Search Results (18)

The paper reports the first findings of a series of alkali carbonate, chloride, and sulfate minerals among the usual groundmass kimberlite minerals, such as olivine, phlogopite, monticellite, calcite, spinel-group minerals, perovskite, ilmenite, rutile, and apatite. The sample was collected from an unserpentinized coherent kimberlite dyke that crosscuts earlier volcaniclastic kimberlite in the central part of the Udachnaya-East pipe. This rock can be described as primary/original kimberlite that did not interact with external/internal hydrothermal fluids either during its formation or after its crystallization. At least three alkali-rich carbonates have been found, a previously unknown (and perhaps, a new one) Na-, Ca-, K-, and S-rich carbonate with the calculated empirical formula (Na,K)₆Ca₄(CO₃,SO₄)₇, shortite Na₂Ca₂(CO₃)₃, and nyerereite (Na,K)₂Ca(CO₃)₂. Chlorides in this kimberlite are halite NaCl and sylvite KCl, and the sulfate is aphthitalite K₃Na(SO₄)₂. The content of the Na-Ca-K-S-rich carbonate in the rock is ~15 vol %, that of shortite and halite is ≤5 vol % each, and those of sylvite and aphthitalite are ≤1 vol %. All alkali-rich minerals are of late magmatic origin. This follows from that (i) the studied kimberlite does not contain any secondary water-rich minerals of hydrothermal transformation of the rocks, such as serpentine, chlorite or iowaite; and (ii) crystalline inclusions of such usual kimberlite minerals as olivine, phlogopite, monticellite, calcite, spinel, perovskite, and apatite were found within Na-Ca-K-S-rich carbonate and halite. This publication expands the list of minerals of magmatic origin identified in the groundmass of worldwide kimberlites by at least three minerals: Na-Ca-K-S-rich (new?) carbonate, sylvite, and aphthitalite. It is important to note that all alkali carbonates, chlorides, and sulfates are unstable during secondary hydrothermal alterations of kimberlites, and hence, these minerals cannot be found in serpentinized rocks. Full article

Phlogopite is a crucial indicator for effectively constraining the magmatic evolution and emplacement mechanism of kimberlite. In this study, samples were collected from the No. 110 kimberlite pipe within diamond belt I and the No. 50 kimberlite pipe within diamond belt II in the southern Liaoning diamond mining area in the eastern North China Craton (NCC). Zonation is highly developed in the phlogopite; the major and trace element compositions of the phlogopite zonation in the samples were analyzed. In this study, phlogopite from the No. 50 pipe kimberlite (#50 phlogopite) zonation is divided into the following components: (1) The cores, low Ti-Cr xenocryst, average Mg^# = 90.6, has a resorption structure, the presence of serpentine and talc minerals in low Ti-Cr cores (xenocrysts) can be used as evidence for hydrothermal metasomatism; (2) cores/inner rims (between core and outer rim), high Ti-Cr, it is thought to be related to the assimilation of mantle materials by deep kimberlite magma, average Mg^# = 88.2; (3) outer rims, low-Cr/Cr-poor, average Mg^# = 82.4, Fe, Al and Ba contents increased, and there was a trend of evolution to biotite composition believed to be related to the metasomatic metamorphism of melt and wall rock during the late magmatic evolution or ascent; (4) rinds, it is characterized by re-enrichment of Mg, rind I (low-Ti-Cr, average Mg^# = 88.4), rind II (high-Ti-Cr, Mg^# = 88.6), rind II may be formed earlier than rind I. Rind is very rare and has been reported for the first time in southern Liaoning kimberlite. This study was only accidentally found in the outermost part of #50 phlogopite, the Mg-rich feature represents an environment in which oxygen fugacity has increased. The phlogopite in samples from pipe No. 110 (#110 phlogopite) exhibits relatively homogeneous characteristics across different zones and is more enriched in Al and Ba, which is likely the result of mantle metasomatism. Due to its euhedral characteristics and limited composition variation, it is considered that #110 phlogopite is more likely to be derived from direct crystallization from magma than from xenocrysts. In addition, based on the simultaneous enrichment of Al and Fe in phlogopite from the core to the outer rim, pipe No. 50 was determined to be a micaceous kimberlite, while pipe No. 110 more closely resembles group I kimberlites. This paper proposes that successive pulses of kimberlite magma emplacement gradually metasomatized the conduit, and subsequent kimberlite magma ascended along the metasomatized conduit, thereby minimizing the interaction between the later magma and the surrounding mantle lithosphere. Full article

The present research discloses a novel hybrid water-cooled Photovoltaic/Parabolic Dish Concentrator coupled with conical cavity receiver and spectral beam splitter (PV/PDC-CCR-BSF). In effect, a compact co-generating solar-concentrating PV system involving a subsequent optical interface has been fully developed and numerically tested. The optical performance of the proposed hybrid solar-concentrating system was modeled and assessed using the RT 3D-4R method while the thermal yield of the system was examined using the Finite Element Method. In addition to that, different configurations of serpentine-shape embedded water-cooling pipes (rectangle, semicircle, semi-ellipse and triangle) have been tested and optimized for maximum heat collection and minimum operating cell temperature. The performance of all the tested serpentine-shape embedded water-cooling pipes was evaluated with respect to conventional serpentine-shape water-cooling pipes. The outcomes indicated that the triangular cross-section outperforms other shapes in terms of heat dissipation capabilities, with about −446 W and maximum useful thermal power in the medium of the heat transfer fluid of 11.834 kW. Full article

In this paper, the thermo-optical performance using novel cooling strategy improvements for a hybrid photovoltaic/parabolic dish concentrator with a conical thermal receiver using a beam splitter filter (PV/PDC-CTR-BSF) is investigated. The study’s main goal is to improve the cooling effectiveness of the serpentine-shaped cooling duct by investigating the effect of the cross-section shape and positioning of the cooling duct under the PV panel. Typical cooling pipes have either a rectangular or circular cross-section and are usually attached to the back sheet of the PV panel using off-the-shelf adhesives that have very low thermal conductivity. With the advent of 3D printing technology, the back sheets could be 3D-printed with integral cooling ducts of different cross-sections at different locations and orientations within the back sheet that allow for increased heat transfer from the back sheet and thus improve PV/PDC-CTR-BSF’s thermos-optical performance. For this purpose, the study investigates and compares the thermal performance of four different cooling duct cross-sections that include: rectangular, semi-circular, semi-elliptical and triangular. For each of the cooling duct cross-sections, several positions and orientations, which include flush below the back sheet layer and embedded inside the back sheet but positioned at the bottom, middle and top of the back sheet, are examined. Numerical simulations using the commercial software ANSYS FLUENT(R2019) are performed to assess the performance of the cooling ducts and, in turn, the thermo-optical performance of the PV/PDC-CTR-BSF system. The semi-elliptical cross-section duct embedded in the middle of the back sheet was found to yield the best cooling performance since its rate of heat removal from the PV back sheet was found to be the highest. Full article

The application of ground heat exchanger technology in backfill mines can actualize subterranean heat storage, which is one of the most effective solutions for addressing solar energy faults such as intermittence and fluctuation. This paper provides a 3D unsteady heat transfer numerical model for full-size horizontal backfill heat exchangers (BFHEs) with five configurations in a mining layer of a metal mine by using a COMSOL environment. In order to ensure the fairness of the comparative analysis, the pipes of BFHEs studied have the same heat exchange surface area. By comparing and evaluating the heat storage/release characteristics of BFHEs in continuous operation for three years, it was discovered that the helical pipe with serpentine layout may effectively enhance the performance of BFHEs. Compared with the traditional SS BFHEs, the heat storage capacity of the S-FH type is significantly increased by 21.7%, followed by the SA-FH type, which is increased by 11.1%, while the performances of U-DH and SH type are considerably lowered. Also, the impact of the critical structural factors (pitch length and pitch diameter) was further studied using the normalized parameters C₁ and C₂ based on the inner diameter of the pipe. It is discovered that BFHEs should be distributed in a pipe with a lower C₁, and increasing C₂ encourages BFHEs to increase the storaged/released heat of BFHEs. By comparatively analysing the effect of thermal conductivity, it is found that the positive effects of thermal conductivity on the performance of SH, U-DH, SA-FH, and S-FH type BFHEs are found to decrease successively. This work proposes a strategy for improving the heat storage and release potential of BFHEs in terms of optimal pipe arrangement. Full article

The fuel cell with a ten-channel serpentine flow field has a low operating pressure drop, which is conducive to extended test operations and stable use. According to numerical results of the ten-channel serpentine flow field fuel cell, the multi-channel flow field usually has poor mass transmission under the ribs, and the lower pressure drop is not favorable for drainage from the outlet. In this paper, an optimized flow field is developed to address these two disadvantages of the ten-channel fuel cell. As per numerical simulation, the optimized flow field improves the gas distribution in the reaction area, increases the gas flow between the adjacent ribs, improves the performance of PEMFC, and enhances the drainage effect. The optimized flow field can enhance water pipe performance, increase fuel cell durability, and decelerate aging rates. According to further experimental tests, the performance of the optimized flow field fuel cell was better than that of the ten-channel serpentine flow field at high current density, and the reflux design requires sufficient gas flow to ensure the full play of the superior performance. Full article

Radiation cooling, as a new terminal mode that has been gradually emerging in recent years, has attracted more and more attention. However, the problem of condensation has become a vital bottleneck restricting the broad application of radiation-cooling technology. This paper used the numerical simulation method of Ansys Fluent to study the effect of different water supply parameters on the concrete radiant roof’s heat transfer performance, temperature uniformity analysis, and anti-condensation temperature control strategy. The accuracy of the simulation model was verified by comparing the numerical simulation values and measured values of temperature monitoring points. In thermal performance research, the inlet temperature significantly impacted the cooling capacity and radiant surface temperature compared with the inlet flow velocity. In the uniformity study, the distance between the serpentine pipes area and the concrete edge was easily neglected, which was also an important factor affecting the distribution of temperature uniformity. Regarding anti-condensation and performance improvement research, first supplying water at low temperatures and then dynamically adjusting high-temperature water could effectively avoid condensation and improve the radiant roof’s heat transfer performance. The research results could provide technical references for the practical application of radiation roof anti-condensation temperature control technology. Full article

This report deals with the first mineralogical examination of secondary crystallized melt inclusions (CMIs) in healed cracks within olivine in a mantle peridotite xenolith from the V. Grib kimberlite pipe (Arkhangelsk diamondiferous province). In contrast to micro/nano-inclusions in diamonds, the studied CMIs are quite large (up to 50 µm), so that the mineral composition of the CMIs can be determined via conventional analytical approaches, e.g., Raman spectroscopy and scanning electron microscopy. Garnet peridotite is a coarse-grained mantle rock that equilibrates at 3.3 GPa and 750 °C (corresponding to a depth of ~100 km). The CMIs are therefore tiny snapshots of melt that existed in the shallow lithospheric mantle and were entrapped in olivine. In total, nineteen mineral species were identified among the daughter magmatic minerals of the CMIs. Various Na-K-Ca-, Na-Ca-, Na-Mg-, Ca-Mg-, Mg- and Ca-carbonates; Na-Mg-carbonates with the additional anions Cl⁻, SO₄²⁻ and PO₄³⁻; alkali sulfates; chlorides; phosphates; sulfides; oxides; and silicates were established. Within the mineral assemblage, carbonates were predominant, with their abundance being more than 62 vol.%. The CMIs contained twelve alkali-rich minerals; nine of them were Na-bearing and showed bulk molar (Na + K)/Ca ≥ 1. The CMIs’ parental melt was an alkali-rich carbonate liquid that contained low amounts of SiO₂ (≤9.6 wt%) and H₂O (≤2.6 wt%). According to our estimates, the time of complete equilibration between olivine within the healed cracks and host olivine in the mantle at the calculated P-T parameters for the studied xenolith should be no more than several years. Based on this geologically short time span, a genetic link between the studied CMIs and the magmatism that formed the V. Grib kimberlite pipe is suggested. Full article

Silicification in New Caledonian pseudo-karsts developed on peridotite was assessed using δ¹⁸O and δ³⁰Si pairs on quartz cements. The objective was to document the chronology of pseudo-karst development and cementation relative to geomorphic evolution. The latter began at the end of the Eocene with the supergene alteration of peridotites and the subsequent formation of extended lateritic weathering profiles. Neogene uplift favoured the dismantling of these early lateritic profiles and valley deepening. The river incision resulted in (i) the stepping of a series of lateritic paleo-landforms and (ii) the development of a pseudo-karst system with subvertical dissolution pipes preferentially along pre-existing serpentine faults. The local collapse of the pipes formed breccias, which were then cemented by white quartz and Ni-rich talc-like (pimelite). The δ³⁰Si of quartz, ranging between −5‰ and −7‰, are typical of silcretes and close to the minimum values recorded worldwide. The estimated δ¹⁸O of −6 to −12‰ for the fluids are lower than those of tropical rainfall typical of present-day and Eocene–Oligocene climates. Evaporation during drier climatic episodes is the main driving force for quartz and pimelite precipitation. The silicification presents similarities with silcretes from Australia, which are considered predominantly middle Miocene in age. Full article

Climate change and the major threat it poses to the environment and human lives is the major challenge the world faces today. To overcome this challenge, it is recommended that future automobiles have zero carbon exhaust emissions. Even though battery electric vehicles reduce carbon emissions relative to combustion engines, a carbon footprint still remains in the overall ecosystem unless the battery is powered by renewable energy sources. The proton exchange membrane fuel cell (PEMFC) is an alternate source for automotive mobility which, similar to battery electric vehicles, has zero carbon emissions from its exhaust pipe. Moreover, the typical system level efficiency of a PEMFC is higher than an equivalent internal combustion powertrain. This review article covers the background history, working principles, challenges and applications of PEMFCs for automotive transportation and power generation in industries. Since the performance of a PEMFC is greatly influenced by the design of the anode and cathode flow channels, an in-depth review has been carried out on different types of flow channel designs. This review reveals the importance of flow channel design with respect to uniform gas (reactant) distribution, membrane proton conductivity, water flooding and thermal management. An exhaustive study has been carried out on different types of flow channels, such as parallel, serpentine, interdigitated and bio-inspired, with respect to their performance and applications. Full article

Radiant cooling systems (RCS) are gaining acceptance as a heating, ventilation, and air conditioning (HVAC) solution for achieving adequate thermal comfort and maintaining acceptable indoor air quality inside buildings. RCS are well known for their energy-saving potential; however, serious condensation problem hinders the growth of this technology. In order to prevent the risk of condensation, the supply water temperature is kept higher than the dew point temperature of the air inside the room. The full potential of the cooling power of a radiant cooling panel is limited. Therefore, this article is on maximizing the cooling capacity of a radiant cooling panel, in terms of flow configuration. Radiant cooling panels (RCP) with different chilled water pipe configurations are designed and compared, side by side with the conventional serpentine flow configuration. The cooling performance of the radiant cooling panels is evaluated by using computational fluid dynamics (CFD) with Ansys Fluent software (Ansys 2020 R2, PA, USA). Under similar flow and operating conditions, the common serpentine flow configuration exhibits the least effective cooling performance, with the highest pressure drop across the pipe. It is concluded that the proposed designs have the potential of improving the overall efficiency of RCP in terms of temperature distribution, cooling capacity, and pressure drop. Full article

This paper presents a proposal to estimate simultaneously, through nonlinear optimization, the roughness and head loss coefficients in a non-straight pipeline. With the proposed technique, the calculation of friction is optimized by minimizing the fitting error in the Colebrook–White equation for an operating interval of the pipeline from the flow and pressure measurements at the pipe ends. The proposed method has been implemented in MATLAB and validated in a serpentine-shaped experimental pipeline by contrasting the theoretical friction for the estimated coefficients obtained from the Darcy–Weisbach equation for a set of steady-state measurements. Full article

More than forty mineral species of epigenetic origin have been identified in an orthopyroxenite from the Udachnaya-East kimberlite pipe, Daldyn kimberlite field, Siberian platform. Epigenetic phases occur as: (1) Mineral inclusions in the rock-forming enstatite, (2) daughter minerals within large (up to 2 mm) crystallized melt inclusions (CMI) in the rock-forming enstatite, and (3) individual grains and intergrowths in the intergranular space of the xenolith. The studied minerals include silicates (olivine, clinopyroxene, phlogopite, tetraferriphlogopite, amphibole-supergroup minerals, serpentine-group minerals, talc), oxides (several generations of ilmenite and spinel, rutile, perovskite, rare titanates of the crichtonite, magnetoplumbite and hollandite groups), carbonates (calcite, dolomite), sulfides (pentlandite, djerfisherite, pyrrhotite), sulfate (barite), phosphates (apatite and phosphate with a suggested crystal-chemical formula Na₂BaMg[PO₄]₂), oxyhydroxide (goethite), and hydroxyhalides (kuliginite, iowaite). The examined epigenetic minerals are interpreted to have crystallized at different time spans after the formation of the host rock. The genesis of minerals is ascribed to a series of processes metasomatically superimposed onto the orthopyroxenite, i.e., deep-seated mantle metasomatism, infiltration of a kimberlite-related melt and late post-emplacement hydrothermal alterations. The reaction of orthopyroxene with the kimberlite-related melt has led to orthopyroxene dissolution and formation of the CMI, the latter being surrounded by complex reaction zones and containing zoned olivine grains with extremely high-Mg# (up to 99) cores. This report highlights the utility of minerals present in minor volume proportions in deciphering the evolution and modification of mantle fragments sampled by kimberlitic and other deep-sourced magmas. The obtained results further imply that the whole-rock geochemical analyses of mantle-derived samples should be treated with care due to possible drastic contaminations from “hiding” minor phases of epigenetic origin. Full article

A pulsating heat pipe (PHP) contains a wickless design with aligned serpentine tube configuration whose simple structure offers a comparatively easy manufacturing capability. The bends with large curvature are often used for serpentine PHPs. This eventually results in a decline in effective contact surface area between evaporator/condenser and PHP circuitry, thereby impairing the benefit of the wickless design of a PHP. A novel thermal module featuring a 3-D configuration pulsating heat pipe, an evaporator, and a fin-and-tube condenser is proposed to tackle the high-flux application. Methanol is used as the working fluid with a filling ratio of around 60%. Test results indicate the thermal resistance of the proposed module varies from 0.148 K/W to 0.0595 K/W when the supplied power changes from 100 to 1000 W. The proposed thermal module can handle a supplied power up to 1 kW and the corresponding power or heat flux is much higher than any existing literatures. Full article

Ultramafic nickel ores are difficult to process because they contain serpentine, an anisotropic mineral with a nonspherical morphology and multiple pH-dependent surface charges. Dehydroxylation of serpentine in ultramafic nickel ores by microwave treatment is proposed to improve the processability of these ores. Upon heating, serpentine is converted to olivine, an isotropic mineral that is benign in mineral processing circuits. The microwave heating of two ultramafic nickel ores is explored in this paper, as well as effects on mineralogy and grindability. The first ore was sourced from the Okanogan nickel deposit in Washington State, USA, while the second ore was obtained from the Vale-owned Pipe deposit located in the Thomson Nickel Belt in Manitoba, Canada. The ultramafic nickel ores were found to heat well upon exposure to microwave radiation and the heating behaviors were a function of the imaginary permittivities. The temperatures achieved during microwave treatment were sufficient to dehydroxylate serpentine, and the serpentine content in ultramafic nickel ores was reduced by 63–84%. The grindability of ore with consistent texture (OK ore) improved dramatically with microwave treatment, whereas the grindability of ore with inconsistent texture (Pipe ore) was found to decrease. Pentlandite liberation and specific surface area improved for both ores with microwave treatment. Ultimately, microwave pretreatment did not decrease the energy required for grinding under the conditions studied. However, energy savings may be realized when overall process improvements are considered (e.g., grinding, rheology, flotation, material handling, dewatering and tailings treatment). Full article