Search Results (338)

Introduction: Heavy metal contamination in water represents a major environmental and public health challenge because toxic ions frequently occur as complex multi-species mixtures rather than isolated pollutants. This study presents a numerical design and optimization of a surface plasmon resonance (SPR) sensor based on a LaF/Au/BaTiO₃/WS₂ heterostructure for monitoring refractive-index changes associated with mixed heavy metal ions in aqueous media. Methodology: The optical response of the multilayer sensor was evaluated using the transfer matrix method under TM-polarized illumination at 633 nm. Systematic optimization was performed for the prism substrate, Au thickness, dielectric oxide layer, and 2D nanomaterial interface. The final configuration consisted of a LaF prism, 50 nm Au film, 2.0 nm BaTiO₃ spacer, and 0.80 nm WS₂ monolayer. Sensor performance was assessed using resonance-angle shift, sensitivity, detection accuracy, quality factor, figure of merit, FWHM, attenuation, and estimated limit of detection. Results and Discussion: The optimized LaF/Au/BaTiO₃/WS₂ configuration produced stable simulated SPR responses across single, binary, quaternary, and five-ion heavy metal matrices. The WS₂ monolayer provided the highest angular displacement among the evaluated 2D materials, while BaTiO₃ improved field confinement and limited optical damping in the numerical model. The configuration maintained attenuation near 1.6%, FWHM values around 7.9°, detection accuracy between 0.030 and 0.032 deg⁻¹, and model-based refractometric LoD values down to 3.49 × 10⁻⁵ RIU under the assumed angular-resolution criterion. Conclusions: The proposed LaF/Au/BaTiO₃/WS₂ SPR configuration provides a numerical framework for label-free monitoring of refractive-index changes associated with complex heavy-metal-ion mixtures in contaminated water. Experimental fabrication and testing are required to validate the simulated performance. Full article

This study presents a systematic terahertz time-domain spectroscopy (THz-TDS) investigation of hardened cement paste, framed as a complex-optical measurement in which the real and imaginary parts of the response probe distinct microstructural attributes. Transmission-mode measurements were made on pastes with water-to-cement (w/c) ratios of 0.3, 0.4, and 0.5 at curing ages of 7, 14, 28, and 56 days. The effective refractive index, obtained from the time-domain pulse delay (7, 28, and 56 days, paired with mercury intrusion porosimetry), correlates strongly and linearly with porosity over nine porosity-paired conditions spanning 15.1–30.4% (pooled R² = 0.94, p < 0.001). In a quasi-static effective-medium framework—where the pores a re far smaller than the THz wavelength—this reflects the dependence of the effective permittivity on the solid volume fraction: the Bruggeman model outperforms the Maxwell–Garnett model, and all data fall within the Wiener bounds, lying close to the upper bound, indicating a continuously connected solid matrix with isolated pores. Cross-validated porosity estimation is reliable to within about ±2 percentage points (refractive-index uncertainty ±0.02–0.04). The absorption follows a power law (β ≈ 1.0–1.3) characteristic of disorder-activated vibrational absorption, in which the loss of long-range order in the amorphous C–S–H relaxes the crystalline selection rules and couples the THz field to the full vibrational density of states. The refractive index (structure-sensitive, governed by volume fraction) and the absorption (material-sensitive, governed by solid disorder; estimated loss tangent of order 0.1) thus form two complementary channels. Combining the THz-derived porosity with the Powers hydration model gives a degree of hydration consistent with literature ranges—an indirect comparison rather than direct validation. These results establish THz-TDS as a non-contact, non-ionizing technique for rapid porosity estimation and hydration assessment of cementitious materials. Full article

Size-exclusion chromatography (SEC) or gel-permeation chromatography (GPC) is an essential tool for determining the molecular weight and polydispersity of water-soluble polymers, including biopolymers used in hydrogels, sealants, bioinks, and other biomedical materials. However, aqueous SEC of polyelectrolytes, i.e., charged polymers, is often complicated by non-size interactions among polymer chains, porous column beads, pore surfaces, frits, tubing, and mobile phase. Salt addition to eluent is commonly used to screen these interactions, but the minimum salt concentration required to restore reliable SEC behavior remains poorly defined, and excessive salt may introduce tailing, refractive-index artifacts, deposits, or instrument concerns. In this study, aqueous SEC with refractive index (RI) and right-angle light scattering (RALS) detection was used to evaluate the effect of salt ($\mathrm{N}{\mathrm{a}}_2\mathrm{S}{\mathrm{O}}_4$) concentration on poly(ethylene oxide) (PEO), a nominally neutral reference standard polymer, and sodium alginate as a model anionic biopolymer. PEO retained a single bell-shaped peak across the tested salt range, but its elution volume and SEC/RALS-derived molecular weights varied slightly with salt concentration, showing that even a nominally neutral reference polymer is affected by mobile-phase conditions. Alginate showed much stronger salt dependence: eluent at very low salt concentration produced broad, noisy, and convoluted chromatograms, whereas increasing salt concentration progressively narrowed the main peak. The first condition that produced a clear, approximately symmetric RI/RALS main peak was $6.25\times {10}^{-3} \mathrm{M}$ $\mathrm{N}{\mathrm{a}}_2\mathrm{S}{\mathrm{O}}_4$, identifying it as the minimum effective salt concentration for this alginate/column/instrument system. To rigorously validate these observations, we propose a set of both qualitative and quantitative peak analyses that objectively confirm the optimal mobile-phase conditions. Ultimately, these results provide a practical workflow for identifying the minimum effective salt concentration required for reliable SEC analysis of water-soluble polymers. Full article

The linear and third-order nonlinear optical (NLO) properties of a water-soluble perylenediimide derivative, N,N′-di(2-(trimethylammonium iodide) ethylene) perylenediimide (TAIPDI), doped with semiconductor nanoparticles (NPs), were systematically investigated under femtosecond laser excitation. ZnO and TiO₂ NPs were synthesized using a pulsed laser ablation technique. Nanocomposite systems were prepared by incorporating different concentrations of ZnO and TiO₂ NPs into the TAIPDI dye solution. The optical properties were characterized using UV–visible absorption spectroscopy together with open- and closed-aperture Z-scan measurements at 800 nm. Linear absorption measurements revealed concentration-dependent modifications in the optical band gap, indicating electronic interaction between the dye molecules and the semiconductor NPs. Open-aperture Z-scan results demonstrated strong nonlinear absorption (NLA) behavior dominated by two-photon absorption and excited-state absorption processes. Closed-aperture measurements showed a negative nonlinear refractive (NLR) index, corresponding to self-defocusing behavior. Both the NLA coefficient and the NLR index increased with increasing NP concentration, resulting in a significant enhancement of the third-order nonlinear susceptibility of the nanocomposite systems. In addition, optical limiting measurements revealed a pronounced reduction in the limiting threshold with increasing nanoparticle concentration, demonstrating improved laser attenuation capability. These findings indicate that ZnO@TAIPDI and TiO₂@TAIPDI nanocomposites are promising candidates for applications in optical limiting, all-optical switching, and advanced photonic devices. Full article

Background/Objectives: Ursodeoxycholic acid (UDCA) is a bile acid widely used for the treatment of cholestatic liver diseases; however, its poor aqueous solubility represents a major limitation for the development of oral liquid formulations, particularly in pediatric patients requiring accurate and flexible dosing. This study aimed to develop and characterize a fully solubilized extemporaneous UDCA oral formulation using the ready-to-use vehicle Wagner, with particular emphasis on the role of hydroxypropyl-β-cyclodextrin (HP-β-CD) as a solubilizing excipient. Methods: Phase-solubility studies, Job’s plot analysis, and ¹H NMR spectroscopy were performed to investigate the host–guest interaction between UDCA and HP-β-CD, confirming the formation of a stable 1:1 inclusion complex responsible for a marked increase in drug solubility. The aqueous solubility of UDCA increased from approximately 0.02 mg/mL in water to 31 ± 1 mg/mL in the Wagner base containing HP-β-CD, compared to ~10 mg/mL in the corresponding cyclodextrin-free vehicle. Chemical stability was evaluated using an HPLC method adapted from the European Pharmacopoeia, employing dual detection (refractive index and photodiode array detector) to ensure specificity and stability-indicating capability. Results: The UDCA solution (20 mg/mL) remained chemically stable for at least 4 months under refrigerated (4–8 °C) and room temperature (25 °C) conditions, with only moderate degradation observed at 40 °C. Physical stability studies confirmed the absence of precipitation, phase separation, or significant pH variations under all storage conditions. Conclusions: Wagner-based formulation enabled the development of a stable and homogeneous UDCA oral solution, providing a complementary formulation strategy to conventional suspension-based preparations. This approach represents a robust and patient-oriented strategy for extemporaneous compounding, particularly suitable for pediatric use. Full article

An optical lens focuses light and a similar device can be developed to focus surface water waves. A detailed description of such hydrodynamic lenses is given, for which the focusing is induced by shaping the bathymetry of the bottom. Classically, the Luneburg lens uses a specific radial variation of the refractive index. The modified Luneburg lens (MLL) introduces an extra degree of freedom, permitting the focal point to be tuned. It is shown how to design the MLL for water waves, and then its performance is evaluated. Compared with a simple parabolic-shaped mount, the MLL is shown to be free of spherical aberration, resulting in a focus with larger intensity and smaller size of the focal point. Moreover, the focusing properties can be tuned and enhanced thanks to the possibility of changing the position of the focal point. The focusing quality of the MLL is described in all water-depth regimes (covering dispersive and non-dispersive waves) and the focusing of linear and nonlinear waves is revealed experimentally. The option of moving the focal point outside the lens, where the water depth is constant, may be useful when locating devices for harvesting wave energy. Full article

Flow over permeable beds is important in sediment transport and mixing processes, yet detailed velocity and stress measurements remain difficult to obtain, particularly close to the sediment–water interface (SWI). In this work, we use refractive-index-matched PIV to study turbulent open-channel flow over and within a permeable bed composed of monodisperse borosilicate glass beads. Measurements are reported for three low-$R{e}_K$ cases, $R{e}_K=0.224$, $R{e}_K=0.335$, and $R{e}_K=0.360$, to resolve the mean velocity structure and the associated viscous, turbulent, Reynolds, and dispersive stress distributions. The results show that both the mean velocity and the turbulence intensity decrease rapidly below the SWI, indicating strong damping within the porous bed. Above the bed, the flow retains a boundary-layer structure, and increasing $R{e}_K$ enhances the turbulence intensity without changing the overall regime. The results indicate a shift from turbulent transport above the bed to viscous control within the porous layer, while dispersive stresses peak near the interface. Overall, the SWI controls momentum exchange within a thin region and the porous bed suppresses turbulence penetration into the subsurface. Full article

In this work, we propose a bamboo-shaped Mach-Zehnder interferometer coated with chitosan for relative humidity (RH) and temperature measurement. The sensor is fabricated by fusing no-core fiber and multimode fiber segments through arc discharge, followed by tapering with a hydrogen–oxygen flame to form a unique bamboo-shaped configuration. To functionalize the structure for humidity sensing, chitosan is coated onto the fiber surface. The refractive index of chitosan varies with water molecule adsorption, which enhances the spectral response of the sensor to RH. Therefore, the sensitivity response is enhanced after the film coating is applied. Experimental results demonstrate that the proposed sensor achieves the maximum sensitivities to RH and temperature determined at −0.9261 nm/%RH and 0.0952 nm/°C, respectively. The sensor features a compact structure, high sensitivity and the ability to achieve dual-parameter sensing, which supports applications in biomedical, agricultural and electronic manufacturing fields. Full article

We present the development of an infrared sensor based on a meta surface utilizing Dolmen plasmonic nanostructures. This meta surface is engineered to enhance the absorption of infrared light at a specific wavelength. The sensor is optimized for high sensitivity and selectivity in the infrared spectrum. This straightforward meta surface sensor shows promise for various applications, including gas sensing, biosensing, and security. The design is compact and easy to fabricate with studied fabrication tolerance ensuring reliable performance. The sensor was tested for water-based sensing applications, and we tested its performance by using different materials such as ZrN, TiN, Cr, and Au on silicon dioxide. In a separate configuration, a gold nanostructure was fabricated on a silicon layer over a silicon dioxide base to examine the resulting plasmonic response. The results surpass those of other water quality sensors, underscoring the potential of this design for high-performance sensing. The sensor’s high sensitivity and low fabrication costs make it a promising technology for future sensing and monitoring applications. Full article

The primary productivity of phytoplankton (PP_eu) is critical to the carbon cycle in aquatic ecosystems. However, in complex lakes covered by ice, the estimation of PP_eu using remote sensing techniques is constrained. To address this limitation, this study developed an estimation model for ice-covered PP_eu by incorporating optical parameters such as the ice surface refractive index and the extinction coefficient of the ice layer into the vertical generalized production model (VGPM). This approach overcomes the challenges associated with remote sensing-based estimation of PP_eu during ice-covered periods. The results indicate that the annual carbon sequestration of the WLSHL is 1.72 × 10⁴ t C, with an average annual PP_eu of 316.96 mg C·m⁻²·d⁻¹. In addition to the indicators that are directly involved in the estimation of PP_eu, the environmental factors that affect PP_eu include water temperature (WT), ice thickness (IT), snow, water depth (D), total dissolved solids (TDSs), salinity (S), ammonia nitrogen (NH₄⁺-N), nitrate nitrogen (NO₃⁻-N), and oxidation–reduction potential (ORP). The PP_eu in the ice period is found to be only 17% lower than that in the ice-free period. However, the PP_eu during the ice period is considerably higher than that during the ice + snow period. The findings indicate that the impact of freezing on PP_eu during the winter is relatively limited, whereas the influence of snowfall is more pronounced. In order to mitigate the elevated PP_eu and the occurrence of algal blooms during the summer, the intensity of underwater radiation can be regulated on a periodic basis. To optimize the function of the carbon sink in winter lakes, the PP_eu can be enhanced through initiatives such as water replenishment prior to freezing and snow removal following freezing. Full article

Eutectic solvents have become a viable choice to create innovative pharmaceutical technologies within the framework of the green chemistry approach. Despite the growing applicative interest, a general gap remains in the pharmaceutical sector regarding thorough and systematic research of their properties and useful applications. In this work, eutectic solvents have been prepared from choline chloride and polyols (sorbitol, xylitol, mannitol, and isomalt) at different molar ratios (1:1, 2:3, and 3:2), characterised, and used for the solubility enhancement of poorly water-soluble drugs (ibuprofen and naproxen) as well as the potential drug candidate apigenin. The interactions between the eutectic solvent components were investigated by DSC, FTIR, and refractive index methods. In all eutectic solvents, the water content detected by Karl Fischer titration and loss on drying was less than 3%. Solubility studies, carried out using the shake-flask method, showed significant solubility enhancement of the following: ibuprofen: ~152-fold increase, naproxen: ~144-fold increase, and apigenin: ~188-fold increase. These findings highlighted the great potential of eutectic solvents as solubility enhancers in the development of novel and more effective drug delivery systems. Full article

The suppression of residual reflectivity in optical elements has become a hot research topic as it addresses the degradation of optical system imaging quality caused by stray light. Antireflective coatings on the outer surface of window glasses require low reflectivity, high hardness, and resistance to mechanical wear. This study investigates the role of reactive gas stoichiometry in tailoring the structure and performance of ${\mathrm{SiO}}_x$${\mathrm{N}}_y$ antireflection (AR) coatings deposited on GG7i glass via capacitively coupled radio-frequency magnetron sputtering. First, the influence of three ${\mathrm{N}}_2$/${\mathrm{O}}_2$ flow ratios on the optical and mechanical properties of ${\mathrm{SiO}}_x$${\mathrm{N}}_y$ films discussed under identical process parameters. Results show that the refractive index, hardness, and surface roughness of the ${\mathrm{SiO}}_x$${\mathrm{N}}_y$ films increase with increasing ${\mathrm{N}}_2$/${\mathrm{O}}_2$ ratio and that the stress of the ${\mathrm{SiO}}_x$${\mathrm{N}}_y$ films increases according to the Stoney formula. The wear resistance of the ${\mathrm{SiO}}_x$${\mathrm{N}}_y$ films combined with an antifingerprint (AF) coating is tested using steel wool. Experimental results show that the water contact angle of the AF decreases with increasing surface roughness of the film. Finally, on the basis of a comprehensive evaluation of optical and mechanical properties, the antireflection coating on the outer surface of the window glass was prepared by optimizing the process parameters. At $0^{°}$ incidence, the average reflectivity from 420 to 680 nm is <1%, the maximum value is <1.2%, the surface hardness is 17.2 GPa, and the water contact angle is ${100}^{°}$ after the steel wool wear test, showing its suitability for durable antifingerprint applications. This work provides a strategic pathway for designing high-performance optical coatings with tailored mechanical robustness. Full article

The interaction between plasmonic nanoparticles and organic dye molecules plays an important role in varied photonic and optoelectronic applications. In this work, we systematically investigate the optical properties of a water-soluble perylenediimide derivative, N,N′-di(2-(trimethylammonium iodide) ethylene) perylenediimide (TAIPDI), in the presence of different concentrations of silver nanoparticles (AgNPs) under femtosecond (fs) laser excitation. The AgNPs were synthesized via the laser ablation technique. The influence of AgNP concentration on the linear, fluorescence, and nonlinear optical properties of the TAIPDI dye was explored through UV–visible absorption spectroscopy, fluorescence emission measurements, and open- and closed-aperture Z-scan techniques. The Ag NP–TAIPDI dye hybrid systems (Ag@TAIPDI nanocomposites) exhibited pronounced reverse saturable absorption and self-defocusing behavior, indicating a negative nonlinear refractive index. Both the nonlinear absorption coefficient and refractive index increased markedly with rising AgNP concentration, leading to a significant enhancement in the third-order nonlinear susceptibility. Fluorescence studies further revealed a concentration-dependent emission enhancement due to metal-enhanced fluorescence arising from surface plasmon resonance-induced local field amplification. The Ag@TAIPDI nanocomposites also demonstrated strong optical limiting performance, with the limiting threshold decreasing as the AgNP concentration increased. These findings highlight the synergistic role of plasmon–exciton coupling and thermal lensing in enhancing the nonlinear response of such nanocomposites. The results establish AgNPs–TAIPDI dye hybrid systems as promising materials for all-optical switching, optical limiting, and photonic device applications. Full article

Accurate knowledge of seawater optical properties is essential for underwater imaging, sensing, and optical communication, particularly in coastal and shallow-water environments where geometric light propagation effects can influence measurement accuracy. While empirical formulations describing the refractive index of seawater are well established and widely used in the visible spectral range, their applicability in the near-ultraviolet region has received limited experimental validation. In this work, the applicability of an established empirical seawater refractive-index formulation in the near-ultraviolet band is investigated through a combined numerical and experimental approach. First, the empirical model is evaluated numerically to examine its spectral behavior across the visible–near-ultraviolet transition. The results indicate smooth and physically consistent refractive-index variation near the ultraviolet boundary. Second, a controlled laboratory experiment is conducted in which near-ultraviolet beam refraction through stratified seawater is measured using a multi-compartment tank designed to emulate discrete ocean depth intervals. Beam displacement measurements at two near-ultraviolet wavelength bands are compared directly with predictions obtained from a multi-layer ray-tracing simulation based on the empirical formulation. The close agreement between simulated and experimentally measured beam displacement across multiple depth configurations provides physical validation of the empirical refractive-index model in the near-ultraviolet region under the investigated conditions. These findings support the use of established refractive-index formulations for near-ultraviolet underwater optical modeling and contribute to a more reliable foundation for near-UV marine optical sensing and measurement applications. Full article

The aim of this review is to explore the improvement in diffraction efficiency, photosensitivity and pressure sensitivity in holographic materials containing glycerol. Glycerol is a well-known, non-toxic, water-soluble polyol compound. Glycerol polymers have attracted increased attention recently due to the diversity of the available compositions. Glycerol provides access to a range of monomers for subsequent polymerizations. Various glycerol containing polymers, including polyvinyl alcohol films, polyesters, polyethers and polycarbonates, have been investigated for different applications. It was discovered in 2009 that the addition of glycerol to the composition of water-soluble holographic photopolymers facilitates the faster formation of holograms due to greater photosensitivity. It was also discovered that the presence of glycerol in holographic photopolymers makes them highly pressure-sensitive. A new family of holographic photopolymer materials, containing glycerol and capable of recording holograms with bright reflections, was reported. The novel photopolymers are composed of glycerol, a polymeric binder, a crosslinking monomer, an initiation system, and sensitising dyes. No wet-processing of holograms is necessary. Each holographic photopolymer film contains bis-acrylamide (BA) monomer in polyvinyl alcohol matrix, triethanolamine and methylene blue dye solution, glycerol and water. It was shown that the new holographic material is capable of reaching a refractive index modulation matching that of the well-known acrylamide photopolymer material, but more quickly. The new holographic photopolymer materials are cheap and environmentally friendly. The use of glycerol to improve diffraction efficiency, photosensitivity and pressure sensitivity in holographic recording layers continues to expand. This review describes the development and applications of glycerol-containing photopolymer materials. An environmentally friendly diacetone-based photopolymer was developed. The positive effect of glycerol on N-vinylpyrrolidone photopolymer was investigated. Finally, potential opportunities for future research in the area of glycerol-containing photopolymers are outlined. Full article