Search Results (223)

Anion exchange membrane fuel cells (AEMFCs) represent a promising class of clean energy devices, with their performance being critically dependent on the efficiency of the cathode oxygen reduction reaction (ORR) catalyst. Manganese-cobalt spinel (Mn_1.5Co_1.5O₄, MCS) has been demonstrated to be a highly active ORR catalyst. Herein, we report a strategy of incorporating Cu (MCCS) and Fe (MCFS) into MCS to form ternary spinel oxides for tuning ORR activity. Among them, MCS exhibits the best ORR performance, with a half-wave potential (E_1/2) of 0.736 V vs. RHE in 0.1 M KOH and a peak power density (PPD) of 248.3 mW·cm⁻² for the fuel cell test. In contrast, MCCS and MCFS show divergent behaviors in a rotating disk-ring electrode (RRDE) and fuel cell tests. X-ray diffraction (XRD) analyses and X-ray photoelectron spectroscopy (XPS) analyses reveal that the introduction of Cu²⁺ and Fe³⁺ induces a phase transformation in the spinel structure, leading to a reduction in oxygen vacancies and an increase in the valence state of Mn, thereby degrading catalytic activity. However, the incorporation of these elements also modulates the hydration capability of the catalysts, which is critical for the ion and charge transfer in the fuel cell environment and has been validated in the distribution of relaxation time (DRT) analysis of the fuel cell test. This study provides a valuable strategy for designing and synthesizing low-cost, highly efficient, and stable ternary spinel electrocatalysts for AEMFC applications, and bridges the gap between RRDE evaluation and fuel cell testing through DRT analysis. Full article

Accurate estimation of the state of health (SOH) of lithium-ion batteries is essential for the safe and efficient operation of electric vehicles (EVs). Conventional approaches, including Coulomb counting, electrochemical impedance spectroscopy, and equivalent circuit models, provide useful insights but face practical limitations such as error accumulation, high equipment requirements, and limited applicability across different conditions. These challenges have encouraged the use of machine learning (ML) methods, which can model nonlinear relationships and temporal degradation patterns directly from cycling data. This paper reviews four machine learning algorithms that are widely applied in SOH estimation: support vector regression (SVR), random forest (RF), convolutional neural networks (CNNs), and long short-term memory networks (LSTMs). Their methodologies, advantages, limitations, and recent extensions are discussed with reference to the existing literature. To complement the review, MATLAB-based simulations were carried out using the NASA Prognostics Center of Excellence (PCoE) dataset. Training was performed on three cells (B0006, B0007, B0018), and testing was conducted on an unseen cell (B0005) to evaluate cross-battery generalisation. The results show that the LSTM model achieved the highest accuracy (RMSE = 0.0146, MAE = 0.0118, R² = 0.980), followed by CNN and RF, both of which provided acceptable accuracy with errors below 2% SOH. SVR performed less effectively (RMSE = 0.0457, MAPE = 4.80%), reflecting its difficulty in capturing sequential dependencies. These outcomes are consistent with findings in the literature, indicating that deep learning models are better suited for modelling long-term battery degradation, while ensemble approaches such as RF remain competitive when supported by carefully engineered features. This review also identifies ongoing and future research directions, including the use of optimisation algorithms for hyperparameter tuning, transfer learning for adaptation across battery chemistries, and explainable AI to improve interpretability. Overall, LSTM and hybrid models that combine complementary methods (e.g., CNN-LSTM) show strong potential for deployment in battery management systems, where reliable SOH prediction is important for safety, cost reduction, and extending battery lifetime. Full article

Raman spectroscopy is a rapid, label-free, and non-destructive technique for probing molecular structures, making it a powerful tool for clinical pathogen identification. However, interpreting its complex spectral data remains challenging. In this study, we evaluate and compare a suite of machine learning models—including Support Vector Machines (SVM), XGBoost, LightGBM, Random Forests, k-nearest Neighbors (k-NN), Convolutional Neural Networks (CNNs), and fully connected Neural Networks—with and without Principal Component Analysis (PCA) for dimensionality reduction. Using Raman spectral data from 30 clinically important bacterial and fungal species that collectively account for over 90% of human infections in hospital settings, we conducted rigorous hyperparameter tuning and assessed model performance based on accuracy, precision, recall, and F1-score. The SVM with an RBF kernel combined with PCA emerged as the top-performing model, achieving the highest accuracy (0.9454) and F1-score (0.9454). Ensemble methods such as LightGBM and XGBoost also demonstrated strong performance, while CNNs provided competitive results among deep learning approaches. Importantly, interpretability was achieved via SHAP (Shapley Additive exPlanations), which identified class-specific Raman wavenumber regions critical to prediction. These interpretable insights, combined with strong classification performance, underscore the potential of explainable AI-driven Raman analysis to accelerate clinical microbiology diagnostics, optimize antimicrobial therapy, and improve patient outcomes. Full article

The concentration characteristics of SO₂, NO₂, O₃, and CO in the marine atmosphere are of great significance for understanding air–sea interactions and regional atmospheric chemical processes. However, due to the challenging conditions of marine monitoring, long-term continuous observational data remain scarce. To address this gap, this study proposes a Transfer Learning–Convolutional Neural Network (TL-CNN) model that integrates ERA5 meteorological data, EAC4 atmospheric composition reanalysis data, and ground-based observations through multi-source data fusion. During data preprocessing, the Data Interpolating Empirical Orthogonal Function (DINEOF), inverse distance weighting (IDW) spatial interpolation, and Gaussian filtering methods were employed to improve data continuity and consistency. Using ERA5 meteorological variables as inputs and EAC4 pollutant concentrations as training targets, a CNN-based inversion framework was constructed. Results show that the CNN model achieved an average coefficient of determination (R²) exceeding 0.80 on the pretraining test set, significantly outperforming random forest and deep neural networks, particularly in reproducing nearshore gradients and regional spatial distributions. After incorporating transfer learning and fine-tuning with station observations, the model inversion results reached an average R² of 0.72 against site measurements, effectively correcting systematic biases in the reanalysis data. Among the pollutants, the inversion of SO₂ performed relatively poorly, mainly because emission reduction trends from anthropogenic sources were not sufficiently represented in the reanalysis dataset. Overall, the TL-CNN model provides more accurate pollutant concentration fields for offshore regions with limited observations, offering strong support for marine atmospheric environment studies and assessments of marine ecological effects. It also demonstrates the potential of combining deep learning and transfer learning in atmospheric chemistry research. Full article

The power system’s dynamic frequency stability is affected by common-mode ultra-low-frequency oscillation and differential-mode low-frequency oscillation. Traditional frequency control based on generators is facing the problem of capacity reduction. It is urgent to explore new regulation resources such as photovoltaics. To address this issue, this paper proposes a distributed active support method based on photovoltaic systems via state–disturbance observation and dynamic surface consensus control. A three-layer distributed control framework is constructed to suppress low-frequency oscillations and ultra-low-frequency oscillations. To solve the high-order problem of the regional grid model and to obtain its unmeasurable variables, a regional observer estimating both system states and external disturbances is designed. Furthermore, a distributed dynamic frequency stability control method is proposed for wide-area photovoltaic clusters based on the dynamic surface control theory. In addition, the stability of the proposed distributed active support method has been proven. Moreover, a parameter tuning algorithm is proposed based on improved chaos game theory. Finally, simulation results demonstrate that, even under a 0–2.5 s time-varying communication delay, the proposed method can restrict the frequency deviation and the inter-area frequency difference index to 0.17 Hz and 0.014, respectively. Moreover, under weak communication conditions, the controller can also maintain dynamic frequency stability. Compared with centralized control and decentralized control, the proposed method reduces the frequency deviation by 26.1% and 17.1%, respectively, and shortens the settling time by 76.3% and 42.9%, respectively. The proposed method can effectively maintain dynamic frequency stability using photovoltaics, demonstrating excellent application potential in renewable-rich power systems. Full article

Short-term passenger flow prediction provides critical data-driven support for optimizing resource allocation, guiding passenger mobility, and enhancing risk response capabilities in urban rail transit systems. To further improve prediction accuracy, this study proposes a hybrid SMA-VMD-Informer-BiLSTM prediction model. Addressing the challenge of error propagation caused by non-stationary components (e.g., noise and abrupt fluctuations) in conventional passenger flow signals, the Variational Mode Decomposition (VMD) method is introduced to decompose raw flow data into multiple intrinsic mode functions (IMFs). A Slime Mould Algorithm (SMA)-based optimization mechanism is designed to adaptively tune VMD parameters, effectively mitigating mode redundancy and information loss. Furthermore, to circumvent error accumulation inherent in serial modeling frameworks, a parallel prediction architecture is developed: the Informer branch captures long-term dependencies through its ProbSparse self-attention mechanism, while the Bidirectional Long Short-Term Memory (BiLSTM) network extracts localized short-term temporal patterns. The outputs of both branches are fused via a fully connected layer, balancing global trend adherence and local fluctuation characterization. Experimental validation using historical entry flow data from Weihouzhuang Station on Xi’an Metro demonstrated the superior performance of the SMA-VMD-Informer-BiLSTM model. Compared to benchmark models (CNN-BiLSTM, CNN-BiGRU, Transformer-LSTM, ARIMA-LSTM), the proposed model achieved reductions of 7.14–53.33% in $f_{mse}$, 3.81–31.14% in $f_{rmse}$, and 8.87–38.08% in $f_{mae}$, alongside a 4.11–5.48% improvement in $R^2$. Cross-station validation across multiple Xi’an Metro hubs further confirmed robust spatial generalizability, with prediction errors bounded within $f_{mse}$: 0.0009–0.01, $f_{rmse}$: 0.0303–0.1, $f_{mae}$: 0.0196–0.0697, and $R^2$: 0.9011–0.9971. Furthermore, the model demonstrated favorable predictive performance when applied to forecasting passenger inflows at multiple stations in Nanjing and Zhengzhou, showcasing its excellent spatial transferability. By integrating multi-level, multi-scale data processing and adaptive feature extraction mechanisms, the proposed model significantly mitigates error accumulation observed in traditional approaches. These findings collectively indicate its potential as a scientific foundation for refined operational decision-making in urban rail transit management, thereby significantly promoting the sustainable development and long-term stable operation of urban rail transit systems. Full article

Tactical production–distribution planning in paper manufacturing involves hierarchical decision-making under hybrid uncertainty, where aleatory randomness (demand fluctuations, machine variations) and epistemic uncertainty (expert judgments, market trends) simultaneously affect operations. Existing approaches fail to address the bi-level nature under hybrid uncertainty, treating production and distribution decisions independently or using single-paradigm uncertainty models. This research develops a bi-level dependent-chance goal programming framework based on uncertain random theory, where the upper level optimizes distribution decisions while the lower level handles production decisions. The framework exploits structural symmetries through machine interchangeability, symmetric transportation routes, and temporal symmetry, incorporating symmetry-breaking constraints to eliminate redundant solutions. A hybrid intelligent algorithm (HIA) integrates uncertain random simulation with a Reinforcement-Learning-enhanced Arithmetic Optimization Algorithm (RL-AOA) for bi-level coordination, where Q-learning enables adaptive parameter tuning. The RL component utilizes symmetric state representations to maintain solution quality across symmetric transformations. Computational experiments demonstrate HIA’s superiority over standard metaheuristics, achieving 3.2–7.8% solution quality improvement and 18.5% computational time reduction. Symmetry exploitation reduces search space by approximately 35%. The framework provides probability-based performance metrics with optimal confidence levels (0.82–0.87), offering 2.8–4.5% annual cost savings potential. Full article

Wind farms situated in proximity to residential areas present environmental challenges, primarily due to noise emissions. Rectangular and parallelogram layouts are commonly employed in current wind farm designs owing to their simplicity and visual appeal. However, such configurations often experience significant power loss under certain wind directions because of intense wake interactions. This paper proposes a layout fine-tuning strategy for low-noise wind farm design. Within a reinforcement learning framework integrated with an engineering wake model and a noise propagation model, the positions of two turbines (controlled by two variables) are optimized. The noise propagation model was validated for idealized long-range sound propagation over flat terrain with acoustically soft surfaces. A case study was conducted on a 12-turbine wind farm located on a flat plain in China, with a noise threshold of 45 dB(A) used to assess the noise impact area. Optimization results demonstrate that the proposed method achieves a balance between power output and noise reduction compared to the original regular layout: Annual Energy Production (AEP) increased slightly by 0.16%, while the noise impact area was reduced by 6.0%. Although these improvements appear modest, the potential of the proposed methodology warrants further investigation. Full article

Bacterial cellulose (BC) is a high-purity biopolymer with excellent physicochemical and mechanical properties, including high crystallinity, water absorption, biocompatibility, and structural tunability. However, its large-scale production is hindered by high substrate costs and limited sustainability. In this study, spent black tea waste was utilized as a low-cost and eco-friendly carbon source for BC synthesis by Komagataeibacter xylinus ATCC 53524 under varying initial pH conditions (4–9). Six different BC membranes were produced and systematically characterized in terms of mechanical strength, water absorption capacity, electrical conductivity, antimicrobial performance, and polyvinyl alcohol (PVA) attachment efficiency. Morphological and chemical analyses were conducted using SEM and FTIR techniques to investigate pH-induced structural variations. The results revealed that the BC6 sample (pH 6) exhibited the highest tensile strength (2.4 MPa), elongation (13%), PVA incorporation (12%), and electrical conductivity, confirming the positive impact of near-neutral conditions on nanofiber assembly and functional integration. In contrast, the BC4 sample (pH 4) demonstrated strong antimicrobial activity (log reduction = 3.5) against E. coli, suggesting that acidic pH conditions enhance bioactivity. SEM images confirmed the most cohesive and uniform fiber morphology at pH 6, while FTIR spectra indicated the preservation of characteristic cellulose functional groups across all samples. Overall, this study presents a sustainable and efficient strategy for BC production using food waste and demonstrates that synthesis pH is a key parameter in tuning its functional performance. The optimized BC membranes show potential for biomedical, flexible electronic, and antibacterial material applications, particularly in wearable electrode technologies. Full article

This work presents the results of a research study focused on the development and evaluation of an algorithmic optimal control framework for energy-efficient operation of screw compressors in smart power systems. The proposed approach is based on the Pontryagin maximum principle (PMP), which enables the synthesis of a mathematically grounded regulator that minimizes the total energy consumption of a nonlinear electromechanical system composed of a screw compressor and a variable-frequency induction motor. Unlike conventional PID controllers, the developed algorithm explicitly incorporates system constraints, nonlinear dynamics, and performance trade-offs into the control law, allowing for improved adaptability and energy-aware operation. Simulation results obtained using MATLAB/Simulink confirm that the PMP-based regulator outperforms classical PID solutions in both transient and steady-state regimes. Experimental tests conducted in accordance with standard energy consumption evaluation methods showed that the proposed PMP-based controller provides a reduction in specific energy consumption of up to 18% under dynamic load conditions compared to a well-tuned basic PID controller, while maintaining high control accuracy, faster settling, and complete suppression of overshoot under external disturbances. The control system demonstrates robustness to parametric uncertainty and load variability, maintaining a statistical pressure error below 0.2%. The regulator’s structure is compatible with real-time execution on industrial programmable logic controllers (PLCs), supporting integration into intelligent automation systems and smart grid infrastructures. The discrete-time PLC implementation of the regulator requires only 10³ arithmetic operations per cycle and less than 10² kB of RAM for state, buffers, and logging, making it suitable for mid-range industrial controllers under 2–10 ms task cycles. Fault-tolerance is ensured via range and rate-of-change checks, residual-based plausibility tests, and safe fallbacks (baseline PID or torque-limited speed hold) in case of sensor faults. Furthermore, the proposed approach lays the groundwork for hybrid extensions combining model-based control with AI-driven optimization and learning mechanisms, including reinforcement learning, surrogate modeling, and digital twins. These enhancements open pathways toward predictive, self-adaptive compressor control with embedded energy optimization. The research outcomes contribute to the broader field of algorithmic control in power electronics, offering a scalable and analytically justified alternative to heuristic and empirical tuning approaches commonly used in industry. The results highlight the potential of advanced control algorithms to enhance the efficiency, stability, and intelligence of energy-intensive components within the context of Industry 4.0 and sustainable energy systems. Full article

With the increasing penetration of renewable energy in power systems, the multi-objective optimal scheduling of microgrids has become increasingly complex. Traditional optimization methods face limitations when addressing high-dimensional, nonlinear, and multi-constrained models. This study proposes a multi-objective optimal scheduling method for microgrids based on the Tuned Dung Beetle Optimization (TDBO) algorithm, aiming to simultaneously minimize operational and environmental costs while satisfying a variety of physical and engineering constraints. The proposed TDBO algorithm integrates multiple strategic mechanisms—including task allocation, spiral search, Lévy flight, opposition-based learning, and Gaussian perturbation—to significantly enhance global exploration and local exploitation capabilities. On the modeling side, a high-dimensional decision-making model is developed, encompassing photovoltaic systems, wind turbines, diesel generators, gas turbines, energy storage systems, and grid interaction. A dual-objective scheduling framework is constructed, incorporating operational economics, environmental sustainability, and physical constraints of the equipment. Simulation experiments conducted under typical scenarios demonstrate that TDBO outperforms both the improved particle swarm optimization (IPSO) and the original DBO in terms of solution quality, convergence speed, and result stability. Simulation results demonstrate that, compared with benchmark algorithms, the proposed TDBO achieves a 2.24–6.18% reduction in average total cost, improves convergence speed by 27.3%, and decreases solution standard deviation by 18.8–23.5%. These quantitative results highlight the superior optimization accuracy, efficiency, and robustness of TDBO in multi-objective microgrid scheduling. The results confirm that the proposed method can effectively improve renewable energy utilization and reduce system operating costs and carbon emissions, and holds significant theoretical value and engineering application potential. Full article

Dengue fever is a mosquito-borne viral disease that annually affects 100–400 million people worldwide. Early detection of dengue enables easy treatment planning and helps reduce mortality rates. This study proposes three Swarm-based Metaheuristic Algorithms, Golden Jackal Optimization, Fox Optimizer, and Sea Lion Optimization, for feature selection and hyperparameter tuning, and an Extreme Gradient Boost classifier to forecast dengue fever using the Predictive Clinical Dengue dataset. Several existing models have been proposed for dengue fever classification, with some achieving high predictive performance. However, most of these studies have overlooked the importance of feature reduction, which is crucial to building efficient and interpretable models. Furthermore, prior research has lacked in-depth analysis of model behavior, particularly regarding the underlying causes of misclassification. Addressing these limitations, this study achieved a 10-fold cross-validation mean accuracy of 99.89%, an F-score of 99.92%, a precision of 99.84%, and a perfect recall of 100% by using only two features: WBC Count and Platelet Count. Notably, FOX-XGBoost and SLO-XGBoost achieved the same performance while utilizing only four and three features, respectively, demonstrating the effectiveness of feature reduction without compromising accuracy. Among these, GJO-XGBoost demonstrated the most efficient feature utilization while maintaining superior performance, emphasizing its potential for practical deployment in dengue fever diagnosis. SHAP analysis identified WBC Count as the most influential feature driving model predictions. Furthermore, DiCE explanations support this finding by showing that lower WBC Counts are associated with dengue-positive cases, whereas higher WBC Counts are indicative of dengue-negative individuals. SHAP interpreted the reasons behind misclassifications, while DiCE provided a correction mechanism by suggesting the minimal changes needed to convert incorrect predictions into correct ones. Full article

This study investigates the feasibility of using wearable technology and machine learning algorithms to predict academic performance based on physiological signals. It also examines the correlation between stress levels, reflected in the collected physiological data, and academic outcomes. To this aim, six key physiological signals, including skin conductance, heart rate, skin temperature, electrodermal activity, blood volume pulse, inter-beat interval, and accelerometer were recorded during three examination sessions using a wearable device. A novel pipeline, comprising data preprocessing and feature engineering, is proposed to prepare the collected data for training machine learning algorithms. We evaluated five machine learning models, including Random Forest, Support Vector Machine (SVM), eXtreme Gradient Boosting (XGBoost), Categorical Boosted (CatBoost), and Gradient-Boosting Machine (GBM), to predict the exam outcomes. The Synthetic Minority Oversampling Technique (SMOTE), followed by hyperparameter tuning and dimensionality reduction, are implemented to optimise model performance and address issues like class imbalance and overfitting. The results obtained by our study demonstrate that physiological signals can effectively predict stress and its impact on academic performance, offering potential for real-time monitoring systems that support student well-being and academic success. Full article

This research introduces a synergistic photoelectrocatalytic (PEC) system designed for the effective degradation of tetracycline (TC), integrating a PO₄³⁻-grafted Mo-doped BiVO₄ (PO₄³⁻-Mo:BiVO₄) photoanode with a Pd-loaded ordered mesoporous carbon (Pd/CMK-3) cathode. The incorporation of Mo doping and PO₄³⁻ modification significantly improved the photoanode’s charge separation efficiency, achieving a photocurrent density of 2.9 mA cm⁻², and fine-tuned its band structure to enhance hydroxyl radical (·OH) generation. Meanwhile, the Pd/CMK-3 cathode promoted a two-electron oxygen reduction reaction pathway, producing hydrogen peroxide (H₂O₂) and facilitating molecular oxygen activation via atomic hydrogen (H*) intermediates. Under optimized conditions—1.0 V vs. Ag/AgCl of anodic potential, pH 6.58, and oxygen saturation—the combined system accomplished 80% TC degradation within 60 min, markedly surpassing the performance of the photoanode (72%) or cathode (71%) alone. Notably, this synergistic approach also reduced energy consumption to 0.0065 kWh m⁻³, outperforming individual components. Radical quenching experiments and liquid chromatography–mass spectrometry (LC-MS) analysis revealed that the photogenerated holes (h⁺) and ·OH were the key reactive species responsible for TC mineralization. The system demonstrated remarkable stability, with only a 2.96% decline in activity, and effectively degraded other contaminants, such as phenol, 4-chlorophenol, and ciprofloxacin. This study highlights an energy-efficient PEC strategy that harnesses the combined strengths of anodic oxidation and cathodic molecular oxygen activation to significantly enhance the removal of organic pollutants. Full article

Unmanned Aerial Vehicles (UAVs) integrated with lightweight deep learning models represent an effective solution for image-based rapid post-earthquake damage assessment. UAVs, equipped with cameras, capture high-resolution aerial imagery of disaster-stricken areas, providing essential data for evaluating structural damage. When paired with light eight Convolutional Neural Network (CNN) models, these UAVs can process the captured images onboard, enabling real-time, accurate damage level predictions that might with potential interest to orient efficiently the efforts of the Search and Rescue (SAR) teams. This study investigates the use of the MobileNetV3-Small lightweight CNN model for real-time post-earthquake damage level prediction using UAV-captured imagery. The model is trained to classify three levels of post-earthquake damage, ranging from no damage to severe damage. Experimental results show that the adapted MobileNetV3-Small model achieves the lowest FLOPs, with a significant reduction of 58.8% compared to the ShuffleNetv2 model. Fine-tuning the last five layers resulted in a slight increase of approximately 0.2% in FLOPs, but significantly improved accuracy and robustness, yielding a 4.5% performance boost over the baseline. The model achieved a weighted average F-score of 0.93 on a merged dataset composed of three post-earthquake damage level datasets. It was successfully deployed and tested on a Raspberry Pi 5, demonstrating its feasibility for edge-device applications. This deployment highlighted the model’s efficiency and real-time performance in resource-constrained environments. Full article