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Search Results (412)

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21 pages, 5750 KiB  
Article
Numerical Simulations of Coupled Vapor, Water, and Heat Flow in Unsaturated Deformable Soils During Freezing and Thawing
by Sara Soltanpour and Adolfo Foriero
Geotechnics 2025, 5(3), 51; https://doi.org/10.3390/geotechnics5030051 - 4 Aug 2025
Abstract
Freezing and thawing cycles significantly affect the mechanical and hydraulic behavior of soils, posing detrimental challenges for infrastructures in cold climates. This study develops and validates a coupled Thermal–Hydraulic–Mechanical (THM) model using COMSOL Multiphysics (Version 6.3) to demonstrate the complexities of vapor and [...] Read more.
Freezing and thawing cycles significantly affect the mechanical and hydraulic behavior of soils, posing detrimental challenges for infrastructures in cold climates. This study develops and validates a coupled Thermal–Hydraulic–Mechanical (THM) model using COMSOL Multiphysics (Version 6.3) to demonstrate the complexities of vapor and water flux, heat transport, frost heave, and vertical stress build-up in unsaturated soils. The analysis focuses on fine sand, sandy clay, and silty clay by examining their varying susceptibilities to frost action. Silty clay generated the highest amount of frost heave and steepest vertical stress gradients due to its high-water retention and strong capillary forces. Fine sand, on the other hand, produced a minimal amount of frost heave and a polarized vertical stress distribution. The study also revealed that vapor flux is more noticeable in freezing fine sand, while silty clay produces the greatest water flux between the frozen and unfrozen zones. The study also assesses the impact of soil properties including the saturated hydraulic conductivity, the particle thermal conductivity, and particle heat capacity on the frost-induced phenomena. Findings show that reducing the saturated hydraulic conductivity has a greater impact on mitigating frost heave than other variations in thermal properties. Silty clay is most affected by these changes, particularly near the soil surface, while fine sand shows less noticeable responses. Full article
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24 pages, 11697 KiB  
Article
Layered Production Allocation Method for Dual-Gas Co-Production Wells
by Guangai Wu, Zhun Li, Yanfeng Cao, Jifei Yu, Guoqing Han and Zhisheng Xing
Energies 2025, 18(15), 4039; https://doi.org/10.3390/en18154039 - 29 Jul 2025
Viewed by 178
Abstract
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones [...] Read more.
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones in their pore structure, permeability, water saturation, and pressure sensitivity, significant variations exist in their flow capacities and fluid production behaviors. To address the challenges of production allocation and main reservoir identification in the co-development of CBM and tight gas within deep gas-bearing basins, this study employs the transient multiphase flow simulation software OLGA to construct a representative dual-gas co-production well model. The regulatory mechanisms of the gas–liquid distribution, deliquification efficiency, and interlayer interference under two typical vertical stacking relationships—“coal over sand” and “sand over coal”—are systematically analyzed with respect to different tubing setting depths. A high-precision dynamic production allocation method is proposed, which couples the wellbore structure with real-time monitoring parameters. The results demonstrate that positioning the tubing near the bottom of both reservoirs significantly enhances the deliquification efficiency and bottomhole pressure differential, reduces the liquid holdup in the wellbore, and improves the synergistic productivity of the dual-reservoirs, achieving optimal drainage and production performance. Building upon this, a physically constrained model integrating real-time monitoring data—such as the gas and liquid production from tubing and casing, wellhead pressures, and other parameters—is established. Specifically, the model is built upon fundamental physical constraints, including mass conservation and the pressure equilibrium, to logically model the flow paths and phase distribution behaviors of the gas–liquid two-phase flow. This enables the accurate derivation of the respective contributions of each reservoir interval and dynamic production allocation without the need for downhole logging. Validation results show that the proposed method reliably reconstructs reservoir contribution rates under various operational conditions and wellbore configurations. Through a comparison of calculated and simulated results, the maximum relative error occurs during abrupt changes in the production capacity, approximately 6.37%, while for most time periods, the error remains within 1%, with an average error of 0.49% throughout the process. These results substantially improve the timeliness and accuracy of the reservoir identification. This study offers a novel approach for the co-optimization of complex multi-reservoir gas fields, enriching the theoretical framework of dual-gas co-production and providing technically adaptive solutions and engineering guidance for multilayer unconventional gas exploitation. Full article
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17 pages, 4206 KiB  
Article
Influence of Particle Size on the Dynamic Non-Equilibrium Effect (DNE) of Pore Fluid in Sandy Media
by Yuhao Ai, Zhifeng Wan, Han Xu, Yan Li, Yijia Sun, Jingya Xi, Hongfan Hou and Yihang Yang
Water 2025, 17(14), 2115; https://doi.org/10.3390/w17142115 - 16 Jul 2025
Viewed by 272
Abstract
The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by [...] Read more.
The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by soil matrix particle size distribution. Changes in the DNE across porous media with discrete particle size fractions are investigated via stepwise drying experiments. Through quantification of saturation–capillary pressure hysteresis and DNE metrics, three critical signatures are identified: (1) the temporal lag between peak capillary pressure and minimum water saturation; (2) the pressure gap between transient and equilibrium states; and (3) residual water saturation. In the four experimental sets, with the finest material (Test 1), the peak capillary pressure consistently precedes the minimum water saturation by up to 60 s. Conversely, with the coarsest material (Test 4), peak capillary pressure does not consistently precede minimum saturation, with a maximum lag of only 30 s. The pressure gap between transient and equilibrium states reached 14.04 cm H2O in the finest sand, compared to only 2.65 cm H2O in the coarsest sand. Simultaneously, residual water saturation was significantly higher in the finest sand (0.364) than in the coarsest sand (0.086). The results further reveal that the intensity of the DNE scales inversely with particle size and linearly with wetting phase saturation (Sw), exhibiting systematic decay as Sw decreases. Coarse media exhibit negligible hysteresis due to suppressed capillary retention; this is in stark contrast with fine sands, in which the DNE is observed to persist in advanced drying stages. These results establish pore geometry and capillary dominance as fundamental factors controlling non-equilibrium fluid dynamics, providing a mechanistic framework for the refinement of multi-phase flow models in heterogeneous porous systems. Full article
(This article belongs to the Section Soil and Water)
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13 pages, 2559 KiB  
Article
Effects of Sand–Cement Columns on Primary Consolidation Settlement
by Benjamin Abankwa, Mehrdad Razavi, Richard Otoo, Abraham Armah and Sandra Donkor
Appl. Sci. 2025, 15(14), 7690; https://doi.org/10.3390/app15147690 - 9 Jul 2025
Viewed by 217
Abstract
The rapid increase in population and the corresponding increase in developments have necessitated the stabilization of areas with poor soil conditions. Due to consolidation settlement, the soft grounds available are deemed unsuitable for such structures. This paper presents the use of cement additives [...] Read more.
The rapid increase in population and the corresponding increase in developments have necessitated the stabilization of areas with poor soil conditions. Due to consolidation settlement, the soft grounds available are deemed unsuitable for such structures. This paper presents the use of cement additives to build sand–cement columns in saturated clayey soils. The approach significantly reduces consolidation settlement and increases the bearing capacity, providing a viable solution to foundation problems. Consolidation tests were conducted on saturated clay specimens and sand–cement columns arranged in various patterns. A 5% cement content by the dry weight of the sand was used in building sand–cement columns. The results showed that the consolidation settlement rate was high due to the extra drainage formed by the widened pores in the sand–cement columns. The extra drainage caused more water to leave the specimen in a given time. However, after full contact between the loading platen and sand–cement columns, the rate of consolidation settlement decreased. At this stage, sand–cement participated in carrying the load. Additionally, the effect of vertical drainage on speeding up consolidation at higher stress levels was minimal, as the widened pores in the sand–cement columns began to close. Full article
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27 pages, 5832 KiB  
Article
Incorporation of Horizontal Aquifer Flow into a Vertical Vadose Zone Model to Simulate Natural Groundwater Table Fluctuations
by Vipin Kumar Oad, Adam Szymkiewicz, Tomasz Berezowski, Anna Gumuła-Kawęcka, Jirka Šimůnek, Beata Jaworska-Szulc and René Therrien
Water 2025, 17(14), 2046; https://doi.org/10.3390/w17142046 - 8 Jul 2025
Viewed by 1108
Abstract
The main goal of our work was to evaluate approaches for modeling lateral outflow from shallow unconfined aquifers in a one-dimensional model of vertical variably-saturated flow. The HYDRUS-1D model was modified by implementing formulas representing lateral flow in an aquifer, with linear or [...] Read more.
The main goal of our work was to evaluate approaches for modeling lateral outflow from shallow unconfined aquifers in a one-dimensional model of vertical variably-saturated flow. The HYDRUS-1D model was modified by implementing formulas representing lateral flow in an aquifer, with linear or quadratic drainage functions describing the relationship between groundwater head and flux. The results obtained by the modified HYDRUS-1D model were compared to the reference simulations with HydroGeoSphere (HGS), with explicit representation of 2D flow in unsaturated and saturated zones in a vertical cross-section of a strip aquifer, including evapotranspiration and plant water uptake. Four series of simulations were conducted for sand and loamy sand soil profiles with deep (6 m) and shallow (2 m) water tables. The results indicate that both linear and quadratic drainage functions can effectively capture groundwater table fluctuations and soil water dynamics. HYDRUS-1D demonstrates notable accuracy in simulating transient fluctuations but shows higher variability near the surface. The study concludes that both quadratic and linear drainage boundary conditions can effectively represent horizontal aquifer flow in 1D models, enhancing the ability of such models to simulate groundwater table fluctuations. Full article
(This article belongs to the Section Hydrology)
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29 pages, 9532 KiB  
Article
Heterogeneity of the Triassic Lacustrine Yanchang Shale in the Ordos Basin, China, and Its Implications for Hydrocarbon Primary Migration
by Yuhong Lei, Likuan Zhang, Xiangzeng Wang, Naigui Liu, Ming Cheng, Zhenjia Cai and Jintao Yin
Appl. Sci. 2025, 15(13), 7392; https://doi.org/10.3390/app15137392 - 1 Jul 2025
Viewed by 309
Abstract
The pathways and mechanisms of primary hydrocarbon migration, which are still not well understood, are of great significance for evaluating both conventional and unconventional oil and gas resources, understanding the mechanisms of shale oil retention, and predicting sweet spots. To investigate the petrography, [...] Read more.
The pathways and mechanisms of primary hydrocarbon migration, which are still not well understood, are of great significance for evaluating both conventional and unconventional oil and gas resources, understanding the mechanisms of shale oil retention, and predicting sweet spots. To investigate the petrography, geochemistry, and pore systems of organic-rich mudstones and organic-lean sand-silt intervals in core samples from the Yanchang shale in the Ordos Basin, China, we conducted thin-section observation, X-ray diffraction, Rock-Eval pyrolysis, field emission scanning electron microscopy (FE-SEM), and porosity analysis. Sand-silt intervals are heterogeneously developed within the Yanchang shale. The petrology, mineral composition, geochemistry, type, and content of solid organic matter as well as the pore type, pore size, and porosity of these intervals differ significantly from those of mudstones. Compared with mudstones, sand-silt intervals typically have coarser detrital grain sizes, higher contents of quartz, feldspar, and migrated solid bitumen (MSB), larger pore sizes, higher porosity, and higher oil saturation index (OSI). In contrast, they have lower contents of clay minerals, total organic carbon (TOC), free liquid hydrocarbons (S1), and total residual hydrocarbons (S2). The sand-silt intervals in the Yanchang shale serve as both pathways for hydrocarbon primary migration and “micro reservoirs” for hydrocarbon storage. The interconnected inorganic and organic pore systems, organic matter networks, fractures, and sand-silt intervals form the hydrocarbons’ primary migration pathways within the Yanchang shale. A model for the primary migration of hydrocarbons within the Yanchang shale is proposed. Full article
(This article belongs to the Section Earth Sciences)
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24 pages, 11727 KiB  
Article
Experimental Evaluation of Residual Oil Saturation in Solvent-Assisted SAGD Using Single-Component Solvents
by Fernando Rengifo Barbosa, Amin Kordestany and Brij Maini
Energies 2025, 18(13), 3362; https://doi.org/10.3390/en18133362 - 26 Jun 2025
Viewed by 315
Abstract
The massive heavy oil reserves in the Athabasca region of northern Alberta depend on steam-assisted gravity drainage (SAGD) for their economic exploitation. Even though SAGD has been successful in highly viscous oil recovery, it is still a costly technology because of the large [...] Read more.
The massive heavy oil reserves in the Athabasca region of northern Alberta depend on steam-assisted gravity drainage (SAGD) for their economic exploitation. Even though SAGD has been successful in highly viscous oil recovery, it is still a costly technology because of the large energy input requirement. Large water and natural gas quantities needed for steam generation imply sizable greenhouse gas (GHG) emissions and extensive post-production water treatment. Several methods to make SAGD more energy-efficient and environmentally sustainable have been attempted. Their main goal is to reduce steam consumption whilst maintaining favourable oil production rates and ultimate oil recovery. Oil saturation within the steam chamber plays a critical role in determining both the economic viability and resource efficiency of SAGD operations. However, accurately quantifying the residual oil saturation left behind by SAGD remains a challenge. In this experimental research, sand pack Expanding Solvent SAGD (ES-SAGD) coinjection experiments are reported in which Pentane -C5H12, and Hexane -C6H14 were utilised as an additive to steam to produce Long Lake bitumen. Each solvent is assessed at three different constant concentrations through time using experiments simulating SAGD to quantify their impact. The benefits of single-component solvent coinjection gradually diminish as the SAGD process approaches its later stages. ES-SAGD pentane coinjection offers a smaller improvement in recovery factor (RF) (4% approx.) compared to hexane (8% approx.). Between these two single-component solvents, 15 vol% hexane offered the fastest recovery. The obtained data in this research provided compelling evidence that the coinjection of solvent under carefully controlled operating conditions, reduced overall steam requirement, energy consumption, and residual oil saturation allowing proper adjustment of oil and water relative permeability curve endpoints for field pilot reservoir simulations. Full article
(This article belongs to the Special Issue Enhanced Oil Recovery: Numerical Simulation and Deep Machine Learning)
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28 pages, 9170 KiB  
Article
Electrical Characteristics and Desaturation Effectiveness During Horizontal Electrolysis in Calcareous Sand
by Yumin Chen, Ying Zhou, Runze Chen, Saeed Sarajpoor and Xiao Xie
Buildings 2025, 15(12), 2061; https://doi.org/10.3390/buildings15122061 - 15 Jun 2025
Viewed by 378
Abstract
Electrolysis desaturation has emerged as an innovative technique to mitigate liquefaction risk by reducing soil saturation in liquefiable foundations. This study evaluated the effectiveness of horizontal electrolysis on calcareous sandy foundations in marine environments by employing 35‰ NaCl solution as pore fluid under [...] Read more.
Electrolysis desaturation has emerged as an innovative technique to mitigate liquefaction risk by reducing soil saturation in liquefiable foundations. This study evaluated the effectiveness of horizontal electrolysis on calcareous sandy foundations in marine environments by employing 35‰ NaCl solution as pore fluid under different current intensities (1A, 2A, and 4A). Experimental results demonstrated that hydrogen gas was generated at the cathode, while chlorine gas was produced at the anode, with peak gas retention rates of 100%, 90.83%, and 63.26% for 1A; 97.61%, 79.04%, and 60.94% for 2A; and 95.37%, 48.49%, and 42.81% for 4A over three electrolysis cycles. Three key findings emerged from our investigation: First, the resistivity of calcareous sand displayed a three-stage variation pattern, primarily governed by temperature and gas content evolution. Second, the temperature-corrected resistivity model provided reliable saturation data, revealing that electrode-adjacent soil layers exhibited significantly greater saturation reduction compared to intermediate layers. The average saturation variation during a single electrolysis cycle reached 3.2%, 2.6%, and 4.4% for 1A, 2A, and 4A, respectively, in the soil layers near the electrodes, compared to 2.1%, 1.7%, and 3.3% in the middle soil layers under the same current intensities. Third, upon stopping electrolysis, gas redistribution led to decreased saturation in upper soil layers, with lower current intensities more effective in retaining gases within the soil matrix. Based on these findings, an electrolytic influence coefficient for calcareous sand applicable to Archie’s formulation is proposed. This study enhances the understanding of the mechanism of electrolysis desaturation and provides a theoretical basis for the effectiveness of electrolysis desaturation on calcareous sand foundations. Full article
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21 pages, 2116 KiB  
Article
Sources of Uncertainty in Bender Element Testing: Execution and Interpretation Challenges in Reconstituted Sandy Soils
by António M. G. Pedro, Paulino Dias Santos, Luís Araújo Santos and Paulo Coelho
Geotechnics 2025, 5(2), 39; https://doi.org/10.3390/geotechnics5020039 - 9 Jun 2025
Viewed by 1114
Abstract
This paper discusses the principal sources of uncertainty in the execution and interpretation of Bender Element (BE) tests conducted on reconstituted sand samples. Based on the experience accumulated by the Geotechnical Laboratory of the University of Coimbra, the study addresses three critical stages [...] Read more.
This paper discusses the principal sources of uncertainty in the execution and interpretation of Bender Element (BE) tests conducted on reconstituted sand samples. Based on the experience accumulated by the Geotechnical Laboratory of the University of Coimbra, the study addresses three critical stages of the testing process: sample preparation, test execution, and result interpretation. For each stage, the key challenges are identified, and potential solutions are proposed. Particular emphasis is placed on the control of relative density and sample saturation during preparation, as well as on factors affecting signal quality and time lag of the system during test execution. The interpretation of the results is analyzed with respect to the limitations of currently employed methods. The overall reliability of the procedures employed throughout the testing process is also assessed, with the results providing guidance for improving the accuracy and consistency of BE test outcomes. Full article
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13 pages, 5825 KiB  
Article
Investigating the Physical Mechanisms of Quicksand Using a Custom-Designed Experimental Apparatus
by Jianhui Long, Rui Dong, Kaixin Zhang, Hangyu Weng and Zhiqiang Yi
Appl. Sci. 2025, 15(12), 6415; https://doi.org/10.3390/app15126415 - 6 Jun 2025
Viewed by 476
Abstract
Quicksand initiation in saturated sandy soils represents a critical geohazard with significant implications for geotechnical infrastructure stability. Despite its importance, the granular-scale mechanisms driving the physical state transitions during quicksand remain insufficiently understood. This study employs a custom-designed hydrodynamic seepage testing system to [...] Read more.
Quicksand initiation in saturated sandy soils represents a critical geohazard with significant implications for geotechnical infrastructure stability. Despite its importance, the granular-scale mechanisms driving the physical state transitions during quicksand remain insufficiently understood. This study employs a custom-designed hydrodynamic seepage testing system to investigate these mechanisms, enabling precise regulation of hydrodynamic velocity and real-time monitoring of pressure variations. Through experiments on quartz sand specimens with varying particle gradations, we demonstrate that particle gradation primarily governs quicksand susceptibility, while hydrodynamic velocity controls its initiation timing and exhibits a linear correlation with seepage discharge. The quicksand process evolves through three distinct stages: self-consolidation, reorganization, and quicksand initiation, with the reorganization stage identified as the pivotal phase where particle rearrangement dictates system stability. These findings elucidate the intrinsic physical mechanisms of quicksand as a hydraulic failure phenomenon, offering valuable insights for predictive modeling and geohazard mitigation in granular media. Full article
(This article belongs to the Section Civil Engineering)
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16 pages, 3116 KiB  
Article
Colloidal Silica-Stabilized Subgrade for Self-Sensing Vehicle Stress Affected by Unsaturation and Crack
by Shuaishuai Ruan, Weifeng Jin and Xiaohui Liao
J. Mar. Sci. Eng. 2025, 13(6), 1127; https://doi.org/10.3390/jmse13061127 - 5 Jun 2025
Viewed by 398
Abstract
Colloidal silica can seep through calcareous sand in the subgrade, forming colloidal-silica-cemented sand with self-sensing ability—that is, it is sensitive to stress changes caused by vehicle loading. Its self-sensing sensitivity is higher than that of traditional Portland-cement-based self-sensing materials. The self-sensing mechanism is [...] Read more.
Colloidal silica can seep through calcareous sand in the subgrade, forming colloidal-silica-cemented sand with self-sensing ability—that is, it is sensitive to stress changes caused by vehicle loading. Its self-sensing sensitivity is higher than that of traditional Portland-cement-based self-sensing materials. The self-sensing mechanism is attributed to the ionic conductive network formed by seawater. However, a change in tidal water level causes an unsaturated state, and foundation deformation leads to cracking of the roadbed. The effect of unsaturation and cracking on self-sensing remains unclear, and they have not been studied in the previous literature. The aim of this paper is to study the self-sensing ability of subgrades formed via colloidal-silica-cemented sand under unsaturated and cracked states, as well as to explore the underlying mechanisms. Specimens with different degrees of saturation and different levels of joint roughness in precracks were prepared; then, the self-sensing ability was tested using the four-electrode method for each specimen under cyclic stress loading. NMR (nuclear magnetic resonance) and an unsaturated triaxial apparatus were also used to investigate the underlying mechanisms. This paper discovers that (1) either unsaturation or crack alone can increase self-sensing, but their self-sensing sensitivities are on the same order; (2) under the coupled effect of unsaturation and cracking, the self-sensing sensitivity increases by one order of magnitude, which is higher than when only unsaturation or cracking exists; and (3) the joint roughness of precracks does not affect self-sensing in the saturated state, but it affects self-sensing dramatically in the unsaturated state. The NMR test demonstrated the conductive ionic water within nanopores, which forms the conductive network for self-sensing. Unsaturation causes suction-induced shrinkage based on the unsaturated triaxial apparatus, while unsaturation increases self-sensing sensitivity, indicating that shrinkage is accompanied by self-sensing improvement. This paper provides the effects of unsaturation and cracking on the self-sensing capabilities of colloidal-silica-cemented sand, and the findings can contribute to the knowledge of subgrades formed via colloidal-silica-cemented sand for stress-sensing under traffic loading. Full article
(This article belongs to the Section Ocean Engineering)
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18 pages, 2361 KiB  
Article
Sensitivity Analysis of the Influence of Heavy-Intensity Rain Duration on the Stability of Granular Soil Slopes Under Unsaturated Conditions
by Javier Bustamante, Ricardo Gallardo-Sepúlveda, Edison Atencio and Pablo F. Parra
Appl. Sci. 2025, 15(11), 6074; https://doi.org/10.3390/app15116074 - 28 May 2025
Viewed by 456
Abstract
This study investigates slope stability under rainfall infiltration using numerical modeling in Plaxis 2D, comparing poorly graded sand (6.5% fines) and well-graded sand (11.9% fines) under high-intensity rainfall of 30 mm/h for durations of 8, 12, 18, and 24 h. The results indicate [...] Read more.
This study investigates slope stability under rainfall infiltration using numerical modeling in Plaxis 2D, comparing poorly graded sand (6.5% fines) and well-graded sand (11.9% fines) under high-intensity rainfall of 30 mm/h for durations of 8, 12, 18, and 24 h. The results indicate that, as rainfall duration increases, soil saturation rises, leading to reduced suction, lower shear strength, and decreased safety factors (S.F.s). Poorly graded sand shows minimal sensitivity to infiltration, with the S.F. dropping by only 4.3% after 24 h, maintaining values close to the initial 1.126. Conversely, well-graded sand demonstrates significant sensitivity, with its S.F. decreasing by 25.4% after 8 h and 73.7% after 24 h, due to higher water retention capacity and suction. This highlights the significant contrast in stability behavior between the two soil types. The findings emphasize the critical role of soil hydro-mechanical properties in assessing slope stability, especially in regions with intense rainfall. This study establishes a methodology for correlating safety factor variations with rainfall duration and soil type, offering valuable insights for modeling and mitigating landslide risks in rainy climates, considering the hydraulic and mechanical parameters of the soil. Full article
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16 pages, 3152 KiB  
Article
Determining the Minimum Detection Limit of Methane Hydrate Using Associated Alpha Particle Technique
by Josip Batur, Davorin Sudac, Ilker Meric, Vladivoj Valković, Karlo Nađ and Jasmina Obhođaš
J. Mar. Sci. Eng. 2025, 13(6), 1050; https://doi.org/10.3390/jmse13061050 - 27 May 2025
Viewed by 396
Abstract
Methane hydrate is a crystalline compound in which methane is trapped within a water lattice under high-pressure, low-temperature conditions. Its presence in oceanic and permafrost sediments makes it a promising alternative energy source, but also a potential contributor to climate change. Accurate in [...] Read more.
Methane hydrate is a crystalline compound in which methane is trapped within a water lattice under high-pressure, low-temperature conditions. Its presence in oceanic and permafrost sediments makes it a promising alternative energy source, but also a potential contributor to climate change. Accurate in situ detection remains a major challenge due to hydrate’s dispersed occurrence and the limitations of conventional geophysical methods. This study investigates the feasibility of using the associated alpha particle (AAP) technique for the direct detection of methane hydrate. A series of laboratory measurements was conducted on sand-based samples with varying levels of methane hydrate simulant. Using a 14 MeV neutron generator and a LaBr3 gamma detector, the 4.44 MeV carbon peak was monitored and calibrated against volumetric hydrate saturation. The minimum detection limit (MDL) was experimentally determined to be (67±25)%. Although the result is subject to high uncertainty, it provides a preliminary benchmark for evaluating the method’s sensitivity and highlights the potential of AAP-based gamma spectroscopy for in situ detection, especially when supported by higher neutron flux in future applications. Full article
(This article belongs to the Special Issue Advances in Marine Gas Hydrates)
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21 pages, 14985 KiB  
Article
The Fate and Clogging Mechanisms of Suspended Particles in Natural Biofilm-Coated Porous Media
by Huan Wang, Junjie Wu, Dengbo Yang, Yudao Chen and Yuan Xia
Water 2025, 17(10), 1480; https://doi.org/10.3390/w17101480 - 14 May 2025
Viewed by 556
Abstract
Managed aquifer recharge (MAR) is widely used globally. However, clogging events remain a major obstacle to long-term operations. This study investigated the effects of natural biofilms on the migration and deposition of suspended particles (SPs) at varying concentrations using column experiments and multiple [...] Read more.
Managed aquifer recharge (MAR) is widely used globally. However, clogging events remain a major obstacle to long-term operations. This study investigated the effects of natural biofilms on the migration and deposition of suspended particles (SPs) at varying concentrations using column experiments and multiple analytical methods. At 74 h, the K′ in the high-concentration group (HT) with biofilm coating decreased by 77.3%, while, in the high-concentration group (HTCK) without biofilm coating, the K′ decreased by 68.5%. Within the same recharge time, the K′ in the medium-concentration group without biofilm coating decreased by 59.9%. The results show that the biofilm covering the porous medium promotes the clogging of suspended particles. Compared with the high-concentration group, the development of porous medium blockage was slower in the low-concentration suspended particle group. SEM and CT analyses revealed that the biofilms altered the surface roughness of the porous media, thereby promoting SP deposition. The study also confirmed that the interactions between SPs and biofilms in recharge water, including electrostatic interactions, hydrophobic interactions, and extracellular polymer flocculation, collectively exacerbated the clogging process in MAR. XDLVO analysis indicated that the biofilm-coated porous media reduced the electrostatic interaction potential energy and energy barrier between SPs and quartz sand, thereby facilitating kaolin deposition in saturated porous media. Correlation and significance analyses identified hydrophobic interactions as the primary mechanism driving SP–biofilm combined with clogging. Moreover, the reduced SP concentrations in the recharge water increased the SP migration distance in porous media, slowing the clogging progression in low-SP groups. These findings offer valuable insights into the prevention and management of MAR clogging caused by the coexistence of biofilms and SPs. Full article
(This article belongs to the Section Hydrogeology)
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31 pages, 16743 KiB  
Article
Model Test and Numerical Analysis of Landslides in Layered Ion-Type Rare Earth Ore Under Rainfall and Mineral Leaching Conditions
by Zhongqun Guo, Yanshuo Liu, Qiqi Liu, Manqiu Zhong and Qiangqiang Liu
Water 2025, 17(10), 1469; https://doi.org/10.3390/w17101469 - 13 May 2025
Viewed by 464
Abstract
The South China region is characterized by diverse landforms and significant stratification of geological materials. The rock and soil layers in this area have obvious layering characteristics. The stability of layered slopes is a critical issue in the safe mining of southern ion-type [...] Read more.
The South China region is characterized by diverse landforms and significant stratification of geological materials. The rock and soil layers in this area have obvious layering characteristics. The stability of layered slopes is a critical issue in the safe mining of southern ion-type rare earth ores. This study investigates the morphological changes, pore water pressure, and moisture content variation of layered ion-type rare earth ore slopes under the combined effects of rainfall and liquid infiltration through indoor model tests. A numerical simulation was conducted to analyze the variations in pore water pressure, moisture content, slope displacement, and safety factor under different working conditions. As rainfall intensity increases, the interface between soil layers in sandy–silty clay slopes is more likely to form a saturated water retention zone, causing rapid pore water pressure buildup and a significant reduction in shear strength. For the silty–sand clay slopes, the low permeability of the upper silty clay layer limits the infiltration rate of water, resulting in significant interlayer water retention effects, which induce softening and an increased instability risk. The higher the initial moisture content, the longer the infiltration time, which reduces the matrix suction of the soil and significantly weakens the shear strength of the slope. When the initial moisture content and rainfall intensity are the same, the safety factor of the silty–sand clay slope is higher than that of the sandy–silty clay slope. When rainfall intensity increases from 10 mm/h to 30 mm/h, the safety factor of the sandy–silty clay slope decreases from 1.30 to 1.15, indicating that the slope is approaching a critical instability state. Full article
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