., Particle Swarm Optimization (PSO), Moth–Flame optimization (MFO), Flower Pollination Optimization (FPO), and Battle Royale Optimization (BRO) algorithm. Further partial least square regression (PLSR) was used to find the latent variable and to evaluate various algorithms for their performance in predicting soil properties. The results indicated that nutrients could be quantified from spectral reflectance measurement with fair to good accuracy through the Battle Royale Optimization technique with a $R^2$ value of 0.45, 0.32, 0.48, 0.21, 0.71, and 0.35 for pH, EC, soil organic carbon, available-N, available-P, and available-K, respectively. Full article

Emerging contaminants (ECs), encompassing pharmaceuticals, personal care products, pesticides, and industrial chemicals, represent a growing threat to ecosystems and human health due to their persistence, bioaccumulation potential, and often-unknown toxicological profiles. Addressing these challenges necessitates advanced analytical tools capable of detecting and quantifying trace levels of ECs in complex environmental matrices. This review highlights the pivotal role of mass spectrometry (MS) in monitoring ECs, emphasizing its high sensitivity, specificity, and versatility across various techniques such as Gas Chromatography-Mass Spectrometry (GC-MS), Liquid Chromatography-Mass Spectrometry (LC-MS), and High-Resolution Mass Spectrometry (HR-MS). The application of MS has facilitated the real-time detection of volatile organic compounds, the comprehensive non-targeted screening of unknown contaminants, and accurate quantification in diverse matrices including water, soil, and air. Despite its effectiveness, challenges such as matrix interferences, a lack of standardized methodologies, and limited spectral libraries persist. However, recent advancements, including hybrid MS systems and the integration of artificial intelligence (AI), are paving the way for more efficient environmental monitoring and predictive modeling of contaminant behavior. Continued innovation in MS technologies and collaborative efforts are essential to overcome existing challenges and ensure sustainable solutions for mitigating the risks associated with emerging contaminants. Full article

Precision agriculture relies on highly detailed soil maps to optimize resource use. Proximal sensing methods, such as EMI, require a certain number of soil samples and laboratory analysis to interpolate the characteristics of the soil. NIR diffuse reflectance spectroscopy offers a rapid, low-cost alternative that increases datapoints and map accuracy. This study tests and optimizes a methodology for high-detail soil mapping in a 2.5 ha hazelnut grove in Grosseto, Southern Tuscany, Italy, using both EMI sensors (GF Mini Explorer, Brno, Czech Republic) and a handheld NIR spectrometer (Neospectra Scanner, Si-Ware Systems, Menlo Park, CA, USA). In addition to two profiles selected by clustering, another 35 topsoil augerings (0–30 cm) were added. Laboratory analyses were performed on only five samples (two profiles + three samples from the augerings). Partial least square regression (PLSR) with a national spectral library, augmented by the five local samples, predicted clay, sand, organic carbon (SOC), total nitrogen (TN), and cation exchange capacity (CEC). The 37 predicted datapoints were used for spatial interpolation, using the ECa map, elevation, and DEM derivatives as covariates. Kriging with external drift (KED) was used to spatialize the results. The errors of the predictive maps were calculated using five additional validation points analyzed by conventional methods. The validation showed good accuracy of the predictive maps, particularly for SOC and TN. Full article

Soil, a non-renewable resource, requires continuous monitoring to prevent degradation and support sustainable agriculture. Visible-near-infrared (Vis-NIR) spectroscopy is a rapid and cost-effective method for predicting soil properties. While traditional machine learning methods are commonly used for modeling Vis-NIR spectral data, large datasets may benefit more from advanced deep learning techniques. In this study, based on the large soil spectral library LUCAS, we aimed to enhance regression model performance in soil property estimation by combining Transformer and convolutional neural network (CNN) techniques to predict 11 soil properties (clay, silt, pH in CaCl₂, pH in H₂O, CEC, OC, CaCO₃, N, P, and K). The Transformer-CNN model accurately predicted most soil properties, outperforming other methods (partial least squares regression (PLSR), random forest regression (RFR), support vector machine regression (SVR), Long Short-Term Memory (LSTM), ResNet18) with a 10–24 percentage point improvement in the coefficient of determination (R²). The Transformer-CNN model excelled in predicting pH in CaCl₂, pH in H₂O, OC, CaCO₃, and N (R² = 0.94–0.96, RPD > 3) and performed well for clay, sand, CEC, P, and K (R² = 0.77–0.85, 2 < RPD < 3). This study demonstrates the potential of Transformer-CNN in enhancing soil property prediction, although future work should aim to optimize computational efficiency and explore a wider range of applications to ensure its utility in different agricultural settings. Full article

The composition of clay minerals in soils, and more particularly the presence of montmorillonite (as part of the smectite family), is a key factor in soil swell–shrinking as well as off–road vehicle mobility. Detecting these topsoil clay minerals and quantifying the montmorillonite abundance are a challenge since they are usually intimately mixed with other minerals, soil organic carbon and soil moisture content. Imaging spectroscopy coupled with unmixing methods can address these issues, but the quality of the estimation degrades the coarser the spatial resolution is due to pixel heterogeneity. With the advent of UAV-borne and proximal hyperspectral acquisitions, it is now possible to acquire images at a centimeter scale. Thus, the objective of this paper is to evaluate the accuracy and limitations of unmixing methods to retrieve montmorillonite abundance from very-high-resolution hyperspectral images (1.5 cm) acquired from a camera installed on top of a bucket truck over three different agricultural fields, in Loiret department, France. Two automatic endmember detection methods based on the assumption that materials are linearly mixed, namely the Simplex Identification via Split Augmented Lagrangian (SISAL) and the Minimum Volume Constrained Non-negative Matrix Factorization (MVC-NMF), were tested prior to unmixing. Then, two linear unmixing methods, the fully constrained least square method (FCLS) and the multiple endmember spectral mixture analysis (MESMA), and two nonlinear unmixing ones, the generalized bilinear method (GBM) and the multi-linear model (MLM), were performed on the images. In addition, several spectral preprocessings coupled with these unmixing methods were applied in order to improve the performances. Results showed that our selected automatic endmember detection methods were not suitable in this context. However, unmixing methods with endmembers taken from available spectral libraries performed successfully. The nonlinear method, MLM, without prior spectral preprocessing or with the application of the first Savitzky–Golay derivative, gave the best accuracies for montmorillonite abundance estimation using the USGS library (RMSE between 2.2–13.3% and 1.4–19.7%). Furthermore, a significant impact on the abundance estimations at this scale was in majority due to (i) the high variability of the soil composition, (ii) the soil roughness inducing large variations of the illumination conditions and multiple surface scatterings and (iii) multiple volume scatterings coming from the intimate mixture. Finally, these results offer a new opportunity for mapping expansive soils from imaging spectroscopy at very high spatial resolution. Full article

Soil visible and near–infrared reflectance spectroscopy is an effective tool for the rapid estimation of soil organic carbon (SOC). The development of spectroscopic technology has increased the application of spectral libraries for SOC research. However, the direct application of spectral libraries for SOC prediction remains challenging due to the high variability in soil types and soil–forming factors. This study aims to address this challenge by improving SOC prediction accuracy through spectral classification. We utilized the European Land Use and Cover Area frame Survey (LUCAS) large–scale spectral library and employed a geographically weighted principal component analysis (GWPCA) combined with a fuzzy c–means (FCM) clustering algorithm to classify the spectra. Subsequently, we used partial least squares regression (PLSR) and the Cubist model for SOC prediction. Additionally, we classified the soil data by land cover types and compared the classification prediction results with those obtained from spectral classification. The results showed that (1) the GWPCA–FCM–Cubist model yielded the best predictions, with an average accuracy of R² = 0.83 and RPIQ = 2.95, representing improvements of 10.33% and 18.00% in R² and RPIQ, respectively, compared to unclassified full sample modeling. (2) The accuracy of spectral classification modeling based on GWPCA–FCM was significantly superior to that of land cover type classification modeling. Specifically, there was a 7.64% and 14.22% improvement in R² and RPIQ, respectively, under PLSR, and a 13.36% and 29.10% improvement in R² and RPIQ, respectively, under Cubist. (3) Overall, the prediction accuracy of Cubist models was better than that of PLSR models. These findings indicate that the application of GWPCA and FCM clustering in conjunction with the Cubist modeling technique can significantly enhance the prediction accuracy of SOC from large–scale spectral libraries. Full article